KR890010295A - 개선된 초기신도를 갖는 폴리올레핀섬유 및 그 제조방법 - Google Patents
개선된 초기신도를 갖는 폴리올레핀섬유 및 그 제조방법 Download PDFInfo
- Publication number
- KR890010295A KR890010295A KR1019880016099A KR880016099A KR890010295A KR 890010295 A KR890010295 A KR 890010295A KR 1019880016099 A KR1019880016099 A KR 1019880016099A KR 880016099 A KR880016099 A KR 880016099A KR 890010295 A KR890010295 A KR 890010295A
- Authority
- KR
- South Korea
- Prior art keywords
- olefin
- carbon atoms
- molecular weight
- polyolefin fiber
- composition
- Prior art date
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/10—Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
- Y10T442/102—Woven scrim
- Y10T442/153—Including an additional scrim layer
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제 1 도는 초고분자량 폴리에티렌섬유(4), 초고분자량 에티렌/부텐-1 공중합체 섬유(5) 및 두 중합체의 조성물로 된 섬유(1)∼(3)의 크리프특성을 나타내는 그라프.
제 2, 3, 4, 5 및 6 도는 전술한 샘플들(1)∼(5)의 시차열곡선.
Claims (12)
- 초고분자량 폴리에틴렌과, 에티렌과 적어도 3 탄소원자를 갖는 올레핀의 초고분자량 공중합체로 구성되는 조성물로 강연신체를 구성하되, 상기 전체 조성물중 적어도 3 탄소원자를 갖는 올레핀의 함량은 상기 조성물중 1000 탄소원자당 측쇄의 수가 평균하여 0.2∼5.0이 되는 그러한 정도가 되는 비로하며, 상기 조성물은 전체적으로 적어도 5dl/g의 고유점도[η]를 가지며, 여기서 상기 강연신체는 시차주사 칼로리케터로 구속상태에서 측정할 때 제2온도상승에서 메인용융 흡열피이크로서 측정되는 조성물의 고유결정 용융온도(Tm)보다 적어도 15℃만큼 더 높은 온도영역에서 서로 인접한 적어도 두 개의 결정용융 흡열온도를 갖고 있는 것이 특징인 개선된 초기신도를 갖는 폴리올레핀섬유.
- 제 1 항에서, 실온에서 파괴하중의 30%에 상당하는 하중이 70℃의 온도분위기에서 1cm의 샘플길이의 섬유에 가해질 때, 하중인가 개시후 60초뒤의 초기신도는 5% 이하이며, 또한 하중인가 개시후 90초로부터 개시후 180℃까지의 기간동안 평균 크리프속도는 1×10-4sec-1이하인 것이 특징인 개선된 초기신도를 갖는 폴리올레핀섬유.
- 제 1 항에서, 에티렌가 적어도 3 탄소원자를 갖는 α-올레핀의 초고분자량 공중합체의 고유점도[η]는 적어도 5dl/g이며, 상기 공중합체중에 α-올레핀의 함량은 공주합체내에서 1000 탄소원자당 측쇄의 수가 평균하여 0.5∼10이 되는 그러한 정도인 것이 특징인 개선된 초기신도를 갖는 폴리올레핀섬유.
- 제 1 항에서, 초고분자량 폴리에티렌의 고유점도는 적어도 5dl/g인 것이 특징인 개선된 초기신도를 갖는 폴리올레핀섬유.
- 제 1 항에서, 초고분자량 폴리에티렌과 초고분자량 에티렌/α-올레핀 공중합체는 10/90∼90/10의 중량비로 존재하는 것이 특징인 개선된 초기신도를 갖는 폴리올레핀섬유.
- 제 1 항에서, 상기 적어도 두 결정용융 흡열피이크들 즉, 고온측 흡열피이크(TH)와 저온측 흡열피이크(TL)은 TH=150∼157℃, TL=149∼155℃ 및 TH-TL=2.5∼0.5℃의 조건을 만족시키는 온도에서 나타나며, 또한 고온쪽 피이크의 높이(IH) 대 저온쪽 피이크이 높이(IL)의 비(TH/TL)은 1.5∼0.5인 것이 특징인 개선된 초기신도를 갖는 폴리올레핀섬유.
- 제 6 항에서, TH와 TL은 TH=151∼156℃ TL=150∼154℃ 및 TH-TL=2.0∼1.0℃의 조건을 만족시키는 온도에서 나타나며 비 IH/IL은 1.4∼0.6인 것이 특징인 개선된 초기신도를 갖는 폴리올레핀섬유.
- 제 1 항에서, 섬유는 5분동안 170℃의 열이력을 받을 때, 강도보유비가 적어도 90%이고 탄성계수가 적어도 90%인것이 특징인 개선된 초기 신도를 갖는 폴리올레핀 섬유.
- 제 1 항에서, 적어도 30Gpa의 탄성계수와 적어도 1.5Gpa의 인장강도를 갖는 것이 특징인 개선된 초기신도를 갖는 폴리올레핀섬유.
- 제 1 항의 폴리올레핀섬유로 구성되는 것이 특징인 수지 또는 고무보강재.
- 적어도 5dl/g의 고유점도[η]를 갖는 초고분자량 폴리에티렌과 적어도 5dl/g의 고유점도[η]를 갖는 초고분자량 에티렌/α-올레핀 공중합체로 구성하되, 상기 α-올레핀은 적어도 3 탄소원자를 갖고 있으며, 또한 적어도 3 탄소원자를 갖는 상기 α-올레핀의 함량은 상기 공중합체중 1000 탄소원자당 α-올레핀의 측쇄의 수가 평균하여 0.5∼10이 되는 정도인 상기 조성물을 희석제의 존재하에서 10/90∼90/10의 중량비로 용융혼련시키고, 그 용융혼합물을 방사하고, 방사하여 얻은 섬유를 적어도 10의 연신비로 연신하는 것을 포함하는 개선된 초기신도를 갖는 폴리올레핀섬유 제조방법.
- 제 12 항에서, 희석제는 왁스이고, 초고분자량 올레핀수지 조성물과 왁스는 15/85∼60/40의 중량비로 사용되는 것이 특징인 개선된 초기신도를 갖는 폴리올레핀섬유 제조방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62-304484 | 1987-12-03 | ||
JP62304484A JPH089804B2 (ja) | 1987-12-03 | 1987-12-03 | 初期伸びの改善されたポリオレフィン系繊維及びその製法 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR890010295A true KR890010295A (ko) | 1989-08-08 |
KR910004698B1 KR910004698B1 (ko) | 1991-07-10 |
Family
ID=17933587
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019880016099A KR910004698B1 (ko) | 1987-12-03 | 1988-12-03 | 개선된 초기신도를 갖는 폴리올레핀섬유 및 그 제조방법 |
Country Status (8)
Country | Link |
---|---|
US (2) | US5015525A (ko) |
EP (1) | EP0320188B1 (ko) |
JP (1) | JPH089804B2 (ko) |
KR (1) | KR910004698B1 (ko) |
CN (1) | CN1028547C (ko) |
AT (1) | ATE118826T1 (ko) |
CA (1) | CA1309817C (ko) |
DE (1) | DE3853140T2 (ko) |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0205960B1 (en) * | 1985-06-17 | 1990-10-24 | AlliedSignal Inc. | Very low creep, ultra high moduls, low shrink, high tenacity polyolefin fiber having good strength retention at high temperatures and method to produce such fiber |
JP3206204B2 (ja) * | 1992-05-22 | 2001-09-10 | 株式会社デンソー | スロットルポジションセンサ |
US8865788B2 (en) * | 1996-02-13 | 2014-10-21 | The General Hospital Corporation | Radiation and melt treated ultra high molecular weight polyethylene prosthetic devices |
US8563623B2 (en) * | 1996-02-13 | 2013-10-22 | The General Hospital Corporation | Radiation melt treated ultra high molecular weight polyethylene prosthetic devices |
DE69912160T2 (de) * | 1998-06-04 | 2004-07-08 | Dsm Ip Assets B.V. | Hochfeste polyethylenfasern und verfahren zu deren herstellung |
US6680265B1 (en) | 1999-02-22 | 2004-01-20 | Kimberly-Clark Worldwide, Inc. | Laminates of elastomeric and non-elastomeric polyolefin blend materials |
WO2001012885A1 (fr) * | 1999-08-11 | 2001-02-22 | Toyo Boseki Kabushiki Kaisha | Fibre de polyethylene haute resistance, et son utilisation |
DE19942611C1 (de) * | 1999-08-31 | 2001-07-05 | Ethicon Gmbh | Verstärktes flächiges Implantat |
US7344668B2 (en) | 2003-10-31 | 2008-03-18 | Honeywell International Inc. | Process for drawing gel-spun polyethylene yarns |
DK1699954T3 (da) * | 2004-01-01 | 2012-02-06 | Dsm Ip Assets Bv | Fremgangsmåde til fremstilling af multifilament polyethylengarn med høj ydeevne |
US7846363B2 (en) | 2006-08-23 | 2010-12-07 | Honeywell International Inc. | Process for the preparation of UHMW multi-filament poly(alpha-olefin) yarns |
US20090163679A1 (en) * | 2007-12-19 | 2009-06-25 | Braskem S.A. | Suspension polymerization process for manufacturing ultra high molecular weight polyethylene, a multimodal ultra high molecular weight polyethylene homopolymeric or copolymeric composition, a ultra high molecular weight polyethylene, and their uses |
JP6177526B2 (ja) * | 2009-12-23 | 2017-08-09 | インヴィスタ テクノロジーズ エスアエルエルINVISTA TECHNOLOGIES S.a.r.l. | 伸縮性ポリオレフィン繊維を含有する布 |
NL2005455C2 (en) * | 2010-10-05 | 2012-04-06 | Polymer Res & Dev | Process for producing high-performance polymer fibers. |
CN102002769B (zh) * | 2010-11-08 | 2012-12-12 | 宁波大成新材料股份有限公司 | 超高分子量聚乙烯纤维制备方法 |
JP6069676B2 (ja) * | 2011-04-13 | 2017-02-01 | ディーエスエム アイピー アセッツ ビー.ブイ. | クリープ最適化uhmwpe繊維 |
EP3133191B1 (en) * | 2014-03-28 | 2021-06-02 | Toyobo Co., Ltd. | Multifilament and braid |
KR102224261B1 (ko) * | 2014-03-28 | 2021-03-05 | 도요보 가부시키가이샤 | 멀티필라멘트 및 끈목 |
US10626531B2 (en) | 2015-02-20 | 2020-04-21 | Toyobo Co., Ltd. | Multifilament and braid using same |
ES2811922T3 (es) * | 2015-12-15 | 2021-03-15 | Dsm Ip Assets Bv | Fibra de baja deformación plástica |
CN111210723B (zh) * | 2020-01-13 | 2022-06-03 | 京东方科技集团股份有限公司 | 一种柔性显示组件、可卷曲显示装置及其制备方法 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5551814A (en) * | 1978-10-04 | 1980-04-15 | Mitsui Petrochem Ind Ltd | Production of drawn filament yarn having uneven surface |
NL177759B (nl) * | 1979-06-27 | 1985-06-17 | Stamicarbon | Werkwijze ter vervaardiging van een polyetheendraad, en de aldus verkregen polyetheendraad. |
JPS5841908A (ja) * | 1981-09-04 | 1983-03-11 | Showa Denko Kk | 高強力モノフイラメントの製造方法 |
NL8104728A (nl) * | 1981-10-17 | 1983-05-16 | Stamicarbon | Werkwijze voor het vervaardigen van polyetheen filamenten met grote treksterkte. |
US4455273A (en) * | 1982-09-30 | 1984-06-19 | Allied Corporation | Producing modified high performance polyolefin fiber |
JPS5982406A (ja) * | 1982-10-28 | 1984-05-12 | Nippon Petrochem Co Ltd | ポリオレフイン糸 |
JPS59130313A (ja) * | 1982-12-28 | 1984-07-26 | Mitsui Petrochem Ind Ltd | 超高分子量ポリエチレンの延伸物の製造方法 |
JPS59187614A (ja) * | 1983-04-07 | 1984-10-24 | Mitsui Petrochem Ind Ltd | 超高分子量ポリエチレン延伸物の製造法 |
DE3363610D1 (en) * | 1982-12-28 | 1986-06-26 | Mitsui Petrochemical Ind | Process for producing stretched articles of ultrahigh-molecular-weight polyethylene |
US4737402A (en) * | 1985-02-28 | 1988-04-12 | Allied Corporation | Complex composite article having improved impact resistance |
JPS6241341A (ja) * | 1985-08-08 | 1987-02-23 | 東洋紡績株式会社 | ゲル繊維の高速延伸方法 |
US4769433A (en) * | 1985-11-25 | 1988-09-06 | E. I. Du Pont De Nemours And Company | High strength polyolefins |
JPH0794565B2 (ja) * | 1987-08-04 | 1995-10-11 | 東洋紡績株式会社 | 耐クリ−プ性高強力ポリエチレン成型物およびその製造方法 |
IN170335B (ko) * | 1986-10-31 | 1992-03-14 | Dyneema Vof | |
DE3850905T2 (de) * | 1987-05-06 | 1994-12-01 | Mitsui Petrochemical Ind | Molekular orientiertes geformtes Gebilde aus Ethylen-alpha-olefin-copolymer mit ultrahohem Molekulargewicht. |
US4842922A (en) * | 1987-10-27 | 1989-06-27 | The Dow Chemical Company | Polyethylene fibers and spunbonded fabric or web |
-
1987
- 1987-12-03 JP JP62304484A patent/JPH089804B2/ja not_active Expired - Lifetime
-
1988
- 1988-12-02 US US07/279,084 patent/US5015525A/en not_active Expired - Lifetime
- 1988-12-02 CA CA000584905A patent/CA1309817C/en not_active Expired - Fee Related
- 1988-12-03 CN CN88108372A patent/CN1028547C/zh not_active Expired - Fee Related
- 1988-12-03 KR KR1019880016099A patent/KR910004698B1/ko not_active IP Right Cessation
- 1988-12-05 DE DE3853140T patent/DE3853140T2/de not_active Expired - Fee Related
- 1988-12-05 AT AT88311495T patent/ATE118826T1/de not_active IP Right Cessation
- 1988-12-05 EP EP88311495A patent/EP0320188B1/en not_active Expired - Lifetime
-
1991
- 1991-03-11 US US07/668,138 patent/US5143977A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
US5143977A (en) | 1992-09-01 |
EP0320188A3 (en) | 1990-03-21 |
US5015525A (en) | 1991-05-14 |
JPH01148807A (ja) | 1989-06-12 |
JPH089804B2 (ja) | 1996-01-31 |
CA1309817C (en) | 1992-11-10 |
ATE118826T1 (de) | 1995-03-15 |
DE3853140T2 (de) | 1995-06-29 |
CN1028547C (zh) | 1995-05-24 |
CN1034591A (zh) | 1989-08-09 |
DE3853140D1 (de) | 1995-03-30 |
EP0320188A2 (en) | 1989-06-14 |
EP0320188B1 (en) | 1995-02-22 |
KR910004698B1 (ko) | 1991-07-10 |
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