KR890700562A - 활성화 올레핀성 케톤 및 알데히드의 가수분해 방법 - Google Patents

활성화 올레핀성 케톤 및 알데히드의 가수분해 방법

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Publication number
KR890700562A
KR890700562A KR1019880701226A KR880701226A KR890700562A KR 890700562 A KR890700562 A KR 890700562A KR 1019880701226 A KR1019880701226 A KR 1019880701226A KR 880701226 A KR880701226 A KR 880701226A KR 890700562 A KR890700562 A KR 890700562A
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KR
South Korea
Prior art keywords
produce
carbonyl
containing compound
hydrolyzed
activated olefin
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Application number
KR1019880701226A
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English (en)
Other versions
KR960001702B1 (ko
Inventor
이.돌피니 조셉
글린카 제롬
Original Assignee
원본미기재
멜린크로트, 인코포레이티드
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Priority claimed from US07/010,902 external-priority patent/US4709098A/en
Application filed by 원본미기재, 멜린크로트, 인코포레이티드 filed Critical 원본미기재
Publication of KR890700562A publication Critical patent/KR890700562A/ko
Application granted granted Critical
Publication of KR960001702B1 publication Critical patent/KR960001702B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/42—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by hydrolysis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/54—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of compounds containing doubly bound oxygen atoms, e.g. esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/06—Formation or introduction of functional groups containing oxygen of carbonyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/673—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Fats And Perfumes (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음.

Description

활성화 올레핀성 케톤 및 알데히드의 가수분해 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (18)

  1. 물의 존재하, 실질적으로 중심 pH에서 가수분해 반응을 수행하기에 충분한 대기압이상의 압력에서 가열에 의해 다음 화학방정식이 아사이클릭 올레핀의 반응을 수행하여 카보닐-함유 화합물을 생성시킴을 특징으로하는 카보닐-함유 화합물을 생성하기 위한 활성화 올레핀의 가수분해 방법.
    상기식에서, R, R′ 및 R 수소, 알킬, 사이클로알킬 또는 아릴 탄화수소 그룹 또는 이의 치환된 유도체이고, 올레핀 중의 A는 상기 올레핀과 공액된 알데히드 또는 케톤의 부류로부터 선택된 라디칼이며, R″ 또한 A일 수도 있다.
  2. 제1항에 있어서, 온도가 적어도 약 200℃이고 압력이 적어도 약 225psi인 방법.
  3. 제1항에 있어서, 온도가 약 200℃ 내지 약 325℃정도이고 압력이 약 225 내지 약 2000psi정도인 방법.
  4. 제1항에 있어서, 반응을 오토클레이브 또는 다른 압력 반응기 내에서 수행하는 방법.
  5. 제1항에 있어서, 가수분해 반응을 튜브 반응기 내에서 연속적으로 수행하는 방법.
  6. 제1항에 있어서, 물의 용적이 활성화 올레핀의 용적을 초과하는 방법.
  7. 제1항에 있어서, 활성화 올레핀 신남알데히드를 가수분해하여 카보닐-함유 화합물인 벤즈알데히드를 생성시키는 방법.
  8. 제1항에 있어서, 활성화 올레핀 시트랄을 가수분해하여 카보닐-함유 화합물인 6-메틸-5-헵텐-2-온을 생성시키는 방법.
  9. 제1항에 있어서, 활성화 올레핀 1, 2-디벤조일에티렌을 가수분해하여 카보닐-함유 화합물인 아세토페논을 생성시키는 방법.
  10. 제1항에 있어서, 활성화 올레핀 4-페닐-3-부텐-2-온을 가수분해하여 카보닐-함유 화합물인 벤즈알데히드를 생성시키는 방법.
  11. 제1항에 있어서, 활성화 올레핀 3-데켄-2-온을 가수분해하여 카보닐-함유 화합물인 헵탄알을 생성시키는 방법.
  12. 제1항에 있어서, 활성화 올레핀 쿠르쿠민을 가수분해하여 카보닐-함유 화합물인 바닐린을 생성시키는 방법.
  13. 제1항에 있어서, 활성화 올레핀 2, 4-데카디엔알을 가수분해하여 카보닐-함유 화합물인 헥산알을 생성시키는 방법.
  14. 제1항에 있어서, 활성화 올레핀 신남알데히드를 가수분해하여 카보닐-함유 화합물인 벤즈알데히드를 생성시키는 방법.
  15. 제1항에 있어서, 활성화 올레핀 시트랄을 가수분해하여 카보닐-함유 화합물인 6-메틸-5-헵텐-2-온을 생성시키는 방법.
  16. 쿠르쿠민을 가수분해하여 방향 성분을 생성시키는 방법.
  17. 제16항에 있어서, 쿠르쿠민을 가수분해하여 바닐린을 생성시키는 방법.
  18. 제1항 내지 제17항중 어느 한 항에 따라 제조된 생성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880701226A 1987-02-04 1988-02-01 활성화 올레핀성 케톤 및 알데히드의 가수분해 방법 KR960001702B1 (ko)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US?010,902? 1987-02-04
US07/010,902 US4709098A (en) 1987-02-04 1987-02-04 Hydrolysis of activated olefinic ketones and aldehydes
US010,902 1987-02-04
US123,137 1987-11-20
US?123,137? 1987-11-20
US07/123,137 US4810824A (en) 1987-02-04 1987-11-20 Hydrolysis of activated olefinic ketones and aldehydes
PCT/US1988/000420 WO1988005771A1 (en) 1987-02-04 1988-02-01 Hydrolysis of activated olefinic ketones and aldehydes

Publications (2)

Publication Number Publication Date
KR890700562A true KR890700562A (ko) 1989-04-25
KR960001702B1 KR960001702B1 (ko) 1996-02-03

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ID=26681734

Family Applications (1)

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KR1019880701226A KR960001702B1 (ko) 1987-02-04 1988-02-01 활성화 올레핀성 케톤 및 알데히드의 가수분해 방법

Country Status (14)

Country Link
US (1) US4810824A (ko)
EP (2) EP0606934B1 (ko)
JP (2) JP2630334B2 (ko)
KR (1) KR960001702B1 (ko)
CN (1) CN1018179B (ko)
AT (2) ATE111433T1 (ko)
AU (1) AU1363588A (ko)
CA (1) CA1333489C (ko)
DE (2) DE3851528T2 (ko)
ES (1) ES2006072A6 (ko)
GR (1) GR880100035A (ko)
MY (1) MY103053A (ko)
NZ (1) NZ223388A (ko)
WO (1) WO1988005771A1 (ko)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4871881A (en) * 1987-02-04 1989-10-03 Mallinckrodt, Inc. Hydrolysis of activated olefinic ketones and aldehydes
US5426118A (en) * 1993-12-30 1995-06-20 Allergan, Inc. [4-(1,2-epoxycyclohexanyl)but-3-en-1-ynyl]aromatic and heteroaromatic acids and derivatives having retinoid-like biological activity
US6048560A (en) * 1995-01-25 2000-04-11 Quest International B.V. Process for the preparation of a flavoring component
EP2334629B1 (de) * 2008-08-29 2016-08-10 Basf Se Verfahren zur herstellung von zyklischen ketonen
RS57403B2 (sr) 2013-10-23 2023-04-28 Arla Foods Amba Visoko proteinske kombinacije denaturisanog proteina surutke sa sadržajem kazeinmakropeptida, proizvodi koji ih sadrže, i njihove upotrebe
EA033333B1 (ru) 2013-10-23 2019-09-30 Арла Фудс Амба Высокобелковый ароматизированный фруктами напиток, высокобелковый фруктовый и овощной препарат, а также связанные с ними способы и пищевые продукты
EP3060065A1 (en) 2013-10-23 2016-08-31 Arla Foods amba High protein denatured whey protein composition, related products, method of production and uses thereof

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1999620A (en) * 1929-05-23 1935-04-30 Shell Dev Process for the manufacture of alcohols
US2623905A (en) * 1950-08-23 1952-12-30 Universal Oil Prod Co Production of aliphatic aldehydes
DE875512C (de) * 1951-04-01 1953-05-04 Bayer Ag Verfahren zur Spaltung von ungesaettigten Ketonen
DE927688C (de) * 1953-01-23 1955-05-16 Basf Ag Verfahren zur Herstellung von Cyclohexanon
DE946443C (de) * 1953-02-24 1956-08-02 Bayer Ag Verfahren zur Spaltung von ungesaettigten Ketonen
US3833659A (en) * 1969-12-08 1974-09-03 Universal Oil Prod Co Preparation of oxygen-containing compounds
GB1519093A (en) * 1976-03-04 1978-07-26 Rhone Poulenc Ind Process for preparing methyl heptenone
US4617419A (en) * 1985-09-26 1986-10-14 International Flavors & Fragrances Inc. Process for preparing natural benzaldehyde and acetaldehyde, natural benzaldehyde and acetaldehyde compositions, products produced thereby and organoleptic utilities therefor
US4709098A (en) * 1987-02-04 1987-11-24 Mallinckrodt, Inc. Hydrolysis of activated olefinic ketones and aldehydes

Also Published As

Publication number Publication date
AU1363588A (en) 1988-08-24
GR880100035A (el) 1988-12-16
DE3851528T2 (de) 1995-02-16
ATE111433T1 (de) 1994-09-15
NZ223388A (en) 1991-01-29
JPH0912503A (ja) 1997-01-14
EP0606934A1 (en) 1994-07-20
CN1018179B (zh) 1992-09-09
US4810824A (en) 1989-03-07
EP0346383B1 (en) 1994-09-14
WO1988005771A1 (en) 1988-08-11
CN88100615A (zh) 1988-08-17
DE3856006T2 (de) 1997-12-11
ATE157076T1 (de) 1997-09-15
CA1333489C (en) 1994-12-13
KR960001702B1 (ko) 1996-02-03
DE3856006D1 (de) 1997-09-25
DE3851528D1 (de) 1994-10-20
MY103053A (en) 1993-04-30
JP2667141B2 (ja) 1997-10-27
ES2006072A6 (es) 1989-04-01
EP0606934B1 (en) 1997-08-20
EP0346383A1 (en) 1989-12-20
JP2630334B2 (ja) 1997-07-16
JPS63301841A (ja) 1988-12-08

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