KR20140031838A - 질소 함유 다공성 탄소질 물질의 제조 방법 - Google Patents
질소 함유 다공성 탄소질 물질의 제조 방법 Download PDFInfo
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- KR20140031838A KR20140031838A KR1020137016365A KR20137016365A KR20140031838A KR 20140031838 A KR20140031838 A KR 20140031838A KR 1020137016365 A KR1020137016365 A KR 1020137016365A KR 20137016365 A KR20137016365 A KR 20137016365A KR 20140031838 A KR20140031838 A KR 20140031838A
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- Prior art keywords
- carbonaceous material
- per molecule
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- nitrogen
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- 239000003575 carbonaceous material Substances 0.000 title claims abstract description 57
- 238000000034 method Methods 0.000 title claims abstract description 44
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 title claims abstract description 10
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 7
- 125000003172 aldehyde group Chemical group 0.000 claims abstract description 18
- -1 heterocyclic hydrocarbon Chemical class 0.000 claims abstract description 14
- 238000010438 heat treatment Methods 0.000 claims abstract description 11
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000001301 oxygen Substances 0.000 claims abstract description 9
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 7
- 229910017053 inorganic salt Inorganic materials 0.000 claims abstract description 7
- 150000001491 aromatic compounds Chemical class 0.000 claims abstract description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 4
- 150000001875 compounds Chemical class 0.000 claims description 71
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 48
- 238000006243 chemical reaction Methods 0.000 claims description 31
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 30
- 239000011148 porous material Substances 0.000 claims description 27
- 239000003990 capacitor Substances 0.000 claims description 25
- 229910052757 nitrogen Inorganic materials 0.000 claims description 25
- 239000002904 solvent Substances 0.000 claims description 19
- 125000003118 aryl group Chemical group 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 17
- 239000011230 binding agent Substances 0.000 claims description 15
- 239000003054 catalyst Substances 0.000 claims description 15
- 125000000623 heterocyclic group Chemical group 0.000 claims description 12
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 11
- 229910052717 sulfur Inorganic materials 0.000 claims description 11
- 239000011593 sulfur Substances 0.000 claims description 11
- 125000001072 heteroaryl group Chemical group 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 8
- 238000001179 sorption measurement Methods 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 239000000654 additive Substances 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- ZNZYKNKBJPZETN-WELNAUFTSA-N Dialdehyde 11678 Chemical compound N1C2=CC=CC=C2C2=C1[C@H](C[C@H](/C(=C/O)C(=O)OC)[C@@H](C=C)C=O)NCC2 ZNZYKNKBJPZETN-WELNAUFTSA-N 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 3
- 125000002529 biphenylenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3C12)* 0.000 claims description 3
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- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 claims description 3
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- RMBPEFMHABBEKP-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2C3=C[CH]C=CC3=CC2=C1 RMBPEFMHABBEKP-UHFFFAOYSA-N 0.000 claims description 2
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- NIHNNTQXNPWCJQ-UHFFFAOYSA-N o-biphenylenemethane Natural products C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 claims description 2
- 125000005548 pyrenylene group Chemical group 0.000 claims description 2
- GBXQPDCOMJJCMJ-UHFFFAOYSA-M trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCCCCC[N+](C)(C)C GBXQPDCOMJJCMJ-UHFFFAOYSA-M 0.000 claims description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 2
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- 239000000463 material Substances 0.000 description 53
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 26
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 26
- 229920000877 Melamine resin Polymers 0.000 description 20
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 20
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 18
- 239000000126 substance Substances 0.000 description 16
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- 239000000843 powder Substances 0.000 description 14
- 238000002360 preparation method Methods 0.000 description 14
- 238000000944 Soxhlet extraction Methods 0.000 description 13
- 229910052786 argon Inorganic materials 0.000 description 13
- 239000012300 argon atmosphere Substances 0.000 description 13
- 238000001816 cooling Methods 0.000 description 13
- 238000001914 filtration Methods 0.000 description 13
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 13
- 230000005587 bubbling Effects 0.000 description 12
- 238000007872 degassing Methods 0.000 description 12
- 125000000524 functional group Chemical group 0.000 description 12
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- 125000004432 carbon atom Chemical group C* 0.000 description 11
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 10
- 239000007789 gas Substances 0.000 description 9
- 125000006850 spacer group Chemical group 0.000 description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 7
- 239000003792 electrolyte Substances 0.000 description 7
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- 150000003254 radicals Chemical class 0.000 description 7
- 125000004122 cyclic group Chemical group 0.000 description 6
- 229910052736 halogen Inorganic materials 0.000 description 6
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- 125000002015 acyclic group Chemical group 0.000 description 5
- 125000001931 aliphatic group Chemical group 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 125000005842 heteroatom Chemical group 0.000 description 5
- 150000002431 hydrogen Chemical class 0.000 description 5
- 229920006395 saturated elastomer Polymers 0.000 description 5
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 4
- OFAPSLLQSSHRSQ-UHFFFAOYSA-N 1H-triazine-2,4-diamine Chemical compound NN1NC=CC(N)=N1 OFAPSLLQSSHRSQ-UHFFFAOYSA-N 0.000 description 4
- ZCJZVMNBJKPQEV-UHFFFAOYSA-N 4-[3,5-bis(4-formylphenyl)phenyl]benzaldehyde Chemical compound C1=CC(C=O)=CC=C1C1=CC(C=2C=CC(C=O)=CC=2)=CC(C=2C=CC(C=O)=CC=2)=C1 ZCJZVMNBJKPQEV-UHFFFAOYSA-N 0.000 description 4
- AEKQNAANFVOBCU-UHFFFAOYSA-N benzene-1,3,5-tricarbaldehyde Chemical compound O=CC1=CC(C=O)=CC(C=O)=C1 AEKQNAANFVOBCU-UHFFFAOYSA-N 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 230000001186 cumulative effect Effects 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229910021607 Silver chloride Inorganic materials 0.000 description 3
- 150000001449 anionic compounds Chemical class 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 229910001412 inorganic anion Inorganic materials 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 3
- 239000004810 polytetrafluoroethylene Substances 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- PMWXGSWIOOVHEQ-UHFFFAOYSA-N pyridine-2,6-dicarbaldehyde Chemical compound O=CC1=CC=CC(C=O)=N1 PMWXGSWIOOVHEQ-UHFFFAOYSA-N 0.000 description 3
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- PXJJKVNIMAZHCB-UHFFFAOYSA-N 2,5-diformylfuran Chemical compound O=CC1=CC=C(C=O)O1 PXJJKVNIMAZHCB-UHFFFAOYSA-N 0.000 description 2
- FEHLIYXNTWAEBQ-UHFFFAOYSA-N 4-(4-formylphenyl)benzaldehyde Chemical compound C1=CC(C=O)=CC=C1C1=CC=C(C=O)C=C1 FEHLIYXNTWAEBQ-UHFFFAOYSA-N 0.000 description 2
- SUQGULAGAKSTIB-UHFFFAOYSA-N 6-(5-formylpyridin-2-yl)pyridine-3-carbaldehyde Chemical compound N1=CC(C=O)=CC=C1C1=CC=C(C=O)C=N1 SUQGULAGAKSTIB-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
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- 125000004429 atom Chemical group 0.000 description 2
- IZALUMVGBVKPJD-UHFFFAOYSA-N benzene-1,3-dicarbaldehyde Chemical compound O=CC1=CC=CC(C=O)=C1 IZALUMVGBVKPJD-UHFFFAOYSA-N 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
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- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 2
- 238000001095 inductively coupled plasma mass spectrometry Methods 0.000 description 2
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000000468 ketone group Chemical group 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- IQDQMRZGMILNMQ-UHFFFAOYSA-N naphthalene-2,6-dicarbaldehyde Chemical compound C1=C(C=O)C=CC2=CC(C=O)=CC=C21 IQDQMRZGMILNMQ-UHFFFAOYSA-N 0.000 description 2
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- 238000012360 testing method Methods 0.000 description 2
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- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
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- MIDXCONKKJTLDX-UHFFFAOYSA-N 3,5-dimethylcyclopentane-1,2-dione Chemical compound CC1CC(C)C(=O)C1=O MIDXCONKKJTLDX-UHFFFAOYSA-N 0.000 description 1
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- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
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- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
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Classifications
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- C01B32/00—Carbon; Compounds thereof
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- B01J37/082—Decomposition and pyrolysis
- B01J37/084—Decomposition of carbon-containing compounds into carbon
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- C04B35/52—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite
- C04B35/528—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite obtained from carbonaceous particles with or without other non-organic components
- C04B35/532—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite obtained from carbonaceous particles with or without other non-organic components containing a carbonisable binder
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- H—ELECTRICITY
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- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
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- H—ELECTRICITY
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- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
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- C—CHEMISTRY; METALLURGY
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- C—CHEMISTRY; METALLURGY
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- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
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- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/72—Products characterised by the absence or the low content of specific components, e.g. alkali metal free alumina ceramics
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Power Engineering (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Carbon And Carbon Compounds (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
- Catalysts (AREA)
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| EP10192768.9 | 2010-11-26 | ||
| PCT/IB2011/055282 WO2012070013A1 (en) | 2010-11-26 | 2011-11-24 | Process for manufacturing nitrogen-containing porous carbonaceous material |
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| KR20140031838A true KR20140031838A (ko) | 2014-03-13 |
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| EP2100317B1 (en) | 2006-11-15 | 2016-01-27 | Energ2, Inc. | Electric double layer capacitance device |
| FI2448748T3 (fi) | 2009-07-01 | 2024-10-09 | Basf Mobile Emissions Catalysts Llc | Ultrapuhtaita synteettisiä hiilimateriaaleja |
| US9359390B2 (en) * | 2010-03-31 | 2016-06-07 | Kuraray Chemical Co., Ltd. | Activated carbon and use therefor |
| WO2012045002A1 (en) | 2010-09-30 | 2012-04-05 | Energ2 Technologies, Inc. | Enhanced packing of energy storage particles |
| US20120262127A1 (en) | 2011-04-15 | 2012-10-18 | Energ2 Technologies, Inc. | Flow ultracapacitor |
| EP2707456B1 (en) | 2011-05-10 | 2018-09-26 | Basf Se | Novel color converters |
| CN103947017B (zh) | 2011-06-03 | 2017-11-17 | 巴斯福股份公司 | 用于混合能量存储装置中的碳‑铅共混物 |
| JP6092198B2 (ja) | 2011-06-10 | 2017-03-08 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 新規カラーコンバーター |
| US9409777B2 (en) | 2012-02-09 | 2016-08-09 | Basf Se | Preparation of polymeric resins and carbon materials |
| CN102701183A (zh) * | 2012-06-05 | 2012-10-03 | 南京航空航天大学 | 富氮介孔碳材料及无模板制备方法及制作工作电极的方法与应用 |
| CA2902401C (en) * | 2013-02-27 | 2021-03-09 | Nisshinbo Holdings Inc. | Carbon material, fuel cell, electric double layer capacitor, carbon dioxide adsorbing device and method for producing carbon material |
| CN105190948B (zh) | 2013-03-14 | 2019-04-26 | 14族科技公司 | 包含锂合金化的电化学改性剂的复合碳材料 |
| US10195583B2 (en) | 2013-11-05 | 2019-02-05 | Group 14 Technologies, Inc. | Carbon-based compositions with highly efficient volumetric gas sorption |
| EP4496080A3 (en) | 2014-03-14 | 2025-05-07 | Group14 Technologies, Inc. | Novel methods for sol-gel polymerization in absence of solvent and creation of tunable carbon structure from same |
| WO2017031006A1 (en) | 2015-08-14 | 2017-02-23 | Energ2 Technologies, Inc. | Composites of porous nano-featured silicon materials and carbon materials |
| CN113224274A (zh) | 2015-08-28 | 2021-08-06 | 14集团技术公司 | 具有极其持久的锂嵌入的新型材料及其制造方法 |
| WO2017066703A1 (en) * | 2015-10-15 | 2017-04-20 | Energ2 Technologies, Inc. | Low-gassing carbon materials for improving performance of lead acid batteries |
| CN106882783B (zh) * | 2015-12-10 | 2018-10-30 | 中科派思储能技术有限公司 | 一种固相法合成含氮硫多级孔炭的方法 |
| WO2018165610A1 (en) | 2017-03-09 | 2018-09-13 | Group 14 Technologies, Inc. | Decomposition of silicon-containing precursors on porous scaffold materials |
| JP2020040857A (ja) * | 2018-09-12 | 2020-03-19 | 星和電機株式会社 | 共有結合性有機構造体の焼成体およびその製造方法 |
| CN110218301B (zh) * | 2019-07-15 | 2021-08-20 | 台州学院 | 一种基于1,3,5-三(4-甲酰基苯基)苯的共轭有机微孔聚合物及其制备方法 |
| CN110218302B (zh) * | 2019-07-15 | 2021-08-20 | 台州学院 | 一种基于1,3,5-苯三甲醛的共轭微孔聚合物及其制备方法 |
| CN114057178B (zh) * | 2020-08-05 | 2024-03-29 | 中国科学院广州能源研究所 | 纳米复合碳球的制备方法与应用 |
| US11639292B2 (en) | 2020-08-18 | 2023-05-02 | Group14 Technologies, Inc. | Particulate composite materials |
| US11335903B2 (en) | 2020-08-18 | 2022-05-17 | Group14 Technologies, Inc. | Highly efficient manufacturing of silicon-carbon composites materials comprising ultra low z |
| US11174167B1 (en) | 2020-08-18 | 2021-11-16 | Group14 Technologies, Inc. | Silicon carbon composites comprising ultra low Z |
| CN116457309B (zh) | 2020-09-30 | 2025-02-14 | 14集团技术公司 | 控制硅-碳复合材料的氧含量和反应性的钝化方法 |
| CN114031737A (zh) * | 2021-12-14 | 2022-02-11 | 四川金象赛瑞化工股份有限公司 | 大尺寸三聚氰胺基共价有机框架材料及制备方法和应用 |
| CN115101348B (zh) * | 2022-08-01 | 2024-02-09 | 浙江光储充能源科技有限公司 | 一种碳复合钙钛矿纳米晶电极材料的制备方法及其应用 |
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| JPH05811A (ja) * | 1990-12-13 | 1993-01-08 | Mitsubishi Gas Chem Co Inc | 活性炭素材料およびその製造法ならびに用途 |
| US5240893A (en) * | 1992-06-05 | 1993-08-31 | General Motors Corporation | Method of preparing metal-heterocarbon-nitrogen catalyst for electrochemical cells |
| GB0019417D0 (en) * | 2000-08-09 | 2000-09-27 | Mat & Separations Tech Int Ltd | Mesoporous carbons |
| KR100438210B1 (ko) * | 2001-12-28 | 2004-07-01 | 브이케이 주식회사 | 다공성 일체형 탄소의 제조 방법, 그러한 방법에 의하여제조된 다공성 일체형 탄소 및 그러한 다공성 일체형탄소의 전기 이중층 캐패시터에의 응용 |
| DE10243240A1 (de) * | 2002-09-17 | 2004-03-25 | Basf Ag | Vorwiegend aus Kohlenstoff zusammengesetzte Schaumstoffe hoher innerer Oberfläche und Verfahren zu deren Herstellung |
| US7704422B2 (en) * | 2004-08-16 | 2010-04-27 | Electromaterials, Inc. | Process for producing monolithic porous carbon disks from aromatic organic precursors |
| EP1789364A4 (en) * | 2004-08-16 | 2011-04-13 | Jing Wang | PROCESSES FOR THE PRODUCTION OF MONOLITHIC POROUS CARBON DISKS FROM AROMATIC ORGANIC PRECURSORS |
| JP2006264991A (ja) * | 2005-03-22 | 2006-10-05 | Sumitomo Bakelite Co Ltd | 炭素材の製造方法、炭素材、二次電池用負極材、非水電解質二次電池 |
| KR101257966B1 (ko) * | 2005-05-27 | 2013-04-24 | 수미토모 케미칼 컴퍼니 리미티드 | 전기 이중층 캐패시터 |
| US7838687B2 (en) * | 2005-08-29 | 2010-11-23 | Brown University | Redox-active polymers and their applications |
| CN1830769A (zh) * | 2006-03-15 | 2006-09-13 | 大连理工大学 | 一种高比表面积多孔炭材料的制备方法 |
| JP2008120610A (ja) * | 2006-11-09 | 2008-05-29 | Sumitomo Chemical Co Ltd | 活性炭およびその製造方法 |
| EP2244972A2 (en) * | 2008-02-12 | 2010-11-03 | Sumitomo Chemical Company, Limited | Process for producing carbon material |
| WO2010051619A1 (en) * | 2008-11-10 | 2010-05-14 | Institut National De La Recherche Scientifique | Catalyst precursors, catalysts and methods of producing same |
| US20110280789A1 (en) * | 2009-01-16 | 2011-11-17 | Junji Suzuki | Process for producing carbon material |
| CN101823705B (zh) * | 2009-03-04 | 2012-08-01 | 南京大学 | 一种高表面积含氮中孔碳材料的制备方法 |
| CN101531358A (zh) * | 2009-04-28 | 2009-09-16 | 湖南理工学院 | 一种超级电容器用多孔炭电极材料的制备方法 |
| JP5678372B2 (ja) * | 2009-11-30 | 2015-03-04 | 独立行政法人産業技術総合研究所 | 窒素含有多孔質炭素材料とその製造方法、及び該窒素含有多孔質炭素材料を用いた電気二重層キャパシタ |
| US9012344B2 (en) * | 2010-05-13 | 2015-04-21 | Uchicago Argonne, Llc | Electrocatalysts using porous polymers and method of preparation |
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| EP2643840A1 (en) | 2013-10-02 |
| EP2643840A4 (en) | 2014-05-28 |
| WO2012070013A1 (en) | 2012-05-31 |
| US20130244862A1 (en) | 2013-09-19 |
| JP2013544748A (ja) | 2013-12-19 |
| CN103282984A (zh) | 2013-09-04 |
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