EA020178B1 - Способ превращения природного газа в ароматические углеводороды с электрохимическим отделением водорода и электрохимическим превращением водорода в воду - Google Patents

Способ превращения природного газа в ароматические углеводороды с электрохимическим отделением водорода и электрохимическим превращением водорода в воду Download PDF

Info

Publication number
EA020178B1
EA020178B1 EA201171176A EA201171176A EA020178B1 EA 020178 B1 EA020178 B1 EA 020178B1 EA 201171176 A EA201171176 A EA 201171176A EA 201171176 A EA201171176 A EA 201171176A EA 020178 B1 EA020178 B1 EA 020178B1
Authority
EA
Eurasian Patent Office
Prior art keywords
hydrogen
membrane
catalyst
stream
oxygen
Prior art date
Application number
EA201171176A
Other languages
English (en)
Russian (ru)
Other versions
EA201171176A1 (ru
Inventor
Йоана Коэльё Тцу
Александр Панченко
Аннебарт Энгберт Вентинк
Зебастиан Аренс
Томас Хайдеманн
Original Assignee
Басф Се
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=42563010&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EA020178(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Басф Се filed Critical Басф Се
Publication of EA201171176A1 publication Critical patent/EA201171176A1/ru
Publication of EA020178B1 publication Critical patent/EA020178B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • C07C2/78—Processes with partial combustion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
    • B01J29/64—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • C01B3/501—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by diffusion
    • C01B3/503—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by diffusion characterised by membranes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • C01B3/56—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B5/00—Water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/04—Benzene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D64/00—Electrodes of devices having potential barriers
    • H10D64/01—Manufacture or treatment
    • H10D64/011—Manufacture or treatment of electrodes ohmically coupled to a semiconductor
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405—Purification by membrane separation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405—Purification by membrane separation
    • C01B2203/041—In-situ membrane purification during hydrogen production
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042—Purification by adsorption on solids
    • C01B2203/043—Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/048—Composition of the impurity the impurity being an organic compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/30—Aromatics
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Catalysts (AREA)
EA201171176A 2009-04-06 2010-03-29 Способ превращения природного газа в ароматические углеводороды с электрохимическим отделением водорода и электрохимическим превращением водорода в воду EA020178B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP09157396 2009-04-06
PCT/EP2010/054092 WO2010115747A1 (de) 2009-04-06 2010-03-29 Verfahren zur umsetzung von erdgas zu aromaten mit elektrochemischer abtrennung von wasserstoff und elektrochemischer umsetzung des wasserstoffs zu wasser

Publications (2)

Publication Number Publication Date
EA201171176A1 EA201171176A1 (ru) 2012-05-30
EA020178B1 true EA020178B1 (ru) 2014-09-30

Family

ID=42563010

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201171176A EA020178B1 (ru) 2009-04-06 2010-03-29 Способ превращения природного газа в ароматические углеводороды с электрохимическим отделением водорода и электрохимическим превращением водорода в воду

Country Status (9)

Country Link
US (1) US8575411B2 (https=)
EP (1) EP2417083B1 (https=)
JP (1) JP5623503B2 (https=)
KR (1) KR20120022756A (https=)
CN (1) CN102365252B (https=)
EA (1) EA020178B1 (https=)
ES (1) ES2530261T3 (https=)
PL (1) PL2417083T3 (https=)
WO (1) WO2010115747A1 (https=)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010115747A1 (de) 2009-04-06 2010-10-14 Basf Se Verfahren zur umsetzung von erdgas zu aromaten mit elektrochemischer abtrennung von wasserstoff und elektrochemischer umsetzung des wasserstoffs zu wasser
EA020793B9 (ru) 2009-04-06 2015-05-29 Басф Се Способ электрохимического отделения водорода из реакционной смеси
ES2529554T3 (es) * 2009-04-06 2015-02-23 Basf Se Procedimiento para la transformación de gas natural en compuestos aromáticos con separación electroquímica de hidrógeno con generación de corriente eléctrica e hidrógeno
BR112012000628A2 (pt) 2009-07-10 2016-02-10 Basf Se processo para a aminação direta de hidrocarbonetos em amino hidrocarbonetos
JP5800808B2 (ja) 2009-07-10 2015-10-28 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 電気化学的な水素の分離と電気化学的な水素の水への反応とを含む炭化水素をアミノ炭化水素に直接アミノ化するプロセス
AR090778A1 (es) * 2012-04-23 2014-12-03 Shell Int Research Un proceso para la aromatizacion de una corriente de gas que contiene metano
AR090777A1 (es) * 2012-04-23 2014-12-03 Shell Int Research Un proceso para la aromatizacion de una corriente de gas que contiene metano
GB201317870D0 (en) * 2013-10-09 2013-11-20 Protia As Process for dehydroaromatization of alkanes with in-situ hydrogen removal
EP2876097B1 (en) * 2013-11-20 2018-02-28 Haldor Topsøe A/S Process for direct conversion of a hydrocarbon-containing gas to a higher hydrocarbons product and reactor for performing the process
WO2015132200A1 (de) * 2014-03-05 2015-09-11 Basf Se Verfahren zur kombinierten herstellung von aromatischen kohlenwasserstoffen und aromatischen aminokohlenwasserstoffen
CN109385643B (zh) * 2017-08-10 2020-06-09 中国石油天然气股份有限公司 将甲烷转化为脂肪烃的方法、燃料电池及燃料电池的制备方法
CN107649114A (zh) * 2017-09-18 2018-02-02 南昌大学 一种用于甲烷氧化偶联的b位为铈的烧绿石催化剂的制备方法及应用

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4899006A (en) * 1980-10-11 1990-02-06 The British Petroleum Company Plc Production of aromatics from ethane and/or ethylene
WO2003084905A1 (en) * 2002-01-28 2003-10-16 Conocophillips Company Non-oxidative conversion of gas to liquids

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1179033A (en) * 1966-05-31 1970-01-28 Atlantic Richfield Co Fuel Cell and Method of Operation thereof
JP4697921B2 (ja) * 2002-02-22 2011-06-08 電源開発株式会社 電力、水素及び芳香族炭化水素の併産システム
DE102005041140A1 (de) * 2005-08-30 2007-03-01 Basf Ag Direktaminierung von Kohlenwasserstoffen
DE112006003579T5 (de) * 2005-12-28 2009-01-29 Hitachi, Ltd. Katalysator mit einer Dehydrierungsfunktion oder Hydrierungsfunktion, Brennstoffzelle unter Verwendung des Katalysators und Wasserstoff-Speicher/Zufuhr-Vorrichtung
WO2007126811A2 (en) * 2006-04-21 2007-11-08 Exxonmobil Chemical Patent Inc. Process for methane conversion
EP2282835A1 (de) 2008-04-08 2011-02-16 Basf Se Verfahren zur dehydroaromatisierung von methanhaltigen gemischen unter regenerierung der entsprechenden edelmetallfreien katalysatoren
JP5656826B2 (ja) 2008-04-08 2015-01-21 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ メタン及びメタン含有混合物を脱水素芳香族化するための触媒
EA020793B9 (ru) * 2009-04-06 2015-05-29 Басф Се Способ электрохимического отделения водорода из реакционной смеси
WO2010115765A1 (de) * 2009-04-06 2010-10-14 Basf Se Verfahren zur umsetzung von erdgas zu aromaten mit elektrochemischer abtrennung von wasserstoff
ES2529554T3 (es) * 2009-04-06 2015-02-23 Basf Se Procedimiento para la transformación de gas natural en compuestos aromáticos con separación electroquímica de hidrógeno con generación de corriente eléctrica e hidrógeno
WO2010115747A1 (de) 2009-04-06 2010-10-14 Basf Se Verfahren zur umsetzung von erdgas zu aromaten mit elektrochemischer abtrennung von wasserstoff und elektrochemischer umsetzung des wasserstoffs zu wasser

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4899006A (en) * 1980-10-11 1990-02-06 The British Petroleum Company Plc Production of aromatics from ethane and/or ethylene
WO2003084905A1 (en) * 2002-01-28 2003-10-16 Conocophillips Company Non-oxidative conversion of gas to liquids

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
SOLYMOSI F. ET AL.: "Conversion of ethane into benzene on Mo2C/ZSM-5 catalyst", APPLIED CATALYSIS A: GENERAL, ELSEVIER SCIENCE, AMSTERDAM, NL LNKD- DOI:10.1016/S0926-860X(97)00260-3, vol. 166, no. 1, 2 January 1998 (1998-01-02), pages 225-235, XP023613553, ISSN: 0926-860X [retrieved on 1998-01-02], the whole document *

Also Published As

Publication number Publication date
ES2530261T3 (es) 2015-02-27
JP5623503B2 (ja) 2014-11-12
EP2417083B1 (de) 2014-12-03
EP2417083A1 (de) 2012-02-15
PL2417083T3 (pl) 2015-05-29
CN102365252B (zh) 2014-07-16
US20120004482A1 (en) 2012-01-05
WO2010115747A1 (de) 2010-10-14
JP2012522820A (ja) 2012-09-27
US8575411B2 (en) 2013-11-05
CN102365252A (zh) 2012-02-29
KR20120022756A (ko) 2012-03-12
EA201171176A1 (ru) 2012-05-30

Similar Documents

Publication Publication Date Title
EA020178B1 (ru) Способ превращения природного газа в ароматические углеводороды с электрохимическим отделением водорода и электрохимическим превращением водорода в воду
JP5393872B2 (ja) 反応混合物から水素を電気化学的に分離する方法
EA020384B1 (ru) Способ превращения природного газа в ароматические углеводороды с электрохимическим отделением водорода
JP5415610B2 (ja) 水素を電気化学的に除去することによって、電流及び水素を発生させながら天然ガスを芳香族化合物に変換する方法
Olivier et al. Oxidative coupling of methane using catalyst modified dense perovskite membrane reactors
CN101437752A (zh) 用于制造氢气的方法
KR20180101523A (ko) 디메틸에테르를 제조하기 위한 방법 및 시스템
Xia et al. Innovative steam methane reforming for coproducing CO‐free hydrogen and syngas in proton conducting membrane reactor
Kong et al. Catalytic dehydrogenation of ethylbenzene to styrene in a zeolite silicalite-1 membrane reactor
JP2005035842A (ja) 水素製造システム
JP5102932B2 (ja) 高純度水素製造方法
JP2007084378A (ja) 水素の製造方法およびそれに使用する装置
WO2025012512A1 (en) Catalyst, method, and system for producing syngas
JP5083916B2 (ja) 反応物の分離供給による膜リアクターにおける酸化反応の改良

Legal Events

Date Code Title Description
MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM AZ BY KG MD TJ TM