KR830006335A - 올레핀 중합체중의 미중합 단량체 제거방법 - Google Patents

올레핀 중합체중의 미중합 단량체 제거방법 Download PDF

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KR830006335A
KR830006335A KR1019810003203A KR810003203A KR830006335A KR 830006335 A KR830006335 A KR 830006335A KR 1019810003203 A KR1019810003203 A KR 1019810003203A KR 810003203 A KR810003203 A KR 810003203A KR 830006335 A KR830006335 A KR 830006335A
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gas
copolymer
cleaning
monomer
gaseous
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KR1019810003203A
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윌리암 보브스트 로버트
잭 가너 빌리
윌리암 쟈코브 프레드릭
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에드워드 지·그리에르
유니온 카바이드 코포레이숀
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Application filed by 에드워드 지·그리에르, 유니온 카바이드 코포레이숀 filed Critical 에드워드 지·그리에르
Publication of KR830006335A publication Critical patent/KR830006335A/ko

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F6/00Post-polymerisation treatments
    • C08F6/001Removal of residual monomers by physical means
    • C08F6/005Removal of residual monomers by physical means from solid polymers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

내용 없음

Description

올레핀 중합체중의 미중함 단량체 제거방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 및 제2도는 본 발명의 다른 실시예의 태양을 도시한 것이며,
제3도 및 제 4도는 체류시간에 따른 퍼즈유속 및 단량체 최종농도를 나타낸 설명도이다.

Claims (3)

  1. 중합체 및 단량체에 대해 불활성이며 또 산소를 전혀 함유치 않는 제1의 가스흐름으로 중합체를 세정용기(purge vessel)로 운반하고, 이 세정용기에 상기 수지 및 단량체에 불활성이며 또 산소를 전혀 함유치 않은 세정가스를 공급하여, 이 세정용기내에서 상기 중합체와 세정가스를 향류 접촉시켜 상기 세정가스, 수송가스와 가스상단량체를 함유하는 제2의 가스흐름과 가스상단량체 함량이 감소된 중합체흐름을 수득하는 단계로 구성되는 가스단량체 함유 고형 올레핀 중합체로부터 미중합 가스상 단량체를 분리하는 방법.
  2. 공중합체 및 함유된 가스상 단량체에 대해 불활성이며 또 산소를 전혀 함유치 않는 제1의 가스흐름으로 공중합체를 입상으로 세정용기 상부로 운반시켜, 거의 플러그 흐름(plug flow)형태로 세정용기를 통해 하강시키고, 이 세정용기 하부에서 상기 공중합체 불활성이며 또 산소 및 가스상 단량체를 전혀 함유치 않는 세정가스를 공급하여, 이 세정용기내에서 상기 공중합체와 세정가스를 향류 접촉시켜, 상기 세정가스, 수송가스와 가스상단량체를 함유하는 제1의 가스흐름과 가스상 단량체 함량이 감소된 공중합체 흐름을 수득하고 또 제2의 가스흐름중 일부를 제1의 가스흐름으로 재순환시키는 단계로 구성되는, 가스상 단량체를 함유하는 고형의 저압중합된 저밀도 에틸렌 탄화수소 공중합체로부터 미중합 가스상 단량체를 분리하는 방법.
  3. 공중합체에 대해 불활성인 제1의 가스흐름으로 공중합체를 입상으로 세정용기 상기로 운반시켜, 거의 플러그흐름 형태로 세정용기를 통해 하강시키고, 이 세정용기 하부에서 상기 공중합체에 불활성이며 또 가스상 단량체를 함유하는 세정가스를 공급하여, 이 세정용기내에서 상기 공중합체와 세정가스를 향류 접촉시켜, 상기 세정가스, 수송가스와 다량의 가스상 단량체를 함유하는 제2의 가스흐름과 가스상 단량체 함량이 감소된 공중합체 흐름을 수득하고, 또 이 제2의 가스흐름중 일부를 상기 세정가스로 재순환시키는 단계로 구성되는 가스상 단량체를 함유하는 고형의 저압 중합된 저밀도 에틸렌 탄화수소 공중합체로부터 미중합가스상 단량체를 분리하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019810003203A 1980-09-02 1981-08-31 올레핀 중합체중의 미중합 단량체 제거방법 KR830006335A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US183,375 1980-09-02
US06/183,375 US4372758A (en) 1980-09-02 1980-09-02 Degassing process for removing unpolymerized monomers from olefin polymers

Publications (1)

Publication Number Publication Date
KR830006335A true KR830006335A (ko) 1983-09-24

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KR1019810003203A KR830006335A (ko) 1980-09-02 1981-08-31 올레핀 중합체중의 미중합 단량체 제거방법

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US (1) US4372758A (ko)
EP (1) EP0047077B1 (ko)
JP (1) JPS5776006A (ko)
KR (1) KR830006335A (ko)
AR (1) AR226742A1 (ko)
AU (1) AU545086B2 (ko)
BR (1) BR8105547A (ko)
CA (1) CA1171591A (ko)
DD (1) DD201909A5 (ko)
DE (1) DE3173767D1 (ko)
DK (1) DK386981A (ko)
FI (1) FI812638L (ko)
GR (1) GR74665B (ko)
IL (1) IL63601A0 (ko)
MA (1) MA19261A1 (ko)
MX (1) MX158455A (ko)
NO (1) NO812917L (ko)
PL (1) PL232874A1 (ko)
ZA (1) ZA815286B (ko)

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JPS5776006A (en) 1982-05-12
US4372758A (en) 1983-02-08
JPS6247441B2 (ko) 1987-10-08
EP0047077A1 (en) 1982-03-10
AU545086B2 (en) 1985-06-27
MA19261A1 (fr) 1982-04-01
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CA1171591A (en) 1984-07-24
BR8105547A (pt) 1982-05-18
DK386981A (da) 1982-03-03
DE3173767D1 (en) 1986-03-27
GR74665B (ko) 1984-06-29
EP0047077B1 (en) 1986-02-12
AU7369881A (en) 1982-04-01
AR226742A1 (es) 1982-08-13
MX158455A (es) 1989-02-02
NO812917L (no) 1982-03-03
PL232874A1 (ko) 1982-08-02
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DD201909A5 (de) 1983-08-17

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