KR900006284A - Imido-induced peroxide - Google Patents

Imido-induced peroxide Download PDF

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KR900006284A
KR900006284A KR1019890015292A KR890015292A KR900006284A KR 900006284 A KR900006284 A KR 900006284A KR 1019890015292 A KR1019890015292 A KR 1019890015292A KR 890015292 A KR890015292 A KR 890015292A KR 900006284 A KR900006284 A KR 900006284A
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acid
imido
essentially
hexahydrophthalimido
succinimido
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KR0140220B1 (en
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벤투렐로 카를로
카발로티 클라우디오
벤시니 엘레나
안토니에타 사소 마리아
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오틸리오 마세롤리
오시몬트 에스.알.엘
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/32—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D207/325—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with substituted hydrocarbon radicals directly attached to the ring nitrogen atom
    • C07D207/327—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/34—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D207/36—Oxygen or sulfur atoms
    • C07D207/40—2,5-Pyrrolidine-diones
    • C07D207/404—2,5-Pyrrolidine-diones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms, e.g. succinimide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/44—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members
    • C07D207/444—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members having two doubly-bound oxygen atoms directly attached in positions 2 and 5
    • C07D207/448—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members having two doubly-bound oxygen atoms directly attached in positions 2 and 5 with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms, e.g. maleimide
    • C07D207/452—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members having two doubly-bound oxygen atoms directly attached in positions 2 and 5 with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms, e.g. maleimide with hydrocarbon radicals, substituted by hetero atoms, directly attached to the ring nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/44—Iso-indoles; Hydrogenated iso-indoles
    • C07D209/48—Iso-indoles; Hydrogenated iso-indoles with oxygen atoms in positions 1 and 3, e.g. phthalimide

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Indole Compounds (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Pyrrole Compounds (AREA)

Abstract

내용 없음No content

Description

이미도-유도 과산화산Imido-induced peroxide

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (19)

하기 일반식(I)의 이미도 유도 퍼옥시카르복실산Imido-induced peroxycarboxylic acid of the general formula (I) [식중 ; R 및 R1은 서로 동일 또는 상이할 수 있으며, 수소원자, 알킬기를 나타내거나 또는 그것이 결합된 탄소원자와 함께 지방족 고리를 형성하며 ; 이들 모두는 제조조건에 불활성인 기에 의해 임의로 치환될 수 있으며 ; 기호는 단일 또는 올레핀 결합을 의미하며 ; R2는 수소원자, 알킬기, OH기를 나타내고, n은 0 이 아닌 정수이다.]In the formula; R and R 1 may be the same or different from each other and represent a hydrogen atom, an alkyl group or together with the carbon atom to which they are attached form an aliphatic ring; All of these may be optionally substituted by groups which are inert to the production conditions; Symbol means a single or olefin bond; R 2 represents a hydrogen atom, an alkyl group, or an OH group, n is an integer other than 0.] 제 1 항에 있어서, 식중, R 및 R1은 서로 동일 또는 상이할 수 있으며, 수소원자 또는 1 내지 12개의 탄소원자를 함유하는 선형 또는 분지형 알킬기를 나타내며 ; R2는 수소원자 또는 1 내지 5개의 탄소원자를 함유하는 선형 또는 분지형 알킬기 또는 OH기를 나타내고 n은 1 내지 10의 정수를 나타내는 일반식(I)의 이미도-유도 퍼옥시카르복실산.The compound of claim 1, wherein R and R 1 may be the same or different from each other, and represent a linear or branched alkyl group containing a hydrogen atom or 1 to 12 carbon atoms; R 2 represents a hydrogen atom or a linear or branched alkyl group containing 1 to 5 carbon atoms or an OH group and n represents an imido-derived peroxycarboxylic acid of general formula (I) representing an integer of 1 to 10. 제 1 항 또는 제 2 항에 있어서, 식중, R1및 R2는 그것이 결합된 탄소원자와 함께 4 내지 12개의 탄소원자, 바람직하게는 5 내지 6개의 탄소원자를 함유하는 지방족 고리를 형성하는 선형 또는 분지형 알킬기를 나타내는 일반식(I)의 이미도-유도 퍼옥시카르복실산.3. The linear or as claimed in claim 1 , wherein R 1 and R 2 form an aliphatic ring containing 4 to 12 carbon atoms, preferably 5 to 6 carbon atoms, together with the carbon atoms to which they are attached. Imido-derived peroxycarboxylic acid of general formula (I) which represents a branched alkyl group. 제 1 항 내지 제 3 항중 어느 한 항에 있어서, 식중, R, R1및 (CHR1)n기는 F,Cl, OH기, NO2, C1~C5알콕시기로 이루어진 군으로부터 선택된 서로 동일 또는 상이할 수 있는 적어도 하나의 치환체에 의해 치환될 수 있는 일반식(I)의 이미도-유도 퍼옥시카르복실산.4. The compound of claim 1, wherein R, R 1 and (CHR 1 ) n groups are the same as each other selected from the group consisting of F, Cl, OH groups, NO 2 , C 1 to C 5 alkoxy groups Imido-derived peroxycarboxylic acids of general formula (I) which may be substituted by at least one substituent which may be different. 본질적으로 신규 화합물인 4-숙신이미도-퍼부티르산.4-succinimido-perbutyric acid which is essentially a novel compound. 본질적으로 신규 화합물인 3-숙신이미도-퍼프로피온산.3-succinimido-perpropionic acid which is essentially a new compound. 본질적으로 신규 화합물인 숙신이미도-퍼아세트산.Succinimido-peracetic acid, which is essentially a new compound. 본질적으로 신규 화합물인 4-헥사히드로프탈이미도-퍼부티르산.4-hexahydrophthalimido-perbutyric acid which is essentially a novel compound. 본질적으로 신규 화합물인 3-헥사히드로프탈이미도-퍼프로피온산.3-hexahydrophthalimido-perpropionic acid which is essentially a new compound. 본질적으로 신규 화합물인 2-헥사히드로프탈이미도-3-메틸-퍼부티르산.2-hexahydrophthalimido-3-methyl-perbutyric acid which is essentially a novel compound. 본질적으로 신규 화합물인 2-헥사히드로프탈이미도-퍼프로피온산.2-hexahydrophthalimido-perpropionic acid which is essentially a new compound. 본질적으로 신규 화합물인 4-(3,4,5,6-테트라히드로프탈이미도)퍼부티르산.4- (3,4,5,6-tetrahydrophthalimido) perbutyric acid which is essentially a novel compound. 일반식(I)의 목적하는 퍼옥시카르복실산에 상응하는 이미도-유도 카르복실산으로부터 선택된 기질을 진한 H2SO4및 CH2SO3H로부터 선택된 매질내에서 진한 H2O2와 반응 시킨후, 반응 혼합물로부터 퍼옥시카르복실산(I)을 공지된 방법에 따라 분리시킴을 특징으로 하는 청구범위 제 1 항에서 정의된 일반식(I)의 이미도-유도 퍼옥시카르복실산의 제조방법.Reaction of a substrate selected from imido-derived carboxylic acids corresponding to the desired peroxycarboxylic acid of general formula (I) with concentrated H 2 O 2 in a medium selected from concentrated H 2 SO 4 and CH 2 SO 3 H Of the imido-derived peroxycarboxylic acid of formula (I) as defined in claim 1, characterized in that the peroxycarboxylic acid (I) is separated from the reaction mixture according to a known method. Manufacturing method. 제 13항에 있어서, 기질은 4-숙신이미도 부티르산, 3-숙신이미도 프로피온산, 숙신 이미도 아세트산, 4-헥사히드로프탈이미도 부티르산, 3-헥사히드로프탈이미도 프로피온산, 2-헥사히드로프탈이미도-3-메틸-부티르산, 2-헥사히드로프탈이미도 프로피온산, 4-(3,4,5,6-테트라히드로프탈이미도) 부티르산중에서 선택됨을 특징으로 하는 제조방법.The method of claim 13, wherein the substrate is 4-succinimido butyric acid, 3-succinimido propionic acid, succinimido acetic acid, 4-hexahydrophthalimido butyric acid, 3-hexahydrophthalimido propionic acid, 2-hexahydrophthal A method according to claim 1, wherein the method is selected from imido-3-methyl-butyric acid, 2-hexahydrophthalimido propionic acid, 4- (3,4,5,6-tetrahydrophthalimido) butyric acid. 제 13항 또는 제 14항에 있어서, 이미도-유도 카르복실산 기질을 약 70 내지 90 중량%범위의 농도를 가진 H2O2와 0 내지 약 15℃의 온도범위에서 진한 H2SO4또는 CH2SO3H내에서 서서히 반응시킴을 특징으로 하는 제조방법.15. The method according to claim 13 or 14, wherein the imido-derived carboxylic acid substrate is H 2 O 2 having a concentration ranging from about 70 to 90% by weight and concentrated H 2 SO 4 or at a temperature ranging from 0 to about 15 ° C. A process characterized by the slow reaction in CH 2 SO 3 H. 제 13 항 내지 제 15항중 어느 한 항에 있어서, H2SO4또는 CH2SO3H의 양은 기질 1몰당 적어도 3몰, 바람직하게는 약 3 내지 20몰의 범위내임을 특징으로 하는 제조방법.The process according to claim 13, wherein the amount of H 2 SO 4 or CH 2 SO 3 H is in the range of at least 3 moles, preferably about 3 to 20 moles per mole of the substrate. 제 13항 내지 제 16항중 어느 한 항에 있어서, 과산화수소를 기질 1몰당 적어도 1.2몰, 바람직하게는 약 1.5 내지 6몰의 범위내로 사용함을 특징으로 하는 제조방법.17. A process according to any one of claims 13 to 16, wherein hydrogen peroxide is used in the range of at least 1.2 moles, preferably about 1.5 to 6 moles per mole of substrate. 제 13항 내지 제 17항중 어느 한 항에 있어서, 반응 완료시 존재하는 총 H2O에 대한 H2SO4또는 CH2SO3H의 최종 몰비가 적어도 1.0, 바람직하게는 약 1.2 내지 5 임을 특징으로 하는 제조방법.18. The process according to claim 13, wherein the final molar ratio of H 2 SO 4 or CH 2 SO 3 H to the total H 2 O present upon completion of the reaction is at least 1.0, preferably about 1.2 to 5. 18. The manufacturing method to make. 다른 성분 및/또는 첨가제, 빌더, 계면 활성제, 비누, 제올라이트, 용해도증대제, 부식 방지제, 효소, 형광 표백제, 안정제 및 기타 과산화화합물을 함유하는 세제 배합물에 있어 표백제로서의 일반식(I)의 이미도-유도 퍼옥시카르복실산의 용도.Immunity of Formula (I) as a bleach in detergent formulations containing other ingredients and / or additives, builders, surfactants, soaps, zeolites, solubility enhancers, corrosion inhibitors, enzymes, fluorescent bleaches, stabilizers and other peroxide compounds The use of induced peroxycarboxylic acids. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019890015292A 1988-10-24 1989-10-24 Imido-percarboxylic acids KR0140220B1 (en)

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IT22402A/88 1988-10-24
IT8822402A IT1230595B (en) 1988-10-24 1988-10-24 IMMEDIATE PEROXYCID DERIVATIVES

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IT1215739B (en) * 1988-01-20 1990-02-22 Ausimont Spa IMMIDO AROMATIC PEROXYCIDES AS WHITENING AGENTS.
ES2084783T3 (en) * 1990-11-02 1996-05-16 Clorox Co NON-AQUEOUS LIQUID DETERGENT WITH STABLE SOLUBILIZED PERACITY.
GB9105959D0 (en) * 1991-03-21 1991-05-08 Unilever Plc Cationic peroxyacids and bleach compositions comprising said peroxyacids
EP0730632B1 (en) * 1993-11-25 1998-03-18 Warwick International Group Limited Bleach activators
GB9501737D0 (en) * 1994-04-25 1995-03-22 Hoffmann La Roche Hydroxamic acid derivatives
JP2001316361A (en) * 2000-05-01 2001-11-13 Ethyl Corp Succinimide acid compound and its derivative
ITMI20021537A1 (en) * 2002-07-12 2004-01-12 Ausimont Spa IMMIDOALCANPERCARBOXYLIC ACIDS
ITMI20040497A1 (en) * 2004-03-16 2004-06-16 Solvay Solexis Spa DILUTION PROCEDURE
EA019749B1 (en) * 2007-06-29 2014-06-30 Джилид Сайэнс, Инк. Antiviral compounds

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DE1793378C3 (en) * 1968-09-09 1978-12-07 Basf Ag, 6700 Ludwigshafen N-acyl-a-aminopercarboxylic acid tert-butyl ester
IT1233846B (en) * 1988-01-20 1992-04-21 Ausimont Spa IMMEDIATE AROMATIC PEROXIDES
DE3823172C2 (en) * 1988-07-08 1998-01-22 Hoechst Ag Omega-phthalimidoperoxihexanoic acid, process for its preparation and its use
GB8830234D0 (en) * 1988-12-24 1989-02-22 Interox Chemicals Ltd Peroxycarboxylic acids
DE3906768A1 (en) * 1989-03-03 1990-09-06 Henkel Kgaa Peroxycarboxylic acids and their use

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EP0366041B2 (en) 2001-09-12
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IT1230595B (en) 1991-10-28
US5536434A (en) 1996-07-16
BR8905400A (en) 1990-05-22
DE68928767D1 (en) 1998-09-10
JPH02243671A (en) 1990-09-27
JP2915020B2 (en) 1999-07-05
AU619607B2 (en) 1992-01-30
EP0366041B1 (en) 1998-08-05
EP0366041A2 (en) 1990-05-02
EP0366041A3 (en) 1991-10-23
DE68928767T3 (en) 2002-05-08
AU4364089A (en) 1990-04-26
CA2001184A1 (en) 1990-04-24
ATE169289T1 (en) 1998-08-15
IT8822402A0 (en) 1988-10-24

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