KR890008083A - 티오 이미데이트 및 살충제와 그 제조 방법 및 이를 이용한 조성물 및 곤충구 제조방법 - Google Patents

티오 이미데이트 및 살충제와 그 제조 방법 및 이를 이용한 조성물 및 곤충구 제조방법 Download PDF

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KR890008083A
KR890008083A KR1019880015091A KR880015091A KR890008083A KR 890008083 A KR890008083 A KR 890008083A KR 1019880015091 A KR1019880015091 A KR 1019880015091A KR 880015091 A KR880015091 A KR 880015091A KR 890008083 A KR890008083 A KR 890008083A
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South Korea
Prior art keywords
compound
methyl
insecticide
general formula
halo
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KR1019880015091A
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English (en)
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데이비드 브로드허스트 마이클
휴스톤 크로마티 토마스
Original Assignee
데이비드 씨.워커
아이씨아이 아메리카스 인코포레이티드
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Publication of KR890008083A publication Critical patent/KR890008083A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/62—Oxygen or sulfur atoms
    • C07D213/63—One oxygen atom
    • C07D213/64—One oxygen atom attached in position 2 or 6
    • C07D213/643—2-Phenoxypyridines; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/52—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing groups, e.g. carboxylic acid amidines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
    • A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
    • A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
    • A01N43/30—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3 with two oxygen atoms in positions 1,3, condensed with a carbocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/62—Oxygen or sulfur atoms
    • C07D213/63—One oxygen atom
    • C07D213/68—One oxygen atom attached in position 4
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/44—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D317/46—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems condensed with one six-membered ring
    • C07D317/48—Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring
    • C07D317/62—Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to atoms of the carbocyclic ring
    • C07D317/66—Nitrogen atoms not forming part of a nitro radical

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pyridine Compounds (AREA)

Abstract

내용 없음

Description

티오 이미데이트 및 살충제와 그 제조 방법 및 이를 이용한 조성물 및 곤충구 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 하기 일반식의 화합물
    식중, R₁은 4-할로 ; 4-메틸: 치환제가 각각 할로, 메틸, 트리플루오로메틸, 트리플루오로메틸티오, 트리를루오로메톡시인 3,4-2중 치환체 ; 또는 2개 이하의 할로겐으로 임의 치환된 C1-C4의 3,4-알킬렌디옥시기 ; R₂는 메틸 ; 에틸 ; n-프로필 ; C3-C7분기알킬 ; C1-C6할로알킬 ; 또는 4개 이하의 메틸기 또는 2개 이하의 할로겐으로 임의 치환된 시클로프로필 : R₃는
    식중, m은 0 또는 1; A 및 B는 각각 N 또는 -CH, R₄는 수소 또는 할로, R5는 수소, 모노-또는 디-할로, C₁-C₄알킬C₁-C₄알콕시,트리플루오로메틸,시아노,C₁-C₄알킬티오, 또는 C₁-C₄알킬술포닐, R6는 수소 또는 메틸; (b)페타플루오로벤질 ; 또는 (c)2-메틸, 3-페닐벤질 ; X는 유황, 아미노 또는 C₁-C₄ 모조알킬아미노 ; 다음의 조건으로 , (i) R₁이 4-클로로, R₂가 디클로로메틸일때는, X는 유황이 아니고, R₃는 펜타플루오로벤질이 아니며; (ii)R₁이 4-플루오로, R₂가 시클로프로필일때는, X는 아미노 또는 모노알킬아미노가 아니며 ; (iii)R₂는 1,3-디할로프로필이 아닌 것이다
  2. 제 1 항에 있어서, R₂가 이소프로필인 화합물
  3. 제 1 항에 있어서, R₂가 디클로로메틸인 화합물
  4. 제 1 항 내지 제 3 항 중 어느 한항에 있어서 R₁이 3,4-알킬렌디옥시기인 화합물
  5. 제 1 항 내지 제 3 항중 어느 한항에 있어서, R₃가 3-페녹시벤질인 화합물
  6. 제 1 항 내지 제 3 항중 어느 한항에 있어서, X가 유황이고, R₃가 3-페녹시벤질인 화합물
  7. 곤충, 곤충의 출몰지역 또는 곤충구제가 필요한 지역에 제 1 항 내지 제6항중, 어느 한항에 의한 살충유료량의 화합물을 투여하여 이루어지는 곤충구제방법
  8. (a)제 1 항 내지 제 6 항중 어느 한 항에 의한 살충유효량의 화합물과, (b)적합한 살충제 비활성희석액 또는 담체로 이루어지는 살충제 조성물
  9. 염기, M이 알칼리금속인R₃S-M의 일반식을 가진 메츠캅티드, 또는 R7이 수소 또는 C₁-C₄알킬인 R₃NHR7의 일반식을 가진 아민의 존재하에 또는 선택적으로 용매의 존재하에 -40℃ 내지 80℃의 온도로, R-R₂ 의 일반식을 가진 염화이미도일과 R₃SH의 일반식을 가진 메르캅탄과를 반응시켜 이루어지는 제 1 항의 화합물의 제조방법
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880015091A 1987-11-17 1988-11-16 티오 이미데이트 및 살충제와 그 제조 방법 및 이를 이용한 조성물 및 곤충구 제조방법 KR890008083A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US122,878 1987-11-17
US07/122,878 US4931448A (en) 1987-11-17 1987-11-17 Thiomidate insecticides

Publications (1)

Publication Number Publication Date
KR890008083A true KR890008083A (ko) 1989-07-08

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KR1019880015091A KR890008083A (ko) 1987-11-17 1988-11-16 티오 이미데이트 및 살충제와 그 제조 방법 및 이를 이용한 조성물 및 곤충구 제조방법

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Country Link
US (1) US4931448A (ko)
EP (1) EP0317266A3 (ko)
JP (1) JPH01153671A (ko)
KR (1) KR890008083A (ko)
CN (1) CN1034923A (ko)
AU (1) AU2562188A (ko)
BR (1) BR8806001A (ko)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0535227A4 (en) * 1990-05-29 1993-08-18 Nippon Soda Co., Ltd. N-substituted heterocyclic amidine derivative
AU671071B2 (en) * 1990-08-30 1996-08-15 State of Oregon, acting by and through The Oregon State Board of Higher Education, acting for and on behalf of The Oregon Health Sciences University, Portland, Oregon, and The University of Oregon, Eugene, Oregon, Johnson Hall, Substituted amidines having high binding to the sigma receptor and the use thereof
EP1178036A1 (en) * 2000-08-04 2002-02-06 Aventis Cropscience S.A. Fungicidal phenylimidate derivatives
ZA200804378B (en) * 2005-12-01 2009-10-28 Sumitomo Chemical Co Iminopropene compound and use thereof
KR20080072029A (ko) 2005-12-01 2008-08-05 스미또모 가가꾸 가부시끼가이샤 이미노프로펜 화합물 및 그의 용도
TW200901876A (en) * 2007-05-30 2009-01-16 Sumitomo Chemical Co Thioimidate compound and use thereof for controlling pests
JP2009046478A (ja) 2007-07-25 2009-03-05 Sumitomo Chemical Co Ltd イミデート化合物およびその有害生物防除用途

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3899582A (en) * 1970-04-21 1975-08-12 Sumitomo Chemical Co Aromatic imidocarbonate composition and method of use for combatting fungi
US3832351A (en) * 1970-04-21 1974-08-27 Sumitomo Chemical Co Aromatic imidocarbonates
JPS5248177B2 (ko) * 1973-12-25 1977-12-08
DE2944849A1 (de) * 1979-11-07 1981-06-04 Bayer Ag, 5090 Leverkusen (di)thiocarbonsaeure-phenoxybenzylester, zwischenprodukte und verfahren zu ihrer herstellung sowie ihre verwendung als insektizide und akarizide
JPS605593B2 (ja) * 1981-03-20 1985-02-12 北興化学工業株式会社 イミダゾ−ル誘導体および農園芸用殺菌剤
JPS6026391B2 (ja) * 1981-10-15 1985-06-24 北興化学工業株式会社 １，２，４−トリアゾ−ル誘導体および農園芸用殺菌剤
US4427699A (en) * 1982-08-23 1984-01-24 Stauffer Chemical Company Imidoyl thioureas as used to control tobacco budworm
GB8502398D0 (en) * 1985-01-31 1985-03-06 Shell Int Research Imidazole derivatives
US4866079A (en) * 1986-03-19 1989-09-12 Ciba-Geigy Corporation N-pyridyloxyphenylisothioureas and the use thereof in pest control

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BR8806001A (pt) 1989-08-08
US4931448A (en) 1990-06-05
AU2562188A (en) 1989-05-18
JPH01153671A (ja) 1989-06-15
CN1034923A (zh) 1989-08-23
EP0317266A2 (en) 1989-05-24
EP0317266A3 (en) 1990-10-17

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