KR900004703A - 치환된 트리아진 - Google Patents

치환된 트리아진 Download PDF

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Publication number
KR900004703A
KR900004703A KR1019890013423A KR890013423A KR900004703A KR 900004703 A KR900004703 A KR 900004703A KR 1019890013423 A KR1019890013423 A KR 1019890013423A KR 890013423 A KR890013423 A KR 890013423A KR 900004703 A KR900004703 A KR 900004703A
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KR
South Korea
Prior art keywords
alkyl
compound
phenylenediamino
hydrogen
triazine
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KR1019890013423A
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English (en)
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KR970005534B1 (ko
Inventor
엘.윌러 에드워드
에취 바로우 프랭클린
제이.프랭코 로버트
Original Assignee
아이.제이.크라코워
유니로얄 케미칼 컴페니 인코퍼레이티드
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Publication of KR900004703A publication Critical patent/KR900004703A/ko
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Publication of KR970005534B1 publication Critical patent/KR970005534B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/14—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom
    • C07D251/16—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom to only one ring carbon atom
    • C07D251/18—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom to only one ring carbon atom with nitrogen atoms directly attached to the two other ring carbon atoms, e.g. guanamines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
    • C07D251/40—Nitrogen atoms
    • C07D251/42—One nitrogen atom
    • C07D251/46—One nitrogen atom with oxygen or sulfur atoms attached to the two other ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
    • C07D251/40—Nitrogen atoms
    • C07D251/54—Three nitrogen atoms
    • C07D251/70—Other substituted melamines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

내용없음.

Description

치환된 트리아진
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (19)

  1. 하기 일반식(Ⅰ)의 화합물 :
    R1은 수소, C1-C11직쇄 또는 가지쇄 알킬, C3-C6시클로알킬 페닐 또는 C1-C4알킬로 치환된 페닐; R2는 C1-C11알킬, C3-C6시클로알킬 또는
    R2는 --R7(R3가 수소일 때); R3는 수소, 페닐 또는 C1-C11직쇄 도는 가지쇄 알킬; R4는 수소 또는 C1-C8직쇄 또는 가지쇄 알킬; R5는 수소 또는 C1-C8직쇄 또는 가지쇄 알킬; R6는 C1-C8직쇄 도는 가지쇄 알킬 또는 C1-C12알콕시, R1이 C1-C11직쇄 또는 알킬일 때 수소 또는 R1이 수소일 때 C1-C8직쇄 또는 가지쇄 알킬; R7은 C1-C12직쇄 또는 가지쇄 알킬; Y는 X, 수소, C1-C4알킬, -SH, SR8, -OH, OR8,
    R8은 C1-C12직쇄 또는 가지쇄 알킬, R9은 C1-C5직쇄 또는 가지쇄 알킬, R10은 C1-C5직쇄 또는 가지쇄 알킬, R11은 수소, C3-C16직쇄 또는 가지쇄 알킬,
    Z는 X 또는 Y또는
    또는
    A는 C2-C10직쇄 알킬렌, C5-C10시클로알킬렌, 페닐 또는 C7-C9아릴알킬렌; R12은 수소 또는 C3-C11알킬; Y가 X와 동일하지 않을 때는, R6는 수소일 수 있다.
    Z가 Y와 동일한 때는, Y는 -SR8, -OH,, -O-C6H5가 되지 않을 수도 있다.
  2. 제1항에 있어서, 상기 X, Y 및 Z가 동일 라디칼인 화합물.
  3. 제2항에 있어서, R1, R3, R4및 R5는 수소이고 R2은 C3-C18가지쇄 알킬 라디칼로부터 선택되는 화합물.
  4. 제3항에 있어서, R2는 C6-C82차 알킬 라디칼인 화합물.
  5. 제1항에 있어서, R2또는 R3라디칼이 질소에 대하여 알파 위치에 2차 탄소원자를 갖고 있는 화합물.
  6. 제3항에 있어서, R2가 1,4-디메틸펜틸 라디칼인 화합물.
  7. R2알킬 라디칼인 C3-C18가지쇄 또는 직쇄 알킬, 또는 C3-C12시클로알킬 또는 하나 이상의 C3-C12알킬 라디칼인 C1-C12시클로알킬로부터 선택되는 2,4,6-트리스(N-알킬-p-페닐렌디아미노)-1,3,5-트리아진 화합물.
  8. 제7항에 있어서, R2알킬이 1,4-디메틸펜틸; 이소프로필; 시클로헥실; sec-부틸; 1,3-디메틸부틸; 1-메틸헵틸; 2,4-디-t-부틸시클로헥실; 2-sec-부틸시클로헥실; 및 1-메틸데실로 구성되어 있는 군으로부터 선택되는 화합물.
  9. 제7항에 있어서, R2알킬이 2,6-디메틸-4-헵틸인 호합물.
  10. 제7항에 있어서, 상기 화합물이 2,4,6-트리스(N-1,4-디메틸펜틸-p-페닐렌디아미노)-1,3,5-트리아진인 화합물
  11. 제7항에 있어서, 상기 화합물이 2,4,6-트리스(N-1,3-디메틸부틸-p-페닐렌디아미노)-1,3,5-트리아진인 화합물.
  12. 제7항에 있어서, 상기 화합물이 2,4,5-트리스(N-1-메틸헵틸-p-페닐렌디아미노)-1,3,5-트리아진인 화합물.
  13. 제7항에 있어서, 상기 화합물이 2,4,5-트리스(N-sec-부틸-p-페닐렌디아미노)-1,3,5-트리아진인 화합물.
  14. 제1항에 있어서, X와 Y는 동일하고 Z는 상이하며, 상기 화합물이 1,6-비스(2-이미노-4,6-비스(N-페닐-p-페닐렌디아미노)-1,3,5-트리아지노)헥산; 1,6-비스-(2-이미노-4,6-비스(N-페닐-p-페닐렌디아미노)-1,3,5-트리아지노)헥산; 및 N,N'-비스(4,6-디메틸펜틸-p-페닐렌디아미노)-1,3,5-트리아지닐-2)페닐렌디아민으로부터 선택되는 화합물.
  15. 제1항에 있어서, Y와 Z는 동일하고 X는 상이한 화합물.
  16. 제15항에 있어서, 상기화합물이 2-(N-1,4-디메틸펜틸-p-페닐렌디아미노)-4,6-비스메르캅토-1,3,5-트리아진인 화합물.
  17. 제5항에 있어서, 상기 화합물이 2,4,6-트리스(N-1,4-디메틸펜틸-2-에틸-p-페닐렌디아미노)-1,3,5-트리아진; 2,4,6-트리스(N-이소프로필-2-에틸-p-페닐렌디아미노)-1,3,5-트리아진; 2,4,6-트리스(N-이소프로필-2-메틸-p-페닐렌디아미노)-1,3,5-트리아진 또는 2,4,6-트리스(N-1,4-디메틸펜틸-2,5-디메틸-p-페닐렌디아미노)1,3,5-트리아진으로부터 선택되는 화합물.
  18. 불포화 폴리마와 상기 불포화 폴리마내에 첨가된 내봉궤제로 유효한 양의 제1항의 화합물을 포함하는 내봉궤성 조성물.
  19. 제1항의 화합물을 함유하고 있는 타이어.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890013423A 1988-09-21 1989-09-19 치환된 트리아진 KR970005534B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/247,219 US4972010A (en) 1988-09-21 1988-09-21 Substituted triazines
US247,219 1988-09-21

Publications (2)

Publication Number Publication Date
KR900004703A true KR900004703A (ko) 1990-04-12
KR970005534B1 KR970005534B1 (ko) 1997-04-17

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US (1) US4972010A (ko)
EP (1) EP0365127B1 (ko)
JP (1) JP2625213B2 (ko)
KR (1) KR970005534B1 (ko)
AT (1) ATE176229T1 (ko)
AU (1) AU625210B2 (ko)
BR (1) BR8904680A (ko)
CA (1) CA1340224C (ko)
DE (1) DE68928919T2 (ko)
ES (1) ES2126548T3 (ko)
ZA (1) ZA896606B (ko)

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JP2022078359A (ja) * 2019-01-25 2022-05-25 日本ゼオン株式会社 アクリルゴム組成物およびゴム架橋物
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Also Published As

Publication number Publication date
ES2126548T3 (es) 1999-04-01
KR970005534B1 (ko) 1997-04-17
DE68928919D1 (de) 1999-03-11
DE68928919T2 (de) 1999-07-29
EP0365127A1 (en) 1990-04-25
CA1340224C (en) 1998-12-15
ZA896606B (en) 1990-06-27
JP2625213B2 (ja) 1997-07-02
US4972010A (en) 1990-11-20
AU4150989A (en) 1990-03-29
BR8904680A (pt) 1990-05-01
AU625210B2 (en) 1992-07-02
EP0365127B1 (en) 1999-01-27
ATE176229T1 (de) 1999-02-15
JPH02134371A (ja) 1990-05-23

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