KR20230110312A - 란타나이드 및 란타나이드 유사 전이 금속 착물 - Google Patents

란타나이드 및 란타나이드 유사 전이 금속 착물 Download PDF

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Publication number
KR20230110312A
KR20230110312A KR1020237020335A KR20237020335A KR20230110312A KR 20230110312 A KR20230110312 A KR 20230110312A KR 1020237020335 A KR1020237020335 A KR 1020237020335A KR 20237020335 A KR20237020335 A KR 20237020335A KR 20230110312 A KR20230110312 A KR 20230110312A
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South Korea
Prior art keywords
precursor
precursor according
iii
plasma
formula
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KR1020237020335A
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Korean (ko)
Inventor
크리스토프 베첼
홀거 하일
미하우 크롬피에츠
라스 리차우
다비드 브뤼헤
밍 팡
세르게이 브이 이바노프
Original Assignee
메르크 파텐트 게엠베하
버슘머트리얼즈 유에스, 엘엘씨
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Publication of KR20230110312A publication Critical patent/KR20230110312A/ko
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/40Oxides
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/4401Means for minimising impurities, e.g. dust, moisture or residual gas, in the reaction chamber
    • C23C16/4408Means for minimising impurities, e.g. dust, moisture or residual gas, in the reaction chamber by purging residual gases from the reaction chamber or gas lines
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/455Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
    • C23C16/45523Pulsed gas flow or change of composition over time
    • C23C16/45525Atomic layer deposition [ALD]
    • C23C16/45527Atomic layer deposition [ALD] characterized by the ALD cycle, e.g. different flows or temperatures during half-reactions, unusual pulsing sequence, use of precursor mixtures or auxiliary reactants or activations
    • C23C16/45536Use of plasma, radiation or electromagnetic fields
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/455Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
    • C23C16/45523Pulsed gas flow or change of composition over time
    • C23C16/45525Atomic layer deposition [ALD]
    • C23C16/45553Atomic layer deposition [ALD] characterized by the use of precursors specially adapted for ALD

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Vapour Deposition (AREA)
KR1020237020335A 2020-11-20 2021-11-18 란타나이드 및 란타나이드 유사 전이 금속 착물 Pending KR20230110312A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US202063116487P 2020-11-20 2020-11-20
US63/116,487 2020-11-20
PCT/EP2021/082084 WO2022106508A1 (en) 2020-11-20 2021-11-18 Lanthanide and lanthanide-like transition metal complexes

Publications (1)

Publication Number Publication Date
KR20230110312A true KR20230110312A (ko) 2023-07-21

Family

ID=78819507

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020237020335A Pending KR20230110312A (ko) 2020-11-20 2021-11-18 란타나이드 및 란타나이드 유사 전이 금속 착물

Country Status (6)

Country Link
US (1) US12428439B2 (https=)
JP (1) JP7690582B2 (https=)
KR (1) KR20230110312A (https=)
CN (1) CN116583621B (https=)
TW (1) TWI894397B (https=)
WO (1) WO2022106508A1 (https=)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116583621B (zh) 2020-11-20 2025-07-25 默克专利股份有限公司 镧系及类镧系过渡金属的络合物
JP2025527797A (ja) * 2022-08-31 2025-08-22 メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツング 気相薄膜堆積プロセスのための前駆体としての多置換シクロペンタジエニル希土類錯体
KR102952598B1 (ko) * 2022-11-30 2026-04-13 에스케이트리켐 주식회사 이트륨 또는 스칸듐 함유 박막 형성용 전구체, 이를 이용한 이트륨 또는 스칸듐 함유 박막 형성 방법 및 상기 이트륨 또는 스칸듐 함유 박막을 포함하는 반도체 소자.
CN116284065A (zh) * 2022-12-29 2023-06-23 江苏爱姆欧光电材料有限公司 一种含柔性基团茂稀土镧/钆配合物及其制备方法
IL326480A (en) 2023-09-04 2026-04-01 Adeka Corp Raw material for forming a thin layer, a thin layer, a method for producing a thin layer, and a lanthanum compound

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6969539B2 (en) 2000-09-28 2005-11-29 President And Fellows Of Harvard College Vapor deposition of metal oxides, silicates and phosphates, and silicon dioxide
US7816737B2 (en) 2006-03-31 2010-10-19 Tokyo Electron Limited Semiconductor device with gate dielectric containing mixed rare earth elements
KR101802124B1 (ko) 2008-06-05 2017-11-27 레르 리키드 쏘시에떼 아노님 뿌르 레드 에렉스뿔라따시옹 데 프로세데 조르즈 클로드 란탄족 함유 전구체의 제조 및 란탄족 함유 필름의 증착 방법
CN102119238B (zh) 2008-07-24 2014-05-28 乔治洛德方法研究和开发液化空气有限公司 沉积含过渡金属的膜的方法
TWI554636B (zh) 2012-04-25 2016-10-21 應用材料股份有限公司 由金屬脒鹽前驅物製造介電膜的方法
US10913754B2 (en) 2015-07-07 2021-02-09 Samsung Electronics Co., Ltd. Lanthanum compound and methods of forming thin film and integrated circuit device using the lanthanum compound
KR102424961B1 (ko) 2015-07-07 2022-07-25 삼성전자주식회사 란타넘 화합물 및 그 제조 방법과 란타넘 전구체 조성물과 이를 이용한 박막 형성 방법 및 집적회로 소자의 제조 방법
US20160315168A1 (en) * 2016-06-30 2016-10-27 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Process for forming gate insulators for tft structures
US10487398B2 (en) * 2016-12-04 2019-11-26 Applied Materials, Inc. Synthesis of metal nitride thin films materials using hydrazine derivatives
US20180187303A1 (en) 2016-12-30 2018-07-05 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Lanthanide precursors and deposition of lanthanide-containing films using the same
US10760159B2 (en) * 2017-07-13 2020-09-01 Applied Materials, Inc. Methods and apparatus for depositing yttrium-containing films
US20190062916A1 (en) 2017-08-30 2019-02-28 Applied Materials, Inc. Lanthanide, Yttrium and Scandium precursors for ALD, CVD and Thin Film Doping and Methods of Use
KR20220079618A (ko) 2019-10-08 2022-06-13 어플라이드 머티어리얼스, 인코포레이티드 항공우주 컴포넌트들 상에 코킹 방지 보호 코팅들을 증착하는 방법들
JP7653431B2 (ja) 2019-12-27 2025-03-28 ユーピー ケミカル カンパニー リミテッド イットリウム/ランタン族金属前駆体化合物、それを含む膜形成用組成物、及びそれを利用したイットリウム/ランタン族金属含有膜の形成方法
CN116583621B (zh) 2020-11-20 2025-07-25 默克专利股份有限公司 镧系及类镧系过渡金属的络合物

Also Published As

Publication number Publication date
WO2022106508A1 (en) 2022-05-27
JP7690582B2 (ja) 2025-06-10
TWI894397B (zh) 2025-08-21
CN116583621B (zh) 2025-07-25
TW202229302A (zh) 2022-08-01
JP2024500630A (ja) 2024-01-10
CN116583621A (zh) 2023-08-11
US12428439B2 (en) 2025-09-30
US20240400598A1 (en) 2024-12-05

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Patent event date: 20230616

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