KR20140097571A - 유기금속 루테늄 착물, 및 사치환 및 기타 입체장애된 올레핀의 제조를 위한 관련 방법 - Google Patents

유기금속 루테늄 착물, 및 사치환 및 기타 입체장애된 올레핀의 제조를 위한 관련 방법 Download PDF

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KR20140097571A
KR20140097571A KR1020147019358A KR20147019358A KR20140097571A KR 20140097571 A KR20140097571 A KR 20140097571A KR 1020147019358 A KR1020147019358 A KR 1020147019358A KR 20147019358 A KR20147019358 A KR 20147019358A KR 20140097571 A KR20140097571 A KR 20140097571A
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catalyst
substituted
metathesis
mmol
reaction
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Korean (ko)
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제이콥 벌린
로버트 에이치. 그럽스
얀 슈로디
이안 씨. 스튜어드
Original Assignee
마터리아 인코포레이티드
캘리포니아 인스티튜트 오브 테크놀로지
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020147019358A 2005-12-16 2006-12-18 유기금속 루테늄 착물, 및 사치환 및 기타 입체장애된 올레핀의 제조를 위한 관련 방법 Ceased KR20140097571A (ko)

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
US75122505P 2005-12-16 2005-12-16
US60/751,225 2005-12-16
US80174206P 2006-05-19 2006-05-19
US60/801,742 2006-05-19
US85371706P 2006-10-19 2006-10-19
US60/853,717 2006-10-19
US85914806P 2006-11-15 2006-11-15
US60/859,148 2006-11-15
PCT/US2006/047934 WO2007075427A1 (en) 2005-12-16 2006-12-18 Organometallic ruthenium complexes and related methods for the preparation of tetra-substituted and other hindered olefins

Related Parent Applications (1)

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KR1020087017250A Division KR20080103961A (ko) 2005-12-16 2006-12-18 유기금속 루테늄 착물, 및 사치환 및 기타 입체장애된올레핀의 제조를 위한 관련 방법

Publications (1)

Publication Number Publication Date
KR20140097571A true KR20140097571A (ko) 2014-08-06

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KR1020147019358A Ceased KR20140097571A (ko) 2005-12-16 2006-12-18 유기금속 루테늄 착물, 및 사치환 및 기타 입체장애된 올레핀의 제조를 위한 관련 방법
KR1020087017250A Ceased KR20080103961A (ko) 2005-12-16 2006-12-18 유기금속 루테늄 착물, 및 사치환 및 기타 입체장애된올레핀의 제조를 위한 관련 방법

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US (2) US8008224B2 (enExample)
EP (1) EP1971616A1 (enExample)
JP (1) JP5522941B2 (enExample)
KR (2) KR20140097571A (enExample)
CN (1) CN101460513B (enExample)
SG (1) SG169326A1 (enExample)
WO (1) WO2007075427A1 (enExample)

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US8877936B2 (en) * 2008-04-09 2014-11-04 California Institute Of Technology Ruthenium olefin metathesis catalysts bearing N-heterocyclic carbene ligands with substituted backbone
FR2939331B1 (fr) 2008-12-10 2012-08-10 Inst Francais Du Petrole Composition catalytique et procede de metathese de corps gras insature
AU2010245265B2 (en) 2009-05-05 2014-07-31 Stepan Company Sulfonated internal olefin surfactant for enhanced oil recovery
WO2011135029A1 (en) 2010-04-28 2011-11-03 Dsm Ip Assets B.V. Metathesis crosslinkable coating compositions
JP5674059B2 (ja) * 2011-01-24 2015-02-25 国立大学法人名古屋大学 ルテニウム錯体を含む水素移動反応用触媒及び水素移動反応物の製造方法
CN102145304B (zh) * 2011-02-24 2012-08-08 华东师范大学 一种负载型格拉布斯催化剂的制备及其应用
FR2983475B1 (fr) 2011-12-02 2014-01-17 IFP Energies Nouvelles Procede de metathese d'olefines lineaires alpha utilisant un complexe du ruthenium comportant un carbene n-heterocyclique dissymetrique
EP2867243B1 (en) 2012-06-29 2016-04-13 Apeiron Synthesis S.A. Metal complexes, their application and methods of carrying out of metathesis reaction
PL225024B1 (pl) 2012-08-16 2017-02-28 Univ Warszawski Nowe kompleksy rutenu oraz ich zastosowanie
WO2017012379A1 (zh) 2015-07-20 2017-01-26 中国科学院上海有机化学研究所 草酸酰胺类配体及其在铜催化芳基卤代物偶联反应中的用途
WO2017087710A2 (en) 2015-11-18 2017-05-26 Provivi, Inc. Production of fatty olefin derivatives via olefin metathesis
JP6737885B2 (ja) 2015-11-18 2020-08-12 プロヴィヴィ インコーポレイテッド 昆虫フェロモンの生成のための微生物及び関連する化合物
CA3006976A1 (en) * 2015-12-10 2017-06-15 California Institute Of Technology Olefin metathesis catalysts
EP3464311A4 (en) 2016-06-06 2020-03-18 Provivi, Inc. HALF-BIOSYNTHETIC PRODUCTION OF FATTY ALCOHOLS AND FATTY ALDEHYDES
WO2018150379A2 (en) 2017-02-17 2018-08-23 Provivi, Inc. Synthesis of pheromones and related materials via olefin metathesis
CN110914442B (zh) 2017-05-17 2025-02-18 普罗维维股份有限公司 用于产生昆虫信息素及相关化合物的微生物
US10683388B2 (en) * 2017-08-15 2020-06-16 University Of Florida Research Foundation, Incorporated High temperature metathesis chemistry
CN108299506A (zh) * 2018-01-29 2018-07-20 中国科学院成都有机化学有限公司 N-杂环卡宾钌络合物及其制备方法和用途
CN109225334B (zh) * 2018-07-20 2021-05-18 吉林化工学院 一种具有邻位空间位阻结构的钌烯烃复分解催化剂及其制备方法和应用
CN109364998B (zh) * 2018-10-15 2021-07-06 天津科技大学 一种用于烯烃复分解反应的催化剂及其制备和应用方法
CN111250168B (zh) * 2018-11-30 2021-06-01 中国科学院大连化学物理研究所 一种钌基催化剂及其制备方法、应用
CN110041262B (zh) 2019-01-02 2020-03-27 成都开美思商务信息咨询中心(有限合伙) 氮杂环卡宾配体及其钌催化剂、制备方法和应用
CN112547126B (zh) * 2020-12-21 2023-03-21 上海中化科技有限公司 钌卡宾化合物、其组合物、制备方法及应用
CN113000066B (zh) * 2021-01-09 2022-04-12 河南大学 一种z-选择性钌卡宾烯烃复分解催化剂及其制备方法和应用

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DE19815275B4 (de) 1998-04-06 2009-06-25 Evonik Degussa Gmbh Alkylidenkomplexe des Rutheniums mit N-heterozyklischen Carbenliganden und deren Verwendung als hochaktive, selektive Katalysatoren für die Olefin-Metathese
KR100823365B1 (ko) * 1999-05-24 2008-04-17 캘리포니아 인스티튜트 오브 테크놀로지 이미다졸리딘계 금속 카르벤 복분해 촉매
WO2002014376A2 (en) * 2000-08-10 2002-02-21 Trustees Of Boston College Recyclable metathesis catalysts
US6610626B2 (en) * 2000-09-05 2003-08-26 Cymetech, Llp Highly active metathesis catalysts generated in situ from inexpensive and air stable precursors
US6759537B2 (en) * 2001-03-23 2004-07-06 California Institute Of Technology Hexacoordinated ruthenium or osmium metal carbene metathesis catalysts
WO2002079126A1 (en) * 2001-03-30 2002-10-10 California Institute Of Technology Cross-metathesis reaction of functionalized and substituted olefins using group 8 transition metal carbene complexes as metathesis catalysts
AU2002307384A1 (en) * 2001-04-16 2002-10-28 California Institute Of Technology Group 8 transition metal carbene complexes as enantioselective olefin metathesis catalysts
US6818586B2 (en) * 2001-08-01 2004-11-16 Cymetech, Llp Hexacoordinated ruthenium or osmium metal carbene metathesis catalysts
WO2003020775A1 (en) * 2001-08-29 2003-03-13 California Institute Of Technology Ring-opening metathesis polymerization of bridged bicyclic and polycyclic olefins containing two or more heteroatoms

Also Published As

Publication number Publication date
US8361922B2 (en) 2013-01-29
EP1971616A1 (en) 2008-09-24
US8008224B2 (en) 2011-08-30
CN101460513A (zh) 2009-06-17
US20120123133A1 (en) 2012-05-17
WO2007075427A1 (en) 2007-07-05
KR20080103961A (ko) 2008-11-28
JP2009519947A (ja) 2009-05-21
SG169326A1 (en) 2011-03-30
US20070282148A1 (en) 2007-12-06
JP5522941B2 (ja) 2014-06-18
CN101460513B (zh) 2014-08-27

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