KR890001629A - 기체 정제용 흡착제 및 정제 방법 - Google Patents
기체 정제용 흡착제 및 정제 방법 Download PDFInfo
- Publication number
- KR890001629A KR890001629A KR1019880008888A KR880008888A KR890001629A KR 890001629 A KR890001629 A KR 890001629A KR 1019880008888 A KR1019880008888 A KR 1019880008888A KR 880008888 A KR880008888 A KR 880008888A KR 890001629 A KR890001629 A KR 890001629A
- Authority
- KR
- South Korea
- Prior art keywords
- adsorbent according
- gas
- gas purifying
- molecular sieve
- kaolinite
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/12—Naturally occurring clays or bleaching earth
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
- B01J20/183—Physical conditioning without chemical treatment, e.g. drying, granulating, coating, irradiation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/042—Purification by adsorption on solids
- C01B2203/043—Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/047—Composition of the impurity the impurity being carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/048—Composition of the impurity the impurity being an organic compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Combustion & Propulsion (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dispersion Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Separation Of Gases By Adsorption (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Treating Waste Gases (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Silicon Compounds (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (12)
- 5A 제올라이트 유형의 분자체 및 적어도 75%의 카올리나이트 및 많아도 20%의 석영의 건조 중량 농도를 갖는 카올리나이트 계열의 점토질 리안트(liant)를 포함함을 특징으로 하는 하나 또는 다수의 정제될 기체보다 더 극성이거나 더 극성 가능한 불순물들을 미약한 흡착된 불순물의 회복율로 흡착함에 의한 기체 정제용의 분자체를 기재로 하는 기체 정제용 흡착제.
- 제1항에 있어서, 흡착제 중의 점토질 리안트의 중량 농도가 10~40%, 바람직하게는 10~30%임을 특징으로 하는 기체 정제용 흡착제.
- 제1 또는 2항에 있어서, 점토질 리안트가 최소한 80%의 카올리나이트의 건조 중량 농도를 가짐을 특징으로 하는 기체 정제용 흡착제.
- 제1,2 또는 3항에 있어서, 점토질 리안트가 최대한 12%의 석영의 건조 중량 농도를 가짐을 특징으로 하는 기체 정제용 흡착제.
- 제1 내지 4항 중 어느 한 항에 있어서, 점토질 리안트가 dr방 판형 형태하의 카올리 나이트로 주로 구성되며, 그 대부분은 500~5000Å의 외접원 평균 직경을 가짐을 특징으로 하는 기체 정제용 흡착제.
- 제1 내지 5항 중 어느 한 항에 있어서, 분자체는 적어도 65%의 2가 양이온 교환율을 가짐을 특징으로 하는 기체 정제용 흡착제.
- 제6항에 있어서, 분자체의 2가 양이온 교환율이 65~85%임을 특징으로 하는 기체 정제용 흡착제.
- 제1 내지 7항 중 어느 한 항에 있어서, 2가 양이온이 칼슘 양이온임을 특징으로 하는 기체 정제용 흡착제.
- 제1 내지 8항 중 어느 한 항에 있어서, 분자체는 0.15% 이하의 할로겐 농도를 가짐을 특징으로 하는 기체 정제용 흡착제.
- 흡착될 불순물의 미약한 회복율을 갖는 제1 내지 9항 중 어느 한 항에 따르는 흡착제를 사용하고, 상기 불순물이 질소, 산소, 탄소의 산화물, 메탄 또는 탄화수소류임을 특징으로 하는 기체 정제방법.
- 제10항에 있어서, 정제될 기체가 수소임을 특징으로 하는 기체 정제방법.
- 제10항에 있어서, 정제될 기체가 공기임을 특징으로 하는 기체 정제방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR87010109 | 1987-07-17 | ||
| FR10109 | 1987-07-17 | ||
| FR8710109A FR2618085A1 (fr) | 1987-07-17 | 1987-07-17 | Adsorbant pour la purification des gaz et procede de purification |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR890001629A true KR890001629A (ko) | 1989-03-28 |
| KR930005300B1 KR930005300B1 (ko) | 1993-06-17 |
Family
ID=9353243
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019880008888A KR930005300B1 (ko) | 1987-07-17 | 1988-07-16 | 기체 정제용 흡착제 및 정제방법 |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US5001098A (ko) |
| EP (1) | EP0300868B1 (ko) |
| JP (1) | JPH0620544B2 (ko) |
| KR (1) | KR930005300B1 (ko) |
| AT (1) | ATE68370T1 (ko) |
| BR (1) | BR8803576A (ko) |
| CA (1) | CA1324122C (ko) |
| DE (1) | DE3865570D1 (ko) |
| DK (1) | DK172923B1 (ko) |
| ES (1) | ES2027778T3 (ko) |
| FR (1) | FR2618085A1 (ko) |
| GR (1) | GR3003138T3 (ko) |
| IE (1) | IE59721B1 (ko) |
| MX (1) | MX169585B (ko) |
| PT (1) | PT88018B (ko) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5292360A (en) * | 1987-07-17 | 1994-03-08 | Rhone-Poulenc Chimie | 5A zeolite/kaolinite adsorbent for gas purification |
| SE507024C2 (sv) * | 1991-03-21 | 1998-03-16 | Rollen Jarl Erik | Passivt filter innefattande en självregenererande materialkomposition för upptagning av gasformiga ämnen |
| FR2675712B1 (fr) * | 1991-04-29 | 1994-08-26 | Ceca Sa | Perfectionnement aux procedes d'epuration des gaz par adsorption sur adsorbants zeolitiques. |
| RU2127631C1 (ru) * | 1994-07-26 | 1999-03-20 | Сека С.А. | Цеолитовый адсорбент для обессеривания газов и его применение для обработки газов, содержащих co2 |
| US6743745B2 (en) | 2002-01-22 | 2004-06-01 | Zeochem | Process for production of molecular sieve adsorbent blends |
| US20050119112A1 (en) * | 2002-01-22 | 2005-06-02 | Zeochem, Llc | Process for production of molecular sieve adsorbent blends |
| US7300899B2 (en) * | 2002-01-22 | 2007-11-27 | Zeochem, Llc | Lithium exchanged zeolite X adsorbent blends |
| FR2856049B1 (fr) * | 2003-06-11 | 2006-08-18 | Air Liquide | Purification d'un melange h2/co par catalyse des impuretes |
| US8205426B2 (en) * | 2006-07-31 | 2012-06-26 | General Electric Company | Method and apparatus for operating gas turbine engines |
| US8680344B2 (en) | 2011-01-25 | 2014-03-25 | Zeochem Llc | Molecular sieve adsorbent blends and uses thereof |
| KR101203258B1 (ko) | 2011-07-05 | 2012-11-21 | 한국화학연구원 | ＢａＸ형 제올라이트 성형체 및 그의 제조방법 |
| FR3006608B1 (fr) * | 2013-06-10 | 2021-01-01 | Ifp Energies Now | Adsorbant a base d'une zeolithe et d'une argile riche en silice et procede de purification de charges d'hydrocarbures contenant des molecules insaturees |
| US10099201B1 (en) | 2015-02-05 | 2018-10-16 | Zeochem Llc | Zeolite agglomerates with a halloysite clay binder |
| FR3040636B1 (fr) * | 2015-09-08 | 2019-11-01 | Arkema France | Utilisation de tamis moleculaires pour la decarbonatation de gaz naturel |
| CN109126692B (zh) * | 2018-09-14 | 2021-05-04 | 中国地质科学院郑州矿产综合利用研究所 | 一种高性能tc-5a分子筛吸附剂的制备方法 |
| CN112108116B (zh) * | 2020-09-21 | 2023-03-28 | 中国科学院新疆理化技术研究所 | 同时去除多种农残和抗生素成型炭复合材料的制备方法及测试装置 |
| CN115957717A (zh) * | 2022-12-20 | 2023-04-14 | 张家港安储科技有限公司 | 一种单块多孔无机材料吸附剂及其应用 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2973327A (en) * | 1955-07-01 | 1961-02-28 | Union Carbide Corp | Bonded molecular sieves |
| US3158579A (en) * | 1960-12-30 | 1964-11-24 | Universal Oil Prod Co | Molecular sieve sorbents bonded with ion-exchanged clay |
| BE613267A (ko) * | 1961-02-01 | |||
| US3219590A (en) * | 1961-08-01 | 1965-11-23 | Union Carbide Corp | Bonded molecular sieves |
| US3384602A (en) * | 1965-03-24 | 1968-05-21 | Engelhard Min & Chem | Bonded molecular sieve catalysts and preparation of the same |
| GB1139920A (en) * | 1966-05-31 | 1969-01-15 | Wolfen Filmfab Veb | Process for the production of porous zeolitic molecular sieve granulates |
| DE2329210C2 (de) | 1973-06-07 | 1986-04-30 | Bayer Ag, 5090 Leverkusen | Verfahren zur Abtrennung von polaren bzw. polarisierbaren Stoffen mittels Molekularsiebzeolithen |
| GB1478212A (en) * | 1975-01-07 | 1977-06-29 | Le Tekhnolog I Kholodil Promys | Process for the preparation of zeolite pellets |
| US4194892A (en) * | 1978-06-26 | 1980-03-25 | Union Carbide Corporation | Rapid pressure swing adsorption process with high enrichment factor |
-
1987
- 1987-07-17 FR FR8710109A patent/FR2618085A1/fr active Pending
-
1988
- 1988-07-06 EP EP88401759A patent/EP0300868B1/fr not_active Expired - Lifetime
- 1988-07-06 AT AT88401759T patent/ATE68370T1/de not_active IP Right Cessation
- 1988-07-06 ES ES198888401759T patent/ES2027778T3/es not_active Expired - Lifetime
- 1988-07-06 DE DE8888401759T patent/DE3865570D1/de not_active Expired - Lifetime
- 1988-07-14 IE IE215488A patent/IE59721B1/en not_active IP Right Cessation
- 1988-07-15 PT PT88018A patent/PT88018B/pt not_active IP Right Cessation
- 1988-07-15 JP JP63175262A patent/JPH0620544B2/ja not_active Expired - Fee Related
- 1988-07-15 CA CA000572158A patent/CA1324122C/fr not_active Expired - Lifetime
- 1988-07-15 MX MX026498A patent/MX169585B/es unknown
- 1988-07-15 DK DK198803981A patent/DK172923B1/da not_active IP Right Cessation
- 1988-07-15 BR BR8803576A patent/BR8803576A/pt not_active IP Right Cessation
- 1988-07-16 KR KR1019880008888A patent/KR930005300B1/ko not_active IP Right Cessation
- 1988-07-18 US US07/220,253 patent/US5001098A/en not_active Expired - Lifetime
-
1991
- 1991-11-14 GR GR91401749T patent/GR3003138T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP0300868B1 (fr) | 1991-10-16 |
| ES2027778T3 (es) | 1992-06-16 |
| EP0300868A1 (fr) | 1989-01-25 |
| IE59721B1 (en) | 1994-03-23 |
| DK172923B1 (da) | 1999-10-04 |
| GR3003138T3 (en) | 1993-02-17 |
| PT88018B (pt) | 1995-03-31 |
| BR8803576A (pt) | 1989-02-08 |
| FR2618085A1 (fr) | 1989-01-20 |
| JPH0620544B2 (ja) | 1994-03-23 |
| PT88018A (pt) | 1989-06-30 |
| DK398188D0 (da) | 1988-07-15 |
| CA1324122C (fr) | 1993-11-09 |
| ATE68370T1 (de) | 1991-11-15 |
| DE3865570D1 (de) | 1991-11-21 |
| JPH01104342A (ja) | 1989-04-21 |
| MX169585B (es) | 1993-07-13 |
| DK398188A (da) | 1989-01-18 |
| IE882154L (en) | 1989-01-17 |
| US5001098A (en) | 1991-03-19 |
| KR930005300B1 (ko) | 1993-06-17 |
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