KR20130026419A - 카본 나노튜브의 제조 - Google Patents
카본 나노튜브의 제조 Download PDFInfo
- Publication number
- KR20130026419A KR20130026419A KR1020127021267A KR20127021267A KR20130026419A KR 20130026419 A KR20130026419 A KR 20130026419A KR 1020127021267 A KR1020127021267 A KR 1020127021267A KR 20127021267 A KR20127021267 A KR 20127021267A KR 20130026419 A KR20130026419 A KR 20130026419A
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- KR
- South Korea
- Prior art keywords
- catalyst
- carbon nanotubes
- carbon
- cnt
- particularly preferably
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/158—Carbon nanotubes
- C01B32/16—Preparation
- C01B32/162—Preparation characterised by catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- Nanotechnology (AREA)
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- Crystallography & Structural Chemistry (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
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Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102010008173A DE102010008173A1 (de) | 2010-02-16 | 2010-02-16 | Herstellung von Kohlenstoffnanoröhrchen |
| DE102010008173.6 | 2010-02-16 | ||
| PCT/EP2011/052086 WO2011101300A2 (de) | 2010-02-16 | 2011-02-14 | Herstellung von kohlenstoffnanoröhrchen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20130026419A true KR20130026419A (ko) | 2013-03-13 |
Family
ID=43769125
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020127021267A Withdrawn KR20130026419A (ko) | 2010-02-16 | 2011-02-14 | 카본 나노튜브의 제조 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20130039839A1 (enExample) |
| EP (1) | EP2536502A2 (enExample) |
| JP (1) | JP2013519515A (enExample) |
| KR (1) | KR20130026419A (enExample) |
| CN (1) | CN102770206A (enExample) |
| DE (1) | DE102010008173A1 (enExample) |
| WO (1) | WO2011101300A2 (enExample) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20190124744A (ko) * | 2017-03-15 | 2019-11-05 | 토요잉크Sc홀딩스주식회사 | 다층 카본 나노 튜브, 다층 카본 나노 튜브의 제조 방법, 분산액, 수지 조성물, 및 도막 |
| WO2022035142A1 (ko) * | 2020-08-12 | 2022-02-17 | 주식회사 엘지화학 | 저밀도 탄소나노튜브 및 이를 포함하는 복합재 |
| WO2024091032A1 (ko) * | 2022-10-28 | 2024-05-02 | 주식회사 엘지화학 | 탄소나노튜브 제조용 촉매 및 이의 제조방법 |
| WO2024091033A1 (ko) * | 2022-10-28 | 2024-05-02 | 주식회사 엘지화학 | 탄소나노튜브 제조용 촉매 및 이의 제조방법 |
| US12497296B2 (en) | 2020-08-12 | 2025-12-16 | Lg Chem, Ltd. | Carbon nanotube having low density and composite material including the same |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102012218184B4 (de) * | 2012-10-05 | 2020-03-05 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zur Herstellung eines Verbundwerkstoffpulvers mit Kohlenstoffnanoröhren |
| DE102012109524A1 (de) | 2012-10-08 | 2014-04-10 | Baumer Hhs Gmbh | Heißauftragssystem |
| DE102013210679A1 (de) * | 2013-06-07 | 2014-12-11 | Bayer Materialscience Ag | Verfahren zur Herstellung mehrwandiger Kohlenstoffnanoröhrchen, mehrwandiges Kohlenstoffnanoröhrchen und Kohlenstoffnanoröhrchenpulver |
| WO2016076393A1 (ja) * | 2014-11-14 | 2016-05-19 | 戸田工業株式会社 | カーボンナノチューブとその製造方法、及びカーボンナノチューブを用いたリチウムイオン二次電池 |
| JP6447347B2 (ja) * | 2015-04-30 | 2019-01-09 | 住友電気工業株式会社 | カーボンナノ構造体の製造方法 |
| JP7052336B2 (ja) * | 2017-12-20 | 2022-04-12 | 東洋インキＳｃホールディングス株式会社 | 多層カーボンナノチューブおよび多層カーボンナノチューブの製造方法 |
| JP6380588B1 (ja) * | 2017-03-15 | 2018-08-29 | 東洋インキＳｃホールディングス株式会社 | 多層カーボンナノチューブおよび多層カーボンナノチューブの製造方法 |
| CN109476489B (zh) * | 2017-03-17 | 2022-05-17 | Lg化学株式会社 | 束型碳纳米管及其制备方法 |
| US10759663B2 (en) | 2017-05-23 | 2020-09-01 | Indian Oil Corporation Limited | Multi-metal catalyst composition for production of morphology controlled CNT's and process thereof |
| CN111799448A (zh) * | 2019-04-08 | 2020-10-20 | 江苏天奈科技股份有限公司 | 一种硅或其氧化物原位长碳纳米管的方法 |
| CN111498834B (zh) * | 2020-04-20 | 2021-11-23 | 无锡东恒新能源科技有限公司 | 一种碳纳米管材料的提纯装置及方法 |
| KR20230134126A (ko) * | 2021-02-08 | 2023-09-20 | 캐즘 어드밴스드 머티리얼스, 인크. | 탄소 나노튜브 하이브리드 재료 및 하이브리드 재료제조 방법 |
| CN114396868B (zh) * | 2022-01-18 | 2023-06-16 | 陕西科技大学 | 一种a-MWCNTs/MgAl-LDH/皮革柔性可穿戴应变传感材料及其制备方法 |
| CN114950399A (zh) * | 2022-05-16 | 2022-08-30 | 湖北冠毓新材料科技有限公司 | 一种碳纳米管催化剂载体的制作方法 |
| CN116621163B (zh) * | 2023-06-01 | 2024-03-12 | 重庆中润新材料股份有限公司 | 一种碳纳米管的合成方法 |
| CN117105215A (zh) * | 2023-08-31 | 2023-11-24 | 深圳烯湾科技有限公司 | 碳纳米管及其制备方法 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1469930A (en) | 1974-10-11 | 1977-04-06 | Atomic Energy Authority Uk | Carbon filaments |
| CA1175616A (en) | 1981-01-05 | 1984-10-09 | Exxon Research And Engineering Company | Production of iron monoxide and carbon filaments therefrom |
| DE3570124D1 (en) | 1984-11-02 | 1989-06-15 | Quille Entreprise | Process and device for measuring the heating energy consumption share of individual users in a centrally heated building |
| US4663230A (en) | 1984-12-06 | 1987-05-05 | Hyperion Catalysis International, Inc. | Carbon fibrils, method for producing same and compositions containing same |
| US4855091A (en) | 1985-04-15 | 1989-08-08 | The Dow Chemical Company | Method for the preparation of carbon filaments |
| ZA907803B (en) | 1989-09-28 | 1991-07-31 | Hyperion Catalysis Int | Electrochemical cells and preparing carbon fibrils |
| BR9306385A (pt) | 1992-05-22 | 1995-09-12 | Hyperion Catalysis Int | Métodos e catalisadores aperfeiçoados para a fabricação de fibrilas de carbono |
| US6953562B2 (en) * | 2001-12-11 | 2005-10-11 | Catalytic Materials, Llc | Preparation of multifaceted graphitic nanotubes |
| US20090286675A1 (en) * | 2001-05-25 | 2009-11-19 | Tsinghua University | Continuous mass production of carbon nanotubes in a nano-agglomerate fluidized-bed and the reactor |
| WO2003060209A1 (en) | 2002-01-11 | 2003-07-24 | The Trustees Of Boston College | Reinforced carbon nanotubes |
| US7250148B2 (en) * | 2002-07-31 | 2007-07-31 | Carbon Nanotechnologies, Inc. | Method for making single-wall carbon nanotubes using supported catalysts |
| CN1199727C (zh) * | 2003-03-03 | 2005-05-04 | 清华大学 | 用于制备碳纳米管的催化剂 |
| DE102004054959A1 (de) * | 2004-11-13 | 2006-05-18 | Bayer Technology Services Gmbh | Katalysator zur Herstellung von Kohlenstoffnanoröhrchen durch Zersetzung von gas-förmigen Kohlenverbindungen an einem heterogenen Katalysator |
| DE102005032071A1 (de) * | 2005-07-08 | 2007-01-11 | Zentrum für Sonnenenergie- und Wasserstoff-Forschung Baden-Württemberg Gemeinnützige Stiftung e.V. | Nanoporöse Katalysatorteilchen, deren Herstellung und deren Verwendung |
| CN100404130C (zh) * | 2005-09-30 | 2008-07-23 | 清华大学 | 一种制备单壁或双壁碳纳米管的负载型催化剂的制备方法 |
| DE102006007147A1 (de) | 2006-02-16 | 2007-08-23 | Bayer Technology Services Gmbh | Verfahren zur kontinuierlichen Herstellung von Katalysatoren |
| DE102007044031A1 (de) | 2007-09-14 | 2009-03-19 | Bayer Materialscience Ag | Kohlenstoffnanoröhrchenpulver, Kohlenstoffnanoröhrchen und Verfahren zu ihrer Herstellung |
| CN101531363B (zh) * | 2009-04-17 | 2011-04-27 | 北京化工大学 | 一种采用水滑石催化聚合物分解制备碳纳米管的方法 |
| FR2949075B1 (fr) * | 2009-08-17 | 2013-02-01 | Arkema France | Catalyseur fe/mo supporte, son procede de preparation et utilisation pour la fabrication de nanotubes |
| DE102009038464A1 (de) | 2009-08-21 | 2011-02-24 | Bayer Materialscience Ag | Kohlenstoffnanoröhrchen-Agglomerat |
-
2010
- 2010-02-16 DE DE102010008173A patent/DE102010008173A1/de not_active Withdrawn
-
2011
- 2011-02-14 EP EP11704211A patent/EP2536502A2/de not_active Withdrawn
- 2011-02-14 WO PCT/EP2011/052086 patent/WO2011101300A2/de not_active Ceased
- 2011-02-14 JP JP2012553273A patent/JP2013519515A/ja not_active Withdrawn
- 2011-02-14 US US13/579,007 patent/US20130039839A1/en not_active Abandoned
- 2011-02-14 CN CN2011800097730A patent/CN102770206A/zh active Pending
- 2011-02-14 KR KR1020127021267A patent/KR20130026419A/ko not_active Withdrawn
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20190124744A (ko) * | 2017-03-15 | 2019-11-05 | 토요잉크Sc홀딩스주식회사 | 다층 카본 나노 튜브, 다층 카본 나노 튜브의 제조 방법, 분산액, 수지 조성물, 및 도막 |
| WO2022035142A1 (ko) * | 2020-08-12 | 2022-02-17 | 주식회사 엘지화학 | 저밀도 탄소나노튜브 및 이를 포함하는 복합재 |
| KR20220020779A (ko) * | 2020-08-12 | 2022-02-21 | 주식회사 엘지화학 | 저밀도 탄소나노튜브 및 이를 포함하는 복합재 |
| US12497296B2 (en) | 2020-08-12 | 2025-12-16 | Lg Chem, Ltd. | Carbon nanotube having low density and composite material including the same |
| WO2024091032A1 (ko) * | 2022-10-28 | 2024-05-02 | 주식회사 엘지화학 | 탄소나노튜브 제조용 촉매 및 이의 제조방법 |
| WO2024091033A1 (ko) * | 2022-10-28 | 2024-05-02 | 주식회사 엘지화학 | 탄소나노튜브 제조용 촉매 및 이의 제조방법 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20130039839A1 (en) | 2013-02-14 |
| EP2536502A2 (de) | 2012-12-26 |
| WO2011101300A3 (de) | 2012-04-05 |
| JP2013519515A (ja) | 2013-05-30 |
| WO2011101300A2 (de) | 2011-08-25 |
| DE102010008173A1 (de) | 2012-03-01 |
| CN102770206A (zh) | 2012-11-07 |
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