KR890017278A - 광개시제 공중합체 - Google Patents

광개시제 공중합체 Download PDF

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KR890017278A
KR890017278A KR1019890006412A KR890006412A KR890017278A KR 890017278 A KR890017278 A KR 890017278A KR 1019890006412 A KR1019890006412 A KR 1019890006412A KR 890006412 A KR890006412 A KR 890006412A KR 890017278 A KR890017278 A KR 890017278A
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South Korea
Prior art keywords
alkyl
photoinitiator
alkoxy
phenyl
copolymer
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KR1019890006412A
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KR0141602B1 (ko
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쾨흘러 만프레드
도르쉬 디터
은게마하
그래버 게르하르트
Original Assignee
원본미기재
메르크 파텐트 게젤샤프트 미트 베슈랭크터 하프퉁
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F216/14—Monomers containing only one unsaturated aliphatic radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/30—Esters containing oxygen in addition to the carboxy oxygen containing aromatic rings in the alcohol moiety
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F228/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F230/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F246/00—Copolymers in which the nature of only the monomers in minority is defined
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
    • G03F7/031—Organic compounds not covered by group G03F7/029
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G03F7/032—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders
    • G03F7/033—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders the binders being polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Physics & Mathematics (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Paints Or Removers (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

내용 없음

Description

광개시제 공중합체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 일반식(I)일반식(Ⅱ)의 적어도 두개의 상이한 단량체단위를 (I)/(Ⅱ)의 비율이 1내지 100이 되게 공중합시켜서 얻은 분자량 500내지 1,000,000을 가지는 광개시제 공중합체.
    여기서, Ra와 Rb는 상호 독립적으로 각각, H,Cl,CN,C1-6-알킬 또는 페닐이고, X는 CO-,COO-,O-,CO-,(CH2)nY,COO(CH2)nY,CO(OCH2CH|2)nY이고, 여기서 n=1 내지 10 그리고 Y는 단일결합, -O-,-S-,-CO-,-COO-,-OCO-,NH- 또는 -N(C1-6알킬)-이고, IN은 기본 광개시제 구조의 하나로
    또는이고, 여기서 R은 -CR3R4R5또는
    이고, R1은 R2는 H, 할로겐, C1-12알킬 또는 C1-12알콕시이고, R3과 R4는 상호 독립적으로 각각 H, C1-12알킬 또는 C1-12알케닐, C1-12알콕시 또는 함께 C2-6알킬렌이고, R5는 -OH, C1-6알콕시, C1-6알카노일옥시, -N(C1-6알킬)|2,, -SO2R7또는 -OSO2R7이고 R6은 C1-6알킬, C1-6알카노일, 페닐 또는 벤조일이고 각 경우에 임의적으로 할로겐, C1-6알킬 또는 C1-6알콕시로 치환되고 R7은 C1-6알킬 또는 페닐이고, A는 상술한 기본광개시제 구조 IN의 하나 또는 H, C1-12알킬, C1-12알케닐, 페닐, 스티릴, 할로겐, NCO, NCS, N3, SO3H, SO2Cl, CRc=CRdRe또는이고, 여기서, Rc,Rd및 Re는 각각 H 또는 CH3이고, 또 SiRfRgRh이고, 여기서, Rf,Rg및 Rh는 각각 염소, C1-12알킬, C1-12알콕시 또는 C1-12알카노일옥시이다.
  2. 에틸렌성 불포화 화합물 또는 이러한 화합물은 함유하는 계의 광중합반응용 광개시제로 사용되는 제1항에 의한 공중합체로서의 용도.
  3. 적어도 제1항에 의한 광개시제 공중합체 하나를 중합할 혼합물에 가하는 것을 특징으로 하는 에틸렌성 불포화 화합물을 함유하는 공중합성 계의 제조방법.
  4. 제3항에 있어서, 제1항의 광개시제 공중합체 0.1 내지 20중량%를 중합하는 혼합물에 가하는 것을 특징으로 하는 제조방법.
  5. 적어도 제1항에 의한 광개시제 공중합체 하나를 함유하는 것을 특징으로 하는 적어도 하나의 에틸렌성 불포화, 광중합성 화합물 및 필요시, 다른 공지 또는 통상의 첨가제를 함유하는 광중합성 계.
  6. 제1항에 의한 공중합체를 광개시제와 막형성 성분으로서 방사선 경화계에서동시에 사용하는 방사선 경화제.
  7. 실질적으로 제1항에 의한 공중합체 하나 또는 그이상으로 되는 방사선 경화제.
  8. 제5항 또는 제7항에 의한 계를 사용함을 특징으로 하는 기질을 공중합성 계로 피복하고 파장 250∼600nm의 UV광선으로 조사하여 경화가 되는 기질상에 방사선 경화된 피막의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890006412A 1988-05-13 1989-05-13 광개시제 공중합체 KR0141602B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP3816304.7 1988-05-13
DE3816304A DE3816304A1 (de) 1988-05-13 1988-05-13 Fotoinitiator-copolymere

Publications (2)

Publication Number Publication Date
KR890017278A true KR890017278A (ko) 1989-12-15
KR0141602B1 KR0141602B1 (ko) 1998-07-01

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ID=6354278

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EP (1) EP0341560B1 (ko)
JP (1) JP2769628B2 (ko)
KR (1) KR0141602B1 (ko)
AU (1) AU627177B2 (ko)
CA (1) CA1336091C (ko)
DD (1) DD283825A5 (ko)
DE (2) DE3816304A1 (ko)
FI (1) FI892302A (ko)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4302123A1 (de) * 1993-01-27 1994-07-28 Herberts Gmbh Verfahren zum Bedrucken von Glashohlkörpern
GB9522683D0 (en) 1995-11-06 1996-01-10 Coates Brothers Plc Photoinitiator
AU4743696A (en) * 1995-12-29 1997-07-28 Minnesota Mining And Manufacturing Company Use of pendant photoreactive moieties on polymer precursors to prepare hydrophilic pressure sensitive adhesives
JPH1017635A (ja) * 1996-07-08 1998-01-20 Japan Synthetic Rubber Co Ltd 注型重合用放射線硬化性樹脂組成物
US6025408A (en) * 1997-03-27 2000-02-15 First Chemical Corporation Liquid thioxanthone photoinitiators
US6458864B1 (en) 1998-05-29 2002-10-01 Ciba Specialty Chemicals Corporation Photoinitiators having chain transfer groups polymerized to obtain macrophotoinitiators useful to give block copolymers
KR20070042503A (ko) * 2004-04-21 2007-04-23 앳슈랜드 라이센싱 앤드 인텔렉츄얼 프라퍼티 엘엘씨 내장 광개시제를 갖는 복사-경화성 마이클 부가 수지
JP5441574B2 (ja) * 2009-09-08 2014-03-12 富士フイルム株式会社 水性インク組成物、インクセット、およびインクジェット画像形成方法
EP2617783A1 (en) 2012-01-20 2013-07-24 Cytec Surface Specialties, S.A. Photo-reactive Binder
EP2617705A1 (en) * 2012-01-20 2013-07-24 Cytec Surface Specialties, S.A. Amino Photo-Reactive Binder
WO2015010729A1 (en) 2013-07-23 2015-01-29 Allnex Belgium S.A. Polymeric photoinitiators
KR200488154Y1 (ko) 2017-05-31 2018-12-21 이효리 애완동물 배변 봉투 수납 소지구
JP2021024933A (ja) * 2019-08-02 2021-02-22 三菱ケミカル株式会社 共重合体、硬化性重合体組成物、硬化物、積層体
CN114591241B (zh) * 2022-03-14 2024-02-13 内蒙古扬帆新材料有限公司 一种含有吡唑啉和α-氨基酮的分子内敏化大分子光引发剂及其制备方法和应用
EP4310105A1 (en) * 2022-07-20 2024-01-24 Arkema France Acrylic copolymers imparting low yellowing after photocuring

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4318791A (en) * 1977-12-22 1982-03-09 Ciba-Geigy Corporation Use of aromatic-aliphatic ketones as photo sensitizers
IT1176018B (it) * 1984-04-12 1987-08-12 Lamberti Flli Spa Chetoni aromatico alifatici polimerici o polimerizzabili adatti all'impiego come fotoiniziatori di polimerizzazione
DE3738567A1 (de) * 1987-03-12 1988-09-22 Merck Patent Gmbh Coreaktive fotoinitiatoren

Also Published As

Publication number Publication date
FI892302A (fi) 1989-11-14
CA1336091C (en) 1995-06-27
DE58907593D1 (de) 1994-06-09
FI892302A0 (fi) 1989-05-12
EP0341560A3 (de) 1991-01-16
EP0341560B1 (de) 1994-05-04
DD283825A5 (de) 1990-10-24
JPH01319504A (ja) 1989-12-25
EP0341560A2 (de) 1989-11-15
JP2769628B2 (ja) 1998-06-25
DE3816304A1 (de) 1989-11-23
AU627177B2 (en) 1992-08-20
KR0141602B1 (ko) 1998-07-01
AU3472489A (en) 1989-11-16

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