ES8502707A1 - Procedimiento para preparar n-fosfonometilglicina - Google Patents
Procedimiento para preparar n-fosfonometilglicinaInfo
- Publication number
- ES8502707A1 ES8502707A1 ES525235A ES525235A ES8502707A1 ES 8502707 A1 ES8502707 A1 ES 8502707A1 ES 525235 A ES525235 A ES 525235A ES 525235 A ES525235 A ES 525235A ES 8502707 A1 ES8502707 A1 ES 8502707A1
- Authority
- ES
- Spain
- Prior art keywords
- phosphonometilglicina
- chloride
- general formula
- phosphonomethylglycine
- production
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 title 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000004009 herbicide Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C233/00—Carboxylic acid amides
- C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
- C07C233/45—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by carboxyl groups
- C07C233/46—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by carboxyl groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom
- C07C233/47—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by carboxyl groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom having the carbon atom of the carboxamide group bound to a hydrogen atom or to a carbon atom of an acyclic saturated carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
PROCEDIMIENTO PARA LA PREPARACION DE N-FOSFONOMETILGLICINA.COMPRENDE LAS SIGUIENTES OPERACIONES: PRIMERA, SE HACE REACCIONAR 1,3,5-TRICARBOALCOXIMETILHEXAHIDRO-1,3,5-TRIAZINA, DE FORMULA GENERAL (I), CON UN CLORURO DE ACILO DE FORMULA (II), PARA FORMAR LA N-CARBOALCOXIMETIL-N-HALOMETIL AMIDA DE CLORURO DE ACILO; SEGUNDA, SE HACE REACCIONAR LA AMIDA OBTENIDA CON UN FOSFITO, PARA OBTENER UN COMPUESTO DE FORMULA GENERAL (III); Y POR ULTIMO, SE HIDROLIZA EL FOSFONATO OBTENIDO PARA FORMAR LA N-FOSFONOMETILGLICINA.DE APLICACION COMO HERBICIDAS POST-BROTE.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/412,624 US4425284A (en) | 1982-08-30 | 1982-08-30 | Method for preparation of N-phosphonomethylglycine |
US06/468,223 US4482504A (en) | 1982-08-30 | 1983-02-22 | Method for preparation of N-phosphonomethylglycine |
Publications (2)
Publication Number | Publication Date |
---|---|
ES525235A0 ES525235A0 (es) | 1985-01-16 |
ES8502707A1 true ES8502707A1 (es) | 1985-01-16 |
Family
ID=27021837
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES525235A Expired ES8502707A1 (es) | 1982-08-30 | 1983-08-30 | Procedimiento para preparar n-fosfonometilglicina |
Country Status (12)
Country | Link |
---|---|
US (1) | US4482504A (es) |
EP (1) | EP0104775B1 (es) |
AU (1) | AU554999B2 (es) |
BR (1) | BR8304711A (es) |
CA (1) | CA1205488A (es) |
DD (1) | DD213221A5 (es) |
DE (1) | DE3365452D1 (es) |
DK (1) | DK394783A (es) |
ES (1) | ES8502707A1 (es) |
HU (1) | HU194257B (es) |
IL (1) | IL69583A (es) |
MX (1) | MX157972A (es) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4569802A (en) * | 1983-06-27 | 1986-02-11 | Stauffer Chemical Company | Method for preparation of N-phosphonomethylglycine |
ES8603901A1 (es) * | 1983-07-27 | 1986-01-01 | Rhone Poulenc Agrochimie | Procedimiento de preparacion de sulfonamidas con grupo ansinometilfosfonico |
IL76842A0 (en) * | 1984-12-28 | 1986-02-28 | Monsanto Co | Novel n-acyl-n-isopropyl-glycine derivatives |
US5041627A (en) * | 1988-11-25 | 1991-08-20 | Monsanto Company | Preparation of N-acyl-aminomethylphosphonates |
AR027024A1 (es) * | 1999-12-23 | 2003-03-12 | Basf Ag | Procedimiento para la preparacion de n-fosfonometilglicina |
DE10130135A1 (de) * | 2001-06-22 | 2003-01-02 | Basf Ag | Verfahren zur Herstellung von N-Phosphonomethylglycin |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3988142A (en) * | 1972-02-03 | 1976-10-26 | Monsanto Company | Increasing carbohydrate deposition in plants with N-phosphono-methylglycine and derivatives thereof |
GB1445087A (en) * | 1972-11-08 | 1976-08-04 | Ici Ltd | Preparing n-phosphonomethylglycine and nitrile intermediates therefor |
US4053505A (en) * | 1976-01-05 | 1977-10-11 | Monsanto Company | Preparation of n-phosphonomethyl glycine |
-
1983
- 1983-02-22 US US06/468,223 patent/US4482504A/en not_active Expired - Fee Related
- 1983-08-26 EP EP83304951A patent/EP0104775B1/en not_active Expired
- 1983-08-26 DE DE8383304951T patent/DE3365452D1/de not_active Expired
- 1983-08-29 HU HU833017A patent/HU194257B/hu not_active IP Right Cessation
- 1983-08-29 DD DD83254313A patent/DD213221A5/de not_active IP Right Cessation
- 1983-08-29 MX MX198527A patent/MX157972A/es unknown
- 1983-08-29 CA CA000435543A patent/CA1205488A/en not_active Expired
- 1983-08-29 IL IL69583A patent/IL69583A/xx unknown
- 1983-08-30 BR BR8304711A patent/BR8304711A/pt unknown
- 1983-08-30 AU AU18526/83A patent/AU554999B2/en not_active Ceased
- 1983-08-30 ES ES525235A patent/ES8502707A1/es not_active Expired
- 1983-08-30 DK DK394783A patent/DK394783A/da unknown
Also Published As
Publication number | Publication date |
---|---|
ES525235A0 (es) | 1985-01-16 |
EP0104775A1 (en) | 1984-04-04 |
DK394783A (da) | 1984-03-01 |
HU194257B (en) | 1988-01-28 |
EP0104775B1 (en) | 1986-08-20 |
BR8304711A (pt) | 1984-04-10 |
CA1205488A (en) | 1986-06-03 |
DK394783D0 (da) | 1983-08-30 |
IL69583A0 (en) | 1983-11-30 |
DD213221A5 (de) | 1984-09-05 |
MX157972A (es) | 1988-12-28 |
AU554999B2 (en) | 1986-09-11 |
DE3365452D1 (en) | 1986-09-25 |
AU1852683A (en) | 1984-03-08 |
US4482504A (en) | 1984-11-13 |
IL69583A (en) | 1986-11-30 |
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