ES8500284A1 - Procedimiento para preparar n-fosfonometilglicina. - Google Patents
Procedimiento para preparar n-fosfonometilglicina.Info
- Publication number
- ES8500284A1 ES8500284A1 ES523497A ES523497A ES8500284A1 ES 8500284 A1 ES8500284 A1 ES 8500284A1 ES 523497 A ES523497 A ES 523497A ES 523497 A ES523497 A ES 523497A ES 8500284 A1 ES8500284 A1 ES 8500284A1
- Authority
- ES
- Spain
- Prior art keywords
- reaction
- formula
- phosphonomethylglycine
- preparation
- tricianometilhexahidro
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 title abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 230000002363 herbicidal effect Effects 0.000 abstract 1
- 239000004009 herbicide Substances 0.000 abstract 1
- 230000007062 hydrolysis Effects 0.000 abstract 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 abstract 1
- 229910052740 iodine Inorganic materials 0.000 abstract 1
- 239000011630 iodine Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/44—Amides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PROCEDIMIENTO PARA LA OBTENCION DE N-FOSFONOMETILGLICINA.CONSISTE EN LA REACCION DE 1,3,5-TRICIANOMETILHEXAHIDRO-1,3,5-TRIAZINA CON CLORURO DE ACILO DE FORMULA RCOX, EN LA QUE R ES UN GRUPO ALIFATICO O AROMATICO Y X ES CLORO, BROMO O YODO; SEGUIDA DE LA REACCION DE LA AMIDA FORMADA CON UN FOSFITO DE FORMULA (I), EN LA QUE R1, R2 Y R3 PUEDEN SER VARIOS RADICALES; Y, FINALMENTE, HIDROLISIS DEL FOSFONATO FORMADO.ESTE COMPUESTO TIENE APLICACIONES EN AGRICULTURA COMO HERBICIDA POST-BROTE.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US39103382A | 1982-06-22 | 1982-06-22 | |
US06/465,931 US4427599A (en) | 1982-06-22 | 1983-02-14 | Method for preparation of N-phosphonomethylglycine |
Publications (2)
Publication Number | Publication Date |
---|---|
ES523497A0 ES523497A0 (es) | 1984-10-01 |
ES8500284A1 true ES8500284A1 (es) | 1984-10-01 |
Family
ID=27013360
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES523497A Expired ES8500284A1 (es) | 1982-06-22 | 1983-06-22 | Procedimiento para preparar n-fosfonometilglicina. |
Country Status (14)
Country | Link |
---|---|
US (1) | US4427599A (es) |
EP (1) | EP0097522B1 (es) |
KR (1) | KR840005156A (es) |
AU (1) | AU552736B2 (es) |
BR (1) | BR8303297A (es) |
CA (1) | CA1215999A (es) |
CS (1) | CS240964B2 (es) |
DD (1) | DD210055A5 (es) |
DE (2) | DE97522T1 (es) |
DK (1) | DK283083A (es) |
ES (1) | ES8500284A1 (es) |
IL (1) | IL69040A (es) |
PL (1) | PL140910B1 (es) |
RO (1) | RO88128A (es) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4534902A (en) * | 1982-06-22 | 1985-08-13 | Stauffer Chemical Company | Method for preparation of N-phosphonomethylglycine |
US4487724A (en) * | 1982-08-23 | 1984-12-11 | Stauffer Chemical Company | Method for preparation of N-phosphonomethylglycine |
US4569802A (en) * | 1983-06-27 | 1986-02-11 | Stauffer Chemical Company | Method for preparation of N-phosphonomethylglycine |
ES8603901A1 (es) * | 1983-07-27 | 1986-01-01 | Rhone Poulenc Agrochimie | Procedimiento de preparacion de sulfonamidas con grupo ansinometilfosfonico |
ATE36162T1 (de) * | 1984-06-04 | 1988-08-15 | Stauffer Chemical Co | Verfahren zur herstellung von nphosphonomethylglycin. |
US4654072A (en) * | 1985-09-17 | 1987-03-31 | Stauffer Chemical Company | Herbicidal phosphonomethyl amides |
US4810426A (en) * | 1986-01-28 | 1989-03-07 | Monsanto Company | Process for making glyphosate from n-phosphonomethyl-2-oxazolidone |
EP0402887B2 (en) * | 1989-06-15 | 2000-10-04 | FINCHIMICA S.p.A. | A method for the preparation of N-phosphonomethyl glycine |
AR027024A1 (es) * | 1999-12-23 | 2003-03-12 | Basf Ag | Procedimiento para la preparacion de n-fosfonometilglicina |
DE10130135A1 (de) | 2001-06-22 | 2003-01-02 | Basf Ag | Verfahren zur Herstellung von N-Phosphonomethylglycin |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1445087A (en) * | 1972-11-08 | 1976-08-04 | Ici Ltd | Preparing n-phosphonomethylglycine and nitrile intermediates therefor |
EP0038186B1 (en) * | 1980-04-14 | 1983-10-26 | Monsanto Company | Perfluoroamides of diaryl esters of n-phosphonomethylglycinonitrile, herbicidal compositions and herbicidal use thereof |
-
1983
- 1983-02-14 US US06/465,931 patent/US4427599A/en not_active Expired - Lifetime
- 1983-06-20 DK DK283083A patent/DK283083A/da not_active Application Discontinuation
- 1983-06-20 RO RO83111352A patent/RO88128A/ro unknown
- 1983-06-20 AU AU15939/83A patent/AU552736B2/en not_active Ceased
- 1983-06-21 DE DE198383303559T patent/DE97522T1/de active Pending
- 1983-06-21 DE DE8383303559T patent/DE3363499D1/de not_active Expired
- 1983-06-21 KR KR1019830002787A patent/KR840005156A/ko not_active Application Discontinuation
- 1983-06-21 IL IL69040A patent/IL69040A/xx not_active IP Right Cessation
- 1983-06-21 CS CS834553A patent/CS240964B2/cs unknown
- 1983-06-21 CA CA000430898A patent/CA1215999A/en not_active Expired
- 1983-06-21 DD DD83252204A patent/DD210055A5/de not_active IP Right Cessation
- 1983-06-21 BR BR8303297A patent/BR8303297A/pt not_active IP Right Cessation
- 1983-06-21 EP EP83303559A patent/EP0097522B1/en not_active Expired
- 1983-06-22 ES ES523497A patent/ES8500284A1/es not_active Expired
- 1983-06-22 PL PL1983242639A patent/PL140910B1/pl unknown
Also Published As
Publication number | Publication date |
---|---|
DE97522T1 (de) | 1984-09-27 |
AU552736B2 (en) | 1986-06-19 |
PL242639A1 (en) | 1984-07-16 |
PL140910B1 (en) | 1987-06-30 |
IL69040A0 (en) | 1983-10-31 |
BR8303297A (pt) | 1984-02-07 |
CS240964B2 (en) | 1986-03-13 |
EP0097522B1 (en) | 1986-05-14 |
CS455383A2 (en) | 1985-06-13 |
DE3363499D1 (en) | 1986-06-19 |
EP0097522A3 (en) | 1984-03-21 |
CA1215999A (en) | 1986-12-30 |
AU1593983A (en) | 1984-01-05 |
ES523497A0 (es) | 1984-10-01 |
EP0097522A2 (en) | 1984-01-04 |
DD210055A5 (de) | 1984-05-30 |
IL69040A (en) | 1986-07-31 |
DK283083A (da) | 1983-12-23 |
RO88128B (ro) | 1985-10-31 |
RO88128A (ro) | 1985-11-30 |
US4427599A (en) | 1984-01-24 |
KR840005156A (ko) | 1984-11-03 |
DK283083D0 (da) | 1983-06-20 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FD1A | Patent lapsed |
Effective date: 20040503 |