KR20140033385A - 개질 액정고분자 마킹을 갖는 기판 - Google Patents
개질 액정고분자 마킹을 갖는 기판 Download PDFInfo
- Publication number
- KR20140033385A KR20140033385A KR1020137032141A KR20137032141A KR20140033385A KR 20140033385 A KR20140033385 A KR 20140033385A KR 1020137032141 A KR1020137032141 A KR 1020137032141A KR 20137032141 A KR20137032141 A KR 20137032141A KR 20140033385 A KR20140033385 A KR 20140033385A
- Authority
- KR
- South Korea
- Prior art keywords
- liquid crystal
- composition
- chiral liquid
- marking
- modifier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000758 substrate Substances 0.000 title claims abstract description 64
- 229920000106 Liquid crystal polymer Polymers 0.000 title claims description 29
- 239000004977 Liquid-crystal polymers (LCPs) Substances 0.000 title claims description 27
- 239000000203 mixture Substances 0.000 claims abstract description 290
- 239000004973 liquid crystal related substance Substances 0.000 claims abstract description 215
- 239000003607 modifier Substances 0.000 claims abstract description 207
- 239000002243 precursor Substances 0.000 claims abstract description 140
- 230000003287 optical effect Effects 0.000 claims abstract description 64
- 230000003098 cholesteric effect Effects 0.000 claims abstract description 18
- -1 lithium tetrafluoroborate Chemical compound 0.000 claims description 108
- 150000003839 salts Chemical class 0.000 claims description 94
- 239000011347 resin Substances 0.000 claims description 80
- 229920005989 resin Polymers 0.000 claims description 80
- 150000001875 compounds Chemical class 0.000 claims description 75
- 238000000034 method Methods 0.000 claims description 75
- 239000002019 doping agent Substances 0.000 claims description 55
- 238000007639 printing Methods 0.000 claims description 32
- 238000010438 heat treatment Methods 0.000 claims description 30
- 238000007641 inkjet printing Methods 0.000 claims description 24
- 239000007788 liquid Substances 0.000 claims description 23
- 239000010410 layer Substances 0.000 claims description 22
- 239000000178 monomer Substances 0.000 claims description 22
- 125000004432 carbon atom Chemical group C* 0.000 claims description 18
- 239000007787 solid Substances 0.000 claims description 16
- 229940126062 Compound A Drugs 0.000 claims description 15
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 claims description 15
- 239000000126 substance Substances 0.000 claims description 15
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 claims description 12
- 239000011159 matrix material Substances 0.000 claims description 12
- 238000000576 coating method Methods 0.000 claims description 11
- 229920000642 polymer Polymers 0.000 claims description 11
- 239000012530 fluid Substances 0.000 claims description 10
- 230000004048 modification Effects 0.000 claims description 10
- 238000012986 modification Methods 0.000 claims description 10
- 239000011248 coating agent Substances 0.000 claims description 9
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 claims description 9
- 229910001486 lithium perchlorate Inorganic materials 0.000 claims description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 8
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 8
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims description 8
- IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 claims description 8
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 8
- 238000001228 spectrum Methods 0.000 claims description 8
- 238000005507 spraying Methods 0.000 claims description 8
- NHGXDBSUJJNIRV-UHFFFAOYSA-M tetrabutylammonium chloride Chemical compound [Cl-].CCCC[N+](CCCC)(CCCC)CCCC NHGXDBSUJJNIRV-UHFFFAOYSA-M 0.000 claims description 8
- 239000002775 capsule Substances 0.000 claims description 7
- 238000004806 packaging method and process Methods 0.000 claims description 7
- 230000005855 radiation Effects 0.000 claims description 7
- 235000013361 beverage Nutrition 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 230000001747 exhibiting effect Effects 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Substances [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 claims description 6
- 238000007650 screen-printing Methods 0.000 claims description 6
- KBLZDCFTQSIIOH-UHFFFAOYSA-M tetrabutylazanium;perchlorate Chemical compound [O-]Cl(=O)(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC KBLZDCFTQSIIOH-UHFFFAOYSA-M 0.000 claims description 6
- 238000012546 transfer Methods 0.000 claims description 6
- 125000005907 alkyl ester group Chemical group 0.000 claims description 5
- 238000007766 curtain coating Methods 0.000 claims description 5
- 238000007646 gravure printing Methods 0.000 claims description 5
- 150000002576 ketones Chemical class 0.000 claims description 5
- 238000007645 offset printing Methods 0.000 claims description 5
- 238000007649 pad printing Methods 0.000 claims description 5
- 238000007761 roller coating Methods 0.000 claims description 5
- 238000010345 tape casting Methods 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 239000011888 foil Substances 0.000 claims description 4
- 125000005842 heteroatom Chemical group 0.000 claims description 4
- 150000005181 nitrobenzenes Chemical class 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 230000010287 polarization Effects 0.000 claims description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 4
- 239000011780 sodium chloride Substances 0.000 claims description 4
- 239000004317 sodium nitrate Substances 0.000 claims description 4
- 235000010344 sodium nitrate Nutrition 0.000 claims description 4
- 150000003863 ammonium salts Chemical class 0.000 claims description 3
- 239000013065 commercial product Substances 0.000 claims description 3
- 238000007644 letterpress printing Methods 0.000 claims description 3
- 229910001496 lithium tetrafluoroborate Inorganic materials 0.000 claims description 3
- 235000015097 nutrients Nutrition 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 230000007704 transition Effects 0.000 claims description 3
- 238000007647 flexography Methods 0.000 claims description 2
- 235000016709 nutrition Nutrition 0.000 claims description 2
- JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims 2
- 150000001720 carbohydrates Chemical class 0.000 claims 2
- 239000008177 pharmaceutical agent Substances 0.000 claims 1
- 241000894007 species Species 0.000 description 51
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 24
- 239000000049 pigment Substances 0.000 description 19
- 239000000463 material Substances 0.000 description 18
- 239000002904 solvent Substances 0.000 description 14
- 239000000976 ink Substances 0.000 description 13
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 12
- 239000002585 base Substances 0.000 description 12
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 11
- 239000000975 dye Substances 0.000 description 11
- 239000004986 Cholesteric liquid crystals (ChLC) Substances 0.000 description 10
- 230000008569 process Effects 0.000 description 9
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 8
- 239000000047 product Substances 0.000 description 7
- 239000003570 air Substances 0.000 description 6
- 239000004020 conductor Substances 0.000 description 6
- 239000003814 drug Substances 0.000 description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 6
- 150000004756 silanes Chemical class 0.000 description 6
- 239000004593 Epoxy Substances 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical class OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 5
- 239000012705 liquid precursor Substances 0.000 description 5
- 229920000570 polyether Polymers 0.000 description 5
- BTJPUDCSZVCXFQ-UHFFFAOYSA-N 2,4-diethylthioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC(CC)=CC(CC)=C3SC2=C1 BTJPUDCSZVCXFQ-UHFFFAOYSA-N 0.000 description 4
- 239000004721 Polyphenylene oxide Substances 0.000 description 4
- 125000003545 alkoxy group Chemical group 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 4
- 238000000151 deposition Methods 0.000 description 4
- 229940079593 drug Drugs 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- LVTJOONKWUXEFR-FZRMHRINSA-N protoneodioscin Natural products O(C[C@@H](CC[C@]1(O)[C@H](C)[C@@H]2[C@]3(C)[C@H]([C@H]4[C@@H]([C@]5(C)C(=CC4)C[C@@H](O[C@@H]4[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@@H](O)[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@H](CO)O4)CC5)CC3)C[C@@H]2O1)C)[C@H]1[C@H](O)[C@H](O)[C@H](O)[C@@H](CO)O1 LVTJOONKWUXEFR-FZRMHRINSA-N 0.000 description 4
- KLDXJTOLSGUMSJ-JGWLITMVSA-N Isosorbide Chemical class O[C@@H]1CO[C@@H]2[C@@H](O)CO[C@@H]21 KLDXJTOLSGUMSJ-JGWLITMVSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 239000012080 ambient air Substances 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- 229910052747 lanthanoid Inorganic materials 0.000 description 3
- 150000002602 lanthanoids Chemical class 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 229920000307 polymer substrate Polymers 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 238000002407 reforming Methods 0.000 description 3
- KLDXJTOLSGUMSJ-KVTDHHQDSA-N (3r,3ar,6r,6ar)-2,3,3a,5,6,6a-hexahydrofuro[3,2-b]furan-3,6-diol Chemical class O[C@@H]1CO[C@@H]2[C@H](O)CO[C@@H]21 KLDXJTOLSGUMSJ-KVTDHHQDSA-N 0.000 description 2
- LLNAMUJRIZIXHF-CLFYSBASSA-N (z)-2-methyl-3-phenylprop-2-en-1-ol Chemical compound OCC(/C)=C\C1=CC=CC=C1 LLNAMUJRIZIXHF-CLFYSBASSA-N 0.000 description 2
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 description 2
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 description 2
- VOBUAPTXJKMNCT-UHFFFAOYSA-N 1-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound CCCCCC(OC(=O)C=C)OC(=O)C=C VOBUAPTXJKMNCT-UHFFFAOYSA-N 0.000 description 2
- HZNVUJQVZSTENZ-UHFFFAOYSA-N 2,3-dichloro-5,6-dicyano-1,4-benzoquinone Chemical compound ClC1=C(Cl)C(=O)C(C#N)=C(C#N)C1=O HZNVUJQVZSTENZ-UHFFFAOYSA-N 0.000 description 2
- AGFMMSHIOPQLEP-UHFFFAOYSA-N 2,5-dimethyl-4-(4-prop-2-enoyloxybutoxy)benzoic acid Chemical compound CC1=CC(C(O)=O)=C(C)C=C1OCCCCOC(=O)C=C AGFMMSHIOPQLEP-UHFFFAOYSA-N 0.000 description 2
- RHDAAWLTXPGJDZ-UHFFFAOYSA-N 2-(ethoxymethyl)butanoic acid Chemical compound CCOCC(CC)C(O)=O RHDAAWLTXPGJDZ-UHFFFAOYSA-N 0.000 description 2
- YBEAWKWJWRXRAL-UHFFFAOYSA-J C(CCC)[N+](CCCC)(CCCC)CCCC.[Cl-].[Cl-].[Cl-].[Cl-].C(CCC)[N+](CCCC)(CCCC)CCCC.C(CCC)[N+](CCCC)(CCCC)CCCC.C(CCC)[N+](CCCC)(CCCC)CCCC Chemical compound C(CCC)[N+](CCCC)(CCCC)CCCC.[Cl-].[Cl-].[Cl-].[Cl-].C(CCC)[N+](CCCC)(CCCC)CCCC.C(CCC)[N+](CCCC)(CCCC)CCCC.C(CCC)[N+](CCCC)(CCCC)CCCC YBEAWKWJWRXRAL-UHFFFAOYSA-J 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-O butylazanium Chemical compound CCCC[NH3+] HQABUPZFAYXKJW-UHFFFAOYSA-O 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- 239000006258 conductive agent Substances 0.000 description 2
- XLJMAIOERFSOGZ-UHFFFAOYSA-N cyanic acid Chemical compound OC#N XLJMAIOERFSOGZ-UHFFFAOYSA-N 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229960002479 isosorbide Drugs 0.000 description 2
- 239000006249 magnetic particle Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 230000000149 penetrating effect Effects 0.000 description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 2
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical class N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 2
- FSDNTQSJGHSJBG-UHFFFAOYSA-N piperidine-4-carbonitrile Chemical compound N#CC1CCNCC1 FSDNTQSJGHSJBG-UHFFFAOYSA-N 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 238000010526 radical polymerization reaction Methods 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N thiocyanic acid Chemical compound SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 1
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 description 1
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 1
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 1
- 125000003562 2,2-dimethylpentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000003660 2,3-dimethylpentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(C([H])([H])[H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- YWEJNVNVJGORIU-UHFFFAOYSA-N 2-(2-hydroxyethoxy)ethyl 2-hydroxy-2-phenylacetate Chemical compound OCCOCCOC(=O)C(O)C1=CC=CC=C1 YWEJNVNVJGORIU-UHFFFAOYSA-N 0.000 description 1
- MBDLEXLQMYYPPK-BSTNIHDZSA-N 2-[(3R,3aR,6R,6aR)-6-[2-carboxy-5-(4-prop-2-enoyloxybenzoyl)oxyphenyl]-2,3,3a,5,6,6a-hexahydrofuro[3,2-b]furan-3-yl]-4-(4-prop-2-enoyloxybenzoyl)oxybenzoic acid Chemical compound C1=C([C@H]2[C@@H]3[C@@H]([C@@H](CO3)C=3C(=CC=C(OC(=O)C=4C=CC(OC(=O)C=C)=CC=4)C=3)C(O)=O)OC2)C(C(=O)O)=CC=C1OC(=O)C1=CC=C(OC(=O)C=C)C=C1 MBDLEXLQMYYPPK-BSTNIHDZSA-N 0.000 description 1
- FQQGGAYSQWVJNI-DSOCELCXSA-N 2-[(3R,3aR,6R,6aR)-6-[2-carboxy-5-(4-prop-2-enoyloxybutoxy)phenyl]-2,3,3a,5,6,6a-hexahydrofuro[3,2-b]furan-3-yl]-4-(4-prop-2-enoyloxybutoxy)benzoic acid Chemical compound OC(=O)C1=CC=C(OCCCCOC(=O)C=C)C=C1[C@H]1[C@H]2OC[C@@H](C=3C(=CC=C(OCCCCOC(=O)C=C)C=3)C(O)=O)[C@H]2OC1 FQQGGAYSQWVJNI-DSOCELCXSA-N 0.000 description 1
- OCBWMSQPSSYMRG-UHFFFAOYSA-N 2-[4-[2-carboxy-5-(4-prop-2-enoyloxybutoxy)phenyl]-3-ethoxyphenyl]-4-(4-prop-2-enoyloxybutoxy)benzoic acid Chemical compound CCOC1=C(C=CC(=C1)C2=C(C=CC(=C2)OCCCCOC(=O)C=C)C(=O)O)C3=C(C=CC(=C3)OCCCCOC(=O)C=C)C(=O)O OCBWMSQPSSYMRG-UHFFFAOYSA-N 0.000 description 1
- SLWMHAMPJRDSHO-UHFFFAOYSA-N 2-[4-[2-carboxy-5-(4-prop-2-enoyloxybutoxycarbonyloxy)phenyl]-3-methoxyphenyl]-4-(4-prop-2-enoyloxybutoxycarbonyloxy)benzoic acid Chemical compound COC1=C(C=CC(=C1)C2=C(C=CC(=C2)OC(=O)OCCCCOC(=O)C=C)C(=O)O)C3=C(C=CC(=C3)OC(=O)OCCCCOC(=O)C=C)C(=O)O SLWMHAMPJRDSHO-UHFFFAOYSA-N 0.000 description 1
- QMIZKXJRSSJRSH-UHFFFAOYSA-N 2-[4-[2-carboxy-5-(4-prop-2-enoyloxybutoxycarbonyloxy)phenyl]-3-methylphenyl]-4-(4-prop-2-enoyloxybutoxycarbonyloxy)benzoic acid Chemical compound CC1=CC(C=2C(=CC=C(OC(=O)OCCCCOC(=O)C=C)C=2)C(O)=O)=CC=C1C1=CC(OC(=O)OCCCCOC(=O)C=C)=CC=C1C(O)=O QMIZKXJRSSJRSH-UHFFFAOYSA-N 0.000 description 1
- ZOUGPYACAVWMCM-UHFFFAOYSA-N 2-[4-[6-carboxy-2,4-dimethoxy-3-(4-prop-2-enoyloxybutoxy)phenyl]-3-methoxyphenyl]-3,5-dimethoxy-4-(4-prop-2-enoyloxybutoxy)benzoic acid Chemical compound COC1=C(C=CC(=C1)C2=C(C(=C(C=C2C(=O)O)OC)OCCCCOC(=O)C=C)OC)C3=C(C(=C(C=C3C(=O)O)OC)OCCCCOC(=O)C=C)OC ZOUGPYACAVWMCM-UHFFFAOYSA-N 0.000 description 1
- UMVNTFZZXCYRTN-UHFFFAOYSA-N 2-[4-[6-carboxy-2,4-dimethoxy-3-(4-prop-2-enoyloxybutoxycarbonyloxy)phenyl]-3-methylphenyl]-3,5-dimethoxy-4-(4-prop-2-enoyloxybutoxycarbonyloxy)benzoic acid Chemical compound CC(C=C(C=C1)C(C(OC)=C(C(OC)=C2)OC(OCCCCOC(C=C)=O)=O)=C2C(O)=O)=C1C(C(OC)=C(C(OC)=C1)OC(OCCCCOC(C=C)=O)=O)=C1C(O)=O UMVNTFZZXCYRTN-UHFFFAOYSA-N 0.000 description 1
- LTLFHGLLGXGIFO-UHFFFAOYSA-N 2-[4-[6-carboxy-2,4-dimethyl-3-(4-prop-2-enoyloxybutoxy)phenyl]-3-methoxyphenyl]-3,5-dimethyl-4-(4-prop-2-enoyloxybutoxy)benzoic acid Chemical compound CC1=CC(=C(C(=C1OCCCCOC(=O)C=C)C)C2=CC(=C(C=C2)C3=C(C=C(C(=C3C)OCCCCOC(=O)C=C)C)C(=O)O)OC)C(=O)O LTLFHGLLGXGIFO-UHFFFAOYSA-N 0.000 description 1
- NMFYKHIDXDHSPW-UHFFFAOYSA-N 2-[4-[6-carboxy-2,4-dimethyl-3-(4-prop-2-enoyloxybutoxy)phenyl]-3-methylphenyl]-3,5-dimethyl-4-(4-prop-2-enoyloxybutoxy)benzoic acid Chemical compound CC1=CC(=C(C(=C1OCCCCOC(=O)C=C)C)C2=CC(=C(C=C2)C3=C(C=C(C(=C3C)OCCCCOC(=O)C=C)C)C(=O)O)C)C(=O)O NMFYKHIDXDHSPW-UHFFFAOYSA-N 0.000 description 1
- FJYBDODYYNNDMR-UHFFFAOYSA-N 2-[4-[6-carboxy-2-methoxy-3-(4-prop-2-enoyloxybutoxy)phenyl]-3-methoxyphenyl]-3-methoxy-4-(4-prop-2-enoyloxybutoxy)benzoic acid Chemical compound COC1=C(C=CC(=C1)C2=C(C=CC(=C2OC)OCCCCOC(=O)C=C)C(=O)O)C3=C(C=CC(=C3OC)OCCCCOC(=O)C=C)C(=O)O FJYBDODYYNNDMR-UHFFFAOYSA-N 0.000 description 1
- PFPJXQYHIAWWMG-UHFFFAOYSA-N 2-[4-[6-carboxy-2-methyl-3-(4-prop-2-enoyloxybutoxy)phenyl]-3-methoxyphenyl]-3-methyl-4-(4-prop-2-enoyloxybutoxy)benzoic acid Chemical compound CC1=C(C=CC(=C1C2=CC(=C(C=C2)C3=C(C=CC(=C3C)OCCCCOC(=O)C=C)C(=O)O)OC)C(=O)O)OCCCCOC(=O)C=C PFPJXQYHIAWWMG-UHFFFAOYSA-N 0.000 description 1
- UHFFVFAKEGKNAQ-UHFFFAOYSA-N 2-benzyl-2-(dimethylamino)-1-(4-morpholin-4-ylphenyl)butan-1-one Chemical compound C=1C=C(N2CCOCC2)C=CC=1C(=O)C(CC)(N(C)C)CC1=CC=CC=C1 UHFFVFAKEGKNAQ-UHFFFAOYSA-N 0.000 description 1
- GTELLNMUWNJXMQ-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical class OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCC(CO)(CO)CO GTELLNMUWNJXMQ-UHFFFAOYSA-N 0.000 description 1
- XMLYCEVDHLAQEL-UHFFFAOYSA-N 2-hydroxy-2-methyl-1-phenylpropan-1-one Chemical compound CC(C)(O)C(=O)C1=CC=CC=C1 XMLYCEVDHLAQEL-UHFFFAOYSA-N 0.000 description 1
- ALODXAKELDHRKZ-UHFFFAOYSA-N 2-methyl-4-(4-prop-2-enoyloxybutoxy)benzoic acid Chemical compound CC1=CC(OCCCCOC(=O)C=C)=CC=C1C(O)=O ALODXAKELDHRKZ-UHFFFAOYSA-N 0.000 description 1
- 125000005916 2-methylpentyl group Chemical group 0.000 description 1
- BKIDJIYDGSCJCR-UHFFFAOYSA-N 2-methylpropan-2-amine;perchloric acid Chemical compound CC(C)(C)[NH3+].[O-]Cl(=O)(=O)=O BKIDJIYDGSCJCR-UHFFFAOYSA-N 0.000 description 1
- KTALPKYXQZGAEG-UHFFFAOYSA-N 2-propan-2-ylthioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC(C(C)C)=CC=C3SC2=C1 KTALPKYXQZGAEG-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- XAEFGAPYMRJGLZ-PWAJYCBGSA-N 3-[(3R,3aR,6R,6aR)-6-(3-carboxy-2-methyl-6-prop-2-enoyloxyphenyl)-2,3,3a,5,6,6a-hexahydrofuro[3,2-b]furan-3-yl]-2-methyl-4-prop-2-enoyloxybenzoic acid Chemical compound CC1=C(C(O)=O)C=CC(OC(=O)C=C)=C1[C@H]1[C@H]2OC[C@@H](C=3C(=CC=C(C=3C)C(O)=O)OC(=O)C=C)[C@H]2OC1 XAEFGAPYMRJGLZ-PWAJYCBGSA-N 0.000 description 1
- ARHDCXNATOYGRE-UHFFFAOYSA-N 3-[4-[3-carboxy-2,5-dimethyl-6-(4-prop-2-enoyloxybutoxy)phenyl]-3-methylphenyl]-2,5-dimethyl-4-(4-prop-2-enoyloxybutoxy)benzoic acid Chemical compound CC(C=C(C=C1)C(C(C)=C(C=C2C)C(O)=O)=C2OCCCCOC(C=C)=O)=C1C(C(C)=C(C=C1C)C(O)=O)=C1OCCCCOC(C=C)=O ARHDCXNATOYGRE-UHFFFAOYSA-N 0.000 description 1
- UBBPRGYHCZUVSX-UHFFFAOYSA-N 3-[4-[3-carboxy-2-methoxy-6-(4-prop-2-enoyloxybutoxy)phenyl]-3-methoxyphenyl]-2-methoxy-4-(4-prop-2-enoyloxybutoxy)benzoic acid Chemical compound COC1=C(C=CC(=C1)C2=C(C=CC(=C2OC)C(=O)O)OCCCCOC(=O)C=C)C3=C(C=CC(=C3OC)C(=O)O)OCCCCOC(=O)C=C UBBPRGYHCZUVSX-UHFFFAOYSA-N 0.000 description 1
- SDVFCGRHIQVYDC-UHFFFAOYSA-N 3-[4-[3-carboxy-2-methyl-6-(4-prop-2-enoyloxybutoxy)phenyl]-3-ethoxyphenyl]-2-methyl-4-(4-prop-2-enoyloxybutoxy)benzoic acid Chemical compound CCOC1=C(C=CC(=C1)C2=C(C=CC(=C2C)C(=O)O)OCCCCOC(=O)C=C)C3=C(C=CC(=C3C)C(=O)O)OCCCCOC(=O)C=C SDVFCGRHIQVYDC-UHFFFAOYSA-N 0.000 description 1
- CMILYNMLDVROLQ-UHFFFAOYSA-N 3-[4-[3-carboxy-2-methyl-6-(4-prop-2-enoyloxybutoxy)phenyl]-3-methylphenyl]-2-methyl-4-(4-prop-2-enoyloxybutoxy)benzoic acid Chemical compound CC1=C(C=CC(=C1)C2=C(C=CC(=C2C)C(=O)O)OCCCCOC(=O)C=C)C3=C(C=CC(=C3C)C(=O)O)OCCCCOC(=O)C=C CMILYNMLDVROLQ-UHFFFAOYSA-N 0.000 description 1
- VXJVRGYHTQGZTG-UHFFFAOYSA-N 3-[4-[3-carboxy-2-methyl-6-(4-prop-2-enoyloxybutoxycarbonyloxy)phenyl]-3-methylphenyl]-2-methyl-4-(4-prop-2-enoyloxybutoxycarbonyloxy)benzoic acid Chemical compound CC1=C(C=CC(=C1)C=1C(=C(C(=O)O)C=CC=1OC(=O)OCCCCOC(C=C)=O)C)C=1C(=C(C(=O)O)C=CC=1OC(=O)OCCCCOC(C=C)=O)C VXJVRGYHTQGZTG-UHFFFAOYSA-N 0.000 description 1
- QFEMWQWSJXNFBP-UHFFFAOYSA-N 3-methoxy-4-(4-prop-2-enoyloxybutoxycarbonyloxy)benzoic acid Chemical compound COC1=C(C=CC(=C1)C(=O)O)OC(=O)OCCCCOC(=O)C=C QFEMWQWSJXNFBP-UHFFFAOYSA-N 0.000 description 1
- 125000005917 3-methylpentyl group Chemical group 0.000 description 1
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ZJTLTWVJESTJAS-YEUAYIGBSA-N C1=C(OC(=O)C=C)C(OC)=CC(C(=O)OC=2C(=C([C@H]3[C@H]4OC[C@H]([C@H]4OC3)C=3C(=CC=C(OC(=O)C=4C=C(OC)C(OC(=O)C=C)=CC=4)C=3OC)C(O)=O)C(C(O)=O)=CC=2)OC)=C1 Chemical compound C1=C(OC(=O)C=C)C(OC)=CC(C(=O)OC=2C(=C([C@H]3[C@H]4OC[C@H]([C@H]4OC3)C=3C(=CC=C(OC(=O)C=4C=C(OC)C(OC(=O)C=C)=CC=4)C=3OC)C(O)=O)C(C(O)=O)=CC=2)OC)=C1 ZJTLTWVJESTJAS-YEUAYIGBSA-N 0.000 description 1
- RSVXOVWAVBNLQV-VNZARTBNSA-N C1=C(OC(=O)C=C)C(OC)=CC(C(=O)OC=2C=C(C(C(O)=O)=CC=2)[C@H]2[C@H]3OC[C@H]([C@H]3OC2)C=2C(=CC=C(OC(=O)C=3C=C(OC)C(OC(=O)C=C)=CC=3)C=2)C(O)=O)=C1 Chemical compound C1=C(OC(=O)C=C)C(OC)=CC(C(=O)OC=2C=C(C(C(O)=O)=CC=2)[C@H]2[C@H]3OC[C@H]([C@H]3OC2)C=2C(=CC=C(OC(=O)C=3C=C(OC)C(OC(=O)C=C)=CC=3)C=2)C(O)=O)=C1 RSVXOVWAVBNLQV-VNZARTBNSA-N 0.000 description 1
- VLBOCWVKOWKZFN-HGDLCUPASA-N C1=CC(C(O)=O)=C([C@@H]2[C@H]3OC[C@H]([C@H]3OC2)C=2C(=CC=C(OC(=O)C=3C=CC(OC(=O)C=C)=CC=3)C=2OC)C(O)=O)C(OC)=C1OC(=O)C1=CC=C(OC(=O)C=C)C=C1 Chemical compound C1=CC(C(O)=O)=C([C@@H]2[C@H]3OC[C@H]([C@H]3OC2)C=2C(=CC=C(OC(=O)C=3C=CC(OC(=O)C=C)=CC=3)C=2OC)C(O)=O)C(OC)=C1OC(=O)C1=CC=C(OC(=O)C=C)C=C1 VLBOCWVKOWKZFN-HGDLCUPASA-N 0.000 description 1
- VLBOCWVKOWKZFN-ULMTZRPPSA-N C1=CC(C(O)=O)=C([C@H]2[C@H]3OC[C@H]([C@H]3OC2)C=2C(=CC=C(OC(=O)C=3C=CC(OC(=O)C=C)=CC=3)C=2OC)C(O)=O)C(OC)=C1OC(=O)C1=CC=C(OC(=O)C=C)C=C1 Chemical compound C1=CC(C(O)=O)=C([C@H]2[C@H]3OC[C@H]([C@H]3OC2)C=2C(=CC=C(OC(=O)C=3C=CC(OC(=O)C=C)=CC=3)C=2OC)C(O)=O)C(OC)=C1OC(=O)C1=CC=C(OC(=O)C=C)C=C1 VLBOCWVKOWKZFN-ULMTZRPPSA-N 0.000 description 1
- RJECBFYYHHQWNH-UHFFFAOYSA-N CC(C=C(C=C1)C(C(OC)=C(C=C2)OC(OCCCCOC(C=C)=O)=O)=C2C(O)=O)=C1C(C(OC)=C(C=C1)OC(OCCCCOC(C=C)=O)=O)=C1C(O)=O Chemical compound CC(C=C(C=C1)C(C(OC)=C(C=C2)OC(OCCCCOC(C=C)=O)=O)=C2C(O)=O)=C1C(C(OC)=C(C=C1)OC(OCCCCOC(C=C)=O)=O)=C1C(O)=O RJECBFYYHHQWNH-UHFFFAOYSA-N 0.000 description 1
- UNLLVYBMFNCFLB-UHFFFAOYSA-N COC1=CC(C=2C(=CC=C(C=2C)C(O)=O)OC(=O)OCCCCOC(=O)C=C)=CC=C1C1=C(C)C(C(O)=O)=CC=C1OC(=O)OCCCCOC(=O)C=C Chemical compound COC1=CC(C=2C(=CC=C(C=2C)C(O)=O)OC(=O)OCCCCOC(=O)C=C)=CC=C1C1=C(C)C(C(O)=O)=CC=C1OC(=O)OCCCCOC(=O)C=C UNLLVYBMFNCFLB-UHFFFAOYSA-N 0.000 description 1
- SNHJYPKMKJLITQ-UHFFFAOYSA-N COc1cc(C(O)=O)c(-c2ccc(c(OC)c2)-c2c(OC)c(OC(=O)OCCCCOC(=O)C=C)c(OC)cc2C(O)=O)c(OC)c1OC(=O)OCCCCOC(=O)C=C Chemical compound COc1cc(C(O)=O)c(-c2ccc(c(OC)c2)-c2c(OC)c(OC(=O)OCCCCOC(=O)C=C)c(OC)cc2C(O)=O)c(OC)c1OC(=O)OCCCCOC(=O)C=C SNHJYPKMKJLITQ-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- XVZXOLOFWKSDSR-UHFFFAOYSA-N Cc1cc(C)c([C]=O)c(C)c1 Chemical group Cc1cc(C)c([C]=O)c(C)c1 XVZXOLOFWKSDSR-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 239000004988 Nematic liquid crystal Substances 0.000 description 1
- 241000208125 Nicotiana Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- XRMBQHTWUBGQDN-UHFFFAOYSA-N [2-[2,2-bis(prop-2-enoyloxymethyl)butoxymethyl]-2-(prop-2-enoyloxymethyl)butyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(CC)COCC(CC)(COC(=O)C=C)COC(=O)C=C XRMBQHTWUBGQDN-UHFFFAOYSA-N 0.000 description 1
- UEEBQQAQBBLNRF-UHFFFAOYSA-N [2-methoxy-4-[3-methoxy-4-(4-prop-2-enoyloxybutoxycarbonyloxy)benzoyl]oxyphenyl] 3,5-dimethoxy-4-(4-prop-2-enoyloxybutoxycarbonyloxy)benzoate Chemical compound C=1C=C(OC(=O)C=2C=C(OC)C(OC(=O)OCCCCOC(=O)C=C)=C(OC)C=2)C(OC)=CC=1OC(=O)C1=CC=C(OC(=O)OCCCCOC(=O)C=C)C(OC)=C1 UEEBQQAQBBLNRF-UHFFFAOYSA-N 0.000 description 1
- HIIYFDZFXVPIKC-UHFFFAOYSA-N [2-methoxy-4-[3-methyl-4-(4-prop-2-enoyloxybutoxy)benzoyl]oxyphenyl] 3,5-dimethyl-4-(4-prop-2-enoyloxybutoxy)benzoate Chemical compound C=1C=C(OC(=O)C=2C=C(C)C(OCCCCOC(=O)C=C)=C(C)C=2)C(OC)=CC=1OC(=O)C1=CC=C(OCCCCOC(=O)C=C)C(C)=C1 HIIYFDZFXVPIKC-UHFFFAOYSA-N 0.000 description 1
- OQGRWHBDDMBKLS-UHFFFAOYSA-N [3-methoxy-4-[4-(4-prop-2-enoyloxybutoxy)benzoyl]oxyphenyl] 3-methyl-4-(4-prop-2-enoyloxybutoxy)benzoate Chemical compound C=1C=C(OC(=O)C=2C=CC(OCCCCOC(=O)C=C)=CC=2)C(OC)=CC=1OC(=O)C1=CC=C(OCCCCOC(=O)C=C)C(C)=C1 OQGRWHBDDMBKLS-UHFFFAOYSA-N 0.000 description 1
- NLGINBDFXRCWQW-UHFFFAOYSA-N [3-methyl-4-[4-(4-prop-2-enoyloxybutoxy)benzoyl]oxyphenyl] 4-(4-prop-2-enoyloxybutoxy)benzoate Chemical compound C=1C=C(OC(=O)C=2C=CC(OCCCCOC(=O)C=C)=CC=2)C(C)=CC=1OC(=O)C1=CC=C(OCCCCOC(=O)C=C)C=C1 NLGINBDFXRCWQW-UHFFFAOYSA-N 0.000 description 1
- MPIAGWXWVAHQBB-UHFFFAOYSA-N [3-prop-2-enoyloxy-2-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]methyl]-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C MPIAGWXWVAHQBB-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 229910052768 actinide Inorganic materials 0.000 description 1
- 150000001255 actinides Chemical class 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000005083 alkoxyalkoxy group Chemical group 0.000 description 1
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 1
- VEQOALNAAJBPNY-UHFFFAOYSA-N antipyrine Chemical compound CN1C(C)=CC(=O)N1C1=CC=CC=C1 VEQOALNAAJBPNY-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- NEAVOOMHANEOIZ-UHFFFAOYSA-N carbonic acid;2-hydroxy-1-[4-(2-hydroxyethoxy)phenyl]-2-methylpropan-1-one Chemical compound OC(O)=O.CC(C)(O)C(=O)C1=CC=C(OCCO)C=C1 NEAVOOMHANEOIZ-UHFFFAOYSA-N 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000010538 cationic polymerization reaction Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 235000012000 cholesterol Nutrition 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 230000002759 chromosomal effect Effects 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 125000004386 diacrylate group Chemical group 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 235000015872 dietary supplement Nutrition 0.000 description 1
- VFHVQBAGLAREND-UHFFFAOYSA-N diphenylphosphoryl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 VFHVQBAGLAREND-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- WOXXJEVNDJOOLV-UHFFFAOYSA-N ethenyl-tris(2-methoxyethoxy)silane Chemical compound COCCO[Si](OCCOC)(OCCOC)C=C WOXXJEVNDJOOLV-UHFFFAOYSA-N 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000005251 gamma ray Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- YDKNBNOOCSNPNS-UHFFFAOYSA-N methyl 1,3-benzoxazole-2-carboxylate Chemical compound C1=CC=C2OC(C(=O)OC)=NC2=C1 YDKNBNOOCSNPNS-UHFFFAOYSA-N 0.000 description 1
- YLHXLHGIAMFFBU-UHFFFAOYSA-N methyl phenylglyoxalate Chemical compound COC(=O)C(=O)C1=CC=CC=C1 YLHXLHGIAMFFBU-UHFFFAOYSA-N 0.000 description 1
- 125000002816 methylsulfanyl group Chemical group [H]C([H])([H])S[*] 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 125000004573 morpholin-4-yl group Chemical group N1(CCOCC1)* 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- VLZLOWPYUQHHCG-UHFFFAOYSA-N nitromethylbenzene Chemical compound [O-][N+](=O)CC1=CC=CC=C1 VLZLOWPYUQHHCG-UHFFFAOYSA-N 0.000 description 1
- MSRJTTSHWYDFIU-UHFFFAOYSA-N octyltriethoxysilane Chemical compound CCCCCCCC[Si](OCC)(OCC)OCC MSRJTTSHWYDFIU-UHFFFAOYSA-N 0.000 description 1
- 229960003493 octyltriethoxysilane Drugs 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
- AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical compound P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- WRAQQYDMVSCOTE-UHFFFAOYSA-N phenyl prop-2-enoate Chemical class C=CC(=O)OC1=CC=CC=C1 WRAQQYDMVSCOTE-UHFFFAOYSA-N 0.000 description 1
- 229960003424 phenylacetic acid Drugs 0.000 description 1
- 239000003279 phenylacetic acid Substances 0.000 description 1
- FAQJJMHZNSSFSM-UHFFFAOYSA-N phenylglyoxylic acid Chemical compound OC(=O)C(=O)C1=CC=CC=C1 FAQJJMHZNSSFSM-UHFFFAOYSA-N 0.000 description 1
- 239000003504 photosensitizing agent Substances 0.000 description 1
- 239000006069 physical mixture Substances 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 229920001290 polyvinyl ester Polymers 0.000 description 1
- 229920001289 polyvinyl ether Polymers 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000000935 solvent evaporation Methods 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 230000029305 taxis Effects 0.000 description 1
- 125000004213 tert-butoxy group Chemical group [H]C([H])([H])C(O*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000005621 tetraalkylammonium salts Chemical class 0.000 description 1
- JXUKBNICSRJFAP-UHFFFAOYSA-N triethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCOCC1CO1 JXUKBNICSRJFAP-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/14—Security printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/364—Liquid crystals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/28—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using thermochromic compounds or layers containing liquid crystals, microcapsules, bleachable dyes or heat- decomposable compounds, e.g. gas- liberating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/28—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using thermochromic compounds or layers containing liquid crystals, microcapsules, bleachable dyes or heat- decomposable compounds, e.g. gas- liberating
- B41M5/281—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using thermochromic compounds or layers containing liquid crystals, microcapsules, bleachable dyes or heat- decomposable compounds, e.g. gas- liberating using liquid crystals only
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D15/00—Printed matter of special format or style not otherwise provided for
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
- B42D25/23—Identity cards
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
- B42D25/24—Passports
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
- B42D25/25—Public transport tickets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
- B42D25/29—Securities; Bank notes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/52—Liquid crystal materials characterised by components which are not liquid crystals, e.g. additives with special physical aspect: solvents, solid particles
- C09K19/58—Dopants or charge transfer agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/52—Liquid crystal materials characterised by components which are not liquid crystals, e.g. additives with special physical aspect: solvents, solid particles
- C09K19/58—Dopants or charge transfer agents
- C09K19/586—Optically active dopants; chiral dopants
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/52—Liquid crystal materials characterised by components which are not liquid crystals, e.g. additives with special physical aspect: solvents, solid particles
- C09K19/58—Dopants or charge transfer agents
- C09K19/586—Optically active dopants; chiral dopants
- C09K19/588—Heterocyclic compounds
-
- B42D2035/20—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/378—Special inks
- B42D25/387—Special inks absorbing or reflecting ultraviolet light
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/378—Special inks
- B42D25/391—Special inks absorbing or reflecting polarised light
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K2019/0444—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group
- C09K2019/0448—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group the end chain group being a polymerizable end group, e.g. -Sp-P or acrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/34—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring
- C09K19/3402—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring having oxygen as hetero atom
- C09K19/3405—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring having oxygen as hetero atom the heterocyclic ring being a five-membered ring
- C09K2019/3408—Five-membered ring with oxygen(s) in fused, bridged or spiro ring systems
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2219/00—Aspects relating to the form of the liquid crystal [LC] material, or by the technical area in which LC material are used
- C09K2219/03—Aspects relating to the form of the liquid crystal [LC] material, or by the technical area in which LC material are used in the form of films, e.g. films after polymerisation of LC precursor
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24835—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including developable image or soluble portion in coating or impregnation [e.g., safety paper, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Accounting & Taxation (AREA)
- Business, Economics & Management (AREA)
- Finance (AREA)
- Credit Cards Or The Like (AREA)
- Liquid Crystal Substances (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Liquid Crystal (AREA)
- Printing Methods (AREA)
- Polarising Elements (AREA)
- Inspection Of Paper Currency And Valuable Securities (AREA)
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161490949P | 2011-05-27 | 2011-05-27 | |
| US61/490,949 | 2011-05-27 | ||
| US201161492171P | 2011-06-01 | 2011-06-01 | |
| US61/492,171 | 2011-06-01 | ||
| EP11168536 | 2011-06-01 | ||
| EP11168536.8 | 2011-06-01 | ||
| PCT/EP2012/059663 WO2012163778A1 (en) | 2011-05-27 | 2012-05-24 | Substrate with a modified liquid crystal polymer marking |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20140033385A true KR20140033385A (ko) | 2014-03-18 |
Family
ID=47258391
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020137032141A Withdrawn KR20140033385A (ko) | 2011-05-27 | 2012-05-24 | 개질 액정고분자 마킹을 갖는 기판 |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US8821756B2 (enExample) |
| EP (1) | EP2714412B1 (enExample) |
| JP (1) | JP5764812B2 (enExample) |
| KR (1) | KR20140033385A (enExample) |
| CN (1) | CN103582569B (enExample) |
| AR (1) | AR086508A1 (enExample) |
| BR (1) | BR112013029939B1 (enExample) |
| CA (1) | CA2834719A1 (enExample) |
| CO (1) | CO6811874A2 (enExample) |
| IL (1) | IL229224A0 (enExample) |
| MA (1) | MA35127B1 (enExample) |
| MX (1) | MX2013013894A (enExample) |
| PH (1) | PH12013502332A1 (enExample) |
| RU (1) | RU2013158145A (enExample) |
| SG (1) | SG194961A1 (enExample) |
| UY (1) | UY34087A (enExample) |
| WO (1) | WO2012163778A1 (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20140231449A1 (en) * | 2013-02-19 | 2014-08-21 | Gojo Industries, Inc. | Refill container labeling |
| NL1040357C2 (en) * | 2013-08-28 | 2015-03-03 | Stichting Dutch Polymer Inst | Liquid crystal network. |
| TW201520216A (zh) | 2013-10-21 | 2015-06-01 | Sicpa Holding Sa | 對掌性摻雜物與使用聚合性液晶材料標記之識別法及鑑別法 |
| WO2015147176A1 (ja) * | 2014-03-26 | 2015-10-01 | 凸版印刷株式会社 | 偽造防止媒体、及び、偽造防止媒体の製造方法 |
| JP6363012B2 (ja) * | 2014-12-11 | 2018-07-25 | 富士フイルム株式会社 | 光学部材および光学部材を有する画像表示装置 |
| JP6433776B2 (ja) * | 2014-12-11 | 2018-12-05 | 富士フイルム株式会社 | 光学部材の製造方法 |
| CN104851361A (zh) * | 2015-02-13 | 2015-08-19 | 厦门天马微电子有限公司 | 一种防伪标签及其制造方法 |
| NO3067214T3 (enExample) * | 2015-03-13 | 2018-05-19 | ||
| CN105398252B (zh) * | 2015-07-28 | 2017-05-10 | 中国人民银行印制科学技术研究所 | 一种含有智能荧光材料的防伪元件 |
| KR102365647B1 (ko) * | 2016-07-25 | 2022-02-21 | 시크파 홀딩 에스에이 | 다성분 반응성 잉크 및 프린팅 방법 |
| GB201803979D0 (en) * | 2018-03-13 | 2018-04-25 | Johnson Matthey Plc | Security device, method of making a security device and method of authenticating a product |
| WO2019188846A1 (ja) | 2018-03-29 | 2019-10-03 | 富士フイルム株式会社 | 画像形成方法 |
| RU2694028C1 (ru) * | 2018-09-17 | 2019-07-08 | Михаил Николаевич Бурдаев | Способ расширения функциональности конструктивных элементов, используемых при пилотируемых космических полетах |
| GB2578117B (en) * | 2018-10-16 | 2021-06-09 | De La Rue Int Ltd | Security devices and methods for their manufacture |
| US11351811B2 (en) * | 2020-05-29 | 2022-06-07 | International Business Machines Corporation | Optically-passive magnetic signature and identification feature with electromagnetic tamper detection |
| KR20230109756A (ko) * | 2020-12-25 | 2023-07-20 | 후지필름 가부시키가이샤 | 화상 기록 방법 및 잉크젯 기록물 |
Family Cites Families (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2586724B1 (fr) | 1985-08-27 | 1988-03-11 | Routier Equip Sa | Barriere metallique, notamment pour l'equipement de voies de circulation routiere |
| DE69325555D1 (de) | 1992-04-27 | 1999-08-12 | Merck Patent Gmbh | Elektrooptisches fluessigkristallsystem |
| GB2268906A (en) | 1992-07-24 | 1994-01-26 | Portals Ltd | Counterfeit protection for documents using optical effects of liquid crystal |
| DE4405316A1 (de) | 1994-02-19 | 1995-08-24 | Basf Ag | Neue polymerisierbare flüssigkristalline Verbindungen |
| DE19532408A1 (de) | 1995-09-01 | 1997-03-06 | Basf Ag | Polymerisierbare flüssigkristalline Verbindungen |
| DE19843724A1 (de) | 1997-10-08 | 1999-04-15 | Basf Ag | Polymerisierbare chirale Verbindungen und deren Verwendung |
| DE19836885A1 (de) | 1998-08-14 | 2000-02-17 | Clariant Gmbh | Lasermarkierung von Effektbeschichtungen |
| WO2001024106A1 (en) | 1999-09-27 | 2001-04-05 | Sicpa Holding S.A. | Multi-dimensional barcode and apparatus for reading a multi-dimensional barcode |
| US6589445B2 (en) * | 2000-06-27 | 2003-07-08 | Fuji Photo Film Co., Ltd. | Light-reaction type optically active compound, light-reaction type chiral agent, liquid crystal composition, liquid crystal color filter, optical film, recording medium, and method of changing twist structure of liquid crystal |
| US6917399B2 (en) * | 2001-02-22 | 2005-07-12 | 3M Innovative Properties Company | Optical bodies containing cholesteric liquid crystal material and methods of manufacture |
| CA2445080A1 (en) | 2001-04-24 | 2002-10-31 | Merck Patent Gesellschaft Mit Beschraenkter Haftung | Birefringent marking |
| GB0319908D0 (en) * | 2003-08-23 | 2003-09-24 | Koninkl Philips Electronics Nv | Method of producing an electronic device, electronic device and apparatus for implementing the method |
| JP2007503609A (ja) * | 2003-08-23 | 2007-02-22 | コーニンクレッカ フィリップス エレクトロニクス エヌ ヴィ | カラーディスプレイ装置の製造方法及びカラーディスプレイ装置 |
| DE10342674B4 (de) * | 2003-09-16 | 2007-07-19 | Leonhard Kurz Gmbh & Co. Kg | Verfahren und Foliensystem zur Herstellung eines individualisierten optisch variablen Elements |
| WO2005049703A1 (de) | 2003-11-21 | 2005-06-02 | Merck Patent Gmbh | Verfahren zur modifikation von chiralen flüssigkristallfilmen mit hilfe von extraktionsmitteln |
| JP4446444B2 (ja) | 2004-11-22 | 2010-04-07 | 日東電工株式会社 | 偽造防止機能付シートの製造方法、物品、認証カード、バーコードラベル、及び認証システム |
| US20060257633A1 (en) | 2005-04-27 | 2006-11-16 | Hitachi Maxell, Ltd. | Method for modifying surface of polymer substrate, method for forming plated film on polymer substrate, method for producing polymer member, and coating member |
| CN1881077A (zh) * | 2005-04-27 | 2006-12-20 | 日立麦克赛尔株式会社 | 聚合物的表面改性方法 |
| JP4985643B2 (ja) * | 2006-03-13 | 2012-07-25 | 大日本印刷株式会社 | 光学拡散素子、投影スクリーン、意匠性部材及びセキュリティ媒体 |
| EP1876216A1 (en) * | 2006-06-27 | 2008-01-09 | Sicpa Holding S.A. | Cholesteric multi-layers |
| US8905313B2 (en) | 2007-04-12 | 2014-12-09 | Honeywell International Inc. | Method and system for creating and reading multi-color co-planar emissive indicia using printable dyes and pigments |
| WO2009112206A2 (en) * | 2008-03-11 | 2009-09-17 | Rolic Ltd. | Optical biometric security element |
| TWI422498B (zh) * | 2008-04-02 | 2014-01-11 | Sicpa Holding Sa | 使用液晶材料標記之識別法及鑑別法 |
| JP5540473B2 (ja) | 2008-06-12 | 2014-07-02 | 凸版印刷株式会社 | コレステリック液晶ディスプレイ用品 |
| US20100025641A1 (en) | 2008-08-04 | 2010-02-04 | Fujifilm Corporation | Infrared region selective reflection coat and infrared region selective reflection film |
| JP5451235B2 (ja) * | 2009-07-31 | 2014-03-26 | 富士フイルム株式会社 | 複屈折パターンを有する物品の製造方法及び複屈折パターン作製材料 |
| JP5717324B2 (ja) * | 2009-08-05 | 2015-05-13 | 凸版印刷株式会社 | 偽造防止構造体及びその製造方法 |
| CN102648097B (zh) * | 2009-12-08 | 2015-02-04 | 锡克拜控股有限公司 | 以手性液晶聚合物为基础的改性标志 |
| US8426013B2 (en) * | 2009-12-08 | 2013-04-23 | Sicpa Holding Sa | Marking based on modified chiral liquid crystal polymers |
| WO2011069691A1 (en) * | 2009-12-08 | 2011-06-16 | Sicpa Holding Sa | Marking based on chiral liquid crystal polymers |
| AU2010330331A1 (en) * | 2009-12-08 | 2012-06-07 | Sicpa Holding Sa | Chiral liquid crystal polymer marking |
-
2012
- 2012-05-21 AR ARP120101796A patent/AR086508A1/es unknown
- 2012-05-22 UY UY0001034087A patent/UY34087A/es not_active Application Discontinuation
- 2012-05-24 EP EP12723479.7A patent/EP2714412B1/en active Active
- 2012-05-24 CN CN201280025718.5A patent/CN103582569B/zh active Active
- 2012-05-24 WO PCT/EP2012/059663 patent/WO2012163778A1/en not_active Ceased
- 2012-05-24 BR BR112013029939-8A patent/BR112013029939B1/pt active IP Right Grant
- 2012-05-24 RU RU2013158145/12A patent/RU2013158145A/ru not_active Application Discontinuation
- 2012-05-24 KR KR1020137032141A patent/KR20140033385A/ko not_active Withdrawn
- 2012-05-24 CA CA2834719A patent/CA2834719A1/en not_active Abandoned
- 2012-05-24 JP JP2014511866A patent/JP5764812B2/ja not_active Expired - Fee Related
- 2012-05-24 MX MX2013013894A patent/MX2013013894A/es not_active Application Discontinuation
- 2012-05-24 US US13/479,913 patent/US8821756B2/en active Active
- 2012-05-24 PH PH1/2013/502332A patent/PH12013502332A1/en unknown
- 2012-05-24 SG SG2013084421A patent/SG194961A1/en unknown
-
2013
- 2013-11-04 IL IL229224A patent/IL229224A0/en unknown
- 2013-11-15 MA MA36440A patent/MA35127B1/fr unknown
- 2013-11-21 CO CO13274199A patent/CO6811874A2/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| RU2013158145A (ru) | 2015-07-10 |
| SG194961A1 (en) | 2013-12-30 |
| IL229224A0 (en) | 2014-01-30 |
| JP2014524846A (ja) | 2014-09-25 |
| EP2714412B1 (en) | 2019-03-13 |
| JP5764812B2 (ja) | 2015-08-19 |
| MA35127B1 (fr) | 2014-05-02 |
| CN103582569B (zh) | 2017-04-05 |
| EP2714412A1 (en) | 2014-04-09 |
| BR112013029939A2 (pt) | 2017-08-08 |
| AR086508A1 (es) | 2013-12-18 |
| PH12013502332A1 (en) | 2014-01-06 |
| US20120328852A1 (en) | 2012-12-27 |
| WO2012163778A1 (en) | 2012-12-06 |
| CA2834719A1 (en) | 2012-12-06 |
| CN103582569A (zh) | 2014-02-12 |
| UY34087A (es) | 2012-11-30 |
| MX2013013894A (es) | 2014-01-24 |
| BR112013029939B1 (pt) | 2021-02-02 |
| CO6811874A2 (es) | 2013-12-16 |
| US8821756B2 (en) | 2014-09-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5764812B2 (ja) | 改変された液晶ポリマーマーキングを有する基材 | |
| US8426014B2 (en) | Modified marking based on chiral liquid crystal polymers | |
| EP2509794B1 (en) | Marking based on chiral liquid crystal polymers | |
| KR101845111B1 (ko) | 키랄 액정 전구체계 합성물 마킹 | |
| US10611919B2 (en) | Salt-free composite marking based on chiral liquid crystal precursors comprising chiral acrylate dopants | |
| AU2010330334A1 (en) | Marking based on modified chiral liquid crystal polymers | |
| US10308872B2 (en) | Composite marking based on chiral liquid crystal precursors and modifying resins | |
| CN105899642B (zh) | 基于手性液晶前体和改性树脂的复合标记 | |
| EP3066175B1 (en) | Salt-free composite marking based on chiral liquid crystal precursors comprising chiral acrylate dopants | |
| HK1194331A (en) | Substrate with a modified liquid crystal polymer marking | |
| TW201302990A (zh) | 具有改質液晶聚合物標記之基底 | |
| HK1185905A (en) | Composite marking based on chiral liquid crystal precursors | |
| HK1173704B (en) | Marking based on chiral liquid crystal polymers | |
| EP3066174A1 (en) | Composite marking based on chiral liquid crystal precursors and modifying resins |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0105 | International application |
Patent event date: 20131204 Patent event code: PA01051R01D Comment text: International Patent Application |
|
| PG1501 | Laying open of application | ||
| PC1203 | Withdrawal of no request for examination | ||
| WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |