KR900000327A - 3(4), 8(9)-비스(아미노메틸)트리시클로(5.2.1.0^2,6)데칸의 제조방법 - Google Patents

3(4), 8(9)-비스(아미노메틸)트리시클로(5.2.1.0^2,6)데칸의 제조방법 Download PDF

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Publication number
KR900000327A
KR900000327A KR1019890007191A KR890007191A KR900000327A KR 900000327 A KR900000327 A KR 900000327A KR 1019890007191 A KR1019890007191 A KR 1019890007191A KR 890007191 A KR890007191 A KR 890007191A KR 900000327 A KR900000327 A KR 900000327A
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South Korea
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process according
dicyclopentadiene
moles
tricyclo
decane
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KR1019890007191A
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KR920001988B1 (ko
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루카스 라이너
마티오이 클라우스
퇴네센 프란쯔
뎀프케스 게오르크
뷜헬름 바흐 한스
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라이첼르
훽스트 악티엔 게젤샤프트 베르크 루흐르 헤미에
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
    • C07C211/16—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of a saturated carbon skeleton containing rings other than six-membered aromatic rings
    • C07C211/19—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of a saturated carbon skeleton containing rings other than six-membered aromatic rings containing condensed ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/24—Preparation of compounds containing amino groups bound to a carbon skeleton by reductive alkylation of ammonia, amines or compounds having groups reducible to amino groups, with carbonyl compounds
    • C07C209/26—Preparation of compounds containing amino groups bound to a carbon skeleton by reductive alkylation of ammonia, amines or compounds having groups reducible to amino groups, with carbonyl compounds by reduction with hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/56—Ring systems containing bridged rings
    • C07C2603/58—Ring systems containing bridged rings containing three rings
    • C07C2603/60—Ring systems containing bridged rings containing three rings containing at least one ring with less than six members
    • C07C2603/66—Ring systems containing bridged rings containing three rings containing at least one ring with less than six members containing five-membered rings
    • C07C2603/68—Dicyclopentadienes; Hydrogenated dicyclopentadienes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Cephalosporin Compounds (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)

Abstract

내용 없음

Description

3(4), 8(9)-비스(아미노메틸)트리시클로(5.2.1.02,6)데칸의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 디시클로펜타디엔을 로튬 촉매의 존재하에 히드로포르밀화 반응시키고, 수득된 트리시클로데칸 디알데히드를 연속하여 환원적 아민화시키는 3(4),8(9)-비스(아미노메틸)트리시클로(5.2.1.02,6)데칸의 제조 방법에 있어서, 히드로포르밀화 반응 생성물을, 미리 조작 처리함에 없이, 특히 로륨 촉매를 분리함이 없이, 그리고 경우에 따라서는 제1급 아민과 반응 후에 환원적 아민화시킴을 특징으로 하는 3(4),8(9)-비스(아미노메틸)트리시클로(5.2.1.02,6)데칸의 제조방법.
  2. 제1항에 있어서, 디시클로펜타디엔의 히드로포르밀화 반응이 용매의 존재 또는 비존재 하에 100-200℃의 온도 및 20-30MPa의 입력에서 발생함을 특징으로 하는 방법.
  3. 제1 또는 2항에 있어서, 로튬을 20-100mg/Kg 디시클로펜타디엔 바람직하게는 20-50mg/Kg 디시클로펜타디엔의 농도를 사용함을 특징으로 하는 방법.
  4. 제1 내지 3항중 어느 한 항에 있어서, 히드로포르밀화 반응생성물에 함유된 트리시클로데칸 디알데히드메 1몰당 1차 아민 2-6몰, 특별화하게는 3-4몰을 사용함을 특징으로 하는 방법.
  5. 제1내지 4항중 어느 한 항에 있어서, 1차 아민이 분자 중에 2-10, 특별하게는 3-6 탄소 원자를 함유함을 특징으로 하는 방법.
  6. 제1내지 5항중 어느 한 항에 있어서, 트리시클로데칸 디알레히드와 아민의 반응이 20-60, 특별하게는 30-50℃에서 일어남을 특징으로 하는 방법.
  7. 제1내지 6항중 어느 한 항에 있어서, 트리시클로데칸 디알데히드의 환원적 아민화 반응을 80-150℃, 바람직하게는 120-140℃의 및 5-12 특별하게는 8-12MPa의 압력에서 수행함을 특징으로 하는 방법.
  8. 제1내지 7항중 어느 한 항에 있어서, 환원적 아민화 반응에서 포르밀기 또는 디아조메틴기 매 1몰당 적어도 2몰, 바람직하게는 4-5몰의 암모니아를 사용함을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890007191A 1988-06-30 1989-05-29 3(4),8(9)-비스(아미노메틸)트리시클로(5.2.1.0^2,6)데칸의 제조방법 KR920001988B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE3822038A DE3822038A1 (de) 1988-06-30 1988-06-30 Verfahren zur herstellung von 3(4),8(9)-bis-(aminomethyl)-tricyclo (5.2.1.0(pfeil hoch)2(pfeil hoch)(pfeil hoch),(pfeil hoch)(pfeil hoch)6(pfeil hoch))-decan
DE3822038,5 1988-06-30
DEP3822038.5 1988-06-30

Publications (2)

Publication Number Publication Date
KR900000327A true KR900000327A (ko) 1990-01-30
KR920001988B1 KR920001988B1 (ko) 1992-03-09

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ID=6357591

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Application Number Title Priority Date Filing Date
KR1019890007191A KR920001988B1 (ko) 1988-06-30 1989-05-29 3(4),8(9)-비스(아미노메틸)트리시클로(5.2.1.0^2,6)데칸의 제조방법

Country Status (10)

Country Link
US (1) US5041675A (ko)
EP (1) EP0348832B1 (ko)
JP (1) JPH0662513B2 (ko)
KR (1) KR920001988B1 (ko)
AT (1) ATE79860T1 (ko)
AU (1) AU610002B2 (ko)
CA (1) CA1321796C (ko)
DE (2) DE3822038A1 (ko)
ES (1) ES2043966T3 (ko)
HU (1) HU202476B (ko)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10352260B3 (de) 2003-11-08 2005-04-14 Celanese Chemicals Europe Gmbh Verfahren zur Herstellung von TCD-Alkohol DM
DE10352261B4 (de) * 2003-11-08 2006-08-24 Celanese Chemicals Europe Gmbh Verfahren zur Herstellung von TCD-Dialdehyd
DE10352258B4 (de) * 2003-11-08 2013-06-13 Oxea Gmbh Verfahren zur Herstellung von TCD-Diamin
DE10357718A1 (de) 2003-12-09 2005-07-21 Basf Ag Verfahren zur Herstellung von Tricyclodecandialdehyd
US7684147B2 (en) * 2003-12-15 2010-03-23 Univ Bar Ilan Magnetoelectronic devices based on colossal magnetoresistive thin films
JP5237800B2 (ja) * 2005-06-30 2013-07-17 ダウ グローバル テクノロジーズ エルエルシー 大環状ポリイミン（ｍａｃｒｏｃｙｃｌｉｃｐｏｌｙｉｍｉｎｅｓ）中間体の形成を介した、アルデヒドおよびケトンの還元性アミノ化方法
DE102006004324A1 (de) * 2006-01-31 2007-08-09 Oxea Deutschland Gmbh 3(4),7(8)-Bis(aminomethyl)-bicyclo[4.3.0]nonan und ein Verfahren zu seiner Herstellung
DE102006004319A1 (de) * 2006-01-31 2007-08-09 Oxea Deutschland Gmbh Bicyclo[4.3.0]nonan-3(4),7(8)-dicarbonsäure und ein Verfahren zu ihrer Herstellung
DE102006025813A1 (de) * 2006-06-02 2007-12-06 Oxea Deutschland Gmbh 3(4)-Aminomethyl-8(9)-hydroxy-tricyclo[5.2.1.02,6]decan und ein Verfahren zu seiner Herstellung
CA2672677C (en) * 2006-12-15 2012-07-10 Dow Global Technologies Inc. Process for the reductive amination of aldehydes and ketones
DE102007053385A1 (de) 2007-11-09 2009-05-20 Oxea Deutschland Gmbh Verfahren zur Herstellung von Aldehyden
WO2011014787A2 (en) 2009-07-31 2011-02-03 Dow Global Technologies Inc. Process for reductive amination of aliphatic cyanoaldehydes to aliphatic diamines
WO2011014747A2 (en) 2009-07-31 2011-02-03 Dow Global Technologies Inc. Cycloaliphatic diamines and method of making the same
JP5829623B2 (ja) 2009-07-31 2015-12-09 ダウ グローバル テクノロジーズ エルエルシー 脂肪族シアノアルデヒド類を脂肪族ジアミン類へ還元的アミノ化するための触媒系の触媒活性を改良するための方法
DE102012016433A1 (de) * 2012-08-17 2014-05-15 Oxea Gmbh Kontinuierliches Verfahren zur Herstellung primärer aliphatischer Amine aus Aldehyden
US10899726B2 (en) 2014-07-10 2021-01-26 Rhodia Operations Process for producing aromatic primary diamines
TW201710276A (zh) 2015-07-02 2017-03-16 烏明克股份有限兩合公司 ２－乙基己酸銠（ｉｉｉ）之製備

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1257782B (de) * 1965-02-17 1968-01-04 Basf Ag Verfahren zur Herstellung von Aminen
FR1525149A (fr) * 1967-03-08 1968-05-17 Melle Usines Sa Procédé de fabrication d'amines primaires
US3597438A (en) * 1968-05-06 1971-08-03 Du Pont Reductive amination of aldehydes with rhodium catalysts
GB1170226A (en) * 1968-07-18 1969-11-12 Juergen Falbe Tricyclodecane Dialdehydes and Dimethylols.
US4229376A (en) * 1979-09-10 1980-10-21 Henkel Corporation Polycyclic polyamines
US4317932A (en) * 1980-02-22 1982-03-02 W. R. Grace & Co. Preparation of secondary amines

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Publication number Publication date
DE58902135D1 (de) 1992-10-01
EP0348832A2 (de) 1990-01-03
CA1321796C (en) 1993-08-31
AU610002B2 (en) 1991-05-09
JPH0662513B2 (ja) 1994-08-17
HU202476B (en) 1991-03-28
EP0348832B1 (de) 1992-08-26
ES2043966T3 (es) 1994-01-01
HUT51231A (en) 1990-04-28
US5041675A (en) 1991-08-20
DE3822038A1 (de) 1990-03-01
EP0348832A3 (en) 1990-05-23
ATE79860T1 (de) 1992-09-15
JPH0248556A (ja) 1990-02-19
KR920001988B1 (ko) 1992-03-09
AU3716889A (en) 1990-01-04

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