KR920000619A - 제오라이트 - Google Patents

제오라이트 Download PDF

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KR920000619A
KR920000619A KR1019910010377A KR910010377A KR920000619A KR 920000619 A KR920000619 A KR 920000619A KR 1019910010377 A KR1019910010377 A KR 1019910010377A KR 910010377 A KR910010377 A KR 910010377A KR 920000619 A KR920000619 A KR 920000619A
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catalyst
zeolite
hydrogen
cation
reactions
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레오넬로 케쓰씨 존
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수잔 제인 젠틀
임페리알 케미칼 인더스트리스 피엘씨
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Abstract

내용 없음

Description

제오라이트
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 실시예1의 생성물의 x-선 회절 패턴이다, 제2도는 실시예2의 생성물의 x-선 회절 패턴이다, 제3도는 실시예6의 생성물의 x-선 회절 패턴이다.

Claims (18)

  1. 무수물을 기본으로 할때 다음과 같은 일반식으로 (화합물의 몰비)표시되는 조성을 지니며 표1에 나타난 라인들은 포함하는 X-선 회절 팬턴을 갖는 NU-86으로 표시되는 제오라이트 :
    100XO2: 10이하의 Y2O3: 20이하의 R2/NO
    식중, R은 하나이상의 n가 양이온, 7는 실리콘 및/또는 게르마늄, Y는 하나이상의 알루미늄, 철, 갈륨, 붕소,티타늄, 바나듐. 지르코늄, 몰리브데늄, 비소, 안티모니, 크로뮴 및 망간.
  2. 제1항에 있어서, 무수물을 기본으로할때 다음과 같은 일반식으로 (산화물의 몰비) 표시되는 조성을 지닌 제오라이트 :
    100XO2: 10이하의 Y2O3: 10이하의 10Q : 10이하의 M2O
    식중,Q는 일반식 ( (R1R2R3) N (CH2)mN (R4R5R6) )2+을 갖는 폴리메틸렌 알파, 오메가-디암모늄 양이온 R1,R2,R3, R4, R5및 R6는 서로 무관하게 C1-C3알킬, m은 8또는 9, M은 알카리금속 및/또는 암모늄.
  3. 제1항 또는 제2항에 있어서, x가 실리콘이고 Y가 알루미늄인 제오라이트.
  4. 제1항에 있어서, 수소, 암모늄 또는 금속-함유물 형태인 제오라이트
  5. 최소한 하나의 산화물 XO2의 쏘스, 최소한 하나의 질소-함유 유기 양이온 Q또는 이의 전구체, 최소한 하나의 산화물 Y2O3거 쏘스 및 임의의 1가 양이온의 쏘스로 구성되며, 몰조성이 최소한 10의 X02/Y203, 0.01-2의 (R1/n) OH/XO2, 1-500의 H2O/XO2, 0.005-1의 Q/XO2, 0-5의 LpZ/XO2, 인 수성 흔합물을 반응시키고 결정화 작용이 일어날때가지 계속 반응시키는 것으로 구성되는, 제1항의 제오라이트 NU-86의 제조방법. 식중, X는 실리콘 및/또는 게르마늄, Q는 일반식 (R1R2R3) N (CH2)mN (R4R5R6)2+의 폴리메틸렌 알파, 오메가-디암모늄 양이온, Y는 하나이상의 알루미늄, 철, 갈륨, 붕소. 티타늄. 바나듐, 지르코늄. 몰리브데늄. 비소,안티모니, 크로뮴 및 망간, R은 Q및/또는 M을 포함할 수 있는 n가의 양이온, M은 알카리 금속 양이온 및/또는 암모늄, Z는 P가의 음이온, L은 알카리 금속 및/또는 암모늄 이온.
  6. 제5항에 있어서, XO2/Y2O3의 비가 최소한 10이고 60을 넘지 않는 방법.
  7. i)갓 만들어진 NU-86을 임의로 하소시키고, ii)산이나 또는 암모늄염 용액으로 이온교환시키는 것으로 구성된 수소형태의 제오라이트 NU-86을 만드는 제조방법.
  8. R이 최소한 부분적으로 수소인 제1항의 재오라이트 NU-86으로 구성된 촉매.
  9. R이 수소이외의 것인 제1항의 제오라이트 NU-86으로 구성된 촉매.
  10. 제8항에 있어서, 수소가 금속에 의해 부분적으로 또는 완전하게 대체된 촉매.
  11. 제8항 부터 제10항가지중 어느 한 항에 있어서, a) 결합재; b) 촉매 지지물질; c)또 다른 제오라이트 또는 분자체: d) 금속: 및 e) 또다른 촉매 또는 이들의 조합물로 부터 선택된 성분으로 더 이루어진 촉매.
  12. 전환 조건하에서 유기 화합물을 제8항부터 제11항중 어느 한 항의 촉매와 접촉시키는 것으로 구성된 유기 화합물의 전환방법.
  13. 산소가 있거나 또는 없는 상태에서 제8항부터 제11항가지 중 어느 한 항의 촉매를 사용하여 방향족 탄화수소를 a)알콜 교환반응: b)불균화반응: c)알콜재거반응, d)알콜화반응중 하나이상의 반응시키는 방법.
  14. 수소가 있거나 또는 없는 상태에서 제8항부터 제11항가지 중 어느한 항의 촉매를 사용하며 치환된 방향족 화합물 또는 지방족 탄화 수소를 이성화시키는 방법.
  15. 수소가 있거나 또는 없는 상태에서 제8항부떠 재11항가지중 어느 한항의 촉매를 사용하여 지방족 탄화수소를 분해시키는 방법.
  16. 제8항부터 제11항가지증 어느 한 항의 촉매를 사용하여 탄화수소 공급물을 욕탄가가 높은 가솔린으로 분해시키는 방법.
  17. 제8항 부터 재11항가지중 어느 한 항의 촉매를 사용하여 지방족 탄화수소를 방향족화시키는 방법.
  18. 제8항부터 제11항가지중 어느 한 항에 있어서, 알콜 및 암모니아로부틴 아민을 제조하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개되는 것임.
KR1019910010377A 1990-06-22 1991-06-22 제올라이트 KR100195902B1 (ko)

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IN184830B (ko) 2000-09-30
EP0463768A3 (en) 1992-04-29
DE69122911T2 (de) 1997-03-20
KR100195902B1 (ko) 1999-06-15
US5108579A (en) 1992-04-28
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DE69122911D1 (de) 1996-12-05
AU7836891A (en) 1992-01-02
AU641018B2 (en) 1993-09-09
EP0463768B1 (en) 1996-10-30
ZA914540B (en) 1992-03-25
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ES2095911T3 (es) 1997-03-01
NO912444L (no) 1991-12-23
CA2044959C (en) 2001-06-05
JP3347752B2 (ja) 2002-11-20
GB9013916D0 (en) 1990-08-15
CA2044959A1 (en) 1991-12-23
EP0463768A2 (en) 1992-01-02
CN1058196A (zh) 1992-01-29

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