BR9909460A - Catalisador e processo para conversão de metanol a hidrocarbonetos - Google Patents

Catalisador e processo para conversão de metanol a hidrocarbonetos

Info

Publication number
BR9909460A
BR9909460A BR9909460-6A BR9909460A BR9909460A BR 9909460 A BR9909460 A BR 9909460A BR 9909460 A BR9909460 A BR 9909460A BR 9909460 A BR9909460 A BR 9909460A
Authority
BR
Brazil
Prior art keywords
catalyst
methanol
temperature
hydrocarbons
dimethylbutane
Prior art date
Application number
BR9909460-6A
Other languages
English (en)
Inventor
Stephen Harold Brown
Larry Arthur Green
Mark Fischer Mathias
David Harold Olson
Robert Adams Ware
William Alois Weber
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of BR9909460A publication Critical patent/BR9909460A/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/005—Mixtures of molecular sieves comprising at least one molecular sieve which is not an aluminosilicate zeolite, e.g. from groups B01J29/03 - B01J29/049 or B01J29/82 - B01J29/89
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/14—Phosphorus; Compounds thereof
    • C07C2527/16—Phosphorus; Compounds thereof containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Patente de Invenção: <B>"CATALISADOR E PROCESSO PARA CONVERSãO DE METANOL A HIDROCARBONETOS"<D>. São fornecidos um catalisador e um processo para a conversão de metanol ou de dimetil éter a um produto que contenha C~ 2~ e C~ 4~ olefinas. O catalisador compreende um material cristalino poroso que tem um Parâmetro de Difusão para 2,2-dimetilbutano de 0,1-20 s^ -1^ quando medido a uma temperatura de 120°C e uma pressão de 2,2-dimetilbutano de 60 torr (8 kPa). Além disso, o catalisador é caracterizado por uma estabilidade hidrotérmica tal que, após tratamento com vapor d'água do catalisador a 1025°C durante 45 minutos em vapor d'água de 1 atmosfera, o catalisador exibe uma atividade de conversão de metanol de pelo menos 50% quando em contato com metanol a uma pressão parcial de metanol de 1 atmosfera, uma temperatura de 430°C e 0,5 WHSV. O material cristalino poroso é de preferência uma zeólita do poro médio, particularmente ZSM-5, que contém fósforo e que foi tratada rigorosamente a uma temperatura de pelo menos 950°C.
BR9909460-6A 1998-04-06 1999-04-01 Catalisador e processo para conversão de metanol a hidrocarbonetos BR9909460A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/055,478 US6048816A (en) 1996-10-02 1998-04-06 Catalyst and process for converting methanol to hydrocarbons
PCT/US1999/007320 WO1999051549A1 (en) 1998-04-06 1999-04-01 Catalyst and process for converting methanol to hydrocarbons

Publications (1)

Publication Number Publication Date
BR9909460A true BR9909460A (pt) 2000-12-12

Family

ID=21998106

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9909460-6A BR9909460A (pt) 1998-04-06 1999-04-01 Catalisador e processo para conversão de metanol a hidrocarbonetos

Country Status (11)

Country Link
US (1) US6048816A (pt)
EP (1) EP1073614A4 (pt)
JP (1) JP2002510660A (pt)
AR (1) AR015265A1 (pt)
AU (1) AU764570B2 (pt)
BR (1) BR9909460A (pt)
CA (1) CA2327688A1 (pt)
ID (1) ID29381A (pt)
MX (1) MX213108B (pt)
NO (1) NO20005020L (pt)
WO (1) WO1999051549A1 (pt)

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US6472569B1 (en) * 1999-04-16 2002-10-29 Phillips Petroleum Company Silicoaluminophosphate material, a method of making such improved material and the use thereof in the conversion of oxygenated hydrocarbons to an olefin and/or an ether
US6613951B1 (en) * 1999-09-23 2003-09-02 Mobil Oil Corporation Process for converting methanol to olefins
IT1314190B1 (it) * 1999-10-18 2002-12-06 Eni Spa Processo per preparare 2,6-dimetilnaftalene
KR20020061011A (ko) * 1999-12-28 2002-07-19 코닝 인코포레이티드 제올라이트/알루미나 촉매 지지체 조성물 및 이의 제조방법
US6743747B1 (en) * 2000-02-24 2004-06-01 Exxonmobil Chemical Patents Inc. Catalyst pretreatment in an oxgenate to olefins reaction system
US6797851B2 (en) 2001-08-30 2004-09-28 Exxonmobil Chemical Patents Inc. Two catalyst process for making olefin
US6823684B2 (en) 2002-02-08 2004-11-30 Tim Allan Nygaard Jensen System and method for cooling air
US6638892B1 (en) * 2002-04-18 2003-10-28 Conocophillips Company Syngas conversion and catalyst system employed therefor
US20040097769A1 (en) * 2002-11-14 2004-05-20 Ou John D. Y. Para-xylene production process employing in-situ catalyst selectivation
US7084318B2 (en) * 2003-08-01 2006-08-01 Saudi Basic Industries Corporation Toluene methylation process
US7060864B2 (en) * 2003-09-30 2006-06-13 Saudi Basic Industries Corporation Toluene methylation process
US7060644B2 (en) * 2004-01-08 2006-06-13 Saudi Basic Industries Corporation Aromatic alkylation catalyst and method
US6943131B1 (en) * 2004-03-02 2005-09-13 Saudi Basic Industries Corporation Selective zeolite catalyst modification
US7285511B2 (en) * 2004-04-23 2007-10-23 Saudi Basic Industries Corporation Method of modifying zeolite catalyst
US7399727B2 (en) * 2004-04-23 2008-07-15 Saudi Basic Industries Corporation Zeolite catalyst and method
US7105713B2 (en) * 2004-06-09 2006-09-12 Saudi Basic Industries Corporation Preparation of alkyl-aromatic products
US7199277B2 (en) * 2004-07-01 2007-04-03 Exxonmobil Chemical Patents Inc. Pretreating a catalyst containing molecular sieve and active metal oxide
US7441412B2 (en) 2005-01-26 2008-10-28 Tim Allan Nygaard Jensen Heat transfer system and method
US7304194B2 (en) * 2005-05-05 2007-12-04 Saudi Basic Industries Corporation Hydrothermal treatment of phosphorus-modified zeolite catalysts
KR100598988B1 (ko) * 2005-05-18 2006-07-12 주식회사 하이닉스반도체 오버레이 버니어 및 이를 이용한 반도체소자의 제조방법
US7368410B2 (en) * 2005-08-03 2008-05-06 Saudi Basic Industries Corporation Zeolite catalyst and method of preparing and use of zeolite catalyst
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TWI406707B (zh) * 2006-08-30 2013-09-01 Jgc Corp 含鹼土類金屬化合物之沸石催化劑及其調製方法與再生方法、以及低級烴之製造方法
CN101172246B (zh) * 2006-11-02 2010-05-12 中国石油化工股份有限公司 甲醇转化制丙烯的方法
JP5543347B2 (ja) 2007-08-13 2014-07-09 サウディ ベーシック インダストリーズ コーポレイション 脂肪族燃料促進物質を芳香族化合物に転化するプロセス
US9061954B2 (en) * 2008-02-07 2015-06-23 Total Research & Technology Feluy Dehydration of alcohols on crystalline silicates
US8846559B2 (en) * 2008-11-03 2014-09-30 Saudi Basic Industries Corporation Stable shape-selective catalyst for aromatic alkylation and methods of using and preparing
US8252967B2 (en) 2009-04-14 2012-08-28 Exxonmobil Chemical Patents Inc. Process for the purification of paraxylene
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CN102744100B (zh) * 2011-04-20 2015-01-07 中国石油化工股份有限公司 生产乙烯与丙烯的流化床催化剂
TWI495511B (zh) 2011-07-27 2015-08-11 Exxonmobil Chem Patents Inc 具有分階擋板的流體床反應器
US9278342B2 (en) 2012-07-02 2016-03-08 Saudi Basic Industries Corporation Method of modifying a phosphorus-containing zeolite catalyst
US9353024B2 (en) 2013-02-06 2016-05-31 Exxonmobil Chemical Patents Inc. Selective hydrogenation of styrene to ethylbenzene
CN105814009B (zh) 2013-12-20 2021-11-12 埃克森美孚研究工程公司 用于将含氧化合物选择性转化成芳香族化合物的催化剂
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CN108779043B (zh) 2016-03-25 2021-09-24 埃克森美孚化学专利公司 用于生产对二甲苯的催化剂和方法
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Also Published As

Publication number Publication date
NO20005020L (no) 2000-12-06
EP1073614A1 (en) 2001-02-07
EP1073614A4 (en) 2002-06-05
JP2002510660A (ja) 2002-04-09
MXPA00009796A (en) 2001-05-01
NO20005020D0 (no) 2000-10-05
WO1999051549A1 (en) 1999-10-14
US6048816A (en) 2000-04-11
AR015265A1 (es) 2001-04-18
CA2327688A1 (en) 1999-10-14
AU764570B2 (en) 2003-08-21
ID29381A (id) 2001-08-30
MX213108B (en) 2003-03-05
AU3379599A (en) 1999-10-25

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B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

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