KR880012694A - 폴리올레핀 조성물 - Google Patents

폴리올레핀 조성물 Download PDF

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KR880012694A
KR880012694A KR1019880004425A KR880004425A KR880012694A KR 880012694 A KR880012694 A KR 880012694A KR 1019880004425 A KR1019880004425 A KR 1019880004425A KR 880004425 A KR880004425 A KR 880004425A KR 880012694 A KR880012694 A KR 880012694A
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weight
parts
polyolefin composition
compound
random copolymer
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KR1019880004425A
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KR910005690B1 (ko
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노부오 고도오
히로히사 이시이
히로가즈 나까지마
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노기 사다오
짓소 가부시끼가이샤
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Priority claimed from JP62096640A external-priority patent/JPS63260944A/ja
Priority claimed from JP62096639A external-priority patent/JPS63260943A/ja
Priority claimed from JP62097908A external-priority patent/JPS63264650A/ja
Application filed by 노기 사다오, 짓소 가부시끼가이샤 filed Critical 노기 사다오
Publication of KR880012694A publication Critical patent/KR880012694A/ko
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/527—Cyclic esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/02—Ziegler natta catalyst

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

내용 없음

Description

폴리올레핀 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. (A) 결정성-올레핀-프로필렌 랜덤공중합체 65 내지 98중량부, (B) 고밀도 에틸렌계 중합체 1 내지 15중량부 및 (C) 비결정성 에틸렌-프로필렌 랜덤공중합체 또는 비결정성 에틸렌-프로필렌-비공액디엔랜덤공중합체 1 내지 20중량부의 각 성분으로 부터 구성되고, 성분(A) 내지 (C)의 합계 100중량부에 대하여, 다음 일반식 [I]의 포스페이트계 화합물(이하, 화합물 A라 한다)을 0.01 내지 1중량부 배합하여 이루어지는 폴리올레핀 조성물.
    상기식에서, R1은 황 또는 탄소수 1 내지 4의 알킬리덴기이고, R2및 R3은 각각 수소 또는 탄소수 1 내지 8의 같거나 서로 다른 알킬기이며, M은 1가 내지 3가의 금속원자이고, m은 0 또는 1이며, n은 1 내지 3의 정수이다.
  2. 제1항에 있어서, R1이 메틸렌기이고, R2및 R3의 알킬기가 t-부틸기인 폴리올레핀 조성물.
  3. 제1항에 있어서, 화합물 A로서 나트륨-2,2`-메틸렌-비스-(4,6-디t-부틸페닐)포스페이트를 배합하여 이루어지는 폴리올레핀 조성물.
  4. (A) 결정성-올레핀-프로필렌 랜덤공중합체 35 내지 97중량부, (D) 프로필렌 단독중합체 1 내지 30중량부, (B) 고밀도 에틸렌계 중합체 1 내지 15중량부 및 (C) 비결정성 에틸렌-프로필렌 랜덤공중합체 또는 비결정성 에틸렌-프로필렌-비공액디엔랜덤공중합체 1 내지 20중량부의 각 성분으로 구성되고, 성분(A) 내지 (D)의 합계 100중량부에 대하여, 다음 일반식 [I]의 포스페이트계 화합물(이하, 화합물 A라 한다)을 0.01 내지 1중량부 배합하여 이루어지는 폴리올레핀 조성물.
    상기식에서, R1은 황 또는 탄소수 1 내지 4의 알킬리덴기이고, R2및 R3은 각각 수소 또는 탄소수 1 내지 8의 같거나 서로 다른 알킬기이며, M은 1가 내지 3가의 금속원자이고, m은 0 또는 1이며, n은 1 내지 3의 정수이다.
  5. 제4항에 있어서, 일반식(I)에서의 R1이 메틸렌기이고, R2및 R3이 t-부틸기인 폴리올레핀 조성물.
  6. 제4항에 있어서, 화합물 A로서 나트륨-2,2`-메틸렌-비스-(4,6-디t-부틸페닐)포스페이트를 배합하여 이루어지는 폴리올레핀 조성물.
  7. (A) 결정성-올레핀-프로필렌 랜덤공중합체 35 내지 97중량부, (E) 아이소텍틱펜닥드 분율(P)과 멜트플로우레이트(MFR; 230℃에서 하중 2.16kg을 가할 경우 10분간의 용융수지의 토출량)의 관계가 1.00P0.015log MFR+0.955인 결정성 프로필렌 단독중합체 1 내지 30중량부, (B)고밀도 에틸렌계 중합체 1 내지 15중량부 및 (C) 비결정성 에틸렌 프로필렌 랜덤공중합체 또는 비결정성 에틸렌-프로필렌-비공액디엔 랜덤공중합체 1 내지 20중량부의 각 성분으로 구성되고, 성분(A), (B), (C), (E)의 합계 100중량부에 대하여, 다음 일반식 [I]의 포스페이트계 화합물(이하, 화합물 A라 한다)을 0.01 내지 1중량부 배합하여 이루어지는 폴리올레핀 조성물.
    상기식에서, R1은 황 또는 탄소수 1 내지 4의 알킬리덴기이고, R2및 R3은 각각 수소 또는 탄소수 1 내지 8의 같거나 서로 다른 알킬기이며, M은 1 내지 3가의 금속원자이고, m은 0 또는 1이며, n은 1 내지 3의 정수이다.
  8. 제7항에 있어서, 일반식(I)에서의 R1이 메틸렌기이고, R2및 R3이 t-부틸기인 폴리올레핀 조성물.
  9. 제7항에 있어서, 화합물 A로서 나트륨-2,2`-메틸렌-비스-(4,6-디t-부틸페닐)포스페이트를 배합하여 이루어지는 폴리올레핀 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880004425A 1987-04-20 1988-04-19 폴리올레핀 조성물 KR910005690B1 (ko)

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
JP(?)62-96640 1987-04-20
JP(?)62-96639 1987-04-20
JP62-96639 1987-04-20
JP62-96640 1987-04-20
JP62096640A JPS63260944A (ja) 1987-04-20 1987-04-20 ポリオレフイン組成物
JP62096639A JPS63260943A (ja) 1987-04-20 1987-04-20 ポリオレフイン組成物
JP62-97908 1987-04-21
JP62097908A JPS63264650A (ja) 1987-04-21 1987-04-21 ポリオレフイン組成物
JP(?)62-97908 1987-04-21

Publications (2)

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KR880012694A true KR880012694A (ko) 1988-11-28
KR910005690B1 KR910005690B1 (ko) 1991-08-02

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US (1) US4820772A (ko)
KR (1) KR910005690B1 (ko)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2812972B2 (ja) * 1989-02-02 1998-10-22 出光興産株式会社 スチレン系樹脂組成物と成形品の製造方法
JPH0343437A (ja) * 1989-07-11 1991-02-25 Mitsui Toatsu Chem Inc ポリプロピレン樹脂組成物
DE69014028T2 (de) * 1989-08-28 1995-05-04 Chisso Corp Kristalline Polyolefinmischung.
GB2261667A (en) * 1991-11-20 1993-05-26 Sandoz Ltd Stabilized polymeric compositions
JP3046428B2 (ja) * 1991-12-05 2000-05-29 旭電化工業株式会社 結晶性合成樹脂組成物
US5378747A (en) * 1992-12-28 1995-01-03 Phillips Petroleum Company Ethylene polymer compositions
JP3270056B2 (ja) * 1995-12-01 2002-04-02 チッソ株式会社 樹脂成形体
DE19801050A1 (de) * 1998-01-14 1999-07-15 Bayer Ag Polycarbonat-ABS-Formmassen
CA2299390A1 (en) * 1998-06-05 1999-12-16 Japan Polychem Corporation Propylene block copolymer and propylene resin composition
US6784226B2 (en) 1999-07-28 2004-08-31 Chi Mei Corporation Process for producing a styrenic resin composition
JP2003531622A (ja) * 2000-05-03 2003-10-28 エクスプレッシブ コンストラクツ，インコーポレイテッド 組み換えタンパク質安定性および可溶性を改善する方法
PT1327648E (pt) * 2000-09-12 2007-08-31 Toyo Boseki Catalizador de polimerização para poliéster, poliéster produzido com o catalizador e processo para a produção do poliéster
DE10296586T5 (de) * 2001-03-29 2004-04-22 Idemitsu Petrochemical Co., Ltd. Verbundharz auf Polyolefin-Basis, Verfahren zu seiner Herstellung, Katalysator für die Polymerisation von Vinylverbindungen und Verfahren zur Polymerisation von Vinylverbindungen unter Verwendung desselben
EP1527106A2 (en) * 2002-08-01 2005-05-04 Basell Poliolefine Italia S.P.A. Highly stereoregular polypropylene with improved properties
CN101389702A (zh) * 2006-02-21 2009-03-18 西巴控股有限公司 芳族磷酸酯阻燃剂组合物
CA2832700A1 (en) 2011-04-26 2012-11-01 Basf Se Additives for high-flow polymers

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US3268499A (en) * 1965-09-10 1966-08-23 Shell Oil Co Polymer crystallization method
US3517086A (en) * 1966-01-31 1970-06-23 Sumitomo Chemical Co Nucleated blend of polypropylene,polyethylene,and ethylene propylene copolymer
JPS581736A (ja) * 1981-06-25 1983-01-07 Adeka Argus Chem Co Ltd ポリオレフイン系樹脂組成物
GB2114581B (en) * 1981-12-17 1985-08-14 Chisso Corp Ziegler catalyst for producing polypropylene
JPS6028411A (ja) * 1983-07-26 1985-02-13 Chisso Corp 高剛性エチレン・プロピレン共重合体の製造方法
JPS61103944A (ja) * 1984-10-29 1986-05-22 Mitsubishi Yuka Badische Kk ポリプロピレン発泡体粒子

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KR910005690B1 (ko) 1991-08-02

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