KR890008232A - 고무함유 매트릭스-분해방지제 - Google Patents
고무함유 매트릭스-분해방지제 Download PDFInfo
- Publication number
- KR890008232A KR890008232A KR1019880014203A KR880014203A KR890008232A KR 890008232 A KR890008232 A KR 890008232A KR 1019880014203 A KR1019880014203 A KR 1019880014203A KR 880014203 A KR880014203 A KR 880014203A KR 890008232 A KR890008232 A KR 890008232A
- Authority
- KR
- South Korea
- Prior art keywords
- matrix
- agent
- rubber
- polymer
- composition
- Prior art date
Links
- 229920001971 elastomer Polymers 0.000 title claims 5
- 239000005060 rubber Substances 0.000 title claims 5
- 238000006731 degradation reaction Methods 0.000 title claims 4
- 239000003112 inhibitor Substances 0.000 title 1
- 239000003795 chemical substances by application Substances 0.000 claims 12
- 239000000203 mixture Substances 0.000 claims 9
- 229920000642 polymer Polymers 0.000 claims 8
- 239000011159 matrix material Substances 0.000 claims 7
- 239000002245 particle Substances 0.000 claims 6
- 238000000354 decomposition reaction Methods 0.000 claims 5
- 238000005192 partition Methods 0.000 claims 5
- 229920000459 Nitrile rubber Polymers 0.000 claims 3
- 239000005062 Polybutadiene Substances 0.000 claims 3
- 229920003244 diene elastomer Polymers 0.000 claims 3
- 229920002857 polybutadiene Polymers 0.000 claims 3
- 229920001195 polyisoprene Polymers 0.000 claims 3
- 229920003048 styrene butadiene rubber Polymers 0.000 claims 3
- 150000001875 compounds Chemical class 0.000 claims 2
- 239000008380 degradant Substances 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 238000002156 mixing Methods 0.000 claims 2
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 claims 1
- ZZMVLMVFYMGSMY-UHFFFAOYSA-N 4-n-(4-methylpentan-2-yl)-1-n-phenylbenzene-1,4-diamine Chemical group C1=CC(NC(C)CC(C)C)=CC=C1NC1=CC=CC=C1 ZZMVLMVFYMGSMY-UHFFFAOYSA-N 0.000 claims 1
- 229920005549 butyl rubber Polymers 0.000 claims 1
- 239000006229 carbon black Substances 0.000 claims 1
- 150000001993 dienes Chemical class 0.000 claims 1
- 238000000227 grinding Methods 0.000 claims 1
- 229920001084 poly(chloroprene) Polymers 0.000 claims 1
- 229920000636 poly(norbornene) polymer Polymers 0.000 claims 1
- 238000010298 pulverizing process Methods 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2321/00—Characterised by the use of unspecified rubbers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S524/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S524/925—Natural rubber compositions having nonreactive materials, i.e. NRM, other than: carbon, silicon dioxide, glass titanium dioxide, water, hydrocarbon or halohydrocarbon
- Y10S524/929—Natural rubber broadly disclosed, nonclaimed
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- 분해방지체가 입자 직경이 100μ 이하이고 분배계수가 2이상인 매트릭스-분해방지제임을 특징으로 하여, 디엠 함유 중합체 분해방지제를 함유하는 조성물.
- 제1항에 있어서, 디엔 항유 중합체가 폴리이소프렌, 폴리부타디엔, 스티렌-부타디엔 공중합체 및 이의 혼합물중에서 선택됨을 특징으로 하는 조성물.
- 제1항에 있어서, 매트릭스-분해방지제가 20 내지 40phr의 분해방지제를 함유하는 니트릴 고무임을 특징으로 하는 조성물.
- 제1항에 있어서, 매트릭스-분해방지제의 입자 직경이 50μ 이하임을 특징으로 하는 조성물.
- 제1항에 있어서, 분배계수가 4이상임을 특징으로 하는 조성물.
- 분해방지제가 부틸고무, 폴리이소프렌, 폴리부타디엔, 스티렌-부타디엔 공중합체, 폴리클로로프렌, 폴리노르보르넨, 니트릴 고무 및 이의 혼합물중에서 선택된 매트릭스 중합체 30 내지 90중량%:파라-페닐렌디아민 및 치환된 유도체중에서 선택된 분해방지제 10 내지 70중량%: 카본 블랙 0 내지 80중량%: 가공오일 및 왁스 0 내지 50중량%: 및 경화성 패키지를 함유하는 가황 매트릭스-분해 방지제이며, 미분된 매트릭스-분해 방지제가 입자직경이 100μ 미만이고 보호될 고무 스톡에 대한 분배계수가 2이상임을 특징으로 하는 미분된 분해방지제.
- 제6항에 있어서, 매트릭스 중합체가 니트릴 고무이고 분해방지제가 N-페닐-N'-(1,3-디메틸부틸)-파라-페닐렌디아민임을 특징으로 하는 미분된 가황 매트릭스-분해방지제.
- (A) 분배계수가 2 이상인 가황성 디엔 탄성 중합체와, (1) 분해방지제를 매트릭스 중합체와 혼합하고, (2) 매트릭스 중합체/분해방지제 화합물을 가황시키고, (3) 생성된 매트릭스 가황물을 입자직경이 100μ 이하인 입자로 분쇄하는 공정을 포함하는 방법으로 제조된 분배계수 2이사의 매트릭스-분해방지제를 혼합하고: (B) 디엔 탄성중합체/매트릭스-분해방지제 혼합물을 가황시키는 공정을 포함하는 방법으로 제조됨을 특징으로 하는 개선된 고무 가황물.
- 제8항에 있어서, 가황성 디엔 탄성중합체가 폴리이소프렌, 폴리부타디엔, 스티렌-부타디엔 공중합체 및 이의 혼합물중에서 선택됨을 특징으로 하는 개선된 고무 가황물.
- (1) 분해방지제와 보호될 고무 스톡에 대하여 분배계수가 2이상이 되도록 선택된 매트릭스 중합체를 혼합하고, (2) 매트릭스 중합체/분해방지제 화합물을 가황시키고, (3) 생성된 매트릭스 가황물을 입자 직경이 100μ 이하인 입자로 분쇄하는 공정을 포함하여, 매트릭스-분해방지제임을 특징으로 하는 분해방지제 조성물을 제조하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/116,850 US5023287A (en) | 1987-11-05 | 1987-11-05 | Rubber containing matrix-antidegradants |
US116,850 | 1987-11-05 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR890008232A true KR890008232A (ko) | 1989-07-10 |
KR960016616B1 KR960016616B1 (ko) | 1996-12-16 |
Family
ID=22369622
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019880014203A KR960016616B1 (ko) | 1987-11-05 | 1988-10-31 | 고무 함유 매트릭스-분해방지제 |
Country Status (9)
Country | Link |
---|---|
US (1) | US5023287A (ko) |
EP (1) | EP0317486B1 (ko) |
JP (1) | JP2516667B2 (ko) |
KR (1) | KR960016616B1 (ko) |
AU (1) | AU622134B2 (ko) |
BR (1) | BR8805701A (ko) |
CA (1) | CA1312687C (ko) |
DE (1) | DE3872492T2 (ko) |
ES (1) | ES2033000T3 (ko) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996039462A2 (en) * | 1995-06-06 | 1996-12-12 | The Dow Chemical Company | High-strength films of block copolymer latices |
US6160043A (en) * | 1997-06-05 | 2000-12-12 | Lord Corporation | Curable compositions having high amount of antiozonant and an article made therefrom |
AUPO760197A0 (en) * | 1997-06-27 | 1997-07-24 | Hotchkin, Darren John | Shock absorbing member |
US6533859B2 (en) * | 2000-05-26 | 2003-03-18 | Flexsys America L.P. | Surface treated carbon black having improved dispersability in rubber and compositions of rubber therefrom having improved processability, rheological and dynamic mechanical properties |
US6441070B1 (en) * | 2000-07-14 | 2002-08-27 | The Goodyear Tire & Rubber Company | Rubber compositions containing a trivalent phosphorous compound-silica complex |
US6612351B1 (en) * | 2001-02-05 | 2003-09-02 | The Goodyear Tire & Rubber Company | Pneumatic tire having dual air retention quasi envelopes |
US10538642B2 (en) * | 2013-03-22 | 2020-01-21 | Honeywell International Inc. | Rubber-based elastomeric compositions and articles of manufacture produced therewith |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3073371A (en) * | 1958-12-22 | 1963-01-15 | Monsanto Chemicals | Light colored tire sidewall impervious to migratory staining materials |
NL6704047A (ko) * | 1966-03-21 | 1967-09-22 | ||
GB1128388A (en) * | 1966-06-14 | 1968-09-25 | Monsanto Chemicals | Rubber antioxidants |
US3704741A (en) * | 1970-08-17 | 1972-12-05 | Goodyear Tire & Rubber | Ozone resistant ethylene/propylene terpolymer laminates to other rubber |
US4092285A (en) * | 1976-07-30 | 1978-05-30 | Wyrough And Loser, Inc. | Encapsulation of critical chemicals |
JPS5738836A (en) * | 1980-08-21 | 1982-03-03 | Toyo Soda Mfg Co Ltd | Production of particulate organic rubber chemicals composition |
DE3100572A1 (de) * | 1981-01-10 | 1982-08-12 | Bayer Ag, 5090 Leverkusen | Verfahren zur erhoehung der haftfestigkeit zwischen kautschuk und metallen |
US4569382A (en) * | 1981-05-11 | 1986-02-11 | The Goodyear Tire & Rubber Company | Composite of rubber and metal reinforcement therefor |
GB8315977D0 (en) * | 1983-06-10 | 1983-07-13 | Monsanto Europe Sa | Sulphur-containing polymers |
US4632954A (en) * | 1985-06-27 | 1986-12-30 | Calgon Corporation | Halogen-containing rubbers and a method for their manufacture |
-
1987
- 1987-11-05 US US07/116,850 patent/US5023287A/en not_active Expired - Lifetime
-
1988
- 1988-10-21 CA CA000580980A patent/CA1312687C/en not_active Expired - Fee Related
- 1988-10-31 KR KR1019880014203A patent/KR960016616B1/ko not_active IP Right Cessation
- 1988-11-02 JP JP63278528A patent/JP2516667B2/ja not_active Expired - Lifetime
- 1988-11-03 BR BR888805701A patent/BR8805701A/pt not_active IP Right Cessation
- 1988-11-04 AU AU24747/88A patent/AU622134B2/en not_active Ceased
- 1988-11-04 DE DE8888630190T patent/DE3872492T2/de not_active Expired - Fee Related
- 1988-11-04 EP EP88630190A patent/EP0317486B1/en not_active Expired - Lifetime
- 1988-11-04 ES ES198888630190T patent/ES2033000T3/es not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
ES2033000T3 (es) | 1993-03-01 |
JP2516667B2 (ja) | 1996-07-24 |
DE3872492D1 (de) | 1992-08-06 |
AU622134B2 (en) | 1992-04-02 |
DE3872492T2 (de) | 1993-02-04 |
CA1312687C (en) | 1993-01-12 |
KR960016616B1 (ko) | 1996-12-16 |
EP0317486A1 (en) | 1989-05-24 |
BR8805701A (pt) | 1989-07-18 |
EP0317486B1 (en) | 1992-07-01 |
US5023287A (en) | 1991-06-11 |
AU2474788A (en) | 1989-05-11 |
JPH01161032A (ja) | 1989-06-23 |
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Payment date: 20001013 Year of fee payment: 5 |
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