KR880000496B1 - 탄소섬유 제조용 유제 - Google Patents

탄소섬유 제조용 유제 Download PDF

Info

Publication number
KR880000496B1
KR880000496B1 KR1019850005525A KR850005525A KR880000496B1 KR 880000496 B1 KR880000496 B1 KR 880000496B1 KR 1019850005525 A KR1019850005525 A KR 1019850005525A KR 850005525 A KR850005525 A KR 850005525A KR 880000496 B1 KR880000496 B1 KR 880000496B1
Authority
KR
South Korea
Prior art keywords
group
amino
organopolysiloxane
modified polysiloxane
general formula
Prior art date
Application number
KR1019850005525A
Other languages
English (en)
Other versions
KR860002614A (ko
Inventor
쓰가사 후지이
이소베쥰
Original Assignee
다께모도유시 가부시끼가이샤
다께모도 다이이찌
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 다께모도유시 가부시끼가이샤, 다께모도 다이이찌 filed Critical 다께모도유시 가부시끼가이샤
Publication of KR860002614A publication Critical patent/KR860002614A/ko
Application granted granted Critical
Publication of KR880000496B1 publication Critical patent/KR880000496B1/ko

Links

Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • D01F9/14—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
    • D01F9/20—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products
    • D01F9/21—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F9/22—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyacrylonitriles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/12—Polysiloxanes containing silicon bound to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/26—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42—Block-or graft-polymers containing polysiloxane sequences
    • C08G77/46—Block-or graft-polymers containing polysiloxane sequences containing polyether sequences
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/50—Lubricating compositions characterised by the base-material being a macromolecular compound containing silicon
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/02—Unspecified siloxanes; Silicones
    • C10M2229/025—Unspecified siloxanes; Silicones used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/0405—Siloxanes with specific structure used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
    • C10M2229/0415—Siloxanes with specific structure containing aliphatic substituents used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/042—Siloxanes with specific structure containing aromatic substituents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/042—Siloxanes with specific structure containing aromatic substituents
    • C10M2229/0425—Siloxanes with specific structure containing aromatic substituents used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/043—Siloxanes with specific structure containing carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/043—Siloxanes with specific structure containing carbon-to-carbon double bonds
    • C10M2229/0435—Siloxanes with specific structure containing carbon-to-carbon double bonds used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/044—Siloxanes with specific structure containing silicon-to-hydrogen bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/044—Siloxanes with specific structure containing silicon-to-hydrogen bonds
    • C10M2229/0445—Siloxanes with specific structure containing silicon-to-hydrogen bonds used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/045—Siloxanes with specific structure containing silicon-to-hydroxyl bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/045—Siloxanes with specific structure containing silicon-to-hydroxyl bonds
    • C10M2229/0455—Siloxanes with specific structure containing silicon-to-hydroxyl bonds used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/046—Siloxanes with specific structure containing silicon-oxygen-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/046—Siloxanes with specific structure containing silicon-oxygen-carbon bonds
    • C10M2229/0465—Siloxanes with specific structure containing silicon-oxygen-carbon bonds used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/047—Siloxanes with specific structure containing alkylene oxide groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/047—Siloxanes with specific structure containing alkylene oxide groups
    • C10M2229/0475—Siloxanes with specific structure containing alkylene oxide groups used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/048—Siloxanes with specific structure containing carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/048—Siloxanes with specific structure containing carboxyl groups
    • C10M2229/0485—Siloxanes with specific structure containing carboxyl groups used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
    • C10M2229/051—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing halogen
    • C10M2229/0515—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing halogen used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
    • C10M2229/052—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
    • C10M2229/052—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing nitrogen
    • C10M2229/0525—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing nitrogen used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
    • C10M2229/053—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing sulfur
    • C10M2229/0535—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing sulfur used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
    • C10M2229/054—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing phosphorus
    • C10M2229/0545—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing phosphorus used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/30—Refrigerators lubricants or compressors lubricants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/32—Wires, ropes or cables lubricants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/34—Lubricating-sealants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/36—Release agents or mold release agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/38—Conveyors or chain belts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/40—Generators or electric motors in oil or gas winning field
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/42—Flashing oils or marking oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/44—Super vacuum or supercritical use
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/50—Medical uses
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/40—Fibres of carbon
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Textile Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Inorganic Fibers (AREA)
  • Silicon Polymers (AREA)

Abstract

내용 없음.

Description

탄소섬유 제조용 유제
본 발명은 탄소섬유 제조용 유제에 관한 것이며, 더욱 상세하게는 탄소섬유의 제조에 있어서, 내염화(또는 불융화, 이하 내염화라 칭함)공정전에 전구체(前驅體)로서 사용하는 아크릴게 섬유나, 피치계 섬유(이하 이들을 프리커서라 함)에 부여함으로써 이 프리커서에 우수한 분섬성 내지 공정 통과성을 부여함과 동시에, 내염화 공정이후에 있어서의 유착을 방지하여 우수한 물성의 탄소섬유를 제조할 수 있는 유제에 관한 것이다.
일반적으로 탄소섬유는 프리커서를 산화성 분위기하에서 200℃내지 300℃로 가열 소성하는 내염화 공정에 의해 내염화 섬유로 만든 후, 불활성 분위기하에서 700℃ 이상의 높은 온도로 탄소화 시키는 탄소와 공정을 거쳐 제조되는 데, 이때 내염화 공정전에, 보통은 프리커서를 제조하는 공정에서 유제를 부여한다. 그리고 이 유제에는 평활성, 대전방지성, 집속성등의 일반적 제기능외에 전술한 바와 같은 탄소섬유의 제조조건에 대응하는 성능상 특히 섬유의 분섬성이 우수하고, 또 융착을 방지하는 기능이 중요하다.
위와 같은 유형의 유제로서 종래에는 일반적으로 포스페이트의 알칼리금속염, 각종 양이온 활성제, 폴리옥시알킬렌 에테르 등이 주로 사용되고 있으나, 이들은 대전방지성, 집속성, 평활성의 점에서는 일응 성능을 가지고 있으나, 그 본래의 성질로 인한 분해에 의해서 분섬성이 나쁜 문제점이 있고, 또 내염화 공정에서 타르를 생성하거나 혹은 가열초기에서 그 대ㄷ부분이 휘산하고 섬유간에 융착이 일어나는 문제점이 있다.
그래서 종래 이와 같은 유제의 개량품으로, 디메틸 폴리실록산, 페닐 메틸 폴리시록산, 에폭시 폴리실록산, 폴리에테르 폴리실록산, 아미노 폴리실록산 등 각종 실리콘계 유제가 제안되고 있다(참조 : 일본국 특공소 51-12739, 특공소 52-24136, 특공소 52-148227 등).
그러나 이들 실리콘계 유제에도 각각 다음과 같은 문제점이 있다. 즉 디메틸 폴리실록산이나 페닐메틸 폴리실록산의 경우 열적으로는 양호하지만 그 분자내에 극성기가 포함되어 있지 않아 프리커서에 대한 배향성(균일 부착성, 이하 같음)이 불충분하기 때문이라고 생각 되는데 프리커서로서의 분섬성 그리고 내염화 공정시 유착 방지기능이 적고, 또 비극성이기 때문에 정전기에 의한 모우가 일어나고, 사절(
Figure kpo00001
切)과 같은 문제를 일으키기 쉽다.
에폭시 폴리실록산의 경우는 그 분자내에폭시 그룹의 개환중합 등에 의하여 섬유-섬유간을 고착시키고, 또 그들 자신이 타르화 하기 때문에 내염화 공정에서의 융착 방지기능이 전혀 없고, 오히려 해가 된다.
폴리에테르 폴리실록산에 있어서는 그 분자내의 에테르 결합이 열적으로 약하기 때문에 내염과 공정에 있어서 대부분이 열분해, 휘산되어 융착 방지기능을 수행할 수 없게 되고, 또 열분해시의 발열이 섬유자체의 이상 반응을 유인 한다.
그리고 아미노 폴리실록산의 경우 이상 설명한 종래의 다른 실리콘계 유제에 바하면 양호한 성능을 지녔으나, 열적으로는 아직 약한면을 가지고 있고, 분섬성 및 융착 방지기능이 아직도 미흡하고, 또 공업적인 생산면에서 볼때 공정중 각종 가이드나 로울러등에의 검업에 의한 모우나 사절등이 발생하는 문제점도 있다.
본 발명은 상술한 바와 같은 종래의 문제점을 해결하는 것으로서 프리커서의 제조 및 내염화 공정을 포함한 그 이후의 공정에 있어서 공정 통과성 및 분섬성이 우수하고 융착등의 장애가 없는 따라서 고품질의 탄소섬유를 안정적으로 제조할 수 있는 유제를 제공하는 것이다. 그리하여 본 발명자들은 이상의 관점에서 예의 연구한 결과 특정한 오르가노 폴리실록산과 아미노-변성 폴리실록산으로 이루어진 유제가 바람직함을 발견하고 본 발명을 완성함에 이르렀다.
즉 본 발명은 다음 일반식(Ⅰ)로 표시되는 오르가노 폴리실록산 및 아미노- 변성폴리실록산으로 이루어진 탄소섬유 제조용 유제에 관한 것이다.
Figure kpo00002
[다만, R1, R2, R3, R5, R6은 에틸기 또는 에틸기, R4는 수소, 탄소수 1내지 5인 알킬기 또는 페닐기, R7, R8은 메틸기, 에틸기 또는 하이드록실기, m, n은 오르가노 폴리실록산의 25℃에 있어서의 점도가 5내지 1000센티스토크로 되는 정수]
본 발명에 있어서, 일반식(Ⅰ)로 표시되는 오르가노 폴리실록산은 25℃에 있어서의 점도가 5내지 1000센티스토크(이하 점도는 25℃에 있어서의 센티스토크로 표시한다)의 것이다.
점도가 5미만이면 분자량 부곧이 되어 프리커서 제조공정이나 내염화 공정 초기에 그 대부분이 휘산하여 본 발명의 효과를 발휘하지 못한다.
거꾸로 점도가 1000을 초과하면 융착 방지기능이 저하 된다. 바람직한 저도 범위는 10내지 100의 범위이다. 해당되는 디메틸 폴리실록산은 좋은 예이다.
또는, 본 발명에 있어서 아미노-변성 폴리실록산에는 분자내에 아미노-변성기를 갖는 폴리실록산의 전부가 포함되어 동일 분자내에 폴리에테르 변성기나 알코올 변성기등 기타 변성기를 포함하고 있어도 좋으나, 이 아미노- 변성 폴리실록산은 다음 일반식(Ⅱ)로 표시되는 것이 좋다.
Figure kpo00003
[다만, R9은 수소, 탄소수 1내지 5인 알킬기 또는 페닐기, R10, R11, R12, R13은 메틸기 또는 에틸기, R14, R15는 메틸기, 에틸기 또는 하이드록실기, R16, R17, R18은 수소, 메틸기 또는 X는 탄소수 3내지 5인 알킬렌기, Y는 탄소수 2내지 6인 알킬렌기, p, q는 아미노-변성폴리실록산의 25℃에 있어서의 점도가 10내지 10000센티스토크로되는 정수]
일반식(Ⅱ)로 표시되는 아미노-변성 폴리실록산은 분자내에 아미노-변성기 1개당 질소원자 2개를 갖는 것으로 섬유에 대한 배향성이 좋아진 것으로 생각되는데 본 발명의 목적에 적합하여 특히 유효하다.
본 발명에서는 전술한 오르가노 폴리실록산과 아미노-변성 폴리실록산과의 배합비에는 특별한 제한은 없지만, 표과의 발현정도의 점에서 오르가노 폴리실록산/아미노-변성 폴리실록산=10/90~90/10(중량비)가 바람직 하며, 이것이 25/75~90/10(중량비)일때 더욱 바람직하다.
본 발명에 관한 유제는 이상 설명한 오르가노 폴리실록산과 아미노-변성 폴리실록산으로 조성되는데. 이 유제를 사용함에 있어서 본 발명의 효과를 손상시키지 않는 범위내에서 공지의 평활제, 유연제, 대전 방지제, 계면활성제, 산화방지제, 방부제 또는 여기에 종래 제안된 탄소섬유 제조용 유제를 적당히 선정해서 병용할 수도 있다.
그리고 본 발명에 관한 유제는 프리커서 제조공정 또는 이 공정후 내염화 공정전의 단계에서 부여하고, 그 부여 형태는 에멀젼, 유기용제 용액 또는 스트레이트 등 어느것이나 좋고, 그 부여수단은 로울러급유법,스프레이 급유법 또는 가이드 오일링법 등 어느것이나 좋다.
이때 유제 부착랑은 일방으로는 본 발명의 효과를 충분히 발현시키면서 타방으로는 경제성도 포함해서 부착량에 합당한 효과를 발현시키기 위하여 프리커서에 대하여 0.01~5중량%로 하는 것이 바람직 하다.
이상 설명한 바와 같이 본 발명에 관한 유제에 의하면 프리커서의 제조 공정이나 내염화 공정에서의 공정 통과성이 우수하고 특히 프리커서의 분섬성이나 내염화 공정에서의 융착 방지 기능이 우수하여 종래 제안된 예를 들면 오르가노 폴리실록산 단독의 경우에 비하여 탁월한 효과를 나타낸다.
이하 시험예를 들어서 본 발명의 구성 및 효과를 더욱 구체적으로 설명하겠으나 본 발명은 여기에서 들은 실시예에 한정된 것은 아니다.
[시험예]
제1표 및 제2표에 표시된 유제(실시예 1~15, 비교예 1~15)를 배합하여 이 유제 85중량부와 폴리옥시에틸렌 노닐 페닐 에테르 15중량부의 비율로 함유된 수유화액을 조제 하였다.
그리고 아크릴 필라멘트사(16000데니어/12000필라멘트)에 이 수유화액을 각각 부착량 0.5±0.1중량%(물을 제외한 성분 환산, 이하같음)가 되도록 침지법으로 부여한 후, 건열 로울러를 사용하여 115℃×4초간 건조하여 프리커서 토우를 조제하고, 이것을 시료로 하여 그 분섬성을 후술한 방법으로 평가 하였다.
그리고 이 프리커서 토우를 240℃의 강제 순환식 오븐중에서 60분간 처리하여 내염화 섬유를 얻고, 이것을 시료로 하여 그 융착 방지성을 후술한 방법으로 평가했다.
또, 아크릴 필라멘트사(75데니어/40필라멘트)에 전기 수유화액을 각각 부착량 0.5±0.1중량%가 되도록 로울로 급유법으로 부여한 시료사를 조제하여 이 시료사의 마찰계수 및 발생전기를 후술한 방법으로 평가 하였다.
그 결과를 제1표 및 제2표에서 표시 하였다.
‥분섬성의 평가(표중 "분섬"으로 표시하였음)
시료를 2cm로 절단하여 흑지상에서 가볍게 흔들어서 분섬상태를 다음의 기준에 의하여 평가 하였다.
Figure kpo00004
: 분섬성 극히 양호. △ : 분섬성 약간 불량.
◎ : 분섬성 양호. × : 분섬성 극히 불량.
○ : 분섬성 가.
‥융착 방지성 평가(표중 "융착"으로 표시하였음)
시료를 2cm로 절단하여 백지상에서 가볍게 흔들어서 융착 방지 상태를 다음의 기준에 의하여 평가 하였다.
Figure kpo00005
: 융착 전무. △ : 융착 다소 있음.
◎ : 융착 거의 없음. × : 융착 큼.
○ : 융착 약간 있음.
‥마찰계수의 평가(표중 "마찰"으로 표시하였음)
시료사를 20℃×65% RH의 분위기하에서 24시간 방치하고 동 조건하에서 초장력 20g, 사속100m/분으로 크롬-도금이지 가공핀과 접촉주행 시켜서 그 마찰계수를 μ-메터(에이꼬 측기사 제)로 측정하여 다음 기준에 따라 평가 하였다.
◎ : 마찰계수 0.25미만. △ : 마찰계수 0.28~0.31미만.
○ : 마찰계수 0.25~0.28미만. × : 마찰계수 0.31이상.
‥발생전기의 평가(표중 "전기"으로 표시하였음)
전기 마찰계수의 측정시 크롬-도금이지 가동핀과의 접촉후의 발생 전기를 집전식 전위 측정기(가스가 덴끼사 제)로 측정하여 다음 기준에 따라 평가 하였다.
○ : 발생전기 100V 미만. × : 발생전기 300V보다 큼.
△ : 발생전기 100V~300
Figure kpo00006
[표 1]
Figure kpo00007
[표 2]
Figure kpo00008
주) 제1표 및 제2표를 통해서,
DMS는 디메틸 폴리실록산, PS는 페닐폴리실록산, PES는 폴리에테르-변성 폴리실록산, ES는 에폭시-변성 폴리실록산, 괄호안의 수치는 점도, 유제의 우열수치는 중량비, AS는 아미노-변성 폴리실록산이며, 다음과 같다.
Figure kpo00009
Figure kpo00010
[다만, AS-A~AS-D에 있어서, a, b, d, e, f는 정수] 제1표 및 제2표의 결과로 보아도 본 발명의 효과는 명백하다.

Claims (5)

  1. 다음 일반식(Ⅰ)로 표시되는 오르가노 폴리실록산과 아미노-변성 폴리실록산으로 이루어진 탄소섬유 제조용 유제 :
    Figure kpo00011
    [다만, R1, R2, R3, R5, R6은 메틸기 또는 에틸기 ; R4는 수소, 탄소수 1내지 5인 알킬기 또는 페닐기 ; R7, R8은 메틸기, 에틸기 또는 하이드록실기 ; m, n은 오르가노 폴리실록산의 25℃에 있어서의 점도가 5내지 1000센티스토크로 되는 정수.]
  2. 제1항에 있어서, 일반식(Ⅰ)로 표시되는 오르가노 폴리실록산의 25℃에서의 점도가 10내지 100센티스토크인 탄소섬유 제조용 유제.
  3. 제1항 또는 제2항에 있어서, 아미노-변성 폴리실록산이 다음 일반식(Ⅱ)로 표시되는 탄소섬유 제조용 유제 :
    Figure kpo00012
    [다만, R9은 수소, 탄소수 1내지 5인 알킬기 또는 페닐기 ; R10, R11, R12, R13은 메틸기 또는 에틸기 ; R14, R15는 메틸기, 에틸기 또는 하이드록실기 ; R16, R17, R18은 수소, 메틸기 또는 에틸기 ; X는 탄소수 3내지 5인 알킬렌기 ; Y는 탄소수 2내지 6인 알킬렌기 ; p, q는 아미노-변성폴리실록산의 25℃에 있어서의 점도가 10내지 10000센티스토크가 되는 정수.
  4. 제1항에 또는 제2항의 어느 하나에 있어서, 일반식(Ⅰ)로 표시되는 오르가노 폴리실록산/아미노-변성 폴리실록산=10/90~90/10(중량비)인 탄소섬유 제조용 유제.
  5. 제3항에 있어서, 일반식(Ⅰ)로 표시되는 오르가노 폴리실록산/아미노-변성 폴리실록산=10/90~90/10(중량비)인 탄소섬유 제조용 유제.
KR1019850005525A 1984-09-14 1985-07-31 탄소섬유 제조용 유제 KR880000496B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP59-193671 1984-09-14
JP59193671A JPH0686707B2 (ja) 1984-09-14 1984-09-14 炭素繊維の製造における前駆体繊維の融着防止方法

Publications (2)

Publication Number Publication Date
KR860002614A KR860002614A (ko) 1986-04-28
KR880000496B1 true KR880000496B1 (ko) 1988-04-08

Family

ID=16311842

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019850005525A KR880000496B1 (ko) 1984-09-14 1985-07-31 탄소섬유 제조용 유제

Country Status (3)

Country Link
EP (1) EP0174806B1 (ko)
JP (1) JPH0686707B2 (ko)
KR (1) KR880000496B1 (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101138291B1 (ko) * 2009-05-08 2012-04-24 국방과학연구소 라이오셀계 탄소섬유 및 탄소직물의 제조방법

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5185006A (en) * 1990-12-17 1993-02-09 Becton, Dickinson And Company Lubricated metal articles and assembly containing same
JP4456253B2 (ja) * 2000-10-16 2010-04-28 竹本油脂株式会社 炭素繊維製造用合成繊維処理剤及び炭素繊維製造用合成繊維の処理方法
JP6167735B2 (ja) * 2013-08-01 2017-07-26 三菱ケミカル株式会社 炭素繊維前駆体アクリル繊維用油剤組成物と炭素繊維前駆体アクリル繊維用油剤組成物分散液、および炭素繊維前駆体アクリル繊維束の製造方法
CN112771112B (zh) * 2018-10-10 2023-03-21 陶氏环球技术有限责任公司 水性组合物
JP6671698B1 (ja) 2019-05-30 2020-03-25 竹本油脂株式会社 炭素繊維前駆体用処理剤及び炭素繊維前駆体

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3717575A (en) * 1971-05-25 1973-02-20 Union Carbide Corp Spandex lubricant
US4078104A (en) * 1975-02-28 1978-03-07 Sws Silicones Corporation Release composition for bituminous materials
JPS51116225A (en) * 1975-04-04 1976-10-13 Japan Exlan Co Ltd An improved process for producing carbon fibers
JPS5234025A (en) * 1975-09-08 1977-03-15 Japan Exlan Co Ltd Process for producing carbon fibers having excellent performances
JPS52148227A (en) * 1976-05-10 1977-12-09 Mitsubishi Rayon Co Ltd Preparation of carbon fiber from acrylic fiber
JPS597832B2 (ja) * 1979-05-17 1984-02-21 ト−レ・シリコ−ン株式会社 繊維処理剤
US4311626A (en) * 1980-09-25 1982-01-19 Toray Silicone Company, Ltd. Silicone compositions for the treatment of fibers
JPS5926707B2 (ja) * 1981-03-31 1984-06-29 信越化学工業株式会社 繊維質物用処理剤

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101138291B1 (ko) * 2009-05-08 2012-04-24 국방과학연구소 라이오셀계 탄소섬유 및 탄소직물의 제조방법

Also Published As

Publication number Publication date
EP0174806A3 (en) 1988-01-27
EP0174806A2 (en) 1986-03-19
KR860002614A (ko) 1986-04-28
JPH0686707B2 (ja) 1994-11-02
EP0174806B1 (en) 1992-01-29
JPS6175881A (ja) 1986-04-18

Similar Documents

Publication Publication Date Title
EP0100826B1 (en) Acrylic fibers for producing carbon fibers
US3672977A (en) Production of polyesters
JPS60185879A (ja) 炭素繊維製造用油剤
KR880000496B1 (ko) 탄소섬유 제조용 유제
EP0159120B1 (en) Lubricating agents for use in the production of carbon yarns
US2964470A (en) Tire cord fiber lubricant
JP2012102429A (ja) 炭素繊維製造用アクリル繊維油剤、炭素繊維製造用アクリル繊維および炭素繊維の製造方法
US4944932A (en) Process for producing carbon fiber
JPH0291225A (ja) 炭素繊維用原糸の製造法
JP2007177349A (ja) 炭素繊維製造用処理剤
EP0149348B1 (en) Process for producing pitch carbon fibers
US2286824A (en) Yarn treating
CN116103790B (zh) 一种耐热、高相容性碳纤维原丝油剂及其制备方法
JPH01260020A (ja) ピッチ系炭素繊維の製造方法
JPS6134284A (ja) ポリウレタン弾性繊維用解舒性向上処理剤
JPS59179885A (ja) 炭素繊維原糸用処理剤
JPS58214581A (ja) アクリル系炭素繊維製造用油剤
JPH0291226A (ja) 炭素繊維用原糸の製造方法
KR940007708B1 (ko) 열가소성 합성섬유용 내열성처리제 조성물
KR900003111B1 (ko) 열가소성 합성섬유용 내열성처리제 조성물
JPH0152504B2 (ko)
JPH11256481A (ja) 炭素繊維製造用処理剤
JPH041087B2 (ko)
JPH0364514A (ja) 炭素繊維用アクリル系前駆体糸条の製造法
JP6204211B2 (ja) アクリル繊維処理剤及びその用途

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
G160 Decision to publish patent application
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 19970910

Year of fee payment: 11

LAPS Lapse due to unpaid annual fee