EA201171176A1 - Способ превращения природного газа в ароматические углеводороды с электрохимическим отделением водорода и электрохимическим превращением водорода в воду - Google Patents

Способ превращения природного газа в ароматические углеводороды с электрохимическим отделением водорода и электрохимическим превращением водорода в воду

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EA201171176A1
EA201171176A1 EA201171176A EA201171176A EA201171176A1 EA 201171176 A1 EA201171176 A1 EA 201171176A1 EA 201171176 A EA201171176 A EA 201171176A EA 201171176 A EA201171176 A EA 201171176A EA 201171176 A1 EA201171176 A1 EA 201171176A1
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hydrogen
electrochemical
turning
membrane
aromatic hydrocarbons
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Йоана Коэльё Тцу
Александр Панченко
Аннебарт Энгберт Вентинк
Зебастиан Аренс
Томас Хайдеманн
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Басф Се
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Abstract

Изобретение касается способа превращения алифатических углеводородов, имеющих от 1 до 4 атомов углерода в ароматические углеводороды, включающего следующие ступени: а) превращение потока эдукта Е, который содержит по меньшей мере один алифатический углеводород, имеющий от 1 до 4 атомов углерода, в присутствии катализатора при неокислительных условиях в поток продукта Р, содержащий ароматические углеводороды и водород, и b) электрохимическое отделение по меньшей мере части полученного при превращении водорода из потока продукта Р посредством газонепроницаемой мембраноэлектродной сборки, которая содержит по меньшей мере одну селективно проводящую протоны мембрану, а с каждой стороны мембрана содержит по меньшей мере один электродный катализатор, причем со стороны ретентата по меньшей мере часть водорода окисляется на анодном катализаторе до протонов, и протоны после пересечения мембраны со стороны пермеата превращаются на анодном катализаторе с кислородом в воду, причем кислород происходит из содержащего кислород потока О, который приводят в контакт со стороной пермеата мембраны.
EA201171176A 2009-04-06 2010-03-29 Способ превращения природного газа в ароматические углеводороды с электрохимическим отделением водорода и электрохимическим превращением водорода в воду EA020178B1 (ru)

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EP09157396 2009-04-06
PCT/EP2010/054092 WO2010115747A1 (de) 2009-04-06 2010-03-29 Verfahren zur umsetzung von erdgas zu aromaten mit elektrochemischer abtrennung von wasserstoff und elektrochemischer umsetzung des wasserstoffs zu wasser

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EA020793B9 (ru) 2009-04-06 2015-05-29 Басф Се Способ электрохимического отделения водорода из реакционной смеси
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EP2417084B1 (de) * 2009-04-06 2014-11-26 Basf Se Verfahren zur umsetzung von erdgas zu aromaten mit elektrochemischer abtrennung von wasserstoff unter erzeugung von elektrischem strom und wasserstoff
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EP2417083B1 (de) 2014-12-03
KR20120022756A (ko) 2012-03-12
WO2010115747A1 (de) 2010-10-14
US20120004482A1 (en) 2012-01-05
CN102365252B (zh) 2014-07-16
US8575411B2 (en) 2013-11-05
EA020178B1 (ru) 2014-09-30
PL2417083T3 (pl) 2015-05-29
JP2012522820A (ja) 2012-09-27
EP2417083A1 (de) 2012-02-15
ES2530261T3 (es) 2015-02-27
JP5623503B2 (ja) 2014-11-12

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