KR830010055A - 수용성 디스아조 화합물의 제조방법 - Google Patents
수용성 디스아조 화합물의 제조방법 Download PDFInfo
- Publication number
- KR830010055A KR830010055A KR1019820002211A KR820002211A KR830010055A KR 830010055 A KR830010055 A KR 830010055A KR 1019820002211 A KR1019820002211 A KR 1019820002211A KR 820002211 A KR820002211 A KR 820002211A KR 830010055 A KR830010055 A KR 830010055A
- Authority
- KR
- South Korea
- Prior art keywords
- group
- general formula
- substituted
- following general
- carbon atoms
- Prior art date
Links
- -1 disazo compound Chemical class 0.000 title claims 3
- 238000000034 method Methods 0.000 title claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 5
- 125000004432 carbon atom Chemical group C* 0.000 claims 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 4
- 239000002253 acid Substances 0.000 claims 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 3
- 125000001424 substituent group Chemical group 0.000 claims 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 2
- 150000001412 amines Chemical class 0.000 claims 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 2
- 229910052794 bromium Inorganic materials 0.000 claims 2
- 229910052801 chlorine Inorganic materials 0.000 claims 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims 2
- 125000001624 naphthyl group Chemical group 0.000 claims 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 2
- ZUQOBHTUMCEQBG-UHFFFAOYSA-N 4-amino-5-hydroxynaphthalene-1,7-disulfonic acid Chemical compound OS(=O)(=O)C1=CC(O)=C2C(N)=CC=C(S(O)(=O)=O)C2=C1 ZUQOBHTUMCEQBG-UHFFFAOYSA-N 0.000 claims 1
- APRRQJCCBSJQOQ-UHFFFAOYSA-N 4-amino-5-hydroxynaphthalene-2,7-disulfonic acid Chemical compound OS(=O)(=O)C1=CC(O)=C2C(N)=CC(S(O)(=O)=O)=CC2=C1 APRRQJCCBSJQOQ-UHFFFAOYSA-N 0.000 claims 1
- RJSYPKWVIJGNLO-UHFFFAOYSA-N CCOClOC Chemical compound CCOClOC RJSYPKWVIJGNLO-UHFFFAOYSA-N 0.000 claims 1
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 claims 1
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 230000008878 coupling Effects 0.000 claims 1
- 238000010168 coupling process Methods 0.000 claims 1
- 238000005859 coupling reaction Methods 0.000 claims 1
- 239000012954 diazonium Substances 0.000 claims 1
- 150000001989 diazonium salts Chemical class 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-O diazynium Chemical compound [NH+]#N IJGRMHOSHXDMSA-UHFFFAOYSA-O 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 claims 1
- 239000000376 reactant Substances 0.000 claims 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims 1
- XTHPWXDJESJLNJ-UHFFFAOYSA-N sulfurochloridic acid Chemical compound OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
- C07C303/22—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof from sulfonic acids, by reactions not involving the formation of sulfo or halosulfonyl groups; from sulfonic halides by reactions not involving the formation of halosulfonyl groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
- C09B62/02—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group directly attached to a heterocyclic ring
- C09B62/04—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group directly attached to a heterocyclic ring to a triazine ring
- C09B62/08—Azo dyes
- C09B62/09—Disazo or polyazo dyes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C245/00—Compounds containing chains of at least two nitrogen atoms with at least one nitrogen-to-nitrogen multiple bond
- C07C245/02—Azo compounds, i.e. compounds having the free valencies of —N=N— groups attached to different atoms, e.g. diazohydroxides
- C07C245/06—Azo compounds, i.e. compounds having the free valencies of —N=N— groups attached to different atoms, e.g. diazohydroxides with nitrogen atoms of azo groups bound to carbon atoms of six-membered aromatic rings
- C07C245/10—Azo compounds, i.e. compounds having the free valencies of —N=N— groups attached to different atoms, e.g. diazohydroxides with nitrogen atoms of azo groups bound to carbon atoms of six-membered aromatic rings with nitrogen atoms of azo groups bound to carbon atoms of six-membered aromatic rings being part of condensed ring systems
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
- C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
- C09B62/4401—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring with two or more reactive groups at least one of them being directly attached to a heterocyclic system and at least one of them being directly attached to a non-heterocyclic system
- C09B62/4403—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring with two or more reactive groups at least one of them being directly attached to a heterocyclic system and at least one of them being directly attached to a non-heterocyclic system the heterocyclic system being a triazine ring
- C09B62/4411—Azo dyes
- C09B62/4415—Disazo or polyazo dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Coloring (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (1)
- 등몰량의 1-아미노-8-나프톨-4,6-디설폰산 또는 1-아미노-8-나프톨-3,6-디설폰산을 강산 내지 약산범위내의 다음 일반식(6)의 아민의 디아조늄 화합물과 카플링시킨 다음 생성한 반응물을 약산내지 강알카린 범위내의 다음 일반식(7)의 아민의 디아조늄과 카플링시킴을 특징으로 하는 다음 일반식(1)의 수용성 디스아조 화합물의 제조방법.(1)(6)(7)상기에서, D1및 D2는 각각 페닐기 또는 나프틸기를 나타내며, 이들 모두는 하기에 정의된 일반식 잔기 Y 또는 Z의 기에 의하여 치환되며, 또한 설포, 염소, 브롬, 예를들면 에틸 특히 메틸의 저급알킬, 예를들면 에톡시 특히 메톡시의 저급알콕시로 구성되는 그룹으로부터 선택된 한개 또는 두 개의 치환체에 의하여 부가적으로 치환될 수 있으며, 또한 D1및 D2는 서로 같거나 다른 의미를 가질 수 있으며, Z는 다음 일반식(2a),(2b),(2c),(2d),(2e) 또는 (2f)의 기이며,상기에서 R은 탄소수 1내지 4를 갖는 알킬기, X는 염소원자, 아세톡시기, 티오설파토기, 포스페이트기 또는 설파토기이며, Y는 다음 일반식(3)의 기이며,(3)상기에서 R1은 수소원자 또는 탄소수 1 내지 4의 알킬기이며, R2는 수소원자 또는 탄소수 1내지 4의 알킬기이며, R1및 R2는 서로 같거나 다를 의미를 가질 수 있으며, A는 수소원자 또는 치환될 수 있는 탄소수 1내지 6의 알킬기, 또는 메틸, 에틸, 메톡시, 에톡시, 염소, 브롬, 카복시, 설포, 카바모일 및 설파모일로 구성되는 그룹중에서 치환체에 의하여 치환될 수 있은 페닐기이거나, 또는 일반식(4) -B-Z(여기에서 B는 페닐렌기 또는 나프탈렌기를 나타내며, 이들 모두는 하나의 설포기, 하나의 염소원자, 하나 또는 두개의 메틸기 또는 에틸기 및 하나 또는 두개의 메톡시 또는 에톡시기를 포함하는 것중에서 선택된 하나 또는 두 개의 치환체에 의하여 치환될 수 있으며, Z는 상기 언급한 바와같다)이미, n은 1 또는 2이며, m은 0 또는 1이며, (m+n)의 합계는 2가 되어야 하며, 일반식(1)의 화합물은 상기 언급한 일반식(2a)내지 (2f)의 기 및 일반식(5)(5)(여기에서 M은 수소원자 또는 등 가금속물)의 기에 속하는 적어도 3개의 필요한 기를 포함해야 한다.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3120187.3 | 1981-05-21 | ||
DE19813120187 DE3120187A1 (de) | 1981-05-21 | 1981-05-21 | Wasserloesliche disazoverbindungen, verfahren zu deren herstellung und ihre verwendung als farbstoffe |
Publications (2)
Publication Number | Publication Date |
---|---|
KR830010055A true KR830010055A (ko) | 1983-12-24 |
KR890000796B1 KR890000796B1 (ko) | 1989-04-07 |
Family
ID=6132860
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR8202211A KR890000796B1 (ko) | 1981-05-21 | 1982-05-20 | 수용성 디스아조 화합물의 제조방법 |
Country Status (9)
Country | Link |
---|---|
US (1) | US4730038A (ko) |
EP (1) | EP0065732B1 (ko) |
JP (1) | JPS57198757A (ko) |
KR (1) | KR890000796B1 (ko) |
AR (1) | AR246979A1 (ko) |
BR (1) | BR8202936A (ko) |
CS (1) | CS228928B2 (ko) |
DE (2) | DE3120187A1 (ko) |
IN (1) | IN157495B (ko) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3201114A1 (de) * | 1982-01-15 | 1983-07-28 | Bayer Ag, 5090 Leverkusen | Disazoreaktivfarbstoffe |
EP0120807B1 (de) * | 1983-02-24 | 1989-01-18 | Ciba-Geigy Ag | Reaktivfarbstoffe, deren Herstellung und Verwendung |
DE3325788A1 (de) * | 1983-03-15 | 1984-09-20 | Bayer Ag, 5090 Leverkusen | Faserreaktive disazofarbstoffe, verfahren zu ihrer herstellung und ihre verwendung zum faerben oder bedrucken von stubstraten |
DE3470555D1 (en) * | 1983-07-08 | 1988-05-26 | Ciba Geigy Ag | Reactive dyes, their preparation and their use |
EP0141367B1 (de) * | 1983-10-26 | 1988-03-30 | Ciba-Geigy Ag | Reaktivfarbstoffe, deren Herstellung und Verwendung |
JPH06104781B2 (ja) * | 1986-02-17 | 1994-12-21 | 住友化学工業株式会社 | ビスアゾ化合物およびそれを用いる染色または捺染法 |
DE3731202A1 (de) * | 1987-09-17 | 1989-07-13 | Basf Ag | Doppelankerreaktivfarbstoffe und benzylsulfonylverbindungen als deren zwischenprodukte |
US5210187A (en) * | 1988-07-28 | 1993-05-11 | Basf Aktiengesellschaft | Double attachment reactive dyes having alkyl- or alkenylsulfonyl and alkyl- or alkenylsulfonylalkyl groups |
US5112959A (en) * | 1989-06-01 | 1992-05-12 | Sumitomo Chemical Company, Limited | Polyazo dye compounds having plural vinylsulfone type fiber reactive groups in one molecule |
EP0501252B1 (de) * | 1991-02-27 | 1996-04-10 | Bayer Ag | Bifunktionelle Reaktivfarbstoffe |
US5428141A (en) * | 1991-12-05 | 1995-06-27 | Bayer Aktiengesellschaft | Azo dyestuffs containing fluorotriazinyl and vinylsulfonylmethyl-type reactive groups |
DE4203280A1 (de) * | 1992-02-06 | 1993-08-12 | Bayer Ag | Reaktivfarbstoffe, deren herstellung und verwendung |
DE59307910D1 (de) * | 1992-03-05 | 1998-02-12 | Ciba Geigy Ag | Reaktivfarbstoffe, Verfahren zu deren Herstellung und deren Verwendung |
TW411357B (en) * | 1994-11-17 | 2000-11-11 | Ciba Sc Holding Ag | Reactive azo dyes and their preparation |
GB9606933D0 (en) * | 1996-04-02 | 1996-06-05 | Zeneca Ltd | Compounds |
JP2001002952A (ja) * | 1999-04-19 | 2001-01-09 | Sumitomo Chem Co Ltd | ビスアゾ化合物又はその塩及びそれらの繊維材料への適用 |
GB2348648B (en) | 1999-04-07 | 2001-03-14 | Sumitomo Chemical Co | Bisazo compounds and process for dyeing or printing using them |
JP4595632B2 (ja) * | 1999-04-19 | 2010-12-08 | 住友化学株式会社 | ビスアゾ化合物又はその塩 |
EP1762569A1 (en) * | 2005-09-12 | 2007-03-14 | Alcasynn Pharmaceuticals Gmbh | Novel 6-amino-morphinan derivatives, method of manufacturing them and their application as analgesics |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1265698C2 (de) * | 1961-05-06 | 1968-11-07 | Hoechst Ag | Verfahren zur Erzeugung von nassechten Faerbungen und Drucken |
DE2807260C2 (de) * | 1978-02-21 | 1986-10-09 | Hoechst Ag, 6230 Frankfurt | Wasserlösliche Farbstoffe, Verfahren zu deren Herstellung, ihre Verwendung als faserreaktive Farbstoffe zum Färben und Bedrucken von Fasermaterialien |
DE2842640A1 (de) * | 1978-09-29 | 1980-04-10 | Bayer Ag | Reaktivfarbstoffe |
DE2951541A1 (de) * | 1979-12-21 | 1981-07-16 | Basf Ag, 6700 Ludwigshafen | Verbindungen mit reaktiven resten |
JPS56155250A (en) * | 1980-04-10 | 1981-12-01 | Nippon Kayaku Co Ltd | Reactive dis-azo compound, production thereof and dyeing method employing the same |
DE3033611A1 (de) * | 1980-09-06 | 1982-04-29 | Hoechst Ag, 6000 Frankfurt | Wasserloesliche disazoverbindungen, verfahren zu deren herstellung und ihre verwendung als farbstoffe |
-
1981
- 1981-05-21 DE DE19813120187 patent/DE3120187A1/de not_active Withdrawn
-
1982
- 1982-05-14 IN IN542/CAL/82A patent/IN157495B/en unknown
- 1982-05-17 EP EP82104301A patent/EP0065732B1/de not_active Expired
- 1982-05-17 DE DE8282104301T patent/DE3265589D1/de not_active Expired
- 1982-05-19 AR AR82289450A patent/AR246979A1/es active
- 1982-05-20 KR KR8202211A patent/KR890000796B1/ko active
- 1982-05-20 CS CS823733A patent/CS228928B2/cs unknown
- 1982-05-20 BR BR8202936A patent/BR8202936A/pt not_active IP Right Cessation
- 1982-05-20 JP JP57084144A patent/JPS57198757A/ja active Granted
-
1985
- 1985-12-16 US US06/811,303 patent/US4730038A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
AR246979A1 (es) | 1994-10-31 |
DE3265589D1 (en) | 1985-09-26 |
US4730038A (en) | 1988-03-08 |
KR890000796B1 (ko) | 1989-04-07 |
EP0065732B1 (de) | 1985-08-21 |
DE3120187A1 (de) | 1982-12-09 |
IN157495B (ko) | 1986-04-12 |
JPH0410508B2 (ko) | 1992-02-25 |
EP0065732A1 (de) | 1982-12-01 |
BR8202936A (pt) | 1983-05-03 |
CS228928B2 (en) | 1984-05-14 |
JPS57198757A (en) | 1982-12-06 |
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