KR850007066A - 염소화된 포스포릴메틸카르보닐피라졸 유도체의 제조방법 - Google Patents
염소화된 포스포릴메틸카르보닐피라졸 유도체의 제조방법 Download PDFInfo
- Publication number
- KR850007066A KR850007066A KR1019850001571A KR850001571A KR850007066A KR 850007066 A KR850007066 A KR 850007066A KR 1019850001571 A KR1019850001571 A KR 1019850001571A KR 850001571 A KR850001571 A KR 850001571A KR 850007066 A KR850007066 A KR 850007066A
- Authority
- KR
- South Korea
- Prior art keywords
- alkyl
- alkoxy
- butoxy
- carbon atoms
- represents hydrogen
- Prior art date
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- BNWRKKRNBHHWIM-UHFFFAOYSA-N 2-(oxo-$l^{5}-phosphanylidyne)-1-(1h-pyrazol-5-yl)ethanone Chemical class O=P#CC(=O)C1=CC=NN1 BNWRKKRNBHHWIM-UHFFFAOYSA-N 0.000 title claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 9
- 239000001257 hydrogen Substances 0.000 claims 9
- 125000000217 alkyl group Chemical group 0.000 claims 7
- 125000004432 carbon atom Chemical group C* 0.000 claims 6
- 229910052736 halogen Inorganic materials 0.000 claims 5
- 150000002367 halogens Chemical class 0.000 claims 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 4
- 125000003545 alkoxy group Chemical group 0.000 claims 4
- 229910052801 chlorine Chemical group 0.000 claims 4
- 239000000460 chlorine Chemical group 0.000 claims 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 3
- 125000003710 aryl alkyl group Chemical group 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- -1 ethoxy, n-propoxy, i-propoxy, n-butoxy, i-butoxy, secondary-butoxy, tert-butoxy Chemical group 0.000 claims 2
- 150000002431 hydrogen Chemical class 0.000 claims 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 1
- 125000004453 alkoxycarbonyl group Chemical group 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 150000001721 carbon Chemical group 0.000 claims 1
- 239000012320 chlorinating reagent Substances 0.000 claims 1
- 239000003085 diluting agent Substances 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims 1
- 150000003217 pyrazoles Chemical class 0.000 claims 1
- 125000005415 substituted alkoxy group Chemical group 0.000 claims 1
- 125000000547 substituted alkyl group Chemical group 0.000 claims 1
- 125000004213 tert-butoxy group Chemical group [H]C([H])([H])C(O*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/24—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing heterocyclic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
- C07F9/576—Six-membered rings
- C07F9/58—Pyridine rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/645—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having two nitrogen atoms as the only ring hetero atoms
- C07F9/6503—Five-membered rings
- C07F9/65031—Five-membered rings having the nitrogen atoms in the positions 1 and 2
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (3)
- 하기 일반식(Ⅱ)의 포스포릴메틸카르보닐피라졸 유도체를 필요시 산 수용체의 존재하 및 필요시 회석제의 존재하에서, 염소화제와 반응시킴을 특징으로 하여, 하기 일반식(Ⅰ)의 염소화된 포스포릴메티카르보닐 피라졸 유도체를 제조하는 방법.상기 식에서, R1은 임의로 치환된 알킬, 아릴, 아르알킬, 알콕시 또는 아르알콕시 라디칼을 나타내고, R2는 임의로 치환된, 알콕시 또는 아르알콕시라디칼을 나타내거나 R1및 R2가 함께는 알칸디옥시 라디칼을 나타내며, X는 수소 또는 염소를 나타내고, R3및 R5는 동일하거나 상이하며, 수소 또는 알킬을 나타내고, R4는 수소, 할로겐 또는 알킬을 나타낸다.
- 제1항에 있어서, R1이 할로겐 또는 C1내지 C4알콕시에 의해 임의로 일치환 또는 다치환 될 수 있는 탄소수 6이하의 알킬, 탄소수 6이하의 알콕시, 아릴부분에 탄소원자 6내지 10개를 가지며 알킬부분에 탄소원자 2개 이하를 갖는 아르아킬 및 아르알콕시로 이루어진 그룹중에서 선택된 라디칼을 나타내거나, 할로겐, 니트로, C1내지 C4알킬, C1내지 C4알콕시 및/또는 C1내지 C4알콕시카르보닐에 의해 임의로 일치환 또는 다치환된 페닐을 나타내며, R2는 탄소수 6이하이며, 할로겐 또는 C1내지 C4알콕시에 의해 임의로 일치환 또는 다치환된 알콕시를 나타내거나, 아릴부분에 6내지 10개의 탄소원자를 가지며 알킬부분에 2개 이하의 탄소 원자를 갖는 아르알콕시를 나타내거나, R1및 R2가 함께는 알킬부분에 2내지 5개의 탄소원자를 갖는 직쇄 또는 측쇄의 알칸디옥시 라디칼을 나타내며, X가 수소 또는 염소를 나타내고, R3및 R5는 동일하거나 상이하며 수소 또는 C1내지 C4알킬을 나타내고, R4가 수소, 할로겐 또는 C1내지 C4알킬을 나타내는 방법.
- 제1항에 있어서, R1이 에톡시, n-프로폭시, i-프로폭시, n-부톡시, i-부톡시, 2급-부톡시, 3급-부톡시 또는 페닐을 나타내며, R2가 에톡시, n-프로폭시, i-프로폭시, n-부톡시, i-부톡시, 2급-부톡시 또는 3급-부톡시를 나타내고, X가 수소 또는 염소를 나타내며, R3및 R5가 동일하거나 상이하며 수소 또는 메틸을 나타내고, R4가 수소 또는 염소를 나타내는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19843409081 DE3409081A1 (de) | 1984-03-13 | 1984-03-13 | Chlorierte phosphorylmethylcarbonylpyrazol-derivate |
| DE3409081.9 | 1984-03-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR850007066A true KR850007066A (ko) | 1985-10-30 |
Family
ID=6230296
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019850001571A KR850007066A (ko) | 1984-03-13 | 1985-03-12 | 염소화된 포스포릴메틸카르보닐피라졸 유도체의 제조방법 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4602931A (ko) |
| EP (1) | EP0155566A1 (ko) |
| JP (1) | JPS60204793A (ko) |
| KR (1) | KR850007066A (ko) |
| BR (1) | BR8501082A (ko) |
| DE (1) | DE3409081A1 (ko) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10046267A1 (de) * | 2000-09-19 | 2002-03-28 | Bayer Ag | Verwendung von Riboflavin und Flavinderivaten als Inhibitoren von Chitinasen |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH310406A (de) * | 1951-09-25 | 1955-10-15 | Ciba Geigy | Verfahren zur Herstellung einer Phosphor und Halogen enthaltenden organischen Verbindung. |
| US4197295A (en) * | 1978-10-02 | 1980-04-08 | Stauffer Chemical Company | Pyrazole phosphates and phosphonates - insecticides |
| US4371526A (en) * | 1981-08-21 | 1983-02-01 | E. R. Squibb & Sons, Inc. | Phosphinylalkanoyl substituted 4,5-dihydropyrazole-5-carboxylic acid derivatives and hypotensive method and composition |
| EP0078613B1 (en) * | 1981-11-02 | 1986-10-01 | Imperial Chemical Industries Plc | Substituted propyl phosphonic acid derivatives, their use as herbicides, herbicidal compositions containing them, and methods of preparing them |
| DE3313070A1 (de) * | 1983-04-12 | 1984-10-18 | Bayer Ag, 5090 Leverkusen | Chlorierte phosphorylmethylcarbonyl-derivate, verfahren zu ihrer herstellung und ihre verwendung in pflanzenschutmitteln |
-
1984
- 1984-03-13 DE DE19843409081 patent/DE3409081A1/de not_active Withdrawn
-
1985
- 1985-03-01 EP EP85102291A patent/EP0155566A1/de not_active Withdrawn
- 1985-03-05 US US06/708,324 patent/US4602931A/en not_active Expired - Fee Related
- 1985-03-11 JP JP60046687A patent/JPS60204793A/ja active Pending
- 1985-03-12 KR KR1019850001571A patent/KR850007066A/ko not_active Application Discontinuation
- 1985-03-12 BR BR8501082A patent/BR8501082A/pt unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BR8501082A (pt) | 1985-10-29 |
| EP0155566A1 (de) | 1985-09-25 |
| DE3409081A1 (de) | 1985-09-19 |
| JPS60204793A (ja) | 1985-10-16 |
| US4602931A (en) | 1986-07-29 |
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