KR20140078688A - 혼합 금속 산화물 촉매 - Google Patents

혼합 금속 산화물 촉매 Download PDF

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Publication number
KR20140078688A
KR20140078688A KR1020147010457A KR20147010457A KR20140078688A KR 20140078688 A KR20140078688 A KR 20140078688A KR 1020147010457 A KR1020147010457 A KR 1020147010457A KR 20147010457 A KR20147010457 A KR 20147010457A KR 20140078688 A KR20140078688 A KR 20140078688A
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phase
catalyst composition
group
element selected
yield
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Korean (ko)
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제임스 에프 브라즈딜
마크 에이 토프트
스티븐 티 맥케나
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이네오스 유에스에이 엘엘씨
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8878—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N23/00—Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00
    • G01N23/20—Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00 by using diffraction of the radiation by the materials, e.g. for investigating crystal structure; by using scattering of the radiation by the materials, e.g. for investigating non-crystalline materials; by using reflection of the radiation by the materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • B01J35/38—Abrasion or attrition resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Analysing Materials By The Use Of Radiation (AREA)
KR1020147010457A 2011-09-21 2012-09-05 혼합 금속 산화물 촉매 Withdrawn KR20140078688A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13/200,219 2011-09-21
US13/200,219 US9433929B2 (en) 2011-09-21 2011-09-21 Mixed metal oxide catalysts
PCT/US2012/053794 WO2013043371A1 (en) 2011-09-21 2012-09-05 Mixed metal oxide catalysts

Publications (1)

Publication Number Publication Date
KR20140078688A true KR20140078688A (ko) 2014-06-25

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Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020147010457A Withdrawn KR20140078688A (ko) 2011-09-21 2012-09-05 혼합 금속 산화물 촉매

Country Status (10)

Country Link
US (2) US9433929B2 (enExample)
EP (1) EP2758167A1 (enExample)
JP (2) JP6026541B2 (enExample)
KR (1) KR20140078688A (enExample)
CN (1) CN104080529A (enExample)
BR (1) BR112014006456A2 (enExample)
MX (1) MX2014003480A (enExample)
RU (1) RU2612976C2 (enExample)
TW (1) TWI552800B (enExample)
WO (1) WO2013043371A1 (enExample)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG11201501592QA (en) 2012-09-28 2015-05-28 Asahi Kasei Chemicals Corp Oxide catalyst and method for producing the same, and methods for producing unsaturated aldehyde, diolefin, and unsaturated nitrile
EP3148692B1 (en) * 2014-05-29 2019-07-10 Ineos Europe AG Improved selective ammoxidation catalysts
KR20170015900A (ko) * 2014-05-29 2017-02-10 이네오스 유럽 아게 개선된 선택적인 암모산화 촉매
US9844769B2 (en) * 2014-12-17 2017-12-19 Ineos Europe Ag Mixed metal oxide ammoxidation catalysts
US10183958B2 (en) 2015-02-06 2019-01-22 Dow Silicones Corporation Method of producing organohalosilanes
CN107223127B (zh) 2015-02-06 2020-09-11 美国陶氏有机硅公司 制备有机卤代硅烷的方法
ES2851907T3 (es) 2016-01-09 2021-09-09 Ascend Performance Mat Operations Llc Composiciones catalizadoras y procesos de amoxidación
JP6845405B2 (ja) * 2016-02-17 2021-03-17 株式会社リガク 解析装置、解析方法および解析プログラム
CN107282063B (zh) * 2016-04-13 2020-01-03 中国石油化工股份有限公司 丙烯氨氧化法丙烯腈催化剂
CN107282060B (zh) * 2016-04-13 2020-01-03 中国石油化工股份有限公司 氨氧化工艺丙烯腈催化剂
CN107282064B (zh) * 2016-04-13 2020-05-05 中国石油化工股份有限公司 用于生产丙烯腈的催化剂
US10626082B2 (en) 2016-10-11 2020-04-21 Ineos Europe Ag Ammoxidation catalyst with selective co-product HCN production
MY200796A (en) * 2017-07-14 2024-01-16 Asahi Chemical Ind Method for producing catalyst and method for producing unsaturated nitrile
JP6758514B2 (ja) * 2018-04-13 2020-09-23 旭化成株式会社 触媒、触媒の製造方法、アクリロニトリルの製造方法
RU2761968C1 (ru) * 2018-08-23 2021-12-14 Асахи Касеи Кабусики Кайся Способ производства катализатора для аммоксидирования и способ производства акрилонитрила
CN109701554B (zh) * 2019-01-30 2021-05-07 吉林大学 一种Fe2(MoO4)3负载Au纳米催化剂的制备方法及应用
US20250094717A1 (en) * 2023-09-15 2025-03-20 Oracle International Corporation Returning references for answers generated by a language model

Family Cites Families (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA742727A (en) 1962-11-28 1966-09-13 The Standard Oil Company Process for preparing olefinically unsaturated nitriles
US4503001A (en) 1970-10-30 1985-03-05 Standard Oil Company (Indiana) Process for the manufacture of acrylonitrile and methacrylonitrile
US4863891A (en) * 1971-02-04 1989-09-05 The Standard Oil Company Catalyst for the manufacture of acrylonitrile and methacrylonitrile
US4767878A (en) 1971-02-04 1988-08-30 The Standard Oil Company Process for the manufacture of acrylonitrile and methacrylonitrile
US3959341A (en) * 1972-09-25 1976-05-25 The B.F. Goodrich Company Process for low ammonia operation of the nitrile synthesis
US4766232A (en) * 1973-06-04 1988-08-23 The Standard Oil Company Production of unsaturated nitriles using catalysts containing boron, gallium or indium
JPS5245692B2 (enExample) 1973-10-16 1977-11-17
US3961896A (en) * 1974-08-26 1976-06-08 The B. F. Goodrich Company Analysis of nitrile synthesis gas streams
US4168246A (en) * 1975-11-28 1979-09-18 Monsanto Company Production of (amm)oxidation catalyst
US4040978A (en) * 1975-11-28 1977-08-09 Monsanto Company Production of (amm)oxidation catalyst
US4148757A (en) * 1977-08-10 1979-04-10 The Standard Oil Company Process for forming multi-component oxide complex catalysts
US4377534A (en) * 1978-02-27 1983-03-22 The Standard Oil Co. Production of unsaturated nitriles
JPS62234548A (ja) * 1986-03-24 1987-10-14 Mitsubishi Petrochem Co Ltd 複合酸化物触媒の製造法
US5212137A (en) * 1990-01-09 1993-05-18 Standard Oil Company Catalyst for the manufacture of acrylonitrile and methacrylonitrile
US5093299A (en) * 1990-01-09 1992-03-03 The Standard Oil Company Catalyst for process for the manufacture of acrylonitrile and methacrylonitrile
US5378668A (en) * 1990-07-13 1995-01-03 Ec Erdolchemie Gmbh Process for reactivating ammoxidation catalysts
CN1021638C (zh) * 1990-11-05 1993-07-21 中国石油化工总公司 丙烯腈流化床催化剂
US5658842A (en) * 1993-08-10 1997-08-19 Asahi Kasei Kogyo Kabushiki Kaisha Ammoxidation catalyst composition, and process for producing acrylonitrile or methacrylonitrile using the same
US5834394A (en) * 1996-08-06 1998-11-10 China-Petro-Chemical Corporation Fluidized-bed catalyst for propylene ammoxidation to acrylonitrile
WO1999041012A1 (en) 1998-02-13 1999-08-19 Korea Research Institute Of Chemical Technology A solid catalyst with core-shell catalytic phase and a method of preparation thereof
JP3680115B2 (ja) * 1998-04-23 2005-08-10 ダイヤニトリックス株式会社 不飽和ニトリル製造用触媒組成物
EP1075871B1 (en) 1998-04-23 2004-09-22 Mitsubishi Rayon Co., Ltd. Catalyst for producing unsaturated nitrile
ES2265984T3 (es) 1999-10-18 2007-03-01 Mitsubishi Rayon Co., Ltd. Metodo para producir acrilonitrilo, catalizador para uso en el metodo, y metodo para producir el catalizador.
US6458742B1 (en) * 2000-08-17 2002-10-01 The Standard Oil Company Catalyst for the manufacture of acrylonitrile
JP4854151B2 (ja) 2001-08-29 2012-01-18 旭化成ケミカルズ株式会社 アセトニトリル及び青酸を安定に増産する方法
CN100438981C (zh) * 2002-12-02 2008-12-03 伊内奥斯美国公司 用于制造丙烯腈的K、Cs、Ce、Cr、Co、Ni、Fe、Bi和Mo的混合氧化物催化剂
CA2507182A1 (en) * 2002-12-02 2004-06-17 The Standard Oil Company Mixed oxide catalyst of k, cs, ce, cr, co, ni, fe, bi and mo for the manufacture of acrylonitrile
US7071140B2 (en) * 2002-12-02 2006-07-04 The Standard Oil Company Catalyst for the manufacture of acrylonitrile
CN100345630C (zh) 2003-03-05 2007-10-31 旭化成化学株式会社 粒状多孔氨氧化催化剂
JP4242197B2 (ja) 2003-04-18 2009-03-18 ダイヤニトリックス株式会社 アクリロニトリル合成用触媒
BRPI0500616A (pt) * 2004-03-10 2007-07-10 Rohm & Haas processos para aperfeiçoar uma ou mais caracterìsticas de desempenho de um ou mais catalisadores de óxido metálico, e para produzir ácidos carboxìlicos insaturados
US8431743B2 (en) * 2004-07-01 2013-04-30 Basf Aktiengesellschaft Preparation of acrylic acid by heterogeneously catalyzed partial gas phase oxidation of propylene
ES2449580T3 (es) 2006-10-26 2014-03-20 Mitsubishi Rayon Co., Ltd. Catalizador de lecho fluidizado para producir acrilonitrilo y procedimiento para producir acrilonitrilo
US8455388B2 (en) 2010-03-23 2013-06-04 Ineos Usa Llc Attrition resistant mixed metal oxide ammoxidation catalysts
EP2550097B1 (en) 2010-03-23 2020-11-11 INEOS Europe AG High efficiency ammoxidation process and mixed metal oxide catalysts
US8258073B2 (en) 2010-03-23 2012-09-04 Ineos Usa Llc Process for preparing improved mixed metal oxide ammoxidation catalysts
US8153546B2 (en) 2010-03-23 2012-04-10 Ineos Usa Llc Mixed metal oxide ammoxidation catalysts

Also Published As

Publication number Publication date
US9433929B2 (en) 2016-09-06
WO2013043371A1 (en) 2013-03-28
US20160340296A1 (en) 2016-11-24
CN104080529A (zh) 2014-10-01
JP6026541B2 (ja) 2016-11-16
TW201318700A (zh) 2013-05-16
US20130072710A1 (en) 2013-03-21
TWI552800B (zh) 2016-10-11
RU2014114385A (ru) 2015-10-27
BR112014006456A2 (pt) 2017-04-04
MX2014003480A (es) 2014-07-22
EP2758167A1 (en) 2014-07-30
JP2014531311A (ja) 2014-11-27
RU2612976C2 (ru) 2017-03-14
JP2017024008A (ja) 2017-02-02
US9550729B2 (en) 2017-01-24

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