KR20120022756A - 수소를 전기화학적으로 제거하고 그 수소를 전기화학적으로 물로 전환시키면서 천연 가스를 방향족화합물로 전환시키는 방법 - Google Patents

수소를 전기화학적으로 제거하고 그 수소를 전기화학적으로 물로 전환시키면서 천연 가스를 방향족화합물로 전환시키는 방법 Download PDF

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KR20120022756A
KR20120022756A KR1020117023390A KR20117023390A KR20120022756A KR 20120022756 A KR20120022756 A KR 20120022756A KR 1020117023390 A KR1020117023390 A KR 1020117023390A KR 20117023390 A KR20117023390 A KR 20117023390A KR 20120022756 A KR20120022756 A KR 20120022756A
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hydrogen
membrane
catalyst
stream
oxygen
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Korean (ko)
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요아나 코엘료 트소우
알렉산더 판첸코
안느바르트 엔베르트 벤팅크
세바스티안 아렌스
토마스 하이데만
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바스프 에스이
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • C07C2/78—Processes with partial combustion
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
    • B01J29/64—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • C01B3/501—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by diffusion
    • C01B3/503—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by diffusion characterised by membranes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • C01B3/56—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B5/00—Water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/04—Benzene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D64/00—Electrodes of devices having potential barriers
    • H10D64/01—Manufacture or treatment
    • H10D64/011—Manufacture or treatment of electrodes ohmically coupled to a semiconductor
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
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    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405—Purification by membrane separation
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    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405—Purification by membrane separation
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    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042—Purification by adsorption on solids
    • C01B2203/043—Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/048—Composition of the impurity the impurity being an organic compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/30—Aromatics
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Catalysts (AREA)
KR1020117023390A 2009-04-06 2010-03-29 수소를 전기화학적으로 제거하고 그 수소를 전기화학적으로 물로 전환시키면서 천연 가스를 방향족화합물로 전환시키는 방법 Abandoned KR20120022756A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP09157396.4 2009-04-06
EP09157396 2009-04-06

Publications (1)

Publication Number Publication Date
KR20120022756A true KR20120022756A (ko) 2012-03-12

Family

ID=42563010

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Application Number Title Priority Date Filing Date
KR1020117023390A Abandoned KR20120022756A (ko) 2009-04-06 2010-03-29 수소를 전기화학적으로 제거하고 그 수소를 전기화학적으로 물로 전환시키면서 천연 가스를 방향족화합물로 전환시키는 방법

Country Status (9)

Country Link
US (1) US8575411B2 (https=)
EP (1) EP2417083B1 (https=)
JP (1) JP5623503B2 (https=)
KR (1) KR20120022756A (https=)
CN (1) CN102365252B (https=)
EA (1) EA020178B1 (https=)
ES (1) ES2530261T3 (https=)
PL (1) PL2417083T3 (https=)
WO (1) WO2010115747A1 (https=)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010115747A1 (de) 2009-04-06 2010-10-14 Basf Se Verfahren zur umsetzung von erdgas zu aromaten mit elektrochemischer abtrennung von wasserstoff und elektrochemischer umsetzung des wasserstoffs zu wasser
EA020793B9 (ru) 2009-04-06 2015-05-29 Басф Се Способ электрохимического отделения водорода из реакционной смеси
ES2529554T3 (es) * 2009-04-06 2015-02-23 Basf Se Procedimiento para la transformación de gas natural en compuestos aromáticos con separación electroquímica de hidrógeno con generación de corriente eléctrica e hidrógeno
BR112012000628A2 (pt) 2009-07-10 2016-02-10 Basf Se processo para a aminação direta de hidrocarbonetos em amino hidrocarbonetos
JP5800808B2 (ja) 2009-07-10 2015-10-28 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 電気化学的な水素の分離と電気化学的な水素の水への反応とを含む炭化水素をアミノ炭化水素に直接アミノ化するプロセス
AR090778A1 (es) * 2012-04-23 2014-12-03 Shell Int Research Un proceso para la aromatizacion de una corriente de gas que contiene metano
AR090777A1 (es) * 2012-04-23 2014-12-03 Shell Int Research Un proceso para la aromatizacion de una corriente de gas que contiene metano
GB201317870D0 (en) * 2013-10-09 2013-11-20 Protia As Process for dehydroaromatization of alkanes with in-situ hydrogen removal
EP2876097B1 (en) * 2013-11-20 2018-02-28 Haldor Topsøe A/S Process for direct conversion of a hydrocarbon-containing gas to a higher hydrocarbons product and reactor for performing the process
WO2015132200A1 (de) * 2014-03-05 2015-09-11 Basf Se Verfahren zur kombinierten herstellung von aromatischen kohlenwasserstoffen und aromatischen aminokohlenwasserstoffen
CN109385643B (zh) * 2017-08-10 2020-06-09 中国石油天然气股份有限公司 将甲烷转化为脂肪烃的方法、燃料电池及燃料电池的制备方法
CN107649114A (zh) * 2017-09-18 2018-02-02 南昌大学 一种用于甲烷氧化偶联的b位为铈的烧绿石催化剂的制备方法及应用

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1179033A (en) * 1966-05-31 1970-01-28 Atlantic Richfield Co Fuel Cell and Method of Operation thereof
NZ198555A (en) 1980-10-11 1983-11-30 British Petroleum Co Catalytic production of aromatic hydrocarbons
US7019184B2 (en) 2002-01-28 2006-03-28 Conocophillips Company Non-oxidative conversion of gas to liquids
JP4697921B2 (ja) * 2002-02-22 2011-06-08 電源開発株式会社 電力、水素及び芳香族炭化水素の併産システム
DE102005041140A1 (de) * 2005-08-30 2007-03-01 Basf Ag Direktaminierung von Kohlenwasserstoffen
DE112006003579T5 (de) * 2005-12-28 2009-01-29 Hitachi, Ltd. Katalysator mit einer Dehydrierungsfunktion oder Hydrierungsfunktion, Brennstoffzelle unter Verwendung des Katalysators und Wasserstoff-Speicher/Zufuhr-Vorrichtung
WO2007126811A2 (en) * 2006-04-21 2007-11-08 Exxonmobil Chemical Patent Inc. Process for methane conversion
EP2282835A1 (de) 2008-04-08 2011-02-16 Basf Se Verfahren zur dehydroaromatisierung von methanhaltigen gemischen unter regenerierung der entsprechenden edelmetallfreien katalysatoren
JP5656826B2 (ja) 2008-04-08 2015-01-21 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ メタン及びメタン含有混合物を脱水素芳香族化するための触媒
EA020793B9 (ru) * 2009-04-06 2015-05-29 Басф Се Способ электрохимического отделения водорода из реакционной смеси
WO2010115765A1 (de) * 2009-04-06 2010-10-14 Basf Se Verfahren zur umsetzung von erdgas zu aromaten mit elektrochemischer abtrennung von wasserstoff
ES2529554T3 (es) * 2009-04-06 2015-02-23 Basf Se Procedimiento para la transformación de gas natural en compuestos aromáticos con separación electroquímica de hidrógeno con generación de corriente eléctrica e hidrógeno
WO2010115747A1 (de) 2009-04-06 2010-10-14 Basf Se Verfahren zur umsetzung von erdgas zu aromaten mit elektrochemischer abtrennung von wasserstoff und elektrochemischer umsetzung des wasserstoffs zu wasser

Also Published As

Publication number Publication date
ES2530261T3 (es) 2015-02-27
JP5623503B2 (ja) 2014-11-12
EP2417083B1 (de) 2014-12-03
EP2417083A1 (de) 2012-02-15
PL2417083T3 (pl) 2015-05-29
EA020178B1 (ru) 2014-09-30
CN102365252B (zh) 2014-07-16
US20120004482A1 (en) 2012-01-05
WO2010115747A1 (de) 2010-10-14
JP2012522820A (ja) 2012-09-27
US8575411B2 (en) 2013-11-05
CN102365252A (zh) 2012-02-29
EA201171176A1 (ru) 2012-05-30

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