KR840004122A - N- 포스포노 메틸글리신 유도체의 제조방법 - Google Patents

N- 포스포노 메틸글리신 유도체의 제조방법 Download PDF

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KR840004122A
KR840004122A KR1019830000894A KR830000894A KR840004122A KR 840004122 A KR840004122 A KR 840004122A KR 1019830000894 A KR1019830000894 A KR 1019830000894A KR 830000894 A KR830000894 A KR 830000894A KR 840004122 A KR840004122 A KR 840004122A
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Prior art keywords
hydrogen
salt
formula
phenyl
iminourea
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KR1019830000894A
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English (en)
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바켈 이자크
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벤-지온 게슈리
게슈리 레이버 래토리스 엘 티 디
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Publication of KR840004122A publication Critical patent/KR840004122A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/44—Amides thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Molecular Biology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

내용 없음

Description

N-포스포노 메틸글리신 유도체의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (15)

  1. 물, 산화제 및 하기구조식(Ⅲ)의 N-(포스포노메틸)이미노디아세트산 이미노우레아염을 혼합한 후, 상기 산화제 및 그 염이 반응하여 하기 구조식(Ⅰ)의 화합물을 생성하는 온도까지 상기 혼합물을 가열하여 하기 구소식(Ⅰ)의 N-포스포노메틸글리신 유도체를 제조하는 방법.
    상기에서, R1,R2및 R3는 각각 -OH 및 -OR4로부터 선정되며, 여기서 R4는 하기 구조식(Ⅱ)의 양이온 이미노우레아유도체를 형성하는 염이며, n은 1 또는 2이며,
    상기에서, R5, R5',R6,R6'및 R7은 각각 H, NH2, CH2OH,의해 선택적으로 치환된 아릴시클로알킬, 직쇄 또는 측쇄알킬, 또는 알케닐기, 또는 알킬아릴기이다. 단, (a) R1,R2및 R3중 1 또는 2는 OR4이고, (b) R5, R5',R6,R6' 중 2이하는 아릴 또는 치환된 아릴이고, (c) R5, R5',R6,R6'및 R7중 하나는 CH20H이다.
  2. 제1항에 있어서, 산화제가 산소분자 함유가스이고, 활성화탄소로 구성된 축매존재하에 반응이 실시되는 것을 특징으로 하는 방법.
  3. 제1항에 있어서, 산화제가 H2O2인 것을 특징으로 하는 방법.
  4. 제1항에 있어서, R5,R5',R6,R6' 중 하나가 아미노기이고 다른 것은 수소인 것을 특징으로 하는 방법.
  5. 제1항에 있어서, R5또는 R5'가 페닐 또는 메틸페닐이고 다른 것은 수소이거나, 또는 R6또는 R6'가 페닐 또는 메틸페닐이고 다른 것은 수소인 것을 특징으로 하는 방법.
  6. 제1항에 있어서, R1및 R2가 OR4이고 R3가 하이드록시인 것을 특징으로 하는 방법.
  7. 제1항에 있어서, R2가 OR4이고 R1및 R3가 하이드록시인 것을 특징으로 하는 방법.
  8. 제1항에 있어서, R5, R5',R6및 R6'중 하나가 니트로기이고, 나머지도 수소인것을 특징으로하는 방법.
  9. 제1항에 있어서, 상기 알킬 및 알케닐기가 1-6인 탄소원자를 갖는 것을 특징으로 하는 방법.
  10. 제1항에 있어서, 상기 할로겐이 염소인 것을 특징으로 하는 방법.
  11. 제1항에 있어서, R5, R5',R6,R6'및 R7이 각각 H,NH2페닐, 알킬 및 톨릴로부터 선정되는 것을 특징으로 하는 방법.
  12. 제1항에 있어서, R5, R5',R6,R6'및 R7이 모두 수소인 것을 특징으로 하는 방법.
  13. 청구범위 제1항에 의해 제조된 구조식(Ⅰ)의 N-포스포노메틸글리신이미노우레아염.
  14. 구조식(Ⅰ)의 N-포스포노메틸글리신 이미노우레아염 약 1.75-2.5몰과 물 1ℓ당 표면활성제 2-5%를 혼합하여 초제제 조성물을 제조하는 방법.
  15. 제14항에 따라 제조된 조성물의 제초유효량을 이용하여 잡초를 제거하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019830000894A 1982-03-08 1983-03-05 N- 포스포노 메틸글리신 유도체의 제조방법 KR840004122A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IL65187A IL65187A (en) 1982-03-08 1982-03-08 N-phosphonomethylglycine derivatives,processes for their preparation and herbicidal compositions containing them
IL65187 1982-03-08

Publications (1)

Publication Number Publication Date
KR840004122A true KR840004122A (ko) 1984-10-06

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KR1019830000894A KR840004122A (ko) 1982-03-08 1983-03-05 N- 포스포노 메틸글리신 유도체의 제조방법

Country Status (17)

Country Link
US (1) US4397676A (ko)
EP (1) EP0088180A1 (ko)
JP (1) JPS58219193A (ko)
KR (1) KR840004122A (ko)
AU (1) AU1135183A (ko)
BR (1) BR8301201A (ko)
DK (1) DK89083A (ko)
ES (1) ES8402843A1 (ko)
FI (1) FI830723L (ko)
GR (1) GR78372B (ko)
IE (1) IE830275L (ko)
IL (1) IL65187A (ko)
NO (1) NO830500L (ko)
PH (1) PH19118A (ko)
PT (1) PT76340B (ko)
RO (1) RO86425B (ko)
ZA (1) ZA831153B (ko)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL66824A0 (en) * 1982-06-25 1982-12-31 Geshuri Lab Ltd Process for producing n-phosphonomethylglycine derivatives and herbicidal compounds and compositions prepared thereby
IL68716A (en) * 1983-05-17 1987-03-31 Geshuri Lab Ltd Process for producing n-phosphonomethylglycine
ES534413A0 (es) * 1983-07-27 1986-01-01 Rhone Poulenc Agrochimie Procedimiento de preparacion de sulfonamidas con grupo ansinometilfosfonico
US4568432A (en) * 1984-12-28 1986-02-04 Monsanto Company Process for preparing glyphosate and glyphosate derivatives
HUT41415A (en) * 1984-12-28 1987-04-28 Monsanto Co Process for preparing n-phosphono-methyl-glycine derivatives
US5580841A (en) * 1985-05-29 1996-12-03 Zeneca Limited Solid, phytoactive compositions and method for their preparation
US5468718A (en) * 1985-10-21 1995-11-21 Ici Americas Inc. Liquid, phytoactive compositions and method for their preparation
US5047079A (en) * 1986-08-18 1991-09-10 Ici Americas Inc. Method of preparation and use of solid, phytoactive compositions
NZ231897A (en) * 1988-12-30 1992-09-25 Monsanto Co Dry water-soluble granular composition comprising glyphosate and a liquid surfactant
US6930075B1 (en) 1990-11-02 2005-08-16 Monsanto Technology, Llc Fatty acid-based herbicidal composition
IL101539A (en) 1991-04-16 1998-09-24 Monsanto Europe Sa Mono-ammonium salts of the history of N phosphonomethyl glycyl which are not hygroscopes, their preparations and pesticides containing
CA2148840A1 (en) * 1992-11-06 1994-05-26 Jim F. Stewart Dry water-dispersible glyphosate phytoactive formulation
DE19500121A1 (de) * 1995-01-04 1996-07-11 Bayer Ag Verfahren zur Herstellung von N-Phosphonomethylglycin
US5948938A (en) * 1995-03-07 1999-09-07 Sankyo Company, Limited Process for preparing N-phosphonomethylglycine
TW322481B (ko) * 1995-03-07 1997-12-11 Sankyo Co
ITTO980048A1 (it) * 1998-01-20 1999-07-20 Ipici Spa Composizioni erbicide, procedimenti per la loro preparazione ed impieghi
EP1538910A2 (en) * 2002-08-31 2005-06-15 Monsanto Technology LLC Process for the preparation of a dry pesticidal composition containing a dicarboxylate component
US20050037924A1 (en) * 2002-08-31 2005-02-17 Monsanto Technology Llc Sodium glyphosate compositions and process for their preparation
AR037559A1 (es) * 2002-11-19 2004-11-17 Atanor S A Una formulacion herbicida solida de n-fosfonometilglicina, bajo la forma de polvo, granulos o escamas, soluble o dispersable en agua, y el procedimiento para preparar dicha composicion
US7318374B2 (en) 2003-01-21 2008-01-15 Victor Guerrero Wire cloth coffee filtering systems
EP1599182A4 (en) * 2003-02-21 2008-08-20 Rhodia ORAL HYGIENE AGENT ULTRA-SOFT ANTI-SENSITIVITY, ANTI-CARIES, ANTI-TASKS, ANTI-PLAQUE
US8470741B2 (en) * 2003-05-07 2013-06-25 Croda Americas Llc Homogeneous liquid saccharide and oil systems
US7461587B2 (en) 2004-01-21 2008-12-09 Victor Guerrero Beverage container with wire cloth filter
US8268749B2 (en) * 2004-09-17 2012-09-18 Monsanto Technology Llc Fast symptom glyphosate formulations
CN102792969B (zh) 2005-03-04 2015-01-21 孟山都技术公司 减轻用除草剂草甘膦制剂处理的草甘膦耐受性转基因棉花植物内的坏死
CN102414167B (zh) 2009-04-24 2016-01-06 亨斯迈石油化学有限责任公司 在可注册的、稳定的农业制剂中的含氮羟乙基磺酸盐
US9271488B2 (en) 2009-04-24 2016-03-01 Huntsman Petrochemical Llc Isethionic acid salts in field ready spray and tank mixes
ES2764485T3 (es) 2009-05-07 2020-06-03 Huntsman Corporation Australia Pty Ltd Dispersantes en disoluciones con alto contenido electrolítico
WO2011008453A2 (en) 2009-06-30 2011-01-20 Monsanto Technology Llc N-phosphonomethylglycine guanidine derivative salts

Family Cites Families (7)

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Publication number Priority date Publication date Assignee Title
CH505066A (de) * 1967-09-15 1971-03-31 Bayer Ag Verfahren zur Herstellung von sulfonsauren Salzen substituierter Guanidine
US3799758A (en) * 1971-08-09 1974-03-26 Monsanto Co N-phosphonomethyl-glycine phytotoxicant compositions
US3853530A (en) * 1971-03-10 1974-12-10 Monsanto Co Regulating plants with n-phosphonomethylglycine and derivatives thereof
US3835000A (en) * 1972-12-21 1974-09-10 Monsanto Co Electrolytic process for producing n-phosphonomethyl glycine
US3969398A (en) * 1974-05-01 1976-07-13 Monsanto Company Process for producing N-phosphonomethyl glycine
NL7713959A (nl) * 1976-12-20 1978-06-22 Monsanto Co Werkwijze voor het bereiden van n-fosfono- methylglycinezouten.
US4315765A (en) * 1980-12-04 1982-02-16 Stauffer Chemical Company Trialkylsulfonium salts of n-phosphonomethylglycine and their use as plant growth regulators and herbicides

Also Published As

Publication number Publication date
JPS58219193A (ja) 1983-12-20
ZA831153B (en) 1984-03-28
DK89083D0 (da) 1983-02-25
ES519933A0 (es) 1984-03-16
AU1135183A (en) 1983-09-15
IL65187A (en) 1985-03-31
BR8301201A (pt) 1983-11-22
FI830723L (fi) 1983-09-09
RO86425A (ro) 1985-06-29
PT76340B (en) 1985-11-28
ES8402843A1 (es) 1984-03-16
PH19118A (en) 1986-01-06
IE830275L (en) 1983-09-08
RO86425B (ro) 1985-06-30
NO830500L (no) 1983-09-09
FI830723A0 (fi) 1983-03-03
US4397676A (en) 1983-08-09
PT76340A (en) 1983-04-01
EP0088180A1 (en) 1983-09-14
DK89083A (da) 1983-09-09
IL65187A0 (en) 1982-05-31
GR78372B (ko) 1984-09-26

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