KR880010020A - 폴리에스테르아미드, 폴리에테르에스테르아미드 및 그의 제조방법 - Google Patents

폴리에스테르아미드, 폴리에테르에스테르아미드 및 그의 제조방법 Download PDF

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KR880010020A
KR880010020A KR1019880002023A KR880002023A KR880010020A KR 880010020 A KR880010020 A KR 880010020A KR 1019880002023 A KR1019880002023 A KR 1019880002023A KR 880002023 A KR880002023 A KR 880002023A KR 880010020 A KR880010020 A KR 880010020A
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polyesteramide
polyetheresteramide
general formula
chain
dicarboxylic acid
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KR1019880002023A
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KR930005139B1 (ko
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다니엘 퀴젱
디디에 주다
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끌로드 푸아레
소시에떼 아토샹
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/44—Polyester-amides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyamides (AREA)
  • Measuring Or Testing Involving Enzymes Or Micro-Organisms (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Developing Agents For Electrophotography (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

내용 없음.

Description

폴리에스테르아미드, 폴리에테르에스테르아미드 및 그의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (13)

  1. 하기일반식：
    (상기 식중, A는 폴리아미드 시퀀스를 나타내고, R3및 R4는 수소를 나타내거나 또는 둘중 하나만이 수소를 나타내고, 다른 것은 1 내지 24개, 바람직하게는 한 개의 탄소 원자를 함유하는 알킬기를 나타내고, R1은 1 내지 24개의 탄소 원자를 함유하는 직쇄 또는 측쇄, 포화 또는 불포화 알킬기이거나 또는 방향족 또는 지환족기이고, Y+Z는 2 내지 100이다(각각은 1이상이다). n은 고분자 사슬을 구성하는 반복 단위의 수를 나타낸다)으로 나타내는 폴리에스테르아미드 및 폴리에테르에스테르아미드.
  2. 제1항에 있어서, R3또는 R4가 -CH3를 나타내는 폴리에스테르아미드 및 폴리에테르에스테르아미드.
  3. 제1또는 2항에 있어서, n이 1내지 75인 폴리에스테르아미드 및 폴리에테르에스테르아미드.
  4. 제1또는 2항에 있어서, 디카르복실산 폴리아미드 시퀀스가 하기 일반식：
    [상기 식중, R5는 락탐 및/또는 구조식(식중, R7및 R8은 각각 이산 및 디아민의 탄화수소 잔기이다.)의 아미노산을 구성하는 탄화수소 사슬이고, R6는 유기이산의 나머지를 나타내며, p 및 q는 같거나 다르고, 그들중 하나가 0일 수 있고, 디카르복실산 폴리아미드 시퀀스의 고분자 사슬을 구성하는 되풀이 되는 단위의 반복된 수를 나타낸다]을 갖는 폴리에스테르아미드 및 폴리에테르에스테르아미드.
  5. 제4항에 있어서, R5의 탄화수소화 사슬이 4내지 14개의 탄소원자를 함유하는 폴리에스테르아미드 및 폴리에테르에스테르아미드.
  6. 제4항에 있어서, R6이 지방족, 지환족 또는 방향족기인 폴리에스테르아미드 및 폴리에테르에스테르아미드.
  7. 제4항에 있어서, 디카르복실산 폴리아미드 시퀀스의 평균 분자량이 300내지 15000이고, p+q는 1 내지 100인 폴리에스테르아미드 및 폴리에테르에스테르아미드.
  8. 제1또는 2항에 있어서, 하기 일반식：
    의 기가 하기 일반식：
    의 전체기의 2 내지 90중량%의 비율임을 나타내는 폴리에스테르아미드 및 폴리에테르에스테르아미드.
  9. 산 작용기가 사슬의 말단에 위치한 디카르복실산 폴리아미드와 α, ω디올이 하기 일반식：
    [상기 식중, R3및 R4는 수소를 나타내거나 또는 둘중 하나만이 수소를 나타내고, 다른 것은 1 내지 24개, 바람직하게는 한개의 탄소원자를 함유하는 알킬기를 나타내고, R1은 1 내지 24개의 탄소원자를 함유하는 직쇄 또는 측쇄, 포화 또는 불포화 알킬기이거나 또는 방향족 또는 지환족기이고, Y+Z는 2 내지 100이다(각각은 1이상이다)]의 3차 아민 작용기를 사슬에 함유하는 디베타히드록시화 3차 아민 또는 폴리옥시알킬렌글리콜인 α ω디올과 반응시킴을 특징으로 하는 폴리에스테르아미드 및 폴리에테르에스테르아미드의 제조방법.
  10. 제9항에 있어서, 98내지 10중량%의 디카르복실산 폴리아미드와 2내지 90중량%의 α, ω디올을 반응시키는 방법.
  11. 제9항에 있어서, 실질적으로 폴리아미드의 카르복실산기와 분자마다 3차 아민 작용기를 함유하는 α, ω디올의 히드록실기 사이의 화학량론을 고려하여 시약을 반응시키는 방법.
  12. 제9항에 있어서, 촉매의 존재하에 용융 상태에서 시약을 혼합하여 중축합화하는 방법.
  13. 제9항에 있어서, 촉매가 M(OQ)4(식중, M은 티타늄, 지르코늄 또는 하프늄이고, Q는 1내지 24개의 탄소원자를 갖는 직쇄 또는 측쇄 알킬기이다)의 일반식을 갖는 방법.
    ※참고사항:최초출원 내용에 의하여 공개하는 것임.
KR1019880002023A 1987-02-26 1988-02-26 폴리에스테르아미드, 폴리에테르 에스테르 아미드 및 그의 제조방법 KR930005139B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR8702569 1987-02-26
FR872569 1987-02-26
FR8702569A FR2611727B1 (fr) 1987-02-26 1987-02-26 Polyesteramides et polyetheresteramides - leur procede de fabrication

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KR880010020A true KR880010020A (ko) 1988-10-06
KR930005139B1 KR930005139B1 (ko) 1993-06-16

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US (1) US4839441A (ko)
EP (1) EP0281461B1 (ko)
JP (1) JPS63227626A (ko)
KR (1) KR930005139B1 (ko)
AT (1) ATE88486T1 (ko)
CA (1) CA1311079C (ko)
DE (1) DE3880352T2 (ko)
DK (1) DK97988A (ko)
ES (1) ES2054838T3 (ko)
FI (1) FI880893A (ko)
FR (1) FR2611727B1 (ko)
NO (1) NO169593C (ko)

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DK97988D0 (da) 1988-02-25
FI880893A0 (fi) 1988-02-25
ES2054838T3 (es) 1994-08-16
NO169593B (no) 1992-04-06
NO169593C (no) 1992-07-15
FR2611727A1 (fr) 1988-09-09
KR930005139B1 (ko) 1993-06-16
JPS63227626A (ja) 1988-09-21
ATE88486T1 (de) 1993-05-15
FI880893A (fi) 1988-08-27
DE3880352T2 (de) 1993-09-30
US4839441A (en) 1989-06-13
EP0281461A1 (fr) 1988-09-07
CA1311079C (fr) 1992-12-01
EP0281461B1 (fr) 1993-04-21
DK97988A (da) 1988-08-27
DE3880352D1 (en) 1993-05-27
NO880147D0 (no) 1988-01-14
FR2611727B1 (fr) 1989-06-16
NO880147L (no) 1988-08-29

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