KR870004066A - 발수성 및 발유성 플루오로아크릴 중합체의 제조방법 - Google Patents

발수성 및 발유성 플루오로아크릴 중합체의 제조방법 Download PDF

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KR870004066A
KR870004066A KR1019860008648A KR860008648A KR870004066A KR 870004066 A KR870004066 A KR 870004066A KR 1019860008648 A KR1019860008648 A KR 1019860008648A KR 860008648 A KR860008648 A KR 860008648A KR 870004066 A KR870004066 A KR 870004066A
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monomer
radical
fluorinated
formula
ester
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KR1019860008648A
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KR900000157B1 (ko
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마리-조세리나
드쌩 앙드레
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쟝 르블랑제
소시에떼 아토샹
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C14—SKINS; HIDES; PELTS; LEATHER
    • C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C11/00—Surface finishing of leather
    • C14C11/003—Surface finishing of leather using macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C273/00—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C273/18—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas
    • C07C273/1809—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas with formation of the N-C(O)-N moiety
    • C07C273/1818—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas with formation of the N-C(O)-N moiety from -N=C=O and XNR'R"
    • C07C273/1827—X being H
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
    • C08F20/36—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate containing oxygen in addition to the carboxy oxygen, e.g. 2-N-morpholinoethyl (meth)acrylate or 2-isocyanatoethyl (meth)acrylate
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Paints Or Removers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음

Description

발수성 및 발유성 플루오로아크릴 중합체의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 하기 일반식으로 표시됨을 특징으로 하는 플루오로 아크릴 단량체 ;
    (Ⅰ)
    상기 식에서, RF는 직쇄-또는 측쇄-퍼플루오로알킬 라디칼을 나타내고, R은 수소원자 또는 메틸 라디칼을 나타내고, R′은 알킬 또는 시크로알킬 라디칼을 나타내고, -NR′-은 1,4-피페라지닐렌 라디칼을 나타내고, W는 탄소원자를 경유하여 Q에 연결된 2배위 연쇄로서 하나 이상의 산소, 유황 및/또는 질소 원자를 함유할 수 있는 것을 나타내고, Q는 산소 또는 유황원자, 또는 R″이 수소원자 또는 알칼 라디칼을 나타낼 때의 -NR″-을 나타내고, Z는 2배위 지방족, 알리 시클릭 또는 방향족 연쇄를 나타내며, A는 2 또는 3탄소원자를 갖는 알킬렌기를 나타낸다.
  2. 제 1 항에 있어서, A가 에틸렌기이고, R′이 t-부틸 라디칼이고, Z가 2,4- 및/또는 톨릴렌기임을 특징으로 하는 단량체.
  3. 제 1 항 또는 제 2 항에 있어서, -W-Q가-CH2CH20-, CH2CH2S- -CH2CH2-SO2N(R″)-CH2CH20-연쇄임을 특징으로 하는 단량체.
  4. 제 1 항부터 제 3 항까지에 있어서, RF가 6,8 또는 10 탄소원자를 갖는 직선 퍼플루오로알킬 라디칼임을 특징으로 하는 단량체.
  5. O=C=N-Z-N=C=O의 디이소시아네이트를 동몰수의 폴리플루오로 화합물 RF-W-Q-H 및 동 몰수의 에스테르 R′NH-A-OCO-C(R)=CH2와 유기용매내에서, 30 내지 90℃의 온도로 비활성 기체하에 반응시킴을 특징으로 하는 제 1 항부터 제 4 항까지 중의 하나에 해당하는 단량체의 제조방법.
  6. 제 5 항에 있어서, 폴리플루오로 화합물 RF-W-Q-H 가 먼저 반응하고, 이어서 에스테르 R′NH-A-OCO-C(R)=CH2가 반응함을 특징으로 하는 방법.
  7. 제 1 항 부터 제 4 항까지 중의 하나의 단량체를 단일 중합하고, 또는 상기 단량체를 불소화된 또는 불소화되지 않은 다른 단량체와 공중합하고 또는 플루오로 이소시아네이트 우레탄(식 ⅩⅡ)
    (ⅩⅡ)
    을 에스테르 R′NH-A-O-CO-C(R)=CH2의 단일 중합체, 또는 불소화된 또는 불소화되지 않은 다른 단량체와 에스테르와의 공중합체에 그라프트함을 특징으로 하고, 하기 식의 반복단위를 10 내지 100중량% 포함하는
    중합체의 제조방법.
    상기 식에서, RF,R,R′,W,Q,Z 및 A는 제 1 항부터 제 4 항까지에서와 같은 의미를 갖는다.
  8. 제 7 항에 있어서, 공단체가 알킬 또는 셀로솔브 아크릴레이트 또는 메타크릴레이트, 하기식의 플루오로 화합물 ;
    및 그들의 혼합물임을 특징으로 하는 방법.
    상기 식에서, RF,R 및 W는 제 1 항에서와 같은 의미를 갖는다.
  9. 제 7 항 및 제 8 항에 의해서 제조되는 중합체를 여러가지 물질, 특히 가죽에 처리하여 발수성 및 발유성을 부가함을 특징으로 하는 방법.
  10. 제 7 항 및 제 8 항에 의해서 제조된 중합체로 처리한 물질.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860008648A 1985-10-16 1986-10-15 발수성 및 발유성 플루오로아크릴 중합체의 제조방법 KR900000157B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR15347 1985-10-16
FR15347/85 1985-10-16
FR8515347A FR2588555B1 (fr) 1985-10-16 1985-10-16 Monomeres acryliques fluores, polymeres en derivant et leur application au traitement hydrofuge et oleofuge de substrats divers

Publications (2)

Publication Number Publication Date
KR870004066A true KR870004066A (ko) 1987-05-07
KR900000157B1 KR900000157B1 (ko) 1990-01-23

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US (1) US4778915A (ko)
EP (1) EP0223648B1 (ko)
JP (1) JPS6293267A (ko)
KR (1) KR900000157B1 (ko)
CN (1) CN86106575A (ko)
AU (1) AU594981B2 (ko)
DE (1) DE3667658D1 (ko)
ES (1) ES2002418A6 (ko)
FR (1) FR2588555B1 (ko)

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Publication number Publication date
EP0223648A3 (en) 1988-03-23
US4778915A (en) 1988-10-18
FR2588555B1 (fr) 1987-12-11
AU594981B2 (en) 1990-03-22
EP0223648B1 (fr) 1989-12-20
CN86106575A (zh) 1987-04-22
KR900000157B1 (ko) 1990-01-23
FR2588555A1 (fr) 1987-04-17
AU6412386A (en) 1987-04-30
ES2002418A6 (es) 1988-08-01
DE3667658D1 (de) 1990-01-25
JPS6293267A (ja) 1987-04-28
EP0223648A2 (fr) 1987-05-27

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