CN104080529A - 混合金属氧化物催化剂 - Google Patents

混合金属氧化物催化剂 Download PDF

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Publication number
CN104080529A
CN104080529A CN201280046365.7A CN201280046365A CN104080529A CN 104080529 A CN104080529 A CN 104080529A CN 201280046365 A CN201280046365 A CN 201280046365A CN 104080529 A CN104080529 A CN 104080529A
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CN
China
Prior art keywords
phase
catalyst composition
productive rate
added
acrylonitrile
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201280046365.7A
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English (en)
Chinese (zh)
Inventor
詹姆斯·F·布雷兹迪尔
马克·A·托夫特
史蒂芬·T·麦克纳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ihne Oswald Europe Co Ltd
Original Assignee
BP Corp North America Inc
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Filing date
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Application filed by BP Corp North America Inc filed Critical BP Corp North America Inc
Publication of CN104080529A publication Critical patent/CN104080529A/zh
Pending legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8878—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N23/00—Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00
    • G01N23/20—Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00 by using diffraction of the radiation by the materials, e.g. for investigating crystal structure; by using scattering of the radiation by the materials, e.g. for investigating non-crystalline materials; by using reflection of the radiation by the materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • B01J35/38—Abrasion or attrition resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Analysing Materials By The Use Of Radiation (AREA)
CN201280046365.7A 2011-09-21 2012-09-05 混合金属氧化物催化剂 Pending CN104080529A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13/200,219 2011-09-21
US13/200,219 US9433929B2 (en) 2011-09-21 2011-09-21 Mixed metal oxide catalysts
PCT/US2012/053794 WO2013043371A1 (en) 2011-09-21 2012-09-05 Mixed metal oxide catalysts

Publications (1)

Publication Number Publication Date
CN104080529A true CN104080529A (zh) 2014-10-01

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201280046365.7A Pending CN104080529A (zh) 2011-09-21 2012-09-05 混合金属氧化物催化剂

Country Status (10)

Country Link
US (2) US9433929B2 (enExample)
EP (1) EP2758167A1 (enExample)
JP (2) JP6026541B2 (enExample)
KR (1) KR20140078688A (enExample)
CN (1) CN104080529A (enExample)
BR (1) BR112014006456A2 (enExample)
MX (1) MX2014003480A (enExample)
RU (1) RU2612976C2 (enExample)
TW (1) TWI552800B (enExample)
WO (1) WO2013043371A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107073456A (zh) * 2014-05-29 2017-08-18 英尼奥斯欧洲股份公司 改进的选择性氨氧化催化剂
CN108770365A (zh) * 2016-02-17 2018-11-06 株式会社理学 解析装置、解析方法以及解析程序

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SG11201501592QA (en) 2012-09-28 2015-05-28 Asahi Kasei Chemicals Corp Oxide catalyst and method for producing the same, and methods for producing unsaturated aldehyde, diolefin, and unsaturated nitrile
KR20170015900A (ko) * 2014-05-29 2017-02-10 이네오스 유럽 아게 개선된 선택적인 암모산화 촉매
US9844769B2 (en) * 2014-12-17 2017-12-19 Ineos Europe Ag Mixed metal oxide ammoxidation catalysts
US10183958B2 (en) 2015-02-06 2019-01-22 Dow Silicones Corporation Method of producing organohalosilanes
CN107223127B (zh) 2015-02-06 2020-09-11 美国陶氏有机硅公司 制备有机卤代硅烷的方法
ES2851907T3 (es) 2016-01-09 2021-09-09 Ascend Performance Mat Operations Llc Composiciones catalizadoras y procesos de amoxidación
CN107282063B (zh) * 2016-04-13 2020-01-03 中国石油化工股份有限公司 丙烯氨氧化法丙烯腈催化剂
CN107282060B (zh) * 2016-04-13 2020-01-03 中国石油化工股份有限公司 氨氧化工艺丙烯腈催化剂
CN107282064B (zh) * 2016-04-13 2020-05-05 中国石油化工股份有限公司 用于生产丙烯腈的催化剂
US10626082B2 (en) 2016-10-11 2020-04-21 Ineos Europe Ag Ammoxidation catalyst with selective co-product HCN production
MY200796A (en) * 2017-07-14 2024-01-16 Asahi Chemical Ind Method for producing catalyst and method for producing unsaturated nitrile
JP6758514B2 (ja) * 2018-04-13 2020-09-23 旭化成株式会社 触媒、触媒の製造方法、アクリロニトリルの製造方法
RU2761968C1 (ru) * 2018-08-23 2021-12-14 Асахи Касеи Кабусики Кайся Способ производства катализатора для аммоксидирования и способ производства акрилонитрила
CN109701554B (zh) * 2019-01-30 2021-05-07 吉林大学 一种Fe2(MoO4)3负载Au纳米催化剂的制备方法及应用
US20250094717A1 (en) * 2023-09-15 2025-03-20 Oracle International Corporation Returning references for answers generated by a language model

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107073456A (zh) * 2014-05-29 2017-08-18 英尼奥斯欧洲股份公司 改进的选择性氨氧化催化剂
CN108770365A (zh) * 2016-02-17 2018-11-06 株式会社理学 解析装置、解析方法以及解析程序

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Publication number Publication date
US9433929B2 (en) 2016-09-06
WO2013043371A1 (en) 2013-03-28
US20160340296A1 (en) 2016-11-24
JP6026541B2 (ja) 2016-11-16
TW201318700A (zh) 2013-05-16
US20130072710A1 (en) 2013-03-21
KR20140078688A (ko) 2014-06-25
TWI552800B (zh) 2016-10-11
RU2014114385A (ru) 2015-10-27
BR112014006456A2 (pt) 2017-04-04
MX2014003480A (es) 2014-07-22
EP2758167A1 (en) 2014-07-30
JP2014531311A (ja) 2014-11-27
RU2612976C2 (ru) 2017-03-14
JP2017024008A (ja) 2017-02-02
US9550729B2 (en) 2017-01-24

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