KR20240160110A - 착색 pet 포백을 원료로 한 재생 폴리에스테르 수지 및 착색 pet 포백으로부터 에스테르 모노머를 얻는 방법 - Google Patents
착색 pet 포백을 원료로 한 재생 폴리에스테르 수지 및 착색 pet 포백으로부터 에스테르 모노머를 얻는 방법 Download PDFInfo
- Publication number
- KR20240160110A KR20240160110A KR1020247030011A KR20247030011A KR20240160110A KR 20240160110 A KR20240160110 A KR 20240160110A KR 1020247030011 A KR1020247030011 A KR 1020247030011A KR 20247030011 A KR20247030011 A KR 20247030011A KR 20240160110 A KR20240160110 A KR 20240160110A
- Authority
- KR
- South Korea
- Prior art keywords
- less
- mass
- ester monomer
- polyester resin
- bhet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920001225 polyester resin Polymers 0.000 title claims abstract description 76
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- 229920000139 polyethylene terephthalate Polymers 0.000 claims abstract description 102
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- 239000011347 resin Substances 0.000 claims abstract description 25
- KKEYFWRCBNTPAC-UHFFFAOYSA-N terephthalic acid group Chemical group C(C1=CC=C(C(=O)O)C=C1)(=O)O KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 16
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- QPKOBORKPHRBPS-UHFFFAOYSA-N bis(2-hydroxyethyl) terephthalate Chemical compound OCCOC(=O)C1=CC=C(C(=O)OCCO)C=C1 QPKOBORKPHRBPS-UHFFFAOYSA-N 0.000 claims description 55
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 9
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- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
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- 125000002091 cationic group Chemical group 0.000 description 4
- VVTXSHLLIKXMPY-UHFFFAOYSA-L disodium;2-sulfobenzene-1,3-dicarboxylate Chemical compound [Na+].[Na+].OS(=O)(=O)C1=C(C([O-])=O)C=CC=C1C([O-])=O VVTXSHLLIKXMPY-UHFFFAOYSA-L 0.000 description 4
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- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 3
- CARJPEPCULYFFP-UHFFFAOYSA-N 5-Sulfo-1,3-benzenedicarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(S(O)(=O)=O)=C1 CARJPEPCULYFFP-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
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- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000005481 NMR spectroscopy Methods 0.000 description 2
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
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- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
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- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- ZBYYWKJVSFHYJL-UHFFFAOYSA-L cobalt(2+);diacetate;tetrahydrate Chemical compound O.O.O.O.[Co+2].CC([O-])=O.CC([O-])=O ZBYYWKJVSFHYJL-UHFFFAOYSA-L 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
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- 239000007789 gas Substances 0.000 description 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 2
- 239000003014 ion exchange membrane Substances 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 238000009940 knitting Methods 0.000 description 2
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- QWVGKYWNOKOFNN-UHFFFAOYSA-N o-cresol Chemical compound CC1=CC=CC=C1O QWVGKYWNOKOFNN-UHFFFAOYSA-N 0.000 description 2
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- XTUSEBKMEQERQV-UHFFFAOYSA-N propan-2-ol;hydrate Chemical compound O.CC(C)O XTUSEBKMEQERQV-UHFFFAOYSA-N 0.000 description 2
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- 241000984082 Amoreuxia Species 0.000 description 1
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- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
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- 229910052786 argon Inorganic materials 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
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- QYQADNCHXSEGJT-UHFFFAOYSA-N cyclohexane-1,1-dicarboxylate;hydron Chemical compound OC(=O)C1(C(O)=O)CCCCC1 QYQADNCHXSEGJT-UHFFFAOYSA-N 0.000 description 1
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- ZFTFAPZRGNKQPU-UHFFFAOYSA-N dicarbonic acid Chemical compound OC(=O)OC(O)=O ZFTFAPZRGNKQPU-UHFFFAOYSA-N 0.000 description 1
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- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J11/00—Recovery or working-up of waste materials
- C08J11/04—Recovery or working-up of waste materials of polymers
- C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
- C08J11/18—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material
- C08J11/22—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds
- C08J11/24—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds containing hydroxyl groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/02—Separating plastics from other materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/183—Terephthalic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/143—Feedstock the feedstock being recycled material, e.g. plastics
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Environmental & Geological Engineering (AREA)
- Mechanical Engineering (AREA)
- Analytical Chemistry (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Polyesters Or Polycarbonates (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JPJP-P-2022-039894 | 2022-03-15 | ||
| JP2022039894 | 2022-03-15 | ||
| PCT/JP2023/008940 WO2023176649A1 (ja) | 2022-03-15 | 2023-03-08 | 着色pet布帛を原料とした再生ポリエステル樹脂及び着色pet布帛からエステルモノマーを得る方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20240160110A true KR20240160110A (ko) | 2024-11-08 |
Family
ID=88023197
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020247030011A Pending KR20240160110A (ko) | 2022-03-15 | 2023-03-08 | 착색 pet 포백을 원료로 한 재생 폴리에스테르 수지 및 착색 pet 포백으로부터 에스테르 모노머를 얻는 방법 |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP4495163A1 (https=) |
| JP (1) | JPWO2023176649A1 (https=) |
| KR (1) | KR20240160110A (https=) |
| CN (1) | CN118871497A (https=) |
| TW (1) | TW202402871A (https=) |
| WO (1) | WO2023176649A1 (https=) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP4342943B1 (en) | 2022-09-20 | 2024-07-17 | revalyu Resources GmbH | Process for recycling polyethylene terephthalate using a selected feedstock |
| ES2987870T3 (es) | 2022-09-20 | 2024-11-18 | Revalyu Resources Gmbh | Proceso para reciclar tereftalato de polietileno utilizando un gradiente de concentración de impurezas |
| EP4342945B1 (en) | 2022-09-20 | 2024-07-17 | revalyu Resources GmbH | Process for recycling polyethylene terephthalate using different mono-ethylene glycol levels |
| ES2987897T3 (es) | 2022-09-20 | 2024-11-18 | Revalyu Resources Gmbh | Proceso para reciclar tereftalato de polietileno utilizando un intervalo de temperatura seleccionado para elprocesamiento de oligómeros |
| ES2987868T3 (es) | 2022-09-20 | 2024-11-18 | Revalyu Resources Gmbh | Proceso para reciclar tereftalato de polietileno utilizando material filtrante de partículas porosas |
| EP4342946B1 (en) | 2022-09-20 | 2024-07-17 | revalyu Resources GmbH | Process for recycling polyethylene terephthalate using a washing reactor |
| ES2987865T3 (es) | 2022-09-20 | 2024-11-18 | Revalyu Resources Gmbh | Proceso para reciclar tereftalato de polietileno utilizando coordenadas de color específicas para el procesamiento de oligómeros |
| EP4342942B1 (en) | 2022-09-20 | 2024-07-10 | revalyu Resources GmbH | Process for recycling polyethylene terephthalate determined by intrinsic viscosity of polyethylene terephthalate |
| CN118002600B (zh) * | 2024-04-08 | 2024-07-16 | 国高材高分子材料产业创新中心有限公司 | 一种太阳能电池背板的回收方法 |
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| JP2005255963A (ja) | 2004-02-12 | 2005-09-22 | Is:Kk | 繊維状ポリエステルからエステルモノマーを回収する方法 |
| JP2005330444A (ja) | 2004-05-21 | 2005-12-02 | Is:Kk | 繊維状ポリエステルからエステルモノマーを回収する方法 |
| JP2020176258A (ja) | 2020-02-06 | 2020-10-29 | 株式会社シンテック | 色素付きポリエステルおよび再生ポリエチレンテレフテレートの製造方法 |
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| JP4537288B2 (ja) * | 2005-08-08 | 2010-09-01 | 帝人ファイバー株式会社 | 染着ポリエステル繊維からの有効成分回収方法 |
| JP5189266B2 (ja) * | 2006-09-29 | 2013-04-24 | 株式会社ニスコ | ビス−(2−ヒドロキシエチル)テレフタレートの製造方法およびポリエチレンテレフタレートの製造方法 |
| CN112132505B (zh) | 2020-08-26 | 2024-02-27 | 上海姜歌机器人有限公司 | 机器人拣货方法和系统、机器人、服务器和可读存储介质 |
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- 2023-03-08 KR KR1020247030011A patent/KR20240160110A/ko active Pending
- 2023-03-08 CN CN202380027595.7A patent/CN118871497A/zh active Pending
- 2023-03-08 EP EP23770605.6A patent/EP4495163A1/en active Pending
- 2023-03-08 JP JP2023517349A patent/JPWO2023176649A1/ja active Pending
- 2023-03-14 TW TW112109251A patent/TW202402871A/zh unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005255963A (ja) | 2004-02-12 | 2005-09-22 | Is:Kk | 繊維状ポリエステルからエステルモノマーを回収する方法 |
| JP2005330444A (ja) | 2004-05-21 | 2005-12-02 | Is:Kk | 繊維状ポリエステルからエステルモノマーを回収する方法 |
| JP2020176258A (ja) | 2020-02-06 | 2020-10-29 | 株式会社シンテック | 色素付きポリエステルおよび再生ポリエチレンテレフテレートの製造方法 |
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| WO2023176649A1 (ja) | 2023-09-21 |
| CN118871497A (zh) | 2024-10-29 |
| JPWO2023176649A1 (https=) | 2023-09-21 |
| TW202402871A (zh) | 2024-01-16 |
| EP4495163A1 (en) | 2025-01-22 |
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