KR890016084A - 방향족 폴리이미드, 그의 제조방법 및 그로부터 제조된 고온 안정성 투명 필름 - Google Patents

방향족 폴리이미드, 그의 제조방법 및 그로부터 제조된 고온 안정성 투명 필름 Download PDF

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KR890016084A
KR890016084A KR1019880005877A KR880005877A KR890016084A KR 890016084 A KR890016084 A KR 890016084A KR 1019880005877 A KR1019880005877 A KR 1019880005877A KR 880005877 A KR880005877 A KR 880005877A KR 890016084 A KR890016084 A KR 890016084A
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polyimide
aromatic polyimide
compound
formula
aromatic
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KR1019880005877A
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앨런 헤이즈 리차아드
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제임즈 제이 플린
이 아이 듀우판 디 네모아 앤드 캄파니
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
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    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1042—Copolyimides derived from at least two different tetracarboxylic compounds or two different diamino compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1067—Wholly aromatic polyimides, i.e. having both tetracarboxylic and diamino moieties aromatically bound
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    • C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
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    • C08J2379/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2361/00 - C08J2377/00
    • C08J2379/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C08J2379/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
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Abstract

내용 없음

Description

방향족 폴리이미드, 그의 제조방법 및 그로부터 제조된 고온 안정성 투명 필름
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (16)

  1. 하기 일반식을 갖는 방향족 폴리이미드 :
    상기식에서
    -Ar- 은
    또는 그 혼합물 ;
    -X, -X1, -X2, -X3, 및 -X4는 독립적으로 1-6개의 탄소원자를 갖는 일차 또는 이차 알킬기이고, Z, -Z1, -Z2, -Z3, -Z4및 -Z5은 독립적으로 -H, 또는 -X,
    r=100%-(t+v)
    v=0% 일때 t=0-50%
    t=0% 일때 v=0-19%
    s=100%-u
    (t+v) 1% 일때 u=100%
  2. 제 1 항에 있어서, V=0-25인 방향족 폴리이미드.
  3. 제 2 항에 있어서, -X1, -X2, -X3및 -X4는 -CH3또는 -C2H5인 망향족 폴리 이미드.
  4. 제 1 항에 있어서, t, u 및 v는 0이고 -Ar-은이고, -X, -Z 및 Z2는 -CH3이고 Z1은 -H인 방향족 폴리-이미드.
  5. 제 1 항에 있어서, t, u 및 v는 0이고 -Ar-이이고, -X, -X1, -X2, 및 -X3가 -CH3인 방향족 폴리 이미드.
  6. 제 1 항에 있어서, t, u 및 v는 0이고 -Ar-이의 혼합물이고, -X,-X1, -X2, -X3, Z 및 Z2가 -CH3이고, Z1이 -H인 방향족 폴리이미드.
  7. 제 7 항에 있어서, u 및 v가 0이고, t가 0-50이고, -Ar-이이고,-X, -Z 및 -Z2는 -CH3이고 -Z1은 -H인 방향족 폴리이미드.
  8. 제 1 항에 있어서, t 및 u는 0-49이고, v는 이고, -Ar-은이고,-X, -Z 및 -Z2는 -CH3이고 -Z1은 -H인 방향족 폴리이미드.
  9. 제 8 항에 있어서, 가교 결합된 방향족 폴리이미드.
  10. 제 1 항에 있DJ서, t, u 및 v는 0이고, -Z, -Z1및 -Z2는 -H인 방향족 VHF리이미드.
  11. 적어도 하나의 하기 일반식(a)의 테트라카르복실산, 또는 그의 유도된 이무수물을, 그것만으로 또는 적어도 하나의 하기 일반식(b) 및/또는 (c)의 테트라카르복실산 또는 그의 유도된 이무수물과 함께 적어도 하나의 일반식 H2N-Ar-NH2의 디아민으로 중축합 반응시킨 후, 형성된 폴리아미드산을 열의 영향/또는 탈수제의 작용하에 환화시키는 것을 포함하는, 제 1 항의 폴리이미드를 제조하는 방법.
  12. 하나 이상의 하기 일반식의 테트라카르복실산이나 그의 유도된 이무수물을 하나 이상의 일반식 H2N-Ar-NH2의 디아민으로 중축합 반응시킨 후, 형성된 폴리아미드산을 열의 영향/또는 탈수제의 작용하에 환화시키는 것을 포함하는, 제 1 항의 폴리이미드를 제조하는 방법:
  13. 제 11 항에 있어서, 탈수제가 아세트산 무수물과 트리-에틸아민의 용액인 방법.
  14. 제 12 항에 있어서, 탈수제가 아세트산 무수물과 트리-에틸아민의 용액인 방법.
  15. 제 1 항의 폴리이미드의 코우팅이 위에 적용된 담체 물질로 이루어진 코우팅처리된 물질.
  16. 고온 안정성이고 가시범위 내에서 고도로 광학적으로 투명-무색인, 제 1 항의 폴리이미드로부터 제조된 방향족 폴리이미드 필름.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880005877A 1987-08-14 1988-05-17 방향족 폴리이미드, 그의 제조방법 및 그로부터 제조된 고온 안정성 투명 필름 KR890016084A (ko)

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US8520487A 1987-08-14 1987-08-14
US08204 1987-08-14
US07/178,092 US4912197A (en) 1987-08-14 1988-04-19 Highly soluble clear polyimides
US178092 1988-04-19

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US (1) US4912197A (ko)
EP (1) EP0303774A3 (ko)
JP (1) JPH02160832A (ko)
KR (1) KR890016084A (ko)
CN (1) CN1018183B (ko)
AU (1) AU613626B2 (ko)
BR (1) BR8802383A (ko)
DK (1) DK322988A (ko)
MA (1) MA21281A1 (ko)
NO (1) NO882141L (ko)
NZ (1) NZ224632A (ko)
OA (1) OA08847A (ko)
PT (1) PT87508A (ko)
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DK322988D0 (da) 1988-06-14
EP0303774A3 (en) 1989-05-31
NO882141D0 (no) 1988-05-16
PT87508A (pt) 1989-06-30
EP0303774A2 (en) 1989-02-22
BR8802383A (pt) 1989-02-28
US4912197A (en) 1990-03-27
OA08847A (en) 1989-03-31
NZ224632A (en) 1990-07-26
AU1632388A (en) 1989-02-16
AU613626B2 (en) 1991-08-08
MA21281A1 (fr) 1988-12-31
NO882141L (no) 1989-02-15
CN1031239A (zh) 1989-02-22
DK322988A (da) 1989-02-15
JPH02160832A (ja) 1990-06-20
CN1018183B (zh) 1992-09-09
TNSN88060A1 (fr) 1990-07-10

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