JPS55144028A - Block copolymer metal complex - Google Patents

Block copolymer metal complex

Info

Publication number
JPS55144028A
JPS55144028A JP5230879A JP5230879A JPS55144028A JP S55144028 A JPS55144028 A JP S55144028A JP 5230879 A JP5230879 A JP 5230879A JP 5230879 A JP5230879 A JP 5230879A JP S55144028 A JPS55144028 A JP S55144028A
Authority
JP
Japan
Prior art keywords
metal complex
formula
block
hydrophilic
tercopolymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP5230879A
Other languages
Japanese (ja)
Other versions
JPS584061B2 (en
Inventor
Junko Shigehara
Hidetoshi Tsuchida
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP5230879A priority Critical patent/JPS584061B2/en
Publication of JPS55144028A publication Critical patent/JPS55144028A/en
Publication of JPS584061B2 publication Critical patent/JPS584061B2/en
Expired legal-status Critical Current

Links

Landscapes

  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Polymerisation Methods In General (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

PURPOSE: To provide title metal complex having oxygen adsorption-desorption performance and useful as a catalyst for adsorption-desorption reaction of oxygen, in which tetrapyrrole metal complex is bonded to the hydrophobic block part of a hydrophilic-hydrophobic-hydrophilic block terpolymer by a covalent bond.
CONSTITUTION: A styrene cpd. contg. primary or secondary amino gp is used as a starting material to obtain a block tercopolymer of formula I or II (wherein A is hydrophilic polymer chain; X is -NH-, etc.; X2 is -CONH-(CH2CH2)n-NH-; n is 1W3; Y is H, hydrocarbon gp. which does not have mobile hydrogen; R1 is H, methyle; x.y represent mole % of each unit and x+y=100; R2 is alkyl having not less than three carbon atoms; a is 0W1). The obtained block tercopolymer is reacted with metal complex of caeboxyl gp.-contg. marcrocyclic quadridentate plane liagne of formula III (wherein P is metal complex of macrocyclic quadridentate plane ligand) to produce the desired metal complex of formula IV (wherein X is =c=0; B is a radical of formula V or VI; A, X1, X2, Y, n, x, y, R1, R2, P are as defined above).
COPYRIGHT: (C)1980,JPO&Japio
JP5230879A 1979-04-27 1979-04-27 Block copolymer metal complex Expired JPS584061B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP5230879A JPS584061B2 (en) 1979-04-27 1979-04-27 Block copolymer metal complex

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5230879A JPS584061B2 (en) 1979-04-27 1979-04-27 Block copolymer metal complex

Publications (2)

Publication Number Publication Date
JPS55144028A true JPS55144028A (en) 1980-11-10
JPS584061B2 JPS584061B2 (en) 1983-01-24

Family

ID=12911151

Family Applications (1)

Application Number Title Priority Date Filing Date
JP5230879A Expired JPS584061B2 (en) 1979-04-27 1979-04-27 Block copolymer metal complex

Country Status (1)

Country Link
JP (1) JPS584061B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003018007A1 (en) * 2001-08-31 2003-03-06 Hiroshi Maeda Antitumor agents and process for producing the same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003018007A1 (en) * 2001-08-31 2003-03-06 Hiroshi Maeda Antitumor agents and process for producing the same

Also Published As

Publication number Publication date
JPS584061B2 (en) 1983-01-24

Similar Documents

Publication Publication Date Title
WO1993021238A3 (en) Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
ES470159A1 (en) Components of catalysts for polymerizing alpha-olefins and the catalysts formed from the components
AU3085184A (en) Silicon hydride compounds and polymers modified therewith
CA2295215A1 (en) Catalyst for the production of olefin polymers
EP0891991A3 (en) Tris(pentafluorophenyl)borate complexes and catalysts derived therefrom
AU6974396A (en) Readily supportable metal complexes
JPS5690845A (en) Flame-retardant rubber composition
DE3365340D1 (en) A process for making an olefin polymerization catalyst
JPS5626940A (en) Polyolefin composition and production thereof
JPS55144028A (en) Block copolymer metal complex
KR920006374A (en) Catalyst for chromium-containing complex polymerization
JPS5552338A (en) Oxymethylene copolymer composition
Watanabe et al. First example of photoinduced copolymerizability enhancement: copolymerization of epoxide and episulfide initiated with zinc N-substituted porphyrin under visible light irradiation
JPS5690810A (en) Production of polyethylene
DE3062434D1 (en) Vanadium (iv) compounds soluble in organic media, process for their preparation and their uses
JPS5695912A (en) Preparation of ethylene copolymer
JPS5598205A (en) Catalyst for olefin polymerization
JPS5651495A (en) Preparation of compound containing fluorine and phosphorus
ES8204614A1 (en) Process for the preparation of nickel ylides containing sulfonated group V ligands.
GB1423659A (en) Olefine polymerisation process
JPS57141407A (en) Polymerization of olefin
JPS5770109A (en) Production of polyethylene
JPS54157193A (en) Preparation of poly alpha-olefin
JPS5690809A (en) Production of polyethylene
JPS5728108A (en) Preparation of polyolefin