KR880701703A - 4,6-디아미노-1,3-벤젠디올을 고순도로 제조하는 방법 - Google Patents
4,6-디아미노-1,3-벤젠디올을 고순도로 제조하는 방법Info
- Publication number
- KR880701703A KR880701703A KR1019880700741A KR880700741A KR880701703A KR 880701703 A KR880701703 A KR 880701703A KR 1019880700741 A KR1019880700741 A KR 1019880700741A KR 880700741 A KR880700741 A KR 880700741A KR 880701703 A KR880701703 A KR 880701703A
- Authority
- KR
- South Korea
- Prior art keywords
- benzenediol
- diamino
- dinitro
- ranges
- molar ratio
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
- C07C201/06—Preparation of nitro compounds
- C07C201/12—Preparation of nitro compounds by reactions not involving the formation of nitro groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
- C07C201/06—Preparation of nitro compounds
- C07C201/08—Preparation of nitro compounds by substitution of hydrogen atoms by nitro groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
- C07C205/07—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by halogen atoms
- C07C205/11—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by halogen atoms having nitro groups bound to carbon atoms of six-membered aromatic rings
- C07C205/12—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by halogen atoms having nitro groups bound to carbon atoms of six-membered aromatic rings the six-membered aromatic ring or a condensed ring system containing that ring being substituted by halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
- C07C205/13—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups
- C07C205/26—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups and being further substituted by halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
- C07C211/44—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
- C07C211/49—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring having at least two amino groups bound to the carbon skeleton
- C07C211/50—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring having at least two amino groups bound to the carbon skeleton with at least two amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
- C07C211/51—Phenylenediamines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
- C07C213/02—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reactions involving the formation of amino groups from compounds containing hydroxy groups or etherified or esterified hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/22—Polybenzoxazoles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Light Receiving Elements (AREA)
- Paper (AREA)
- Eye Examination Apparatus (AREA)
- Apparatuses For Bulk Treatment Of Fruits And Vegetables And Apparatuses For Preparing Feeds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (8)
- (a)1,2,3-트리할로벤젠을 1,2,3-트리할로-4,6-디니트로벤젠이 생성되는 반응 조건하에서 니트로화제 및 산과 접촉시키고 :(b) 생성된 1,2,3-트리할로-4,6-디니트로벤젠을 4,6-디니트로-2-할로-1,3-벤젠디올이 생성되는 반응 조건하에서 알칸올 및 염기와 접촉시킨후 (c)생성된 4,6-디니트로-2-할로-1,3-벤젠디올을 4,6-디아미노-1,3-벤젠디올이 생성되는 반응조건하에, 용매 및 촉매의 존재하에서 수소화제와 접촉시키는 단계로 이루어짐을 특징으로 하여, 고순도의 4,6-디아미노-1,3-벤젠디올을 제조하는 방법
- 제1항에 있어서, 1,2,3-트리할로벤젠이 1,2,3-트리클로로벤젠인 방법
- 제2항에 있어서, 니트로화제가 질산이고, 단계(a)에서의 산이 황산이며, 알칸올이 메탄올이고, 염기가 수산화나트륨이며, 수소화제가 수소이고 촉매가 탄소상-팔라듐 수소화 촉매인 방법
- 4,6-디아미노-2,3-벤젠디올이 99중량%이상의 순도로 회수되는 방법
- 제1항에 있어서, 4,6-디아미노벤젠디올이 99.9중량% 이상의 순도로 회수되는 방법
- 제3항에 있어서, 트리클로로벤젠에 대한 진한 질산의 몰비가 약 2.1:1내지 약 2.5:1의 범위이고, 트리클로로벤젠에 대한 황산의 몰비가 약 11:1 내지 약 15:1이며 단계(a)에서의 온도가 약 15℃내지 약 80℃범위인 방법
- 제6항에 있어서, 트리클로로디니트로벤젠에 대한 에탄올의 몰비가 약 1:1내지 약 15:1범위이고 단계(b)에서의 온도가 약 25℃내지 약 85℃범위인 방법
- 제7항에 있어서 4,6-디니트로-2-클로로-2,3-벤젠디올에 대한 수소가스의 몰비가 약7내지 약 2000의 범위이고, 4,6-디니트로-2-클로로-1,3-벤젠디올에 대한 수소화 촉매의 몰당량비가 약 0.01:1내지 약 0.5:1이며 단계(C)에 사용된 온도가 약 40℃내지 약 50℃인 방법※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US925358 | 1986-10-30 | ||
US06/925,358 US4766244A (en) | 1986-10-30 | 1986-10-30 | High purity process for the preparation of 4,6-diamino-1,3-benzenediol |
PCT/US1987/002800 WO1988003131A1 (en) | 1986-10-30 | 1987-10-28 | High purity process for the preparation of 4,6-diamino-1,3-benzenediol |
Publications (2)
Publication Number | Publication Date |
---|---|
KR880701703A true KR880701703A (ko) | 1988-11-04 |
KR910002874B1 KR910002874B1 (ko) | 1991-05-09 |
Family
ID=25451617
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019880700741A KR910002874B1 (ko) | 1986-10-30 | 1987-10-28 | 4,6-디아미노-1,3-벤젠디올을 고순도로 제조하는 방법 |
Country Status (18)
Country | Link |
---|---|
US (1) | US4766244A (ko) |
EP (2) | EP0266222B1 (ko) |
JP (1) | JP2543928B2 (ko) |
KR (1) | KR910002874B1 (ko) |
CN (1) | CN1018181B (ko) |
AT (2) | ATE65491T1 (ko) |
AU (1) | AU606113B2 (ko) |
BR (1) | BR8707856A (ko) |
CA (1) | CA1281742C (ko) |
DE (2) | DE3789972T2 (ko) |
DK (1) | DK346488A (ko) |
ES (2) | ES2054198T3 (ko) |
FI (1) | FI891181A0 (ko) |
GR (1) | GR3002384T3 (ko) |
IE (2) | IE61741B1 (ko) |
NO (1) | NO168171C (ko) |
PT (1) | PT86012B (ko) |
WO (1) | WO1988003131A1 (ko) |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4740621A (en) * | 1985-11-01 | 1988-04-26 | First Chemical Corporation | Co-production of an aromatic monoamine and an aromatic diamine directly from benzene or a benzene derivative through controlled nitration |
LU86905A1 (fr) * | 1987-05-29 | 1989-01-19 | Oreal | Nouvelles metaphenylenediamines,leur procede de preparation,composes intermediaires et utilisation de ces metaphenylenediamines en tant que coupleurs pour la teinture d'oxydation des fibres keratiniques et en particulier des cheveux humains |
US4912246A (en) * | 1987-10-19 | 1990-03-27 | The Dow Chemical Company | 1,3-bis(alkylcarbonato)-nitrobenzenes |
US4982001A (en) * | 1987-10-19 | 1991-01-01 | The Dow Chemical Company | Process for the preparation of amino-1,3-benzenediol |
US5138020A (en) * | 1989-04-21 | 1992-08-11 | The Dow Chemical Company | Phosphate salts of monomers for pbz and their use in preparing pbz polymers |
US5001265A (en) * | 1989-07-28 | 1991-03-19 | The Dow Chemical Company | Aqueous reduction process for halo-nitro-phenols |
US5124432A (en) * | 1989-08-31 | 1992-06-23 | The Dow Chemical Company | Branched polybenzazole polymer and method of preparation |
US5218076A (en) * | 1989-08-31 | 1993-06-08 | The Dow Chemical Company | Branch polybenzazole polymer and method of preparation |
US5001279A (en) * | 1989-11-17 | 1991-03-19 | The Dow Chemical Company | Aqueous synthesis of 2-halo-4,6-dinitroresorcinol and 4,6-diaminoresorcinol |
US5276128A (en) * | 1991-10-22 | 1994-01-04 | The Dow Chemical Company | Salts of polybenzazole monomers and their use |
US5360932A (en) * | 1992-03-23 | 1994-11-01 | The Dow Chemical Company | Process for reducing aromatic halo-dinitro-diols in the presence of hydrogen halide |
US5422416A (en) * | 1993-06-30 | 1995-06-06 | The Dow Chemical Company | Process for the synthesis of polybenzazole polymers |
US5371291A (en) * | 1993-10-15 | 1994-12-06 | The Dow Chemical Company | Synthesis of 4,6-diaminoresorcinol |
US5410083A (en) * | 1993-10-15 | 1995-04-25 | The Dow Chemical Company | Synthesis of diaminoresorcinal from resorcinol |
US5414130A (en) * | 1993-12-23 | 1995-05-09 | The Dow Chemical Company | Process for the preparation of diaminoresorcinol |
US5463129A (en) * | 1993-12-23 | 1995-10-31 | The Dow Chemical Company | Cleaving arylethers |
US5399768A (en) * | 1993-12-23 | 1995-03-21 | The Dow Chemical Company | Process for the preparation of diaminoresorcinol |
US5453542A (en) * | 1994-02-24 | 1995-09-26 | The Dow Chemical Company | Preparation of 4,6-diaminoresorcinol through a bisazoarylresorcinol intermediate |
EP0710644B1 (de) * | 1994-11-03 | 1997-09-24 | Bayer Ag | Verfahren zur Herstellung von 4,6-Diaminoresorcin |
DE69807990T2 (de) * | 1997-06-10 | 2003-04-30 | Toyo Boseki | Verfahren zur Stabilisierung von 4,6-Diaminoresorcin und dessen Salzen |
RU2564844C1 (ru) | 2011-09-23 | 2015-10-10 | Новозимс Биоаг А/С | Хитоолигосахариды и способы их применения для усиления роста растений |
CN106554287A (zh) * | 2015-09-29 | 2017-04-05 | 中国石油化工集团公司 | 一种在4,6-二氨基盐酸盐中定量加入氯化亚锡的方法 |
CN108191669A (zh) * | 2017-12-29 | 2018-06-22 | 东南大学 | 一种1,2,4,5-四氨基苯的合成方法及应用 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB741479A (en) * | 1951-08-31 | 1955-12-07 | Ethyl Corp | Improvements in or relating to trichlorodinitrobenzene |
US3052601A (en) * | 1956-07-10 | 1962-09-04 | Diamond Alkali Co | Phenolic lamprey larvicides |
JPS4827300B1 (ko) * | 1968-06-18 | 1973-08-21 | ||
JPS5132319B2 (ko) * | 1971-07-06 | 1976-09-11 | ||
DE2435818C3 (de) * | 1974-07-25 | 1982-02-25 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung aromatischer Diamine |
-
1986
- 1986-10-30 US US06/925,358 patent/US4766244A/en not_active Ceased
-
1987
- 1987-10-19 CA CA000549590A patent/CA1281742C/en not_active Expired - Lifetime
- 1987-10-28 BR BR8707856A patent/BR8707856A/pt not_active Application Discontinuation
- 1987-10-28 KR KR1019880700741A patent/KR910002874B1/ko not_active IP Right Cessation
- 1987-10-28 WO PCT/US1987/002800 patent/WO1988003131A1/en active Application Filing
- 1987-10-28 PT PT86012A patent/PT86012B/pt not_active IP Right Cessation
- 1987-10-28 JP JP62507129A patent/JP2543928B2/ja not_active Expired - Lifetime
- 1987-10-28 AU AU83230/87A patent/AU606113B2/en not_active Ceased
- 1987-10-29 IE IE291087A patent/IE61741B1/en not_active IP Right Cessation
- 1987-10-29 IE IE940344A patent/IE69029B1/en unknown
- 1987-10-30 ES ES90122352T patent/ES2054198T3/es not_active Expired - Lifetime
- 1987-10-30 DE DE3789972T patent/DE3789972T2/de not_active Expired - Lifetime
- 1987-10-30 ES ES87309645T patent/ES2023914B3/es not_active Expired - Lifetime
- 1987-10-30 CN CN87107214A patent/CN1018181B/zh not_active Expired
- 1987-10-30 EP EP87309645A patent/EP0266222B1/en not_active Expired - Lifetime
- 1987-10-30 AT AT87309645T patent/ATE65491T1/de active
- 1987-10-30 DE DE8787309645T patent/DE3771650D1/de not_active Expired - Lifetime
- 1987-10-30 EP EP90122352A patent/EP0429083B1/en not_active Expired - Lifetime
- 1987-10-30 AT AT90122352T patent/ATE106382T1/de active
-
1988
- 1988-06-23 DK DK346488A patent/DK346488A/da not_active Application Discontinuation
- 1988-06-29 NO NO882885A patent/NO168171C/no unknown
-
1989
- 1989-03-13 FI FI891181A patent/FI891181A0/fi not_active Application Discontinuation
-
1991
- 1991-07-25 GR GR91401079T patent/GR3002384T3/el unknown
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