ES471949A1 - Un procedimiento para la etilacion de mono alquil bencenos. - Google Patents

Un procedimiento para la etilacion de mono alquil bencenos.

Info

Publication number
ES471949A1
ES471949A1 ES471949A ES471949A ES471949A1 ES 471949 A1 ES471949 A1 ES 471949A1 ES 471949 A ES471949 A ES 471949A ES 471949 A ES471949 A ES 471949A ES 471949 A1 ES471949 A1 ES 471949A1
Authority
ES
Spain
Prior art keywords
capacity
ethylation
hydrogen
absorption
orthoxylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES471949A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of ES471949A1 publication Critical patent/ES471949A1/es
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Un procedimiento para la etilación de mono alquil bencenos en los cuales el sustituyente alquilo contiene 1 ó 2 átomos de carbono, caracterizado porque comprende poner en contacto al mono alquil benceno con teileno en presencia de hidrógeno bajo condiciones de conversión que incluyen una temperatura entre 350 y 500ºC, una presión mayor que la atmosférica pero menor que 28 kg/cm2, empleando una relación molar hidrógeno a etileno en la gama aproximada de 0,5 a 10 y en presencia de un catalizador que comprende una zeolita de aluminosilicato cristalino, la cual tiene una actividad en términos de valor alfa de entre aproximadamente 2 y aproximadamente 5000, una capacidad de absorción de xileno mayor que 1 gramo/100 gramos de zeolita y un tiempo de absorción de ortoxileno para el 30% de dicha capacidad de más de 10 minutos, midiéndose dicha capacidad de absorción de ortoxileno para el 30% de dicha capacidad de más de 10 minutos, midiéndose dicha capacidad de absorción y dicho tiempo de absorcióna 120º C y a una presión de xileno de 4,5 +- 0,8 mm. de mercurio, teniendo además dicha zeolita de aluminosilicato cristalino una relación sílice de alúmina de al menos aproximadamente 12 y un índice de constreñimiento dentro de la gama aproximada de 1 a 12, por lo cual el envejecimiento de dicho catalizador durante dicha etilación es sustancialmente reducido en comparación con la reacción llevada a cabo en ausencia de hidrógeno.
ES471949A 1977-07-29 1978-07-21 Un procedimiento para la etilacion de mono alquil bencenos. Expired ES471949A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/820,051 US4117024A (en) 1977-07-29 1977-07-29 Ethylation of aromatic compounds

Publications (1)

Publication Number Publication Date
ES471949A1 true ES471949A1 (es) 1979-03-16

Family

ID=25229757

Family Applications (1)

Application Number Title Priority Date Filing Date
ES471949A Expired ES471949A1 (es) 1977-07-29 1978-07-21 Un procedimiento para la etilacion de mono alquil bencenos.

Country Status (20)

Country Link
US (1) US4117024A (es)
JP (1) JPS6039248B2 (es)
AR (1) AR219330A1 (es)
AU (1) AU516383B2 (es)
BE (1) BE869256A (es)
BR (1) BR7804893A (es)
CA (1) CA1103703A (es)
CS (1) CS210651B2 (es)
DD (1) DD138310A5 (es)
DE (1) DE2829756A1 (es)
ES (1) ES471949A1 (es)
FR (1) FR2398710A1 (es)
GB (1) GB1584547A (es)
IN (1) IN150079B (es)
IT (1) IT1097769B (es)
MX (1) MX4080E (es)
NL (1) NL7808042A (es)
PL (1) PL125353B1 (es)
RO (1) RO81335A (es)
ZA (1) ZA783841B (es)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU538578B2 (en) * 1979-01-31 1984-08-23 Mobil Oil Corp. Zeolite catalyst containing gp za or gp8 metal and its use to convert hydrocarbons
US4357264A (en) * 1980-03-10 1982-11-02 Mobil Oil Corporation Alkaline earth metal modified zeolite catalysts
US4288647A (en) * 1980-03-10 1981-09-08 Mobil Oil Corporation Shape selective reactions with alkaline earth-modified zeolite catalysts
US4520220A (en) * 1982-02-22 1985-05-28 Cosden Technology, Inc. Alkylation of aromatics employing silicalite catalysts
US4469806A (en) * 1982-03-18 1984-09-04 Mobil Oil Corporation Organophosphorus-treated zeolite catalysts for para-selective aromatics conversion
US4409132A (en) * 1982-03-18 1983-10-11 Mobil Oil Corporation Organophosphorus-treated zeolite catalysts for para-selective aromatics conversion
US4554394A (en) * 1982-03-18 1985-11-19 Mobil Oil Corporation Organophosphorus-treated zeolite catalysts for para-selective aromatics conversion
US4504690A (en) * 1982-03-18 1985-03-12 Mobil Oil Corporation Organophosphorus-treated zeolite catalysts for para-selective aromatics conversion
JPS5939836A (ja) * 1982-08-27 1984-03-05 Toyo Soda Mfg Co Ltd １，２，４，５−テトラアルキルベンゼンの製造方法
US4447666A (en) * 1982-12-30 1984-05-08 Mobil Oil Corporation Para-selective alkylation catalysts and processes
EP0217492A1 (en) * 1985-07-26 1987-04-08 Mobil Oil Corporation Process for preparing para-divinylbenzene
US4982030A (en) * 1985-07-26 1991-01-01 Mobil Oil Corporation Process for preparation of para-divinylbenzene
US5157185A (en) * 1989-09-01 1992-10-20 Mobil Oil Corporation Alkylation of aromatics
US5659098A (en) * 1993-05-28 1997-08-19 Beck; Jeffrey S. High conversion touluene disproportionation with ex situ selectivated zeolite catalysts
US5382737A (en) * 1993-05-28 1995-01-17 Mobil Oil Corp. Selective ethylbenzene disproportionation process (SEBDP) with ex situ selectivated zeolite catalysts
US5367099A (en) * 1993-05-28 1994-11-22 Mobil Oil Corp. Selective toluene disproportionation process (STDP) with ex situ selectivated zeolite catalyst
US5698756A (en) * 1993-05-28 1997-12-16 Mobil Oil Corporation Toluene alkylation with ethylene to produce para-ethyloluene
US5365004A (en) * 1993-05-28 1994-11-15 Mobil Oil Corp. Selective toluene disproportionation process (STDP) with ex situ selectivated zeolite catalysts
US5530170A (en) * 1993-05-28 1996-06-25 Mobil Oil Corporation Ethylbenzene alkylation with ethylene to produce para-diethylbenzene
US5476823A (en) * 1993-05-28 1995-12-19 Mobil Oil Corp. Method of preparation of ex situ selectivated zeolite catalysts for enhanced shape selective applications and method to increase the activity thereof
US5403800A (en) * 1993-05-28 1995-04-04 Mobil Oil Corp. Multiple impregnation technique for the preparation of ex situ selectivated zeolite catalysts
US6576582B1 (en) 1993-05-28 2003-06-10 Exxonmobil Oil Corporation Binderless ex situ selectivated zeolite catalyst
US5406015A (en) * 1993-05-28 1995-04-11 Mobil Oil Corp. Selective ethylbenzene disproportionation processes (SEBDP) with ex situ selectivated zeolite catalyst
US5726114A (en) * 1993-10-27 1998-03-10 Mobil Oil Corporation Method of preparation of ex situ selectivated zeolite catalysts for enhanced shape selective applications and methods to increase the activity thereof
US5430211A (en) * 1993-10-29 1995-07-04 The Dow Chemical Company Process of preparing ethylbenzene or substituted derivatives thereof
US5625104A (en) * 1995-06-06 1997-04-29 Mobil Oil Corporation Alkali metal ion exchanged selectivated zeolite catalyst
US5849968A (en) * 1995-06-06 1998-12-15 Mobil Oil Corporation Hydrocarbon conversion process with alkaline earth metal ion exchanged selectivated zeolite catalyst
US5773679A (en) * 1995-12-26 1998-06-30 Mobil Oil Corporation Performance enhancement of zeolite catalysts with water cofeed

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3677973A (en) * 1970-03-16 1972-07-18 Universal Oil Prod Co Transalkylation of alklaromatic hydrocarbons in contact with a zeolite catalyst composition
US3962364A (en) * 1975-03-28 1976-06-08 Mobil Oil Corporation Alkylation in presence of phosphorus-modified crystalline luminosilicate catalyst
US3965209A (en) * 1975-01-06 1976-06-22 Mobil Oil Corporation Selective production of para-xylene
US4016218A (en) * 1975-05-29 1977-04-05 Mobil Oil Corporation Alkylation in presence of thermally modified crystalline aluminosilicate catalyst
NZ183608A (en) * 1976-03-31 1978-12-18 Mobil Oil Corp Aluminosilicate zeolite catalyst for selectine production of para-diakyl substituted benzenes
US4011276A (en) * 1976-04-28 1977-03-08 Mobil Oil Corporation Disproportionation of toluene
PL199748A1 (pl) * 1976-07-19 1978-04-24 Mobil Oil Corp Sposob selektywnego wytwarzania p-dwualkilobenzenow
GB1582842A (en) * 1976-09-29 1981-01-14 Ici Ltd Production of alkylbenzenes
US4107224A (en) * 1977-02-11 1978-08-15 Mobil Oil Corporation Manufacture of ethyl benzene

Also Published As

Publication number Publication date
RO81335A (ro) 1983-07-07
MX4080E (es) 1981-12-04
RO81335B (ro) 1983-06-30
DD138310A5 (de) 1979-10-24
AU516383B2 (en) 1981-05-28
FR2398710B1 (es) 1984-06-22
IN150079B (es) 1982-07-17
ZA783841B (en) 1980-02-27
PL125353B1 (en) 1983-04-30
CS210651B2 (en) 1982-01-29
JPS6039248B2 (ja) 1985-09-05
US4117024A (en) 1978-09-26
PL208675A1 (pl) 1979-07-30
BE869256A (fr) 1979-01-25
AR219330A1 (es) 1980-08-15
BR7804893A (pt) 1979-03-13
IT7826252A0 (it) 1978-07-28
FR2398710A1 (fr) 1979-02-23
DE2829756A1 (de) 1979-02-15
JPS5427528A (en) 1979-03-01
NL7808042A (nl) 1979-01-31
IT1097769B (it) 1985-08-31
AU3827178A (en) 1980-01-31
GB1584547A (en) 1981-02-11
DE2829756C2 (es) 1988-05-19
CA1103703A (en) 1981-06-23

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