KR900006284A - 이미도-유도 과산화산 - Google Patents

이미도-유도 과산화산 Download PDF

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KR900006284A
KR900006284A KR1019890015292A KR890015292A KR900006284A KR 900006284 A KR900006284 A KR 900006284A KR 1019890015292 A KR1019890015292 A KR 1019890015292A KR 890015292 A KR890015292 A KR 890015292A KR 900006284 A KR900006284 A KR 900006284A
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acid
imido
essentially
hexahydrophthalimido
succinimido
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KR1019890015292A
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KR0140220B1 (ko
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벤투렐로 카를로
카발로티 클라우디오
벤시니 엘레나
안토니에타 사소 마리아
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오틸리오 마세롤리
오시몬트 에스.알.엘
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/32—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D207/325—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with substituted hydrocarbon radicals directly attached to the ring nitrogen atom
    • C07D207/327—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/34—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D207/36—Oxygen or sulfur atoms
    • C07D207/40—2,5-Pyrrolidine-diones
    • C07D207/404—2,5-Pyrrolidine-diones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms, e.g. succinimide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/44—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members
    • C07D207/444—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members having two doubly-bound oxygen atoms directly attached in positions 2 and 5
    • C07D207/448—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members having two doubly-bound oxygen atoms directly attached in positions 2 and 5 with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms, e.g. maleimide
    • C07D207/452—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members having two doubly-bound oxygen atoms directly attached in positions 2 and 5 with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms, e.g. maleimide with hydrocarbon radicals, substituted by hetero atoms, directly attached to the ring nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/44—Iso-indoles; Hydrogenated iso-indoles
    • C07D209/48—Iso-indoles; Hydrogenated iso-indoles with oxygen atoms in positions 1 and 3, e.g. phthalimide

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Indole Compounds (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Pyrrole Compounds (AREA)

Abstract

내용 없음

Description

이미도-유도 과산화산
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (19)

  1. 하기 일반식(I)의 이미도 유도 퍼옥시카르복실산
    [식중 ; R 및 R1은 서로 동일 또는 상이할 수 있으며, 수소원자, 알킬기를 나타내거나 또는 그것이 결합된 탄소원자와 함께 지방족 고리를 형성하며 ; 이들 모두는 제조조건에 불활성인 기에 의해 임의로 치환될 수 있으며 ; 기호는 단일 또는 올레핀 결합을 의미하며 ; R2는 수소원자, 알킬기, OH기를 나타내고, n은 0 이 아닌 정수이다.]
  2. 제 1 항에 있어서, 식중, R 및 R1은 서로 동일 또는 상이할 수 있으며, 수소원자 또는 1 내지 12개의 탄소원자를 함유하는 선형 또는 분지형 알킬기를 나타내며 ; R2는 수소원자 또는 1 내지 5개의 탄소원자를 함유하는 선형 또는 분지형 알킬기 또는 OH기를 나타내고 n은 1 내지 10의 정수를 나타내는 일반식(I)의 이미도-유도 퍼옥시카르복실산.
  3. 제 1 항 또는 제 2 항에 있어서, 식중, R1및 R2는 그것이 결합된 탄소원자와 함께 4 내지 12개의 탄소원자, 바람직하게는 5 내지 6개의 탄소원자를 함유하는 지방족 고리를 형성하는 선형 또는 분지형 알킬기를 나타내는 일반식(I)의 이미도-유도 퍼옥시카르복실산.
  4. 제 1 항 내지 제 3 항중 어느 한 항에 있어서, 식중, R, R1및 (CHR1)n기는 F,Cl, OH기, NO2, C1~C5알콕시기로 이루어진 군으로부터 선택된 서로 동일 또는 상이할 수 있는 적어도 하나의 치환체에 의해 치환될 수 있는 일반식(I)의 이미도-유도 퍼옥시카르복실산.
  5. 본질적으로 신규 화합물인 4-숙신이미도-퍼부티르산.
  6. 본질적으로 신규 화합물인 3-숙신이미도-퍼프로피온산.
  7. 본질적으로 신규 화합물인 숙신이미도-퍼아세트산.
  8. 본질적으로 신규 화합물인 4-헥사히드로프탈이미도-퍼부티르산.
  9. 본질적으로 신규 화합물인 3-헥사히드로프탈이미도-퍼프로피온산.
  10. 본질적으로 신규 화합물인 2-헥사히드로프탈이미도-3-메틸-퍼부티르산.
  11. 본질적으로 신규 화합물인 2-헥사히드로프탈이미도-퍼프로피온산.
  12. 본질적으로 신규 화합물인 4-(3,4,5,6-테트라히드로프탈이미도)퍼부티르산.
  13. 일반식(I)의 목적하는 퍼옥시카르복실산에 상응하는 이미도-유도 카르복실산으로부터 선택된 기질을 진한 H2SO4및 CH2SO3H로부터 선택된 매질내에서 진한 H2O2와 반응 시킨후, 반응 혼합물로부터 퍼옥시카르복실산(I)을 공지된 방법에 따라 분리시킴을 특징으로 하는 청구범위 제 1 항에서 정의된 일반식(I)의 이미도-유도 퍼옥시카르복실산의 제조방법.
  14. 제 13항에 있어서, 기질은 4-숙신이미도 부티르산, 3-숙신이미도 프로피온산, 숙신 이미도 아세트산, 4-헥사히드로프탈이미도 부티르산, 3-헥사히드로프탈이미도 프로피온산, 2-헥사히드로프탈이미도-3-메틸-부티르산, 2-헥사히드로프탈이미도 프로피온산, 4-(3,4,5,6-테트라히드로프탈이미도) 부티르산중에서 선택됨을 특징으로 하는 제조방법.
  15. 제 13항 또는 제 14항에 있어서, 이미도-유도 카르복실산 기질을 약 70 내지 90 중량%범위의 농도를 가진 H2O2와 0 내지 약 15℃의 온도범위에서 진한 H2SO4또는 CH2SO3H내에서 서서히 반응시킴을 특징으로 하는 제조방법.
  16. 제 13 항 내지 제 15항중 어느 한 항에 있어서, H2SO4또는 CH2SO3H의 양은 기질 1몰당 적어도 3몰, 바람직하게는 약 3 내지 20몰의 범위내임을 특징으로 하는 제조방법.
  17. 제 13항 내지 제 16항중 어느 한 항에 있어서, 과산화수소를 기질 1몰당 적어도 1.2몰, 바람직하게는 약 1.5 내지 6몰의 범위내로 사용함을 특징으로 하는 제조방법.
  18. 제 13항 내지 제 17항중 어느 한 항에 있어서, 반응 완료시 존재하는 총 H2O에 대한 H2SO4또는 CH2SO3H의 최종 몰비가 적어도 1.0, 바람직하게는 약 1.2 내지 5 임을 특징으로 하는 제조방법.
  19. 다른 성분 및/또는 첨가제, 빌더, 계면 활성제, 비누, 제올라이트, 용해도증대제, 부식 방지제, 효소, 형광 표백제, 안정제 및 기타 과산화화합물을 함유하는 세제 배합물에 있어 표백제로서의 일반식(I)의 이미도-유도 퍼옥시카르복실산의 용도.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890015292A 1988-10-24 1989-10-24 이미도-유도 과산화산 KR0140220B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT8822402A IT1230595B (it) 1988-10-24 1988-10-24 Perossiacidi immido derivati
IT22402A/88 1988-10-24

Publications (2)

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KR900006284A true KR900006284A (ko) 1990-05-07
KR0140220B1 KR0140220B1 (ko) 1998-06-01

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KR1019890015292A KR0140220B1 (ko) 1988-10-24 1989-10-24 이미도-유도 과산화산

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US (1) US5536434A (ko)
EP (1) EP0366041B2 (ko)
JP (1) JP2915020B2 (ko)
KR (1) KR0140220B1 (ko)
AT (1) ATE169289T1 (ko)
AU (1) AU619607B2 (ko)
BR (1) BR8905400A (ko)
CA (1) CA2001184A1 (ko)
DE (1) DE68928767T3 (ko)
IT (1) IT1230595B (ko)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1215739B (it) * 1988-01-20 1990-02-22 Ausimont Spa Perossiacidi immido aromatici come agenti sbiancanti.
EP0484095B1 (en) * 1990-11-02 1996-03-20 The Clorox Company Liquid nonaqueous detergent with stable, solublized peracid
GB9105959D0 (en) * 1991-03-21 1991-05-08 Unilever Plc Cationic peroxyacids and bleach compositions comprising said peroxyacids
US5985815A (en) * 1993-11-25 1999-11-16 Warwick International Group Limited Bleach activators
GB9501737D0 (en) * 1994-04-25 1995-03-22 Hoffmann La Roche Hydroxamic acid derivatives
JP2001316361A (ja) * 2000-05-01 2001-11-13 Ethyl Corp スクシンイミド−酸化合物およびそれの誘導体
ITMI20021537A1 (it) * 2002-07-12 2004-01-12 Ausimont Spa Acidi immidoalcanpercarbossilici
ITMI20040497A1 (it) * 2004-03-16 2004-06-16 Solvay Solexis Spa Procedimento di diluizione
CA2691442C (en) * 2007-06-29 2014-01-21 Gilead Sciences, Inc. Antiviral compounds

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1793378C3 (de) * 1968-09-09 1978-12-07 Basf Ag, 6700 Ludwigshafen N-Acyl-a-aminopercarbonsäuretert-butylester
IT1233846B (it) * 1988-01-20 1992-04-21 Ausimont Spa Perossiacidi immido aromatici
DE3823172C2 (de) * 1988-07-08 1998-01-22 Hoechst Ag omega-Phthalimidoperoxihexansäure, Verfahren zu dessen Herstellung und dessen Verwendung
GB8830234D0 (en) * 1988-12-24 1989-02-22 Interox Chemicals Ltd Peroxycarboxylic acids
DE3906768A1 (de) * 1989-03-03 1990-09-06 Henkel Kgaa Peroxycarbonsaeuren und deren verwendung

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Publication number Publication date
JPH02243671A (ja) 1990-09-27
KR0140220B1 (ko) 1998-06-01
EP0366041B1 (en) 1998-08-05
IT1230595B (it) 1991-10-28
DE68928767T3 (de) 2002-05-08
ATE169289T1 (de) 1998-08-15
IT8822402A0 (it) 1988-10-24
DE68928767T2 (de) 1999-04-15
US5536434A (en) 1996-07-16
JP2915020B2 (ja) 1999-07-05
CA2001184A1 (en) 1990-04-24
AU619607B2 (en) 1992-01-30
DE68928767D1 (de) 1998-09-10
BR8905400A (pt) 1990-05-22
EP0366041A3 (en) 1991-10-23
EP0366041B2 (en) 2001-09-12
EP0366041A2 (en) 1990-05-02
AU4364089A (en) 1990-04-26

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