KR860000235A - 1,4-디알킬벤젠의 제조방법 - Google Patents
1,4-디알킬벤젠의 제조방법 Download PDFInfo
- Publication number
- KR860000235A KR860000235A KR1019850004480A KR850004480A KR860000235A KR 860000235 A KR860000235 A KR 860000235A KR 1019850004480 A KR1019850004480 A KR 1019850004480A KR 850004480 A KR850004480 A KR 850004480A KR 860000235 A KR860000235 A KR 860000235A
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- South Korea
- Prior art keywords
- diffraction
- zeolite
- group
- tetra
- process according
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/02—Monocyclic hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/046—Chromiasilicates; Aluminochromosilicates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/86—Borosilicates; Aluminoborosilicates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
- C07C2/66—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
- C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
- C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
- C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
- C07C6/123—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of only one hydrocarbon
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (9)
- 제올라이트를 규산에스테르가 함유된 기체로 처리한 다음, 산소를 함유하는 기체중에서 소성시켜 SiO2/X2O3(X는 Al, B 및 Cr로 된 기에서 선택한 적어도 하나이다)의 몰비가 10이상이고, 제한지수가 1내지 15인 제올라이트 촉매의 존재하에서 벤젠 또는 모노알킬벤젠을 알킬화제와 증기상으로 반응시킴을 특징으로 하는 1,4-디알킬벤젠의 제조방법.
- 제1항에 있어서 벤젠 또는 모노알킬벤젠과 알킬화제의 반응을 수소의 공존하에서 수행시킴을 특징으로 하는 방법.
- 제1항 또는 제2항에 있어서, 제올라이트가 CuK선을 사용하여 얻은 X-선 회절모양에 있어서, 회절각 8.7°±0.2°또는 8.9°±0.2°에서 회절선의 강도를 100으로 취할때에 다음 각각의 회절각(2)의 위치에서 다음 각각의 상대적 강도를 나타내는 7이상의 회절선을 갖는 결정성 알루미노실리케이트임을 특징으로 하는 방법.
- 제1항 또는 제2항에 있어서, 제올라이트가 CuK선을 사용하여 얻은 X-선 회절모양에 있어서, 회절각 8.9°±0.2°에서 회절선의 강도를 100으로 취할 때에 다음 각각의 회절각(2)의 위치에서 다음 각각의 상대적 강도를 나타내는 8이상의 회절선을 갖는 결정성 보로실리케이트임을 특징으로 하는 방법.
- 제1항 또는 제2항에 있어서, 제올라이트가 CuK선을 사용하여 얻은 X-선 회절모양에 있어서, 회절각 8.8°±0.2°또는 8.9°±0.2°에서 회절선의 강도를 100으로 취할 때에 다음 각각의 회절각(2)의 위치에서 다음 각각의 상대적 강도를 나타내는 9이상의 회절선을 갖는 결정성 크로모실리케이트임을 특징으로 하는 방법.
- 제1항 내지 제5항 중의 어느 한 항에 있어서 모노알킬벤젠이 1 내지 3탄소원자를 갖는 알킬기를 갖음을 특징으로 하는 방법.
- 제1항 또는 제5항 중의 어느 한 항에 있어서, 1,4-디알킬벤젠을 파라-크실렌, 파라-에틸톨루엔 및 파라-디에틸벤젠으로 된 기에서 선택함을 특징으로 하는 방법.
- 제1항 또는 제2항에 있어서, 알킬화제를 에틸렌, 프로필렌, 메탄올 및 에탄올로 된 기에서 선택함을 특징으로 하는 방법.
- 제1항 또는 제2항에 있어서, 규산에스테르를 테트라메톡시실란, 테트라에톡시실란, 테트라-n-프로폭시실란, 테트라-이소-프로폭시실란, 테트라-n-부톡시실란 및 테트라-t-부톡시실란으로 된 기에서 선택함을 특징으로 하는 방법.※ 참고사항 : 최초출원내용에 의하여 공개하는 것임.
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59-129169 | 1984-06-25 | ||
JP59129169A JPS6110519A (ja) | 1984-06-25 | 1984-06-25 | 1,4−ジアルキルベンゼンの製造法 |
JP59-149316 | 1984-07-20 | ||
JP59149316A JPS61126039A (ja) | 1984-07-20 | 1984-07-20 | 1,4−ジアルキルベンゼンの製法 |
JP15304984A JPS6133134A (ja) | 1984-07-25 | 1984-07-25 | 1,4−ジアルキルベンゼンの製造方法 |
JP59-153049 | 1984-07-25 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR860000235A true KR860000235A (ko) | 1986-01-27 |
KR870001873B1 KR870001873B1 (ko) | 1987-10-20 |
Family
ID=27315894
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019850004480A KR870001873B1 (ko) | 1984-06-25 | 1985-06-24 | 1,4-디알킬벤젠의 제조방법 |
Country Status (5)
Country | Link |
---|---|
US (1) | US4613717A (ko) |
KR (1) | KR870001873B1 (ko) |
DE (1) | DE3522727A1 (ko) |
FR (1) | FR2566389B1 (ko) |
GB (1) | GB2163176B (ko) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4849386A (en) * | 1987-04-08 | 1989-07-18 | Taiwan Styrene Monomer Corporation | Novel silicon-modified catalyst Si/HZSM-5 preparation |
US5321183A (en) * | 1992-03-12 | 1994-06-14 | Mobil Oil Corp. | Process for the regioselective conversion of aromatics to para-disubstituted benzenes |
BR0017355A (pt) | 1999-10-20 | 2004-02-10 | Beverly Watts Ramos | Conexão de tubo rosqueada |
US9586873B2 (en) | 2014-06-03 | 2017-03-07 | King Fahd University Of Petroleum And Minerals | Method for the selective production of para-dialkylbenzenes |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NZ183608A (en) * | 1976-03-31 | 1978-12-18 | Mobil Oil Corp | Aluminosilicate zeolite catalyst for selectine production of para-diakyl substituted benzenes |
US4090981A (en) * | 1976-09-23 | 1978-05-23 | Mobile Oil Corporation | Catalyst for selective production of para dialkyl substituted benzenes |
PL199748A1 (pl) * | 1976-07-19 | 1978-04-24 | Mobil Oil Corp | Sposob selektywnego wytwarzania p-dwualkilobenzenow |
US4145315A (en) * | 1976-12-23 | 1979-03-20 | Mobil Oil Corporation | Silica-modified zeolite catalyst |
US4444989A (en) * | 1979-04-20 | 1984-04-24 | E. I. Du Pont De Nemours And Company | Methylation of toluene to para-xylene catalyzed by crystalline silica |
US4491678A (en) * | 1982-10-19 | 1985-01-01 | Idemitsu Kosan Company Limited | Process for the production of para-xylene |
EP0106342B1 (en) * | 1982-10-19 | 1988-08-24 | Idemitsu Kosan Company Limited | Process for the production of para-xylene |
DE3361440D1 (en) * | 1982-12-30 | 1986-01-16 | Asahi Chemical Ind | A crystalline aluminosilicate, a process for producing the same, and a catalyst comprising the crystalline aluminosilicate |
US4465886A (en) * | 1983-06-09 | 1984-08-14 | Mobil Oil Corporation | Silica-modified catalyst and use for selective production of para-dialkyl substituted benzenes |
-
1985
- 1985-06-04 US US06/741,629 patent/US4613717A/en not_active Expired - Fee Related
- 1985-06-20 GB GB08515692A patent/GB2163176B/en not_active Expired
- 1985-06-24 FR FR8509578A patent/FR2566389B1/fr not_active Expired
- 1985-06-24 KR KR1019850004480A patent/KR870001873B1/ko not_active IP Right Cessation
- 1985-06-25 DE DE19853522727 patent/DE3522727A1/de active Granted
Also Published As
Publication number | Publication date |
---|---|
GB2163176A (en) | 1986-02-19 |
US4613717A (en) | 1986-09-23 |
DE3522727A1 (de) | 1986-01-02 |
GB8515692D0 (en) | 1985-07-24 |
FR2566389A1 (fr) | 1985-12-27 |
GB2163176B (en) | 1988-06-29 |
KR870001873B1 (ko) | 1987-10-20 |
DE3522727C2 (ko) | 1987-09-17 |
FR2566389B1 (fr) | 1988-10-28 |
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