KR890004769A - 경 올레핀-함유 탄화수소 원료로부터 아르신을 제거하는 방법 - Google Patents
경 올레핀-함유 탄화수소 원료로부터 아르신을 제거하는 방법 Download PDFInfo
- Publication number
- KR890004769A KR890004769A KR1019880012438A KR880012438A KR890004769A KR 890004769 A KR890004769 A KR 890004769A KR 1019880012438 A KR1019880012438 A KR 1019880012438A KR 880012438 A KR880012438 A KR 880012438A KR 890004769 A KR890004769 A KR 890004769A
- Authority
- KR
- South Korea
- Prior art keywords
- weight
- adsorbent
- nickel
- raw material
- arsine
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
- C07C7/14833—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound with metals or their inorganic compounds
- C07C7/1485—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound with metals or their inorganic compounds oxides; hydroxides; salts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/40—Ethylene production
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Inorganic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Separation Of Gases By Adsorption (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Carbon And Carbon Compounds (AREA)
- Treating Waste Gases (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (14)
- 경 올레핀-함유 탄화수소 원료로부터 아르신을 제거하는 방법에 있어서, a) 상기 원료를 지지체 물질상에 증착된 니켈을 함유하며 상기 니켈이 산화니켈 및 금속니켈 둘 다로서 존재하는 흡착물질에 통과시키고; 및 b) 실질적으로 감소된 아르신 함량을 갖는 탄화수소 스티림을 회수하는 단계들을 포함하는 방법.
- 제1항에 있어서, 산화니켈과 금속니켈의 총량이 흡착물질의 약 80중량% 이하를 차지하며, 단 금속니켈이 흡착제의 10중량% 이하 및 50중량% 이상을 차지하지 않는 방법.
- 제2항에 있어서, 금속니켈과 산화니켈의 중량비가 약 0.4 내지 약 2.0이고 및 흡착제가 약 30 내지 60중량%의 지지체 물질을 함유하는 방법.
- 제1항 내지 제3항중 어느 한 항에 있어서, 상기 흡착물질이 약 100 내지 약 200㎡/g의 비표면적을 갖는 방법.
- 제1항 내지 제4항중 어느 한 항에 있어서, 원료가 77중량% 이상의 프로필렌, 바람직하기로는 약 85 내지 약 99중량%의 프로필렌을 함유하는 방법.
- 제5항에 있어서, 온도 약-10-약80℃, 원료를 액상으로 유지시키기에 충분한 압력 및 WHSV 약 0.1-25kg/kg.h에서 수행되는 방법.
- 제1항 내지 제4항중 어느 한 항에 있어서, 원료가 80중량% 이상의 에틸렌, 바람직하기로는 약 90-약 99중량%의 에틸렌을 함유하는 방법.
- 제7항에 있어서, 온도 약-10-약80℃, 압력이 최소한 1MPa 및 WHSV 약 0.1-25kg/kg.h에서 수행되는 방법.
- 제6항 또는 제8항에 있어서, 온도 약 10- 약 40℃ 및 WHSV 약 1- 약 10kg/kg.h에서 수행되는 방법.
- 제1항 내지 제9항중 어느 한 항에 있어서, 흡착물질에 최소한 1종의 경 올레핀 소량을 함유하는 불활성 기체기류를 통과시켜 미리 조절시키는 방법.
- 제10항에 있어서, 불활성 기체 중의 경 올레핀이 약 0.1-15 부피% 농도의 프로필레인 방법.
- 제10항 또는 제11항에 있어서, 흡착물질을 조절시키기에 앞서, 온도 약 150-250℃ 및 바람직하기로는 대기압하에서 먼저 불활성 기체를 함유하는 기류, 이어서 불활성 기체와 수소의 혼합물로서 수소의 농도가 증가되도록 함유하는 기류를 통과시켜 흡착물질을 예비 처리하는 방법.
- 제1항 내지 제12항중 어느 한 항에 있어서, 회수된 스트림이 50중량 ppb를 초과하지 않는 아르신 농도를 갖는 방법.
- 제1항 내지 제13항중 어느 한 항에 있어서, 원료내의 아르신의 원래 농도가 약 70중량 ppm이하인 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE87870137.4 | 1987-09-24 | ||
| EP87870137A EP0308569B1 (en) | 1987-09-24 | 1987-09-24 | Process for removing arsine from light olefin-containing hydrocarbon feedstocks |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR890004769A true KR890004769A (ko) | 1989-05-09 |
| KR960016465B1 KR960016465B1 (ko) | 1996-12-12 |
Family
ID=8198505
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019880012438A KR960016465B1 (ko) | 1987-09-24 | 1988-09-24 | 경 올레핀-함유 탄화수소 원료로부터 아르신을 제거하는 방법 |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US4861939A (ko) |
| EP (1) | EP0308569B1 (ko) |
| JP (1) | JPH0832641B2 (ko) |
| KR (1) | KR960016465B1 (ko) |
| CN (1) | CN1014402B (ko) |
| AT (1) | ATE73118T1 (ko) |
| AU (1) | AU654260B2 (ko) |
| CA (1) | CA1314689C (ko) |
| DE (1) | DE3777182D1 (ko) |
| ES (1) | ES2038695T3 (ko) |
| GR (1) | GR3003972T3 (ko) |
| MX (1) | MX168866B (ko) |
| NO (1) | NO177421C (ko) |
| PT (1) | PT88582B (ko) |
| RU (1) | RU2007437C1 (ko) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4962272A (en) * | 1989-05-30 | 1990-10-09 | Aristech Chemical Corporation | Treatment of arsine removal catalysts |
| US5268091A (en) * | 1989-08-08 | 1993-12-07 | Institut Francais De Petrole | Method for removing arsenic and phosphorus contained in liquid hydrocarbon cuts, nickel based retaining material |
| BE1003395A3 (fr) * | 1989-10-16 | 1992-03-17 | Fina Research | Procede de traitement d'un materiau absorbant usage a base de nickel. |
| BE1004214A3 (fr) * | 1990-03-23 | 1992-10-13 | Fina Research | Procede pour enlever l'hydrure d'antimoine de charges d'hydrocarbures liquides |
| US5024683A (en) * | 1990-06-12 | 1991-06-18 | Phillips Petroleum Company | Sorption of trialkyl arsines |
| US5085844A (en) * | 1990-11-28 | 1992-02-04 | Phillips Petroleum Company | Sorption of trialkyl arsines |
| US5096681A (en) * | 1991-02-22 | 1992-03-17 | Phillips Petroleum Company | Removal of trialkyl arsine from fluids |
| WO1992017428A2 (en) * | 1991-04-08 | 1992-10-15 | Exxon Chemical Patents Inc. | Process for upgrading the quality of light ends |
| AU9038391A (en) * | 1991-12-09 | 1993-07-19 | Dow Benelux N.V. | Process for removing mercury from organic media |
| US5330560A (en) * | 1993-03-29 | 1994-07-19 | Gas Research Institute | Supported sorbents for removal and recovery of arsenic from gases |
| EP0643028B1 (en) * | 1993-09-15 | 1998-05-06 | Fina Research S.A. | Process for the polymerization of olefins |
| FR2710044B1 (fr) * | 1993-09-17 | 1995-10-13 | Air Liquide | Procédé de séparation d'un hydrure gazeux ou d'un mélange d'hydrures gazeux à l'aide d'une membrane. |
| DE69309680T2 (de) * | 1993-09-20 | 1997-08-21 | Fina Research | Verfahren zur Entfernung von Arsien und Carbonylsulfid aus leichten Olefinen enthaltender Kohlenwasserstoffbeschickungen |
| JPH09239232A (ja) * | 1994-08-05 | 1997-09-16 | Tadahiro Omi | 水素化物ガスの除去方法及び除去装置 |
| DE19840372A1 (de) | 1998-09-04 | 2000-03-09 | Basf Ag | Katalysator und Verfahren zur Reinigung von Stoffströmen |
| FR2794381B1 (fr) * | 1999-06-02 | 2001-06-29 | Inst Francais Du Petrole | Masse d'elimination d'arsenic et de mercure dans des hydrocarbures a base de nickel supporte |
| US6506954B1 (en) | 2000-04-11 | 2003-01-14 | Exxon Mobil Chemical Patents, Inc. | Process for producing chemicals from oxygenate |
| US6660812B2 (en) | 2000-07-13 | 2003-12-09 | Exxonmobil Chemical Patents Inc. | Production of olefin derivatives |
| US6593506B1 (en) | 2000-10-12 | 2003-07-15 | Exxonmobil Chemical Patents Inc. | Olefin recovery in a polyolefin production process |
| US6495609B1 (en) | 2000-11-03 | 2002-12-17 | Exxonmobil Chemical Patents Inc. | Carbon dioxide recovery in an ethylene to ethylene oxide production process |
| US6875899B2 (en) * | 2001-02-01 | 2005-04-05 | Exxonmobil Chemical Patents Inc. | Production of higher olefins |
| US20020103406A1 (en) | 2001-02-01 | 2002-08-01 | Georges Mathys | Production of olefin dimers and oligomers |
| US20030147604A1 (en) * | 2002-02-01 | 2003-08-07 | Tapia Alejandro L. | Housing assembly for providing combined electrical grounding and fiber distribution of a fiber optic cable |
| KR20040105233A (ko) * | 2002-04-03 | 2004-12-14 | 사빅 하이드로카본스 비.브이. | 흡착제에 의해 탄화수소 스트림으로부터 아르신을제거하는 방법 |
| US6960700B1 (en) | 2002-12-19 | 2005-11-01 | Uop Llc | Adsorbent beds for removal of hydrides from hydrocarbons |
| US6843830B2 (en) | 2003-04-15 | 2005-01-18 | Advanced Technology Materials, Inc. | Abatement system targeting a by-pass effluent stream of a semiconductor process tool |
| EP2006012A1 (en) * | 2007-06-22 | 2008-12-24 | Total Petrochemicals Research Feluy | Process for the polymerisation of olefins |
| FR2923837B1 (fr) * | 2007-11-19 | 2009-11-20 | Inst Francais Du Petrole | Procede de desulfuration en deux etapes d'essences olefiniques comprenant de l'arsenic. |
| EP2199269A1 (en) | 2008-12-22 | 2010-06-23 | Total Petrochemicals Research Feluy | Method to purify olefin-containing hydrocarbon feedstocks |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2951034A (en) * | 1957-04-09 | 1960-08-30 | Sun Oil Co | Desulfurization of hydrocarbons with a mixture of a group viii metal and group viii metal oxide or sulfide |
| DE2149997A1 (de) * | 1971-10-07 | 1973-04-19 | Texaco Ag | Verfahren zum entfernen von arsen aus kohlenwasserstoffen |
| US3782076A (en) * | 1972-04-27 | 1974-01-01 | Gulf Research Development Co | Process for reducing the arsenic content of gaseous hydrocarbon streams by use of supported lead oxide |
| US3833498A (en) * | 1973-07-18 | 1974-09-03 | Gulf Research Development Co | Process for reducing the arsenic content of gaseous hydrocarbon streams by the use of selective activated carbon |
| US3933624A (en) * | 1974-01-23 | 1976-01-20 | Atlantic Richfield Company | Slurry system for removal of contaminant from synthetic oil |
| US4083924A (en) * | 1974-01-23 | 1978-04-11 | Atlantic Richfield Company | Method of regenerating used contaminant-removing material |
| US4069140A (en) * | 1975-02-10 | 1978-01-17 | Atlantic Richfield Company | Removing contaminant from hydrocarbonaceous fluid |
| US4075085A (en) * | 1976-09-20 | 1978-02-21 | Union Oil Company Of California | Process for treating arsenic-containing hydrocarbon feedstocks |
| US4439313A (en) * | 1980-12-05 | 1984-03-27 | The Lummus Company | Removal of arsenic impurity from hydrocarbons |
| JPS5949822A (ja) * | 1982-09-14 | 1984-03-22 | Nippon Sanso Kk | 揮発性無機水素化物等を含有するガスの処理方法 |
| US4605812A (en) * | 1984-06-05 | 1986-08-12 | Phillips Petroleum Company | Process for removal of arsenic from gases |
| LU85487A1 (fr) * | 1984-07-27 | 1986-02-12 | Labofina Sa | Procede de purification de charges d'hydrocarbures liquides |
| US4593148A (en) * | 1985-03-25 | 1986-06-03 | Phillips Petroleum Company | Process for removal of arsine impurities from gases containing arsine and hydrogen sulfide |
-
1987
- 1987-09-24 EP EP87870137A patent/EP0308569B1/en not_active Expired - Lifetime
- 1987-09-24 DE DE8787870137T patent/DE3777182D1/de not_active Expired - Lifetime
- 1987-09-24 AT AT87870137T patent/ATE73118T1/de not_active IP Right Cessation
- 1987-09-24 ES ES198787870137T patent/ES2038695T3/es not_active Expired - Lifetime
-
1988
- 1988-09-13 NO NO884051A patent/NO177421C/no not_active IP Right Cessation
- 1988-09-21 CA CA000577973A patent/CA1314689C/en not_active Expired - Lifetime
- 1988-09-22 JP JP63236639A patent/JPH0832641B2/ja not_active Expired - Fee Related
- 1988-09-23 RU SU884356563A patent/RU2007437C1/ru active
- 1988-09-23 PT PT88582A patent/PT88582B/pt not_active IP Right Cessation
- 1988-09-23 US US07/248,533 patent/US4861939A/en not_active Expired - Lifetime
- 1988-09-23 MX MX013144A patent/MX168866B/es unknown
- 1988-09-23 AU AU22742/88A patent/AU654260B2/en not_active Expired
- 1988-09-24 CN CN88107409A patent/CN1014402B/zh not_active Expired
- 1988-09-24 KR KR1019880012438A patent/KR960016465B1/ko not_active IP Right Cessation
-
1992
- 1992-03-05 GR GR910402025T patent/GR3003972T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NO884051D0 (no) | 1988-09-13 |
| MX168866B (es) | 1993-06-11 |
| JPH0832641B2 (ja) | 1996-03-29 |
| ES2038695T3 (es) | 1993-08-01 |
| GR3003972T3 (ko) | 1993-03-16 |
| EP0308569A1 (en) | 1989-03-29 |
| EP0308569B1 (en) | 1992-03-04 |
| CA1314689C (en) | 1993-03-23 |
| NO177421C (no) | 1995-09-13 |
| KR960016465B1 (ko) | 1996-12-12 |
| NO884051L (no) | 1989-03-28 |
| PT88582B (pt) | 1992-11-30 |
| NO177421B (no) | 1995-06-06 |
| AU2274288A (en) | 1989-04-06 |
| PT88582A (pt) | 1988-10-01 |
| DE3777182D1 (de) | 1992-04-09 |
| CN1014402B (zh) | 1991-10-23 |
| US4861939A (en) | 1989-08-29 |
| AU654260B2 (en) | 1994-11-03 |
| CN1033792A (zh) | 1989-07-12 |
| JPH01139536A (ja) | 1989-06-01 |
| RU2007437C1 (ru) | 1994-02-15 |
| ATE73118T1 (de) | 1992-03-15 |
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