KR890008224A - 성형용 에너지 흡수 경질 폴리우레탄 포옴 및 그 제조방법 - Google Patents

성형용 에너지 흡수 경질 폴리우레탄 포옴 및 그 제조방법 Download PDF

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KR890008224A
KR890008224A KR1019880015290A KR880015290A KR890008224A KR 890008224 A KR890008224 A KR 890008224A KR 1019880015290 A KR1019880015290 A KR 1019880015290A KR 880015290 A KR880015290 A KR 880015290A KR 890008224 A KR890008224 A KR 890008224A
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foam
alkylene oxide
percent based
amine adduct
weight percent
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KR1019880015290A
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KR970006671B1 (ko
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로슨 프레이 에드워드
로버트 스톨 존
프리드릭 에이취 플랭크 피이터
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원본미기재
비이에이에스 에프 코오포레이션
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4072—Mixtures of compounds of group C08G18/63 with other macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
    • C08G18/635—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers onto unsaturated polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/6505—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen the low-molecular compounds being compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6511—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen the low-molecular compounds being compounds of group C08G18/32 or polyamines of C08G18/38 compounds of group C08G18/3203
    • C08G18/6517—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen the low-molecular compounds being compounds of group C08G18/32 or polyamines of C08G18/38 compounds of group C08G18/3203 having at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/6505—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen the low-molecular compounds being compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6523—Compounds of group C08G18/3225 or C08G18/3271 or polyamines of C08G18/38
    • C08G18/6535—Compounds of group C08G18/3271
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/6552—Compounds of group C08G18/63
    • C08G18/6558—Compounds of group C08G18/63 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

내용없음.

Description

성형용 에너지 흡수 경질 폴리우레탄 포옴 및 그 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 하기 (a)-(e)의 반응 생성물을 포함하는 성형용 에너지 흡수 경질 포옴 : (a) 그래프트 중합체 분산액을 함유하는 폴리옥시알킬렌 폴리에테르 폴리올, (b) 약 400- 약 800의 분자량을 갖는 톨루엔디아민의 알킬렌 옥사이드 부가물, (c) 약 4-약 8의 알킬렌 옥사이드 단위를 함유하는 에틸렌디아민의 알킬렌 옥사이드 부가물, 트리메틸프로판 및 글리세린으로 이루어진 군으로부터 선택된 가교제, (d) 유기 폴리이소시아네이트, 및 (e) 물, 촉매, 계면활성제 및 부가적인 발포제.
  2. 제1항에 있어서, 아민 부가물이 포옴의 전체 중량을 기준으로 약 0-약 50중량%인 포옴.
  3. 제1항에 있어서, 아민 부가물이 포옴의 전체 중량을 기준으로 약 5-약 40중량%인 포옴.
  4. 하기 (a)-(e)를 반응시키는 것으로 구성되는 성형용 에너지 흡수 경질 포옴의 제조방법 : (a) 그래프트 중합체 분산액을 함유하는 폴리옥시알킬렌 폴리에테르 폴리올, (b) 약 400-약 800의 분자량을 갖는 톨루엔디아민의 알킬렌 옥사이드 부가물, (c) 약 4-약 8의 알킬렌 옥사이드 단위를 함유하는 에틸렌 디아민의 알킬렌 옥사이드 부가물, 트리메틸올프로판 및 글리세린으로 이루어진 군으로부터 선택된 가교제, (d) 방향족 유기 폴리이소시아네이트, 및 (e) 물, 촉매, 계면활성제 및 부가적인 발포제.
  5. 제4항에 있어서, 아민 부가물이 포옴의 전체 중량을 기준으로 약 0-약 50중량%인 방법.
  6. 제4항에 있어서, 아민 부가물이 포옴의 전체 중량을 기준으로 약 5-약 40중량%인 방법.
  7. 하기 (a)-(e)의 반응생성물을 포함하는 성형용 에너지 흡수 경질 포옴 : (a) 그래프트 중합체 분산액을 함유하는 폴리옥시알킬렌 폴리에테르 폴리올, (b) 약 250-약 800의 분자량을 갖는 슈크로우즈, 소르비톨, α-메틸글루코시드, 에틸렌디아민, 및 펜타에리트리톨로 이루어진 군으로부터 선택된 화합물의 알킬렌 옥사이드 부가물, (c) 약 4-약 8의 알킬렌 옥사이드 단위를 함유하는 에틸렌 디아민의 알킬렌 옥사이드 부가물, 트리메틸올프로판 및 글리세린으로 이루어진 군으로부터 선택된 가교제, (d) 유기 폴리이소시아네이트 및, (e) 물, 촉매, 계면활성제 및 부가적인 발포제.
  8. 제7항에 있어서, (b)의 아민 부가물이 포옴의 전체 중량을 기준으로 약 0-약 50중량%인 포옴.
  9. 제7항에 있어서, (b)의 아민 부가물이 포옴의 전체 중량을 기준으로 약 5-약 40중량%인 포옴.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880015290A 1987-11-20 1988-11-19 성형용 에너지 흡수 경질 폴리우레탄 포옴 및 그 제조방법 KR970006671B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US123,186 1987-11-20
US07/123,186 US4866102A (en) 1987-11-20 1987-11-20 Moldable energy absorbing rigid polyurethane foams

Publications (2)

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KR890008224A true KR890008224A (ko) 1989-07-10
KR970006671B1 KR970006671B1 (ko) 1997-04-29

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KR1019880015290A KR970006671B1 (ko) 1987-11-20 1988-11-19 성형용 에너지 흡수 경질 폴리우레탄 포옴 및 그 제조방법

Country Status (9)

Country Link
US (1) US4866102A (ko)
EP (1) EP0316788A3 (ko)
JP (1) JP2828450B2 (ko)
KR (1) KR970006671B1 (ko)
AU (1) AU614309B2 (ko)
BR (1) BR8806091A (ko)
CA (1) CA1314114C (ko)
MX (1) MX165667B (ko)
NZ (1) NZ227002A (ko)

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US5216041A (en) * 1990-12-27 1993-06-01 Basf Corporation Energy absorbing, water blown, rigid polyurethane foam
US5389316A (en) * 1991-08-13 1995-02-14 Woodbridge Foam Corporation Process for producing an energy absorbing panel
US5248703A (en) * 1992-03-13 1993-09-28 Basf Corporation Rigid polyurethane foams containing lithium salts for energy absorbing applications
US5248704A (en) * 1992-06-04 1993-09-28 Basf Corporation Energy absorbing, water blown, rigid polyurethane foam
US5232957A (en) * 1992-09-11 1993-08-03 Davidson Textron Inc. RIM molded energy absorbing polyurethane foam
US5453455A (en) * 1993-01-25 1995-09-26 Basf Corporation Rigid polyurethane foams containing lithium salts for energy absorbing applications
DE4432082A1 (de) * 1994-09-09 1996-03-14 Bayer Ag Stoßfänger auf Basis energieabsorbierender Schaumstoffe
US5415802A (en) * 1994-10-06 1995-05-16 Miles Inc. Water blown, energy absorbing foams
US5417880A (en) * 1994-10-06 1995-05-23 Miles Inc. Water blown, energy absorbing foams
TW514645B (en) * 1996-10-15 2002-12-21 Shell Int Research Polyol combination
US5847014A (en) * 1997-04-15 1998-12-08 Bayer Corporation Water blown, energy absorbing foams
DE19741257A1 (de) * 1997-09-19 1999-03-25 Basf Ag Verfahren zur Herstellung von Polyurethanschaumstoffen
US6028122A (en) * 1997-10-21 2000-02-22 Basf Corporation Energy absorbing, water blown, rigid polyurethane foam
JP2002515527A (ja) * 1998-05-20 2002-05-28 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ 連続気泡硬質ポリウレタンフォームを製造するためのポリオールブレンド
US6005016A (en) * 1998-10-06 1999-12-21 Bayer Corporation Rigid polyurethane foam based on polyethers of TDA
US6127443A (en) * 1998-11-06 2000-10-03 Bayer Antwerp N.V. Energy management polyurethane rigid foams with high recovery
AU7916500A (en) * 1999-10-04 2001-05-10 Shell Internationale Research Maatschappij B.V. Polyol combination
AU3790401A (en) * 1999-10-26 2001-05-14 Mantex Corporation Improved plastic system and articles
US6453476B1 (en) 2000-09-27 2002-09-24 Team Wendy, Llc Protective helmet
KR100771910B1 (ko) * 2001-09-28 2007-11-01 주식회사 엘지이아이 탈형성이 우수한 경질 폴리우레탄 폼 조성물
ATE552285T1 (de) * 2002-10-15 2012-04-15 Basf Se Verfahren zur herstellung von polyurethan- hartschaumstoffen mit graftpolyolen
US7078443B2 (en) * 2003-10-22 2006-07-18 Intellectual Property Holdings, Llc Viscoelastic foam layer and composition
DE102004017294A1 (de) * 2004-04-05 2005-10-20 Basf Ag Verfahren zur Herstellung von Polyurethan-Schaumstoffen
EP2066717B2 (de) * 2006-09-15 2013-11-20 Basf Se Verfahren zur herstellung von polyurethan-hartschaumstoffen
EP2099837A4 (en) * 2006-12-29 2010-06-02 Johnson Controls Tech Co FORMULATION OF POLYURETHANE FOAM, PRODUCTS AND CORRESPONDING PROCESSES
KR100969016B1 (ko) * 2007-12-13 2010-07-09 현대자동차주식회사 내 가수분해성이 향상된 스티어링휠용 폴리우레탄 발포체

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DE2922769A1 (de) * 1979-06-05 1980-12-11 Phoenix Ag Formteil aus polyurethan-integralschaum fuer aussenteile von kraftfahrzeugen
JPS5946970B2 (ja) * 1980-02-19 1984-11-16 旭硝子株式会社 エネルギ−吸収用ポリウレタンフオ−ムの製造方法
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US4689354A (en) * 1982-04-01 1987-08-25 Basf Corporation Process for the preparation of white graft polymer dispersions and flame-retardant polyurethane foams
US4499264A (en) * 1983-06-27 1985-02-12 Texaco Inc. Preparation of amino polyols
US4632943A (en) * 1984-08-23 1986-12-30 Dow Chemical Company Polyurethane foams prepared from alkyl dialkanol amine-containing polyols
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US4826884A (en) * 1987-07-20 1989-05-02 Basf Corporation Flame retardant polyurethane foams resistant to cigarette smoldering ignition

Also Published As

Publication number Publication date
AU2514088A (en) 1989-05-25
JPH01252619A (ja) 1989-10-09
MX165667B (es) 1992-11-27
NZ227002A (en) 1991-04-26
BR8806091A (pt) 1989-08-08
JP2828450B2 (ja) 1998-11-25
EP0316788A3 (en) 1990-08-22
CA1314114C (en) 1993-03-02
US4866102A (en) 1989-09-12
EP0316788A2 (en) 1989-05-24
KR970006671B1 (ko) 1997-04-29
AU614309B2 (en) 1991-08-29

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