KR20120019567A - A sulfur manufacturing method - Google Patents

Abstract

PURPOSE: A producing method of liquid processed sulfur by removing toxicity from sulfur powder is provided to enable users to obtain the liquid processed sulfur in short time. CONSTITUTION: A producing method of liquid processed sulfur comprises the following steps: packaging sulfur powder in the predetermined amount; dipping charcoal in water to obtain charcoal water or far-infrared ray emitting water, and inserting the water with the sulfur powder into a centrifuge dehydrator(B-1); dehydrating the mixture using the centrifuge; inserting the dehydrated sulfur powder into a drying chamber(C-3); and heating the drying chamber at the temperature greater than 35 deg C.

Description

Sulfur powder decontamination and liquid method

The present invention is a method for producing poisonous sulfur powder by eliminating poison (toxic or legal) of poisonous mineral sulfur (硫 黄, element symbol S). In particular, more specifically, the mineral sulfur powder in which far-infrared energy water or charcoal is impregnated into a centrifugal dehydrator, the mineral sulfur powder is impregnated, and the water is completely dehydrated using a centrifugal dehydrator to remove the primary mineral. After detoxifying sulfur, the first detoxified sulfur powder is put into a drying chamber equipped with a far infrared energy filling device, and then sulfur residue is prepared by removing secondary residual toxicity by far infrared rays radiated from the drying chamber and heat heated to 35 ° C or above. In addition, the far-infrared energy water is added to the heater, and the first detoxified sulfur powder is processed into fine powder sulfur, put into the heater, and then agitated. It relates to a method by intermixing heating the far-infrared energy of water and a fine powder sulfur Legislation for preparing legislation sulfur in liquid state.

High sulfur has a long history of being effective in treating diseases. According to ancient literature, the effect of toxic sulfur on the human body is described as follows. In the Chinese Emperor's Endoscopy, when sulfur acts on the gods, the gods are filled with bones and the bones are filled, and sulfur is used to strengthen bones and prevent hair loss. It is recording. In China's "Survey Letter", sulfur is said to be full of yang and enjoy a thousand years of life. In addition, Huh Jun said that sulfur has a lot of heat and strong toxicity, but it helps drive Yanggi by driving cold air in the body, while controlling the capture and fraud of the heart beat. .

Thus, in the classical literature, sulfur is the forbidden ancestor of the forbidden life, which is the main ingredient of forbidden medicine, known as the omen of the world. The evaluation of the weakness of sulfur can be said to be so great that it is said to be a "potion of rejuvenation" that old people will regain their youth.

On the other hand, in New Drug Sancho, sulfur is a very good medicine that helps nourish the body, warm the body, and strengthen muscles and bones. It was said that he had become old and had a lump in his chest, healed the cold wall of morale, and strengthened and strengthened the musculature. In addition, Choi Jin-gu's book, "Family Names Found by Foot," in the past, put sulfur in a well to remove not only poison in water but also poison in iron, stone, soil, and all kinds of miscellaneous substances in the well. Furthermore, sulfur (硫 黃) is said to play a role in eliminating 72 kinds of poison (毒).

Therefore, it has the mysterious detoxification effect that can escape the pollution of pollution, including the most toxic substances, heavy metals, pesticides, antibiotics, etc. of biological health, and legal sulfur is not an essential nutritional agent of the 21st century.

In our body, 14 kinds of elements such as oxygen (O), hydrogen (H), nitrogen (N), sulfur, sodium (Na) as the biological elements are essential elements, among which sulfur is the 8th important Accounted for. In particular, it is widely distributed in bones, skin, hair, etc., due to the lack of hair loss, baldness, nail claw keratinization, skin aging is also a major cause of the occurrence. Glutathione and cells protect DNA from the attack of highly toxic hydroxy radicals that damage healthy cells with free radicals, a harmful substance that causes various cancers, causing aging and fatal cancers (tumors). The Ohio State University has published an experiment showing that sulfur has a role in boosting the immune cell TNF (tumor necrosis factor) that activates and destroys cancer (tumor). In addition, kimchi, soybean paste, soy sauce, cheese, yogurt, etc. are the results of fermentation by the sulfur amino acid methionine (methionine).

Our ancestors visited sulfur hot springs easily as a treatment for skin diseases. This is because the epidermal layer of the body has a keratin protein structure, and sulfur amino acid cystine, a main ingredient, purifies and detoxifies harmful substances accumulated in the skin. Meanwhile, it is well known that the main ingredient that maintains skin elasticity is collagen. The main reason is that the sulfur component plays a role in activating various amino acids constituting the enzyme directly involved in the collagen molecule, and sulfur is so effective that it is called beauty mineral.

As mentioned above, sulfur is not only the fact that it strengthens the bones and fills the bone marrow, but also it can be free from various diseases by increasing the immune action of each part while removing the toxicity in vivo by decomposing anticancer action and various harmful substances. It has a mysterious effect, and from ancient times to the present day, with great interest, the expectation has gradually increased. If the 20th century was the vitamin era, the 21st century could be the trend of sulfur.

Despite these trends, the most important problem from ancient times to modern times is that the mineral fats of mineral sulfur have caused humans to eat sulfur directly because they cannot eat sulfur directly. Indirect intake of sulfur with sulfur is the most desirable method, so it has been studied how to include sulfur in agricultural and livestock products in many ways. A typical example is sulfur ducks. When feeding mineral minerals to ducks, ducks have a higher detoxification capacity than other animals, accumulating sulfur in the body, but the mortality rate of young ducks is more than 30% due to its toxicity. In general, ducks can be shipped as commodities after 43 days of breeding, but sulfur-fed ducks will grow late due to the toxicity of sulfur and can be shipped as commodities only one year later. In other livestock products other than ducks, if 0.2 wt% of the appropriate sulfur feed is fed, the mortality rate is over 80% when it is young.

In addition, some of the sulfur is used when restoring the soil's intellect, or farms that operate orchards with eco-friendly farming methods. However, due to its toxicity, the sulfur is not properly used. Therefore, in order to make it easy for anyone to produce eco-friendly functional sulfur agricultural and livestock products by using sulfur, which is very beneficial to humans, in agricultural and livestock products, Sulfur legislation must be preceded by the poisoning of mineral sulfur.

Second, even if the toxicity of mineral sulfur can be eliminated, mass production is possible, and production costs must be low so that it can be used freely in agricultural and livestock farms.

As a result of many studies and examples that can remove (toxicity) of sulfur, Patent Publication No. 2005-0060557 describes a method of detoxifying feed sulfur that is applied only to livestock and poultry feed. . Specifically, sulfur is precipitated in distilled water of 0oC in which soybean powder is melted for 3 hours or more, the water of the sulfur is removed, and then charged into a reaction vessel and heated to 113oC or more, and then melted into a liquid phase. The molten sulfur is boiled and cooled 5 times to 7 times, and the sulfur is crushed by lowering the temperature to detoxify the sulfur. The sulfur is impregnated in jijang water containing natural calcium and germanium powder. It describes a sulfur detoxification method for feed, which is then collected and dried, but the method is not only complicated, but also time-consuming and costly, and limited to livestock and poultry. Very few of them are used in farms and livestock farms. Meanwhile, as another prior art, Korean Patent Publication No. 2005-0093579 describes a sulfur detoxification method, which is 20-40% by weight of pine boiled water, 3-7% by weight of motherwort extract, 5-10% by weight of green mung bean extract, 5-15% by weight of white charcoal and the remaining amount was mixed with water immersed in 20oC for 12 hours to form a mixed solution, and 25-40% by weight of sulfur based on the total weight of the mixed solution was mixed at 20oC. Precipitate for 12 hours and boil the precipitate for 6 hours at a temperature of 90-100oC, put it in a sachet bag and settle for 6 hours at 20oC in clear water for 2-3 hours and detoxify the precipitated mixture by using a centrifuge. The sulfur detoxification method is described. These methods can not be used to decontaminate large amounts of mineral sulfur due to the nature of the additives, and it takes too much time and costs for decontamination, and is also difficult to decontaminate. Since the value of legal sulfur is likely to be high, ④ It is too small to be applied to agricultural and livestock farms because the production of decontaminated sulfur is too small to be applied to agricultural and livestock farms. It is not competitive due to the cost of water production. Third, the synergy effect that the producer and the consumer can create a profit together to win the competition, it was determined that the existing sulfur detoxification (legislation) method can not solve the present invention.

As discussed above, existing sulfur legislation methods for eliminating sulfur toxicity are very complex and demanding, and, despite the high cost and time required due to the many additives, processing steps and procedures, and the long time required, The production of legislative sulfur is too small to be applied to agricultural and livestock farms because it is only legal sulfur production, and it is not only able to meet the legal sulfur requirements for agricultural and livestock products, but also to buy expensive legislative sulfur in farming and fishing villages. Sulfur legislation process is simple to solve all kinds of problems, such as not only to produce a large amount of sulfur in a short time, significantly reducing time and cost, and furthermore, highly concentrated liquid legislation for convenient application to agricultural and livestock products. The purpose of producing sulfur is to:

First, various toxic substances remain due to fertilizers, pesticides, antibiotics, feed, and soil improvers used in agricultural and livestock products, so that in the period of free trade agreement (FTA), overseas export obstacles (barriers) as well as the health of domestic and foreign consumers In a serious situation threatening the present invention, the present invention is applied to agricultural and livestock products by standardizing the production method of applying the sulfur and the highly concentrated liquid sulfur compound and environmentally friendly far-infrared energy water to the agricultural and livestock products. Producing technology and The primary purpose is to provide a method.

Second, in the case of agricultural and livestock products, soils are severely contaminated by fertilizers, pesticides, antibiotics, feed, and soil improving agents during fertilization, cultivation, aquaculture, and breeding, and in the case of agricultural products, quality deterioration, reduced output, pollution of pesticides and toxic substances, etc. As a result of the FTA era, the export barriers such as the export suspension situation have occurred due to problems such as causing an export suspension and aquatic products and livestock products, such as antibiotics and pollution caused by feed and breeding. Each of the present invention has large and many problems of losing the international competitiveness of the agricultural and livestock industry, and the present invention provides for the improvement of the soil strength of the agricultural and livestock products, the powdered sulfur or the highly concentrated liquid sulfur, and its compounds. By applying fertilization together, non-pesticides and non-toxic products of agricultural and livestock products, as well as pest prevention and sugar content in agricultural products It can improve the quality of products and increase the output, and in the case of aquatic products and livestock products, it purifies and removes antibiotics, heavy metals and toxic substances, and provides non-toxic, non-antibiotic aquatic products and livestock products production technology. There is a second purpose to improve this.

In addition, there is a third purpose to provide all mankind of the world with foods of eco-friendly functional sulfur agricultural and livestock products that produce the various beneficial effects of sulfur described in the background art by producing eco-functional functional sulfur concentrated marine products containing sulfur components.

Another object of the present invention is to spread the environmentally friendly sulfur agricultural and livestock products to prevent the occurrence of various diseases through the activation of skin protection and skin regeneration, hair loss prevention, strong skeleton and kidney function of humans and animals For example, despite the development of biotechnologies for extracting skin graft material from citrus peels, sulfur citrus can help to solve the problem of no pesticides in citrus peels. It aims to provide a foundation for biotechnology development centered on the health promotion of human beings.

The problem solving means of the present invention for achieving the above object of the present invention comprises the steps of packing a certain amount of mineral sulfur powder (eg 1kg, 2kg, 10kg, 20kg, 40kg, etc.) by the non-woven bag (step 1);

The sulfur sack of oak charcoal and cold water is 1 ~ 10: 20 ~ 30 (preferably 1: 20) impregnated oak charcoal in cold water after 5 to 15 hours, and only charcoal is removed to contain the charcoal component Far-infrared energy is filled in 'normal water prepared in a drying room equipped with water or far-infrared energy filling device, and converted into water containing far-infrared energy, that is, contained in far-infrared energy water. Impregnating the sulfur packaged in the centrifugal dehydrator whole with a nonwoven bag (step 2), rotating the centrifugal dehydrator at low speed and completely dehydrating at high speed for about 2 hours at a low speed of 50-60 rpm by an inverter device. Desulfurization of primary minerals by dehydration at high speed after going through the first sulfur decontamination (detoxification) process to rotate and mature at the same time (step 2)

Cirrus and loess are mixed at a ratio of 2 to 4: 6 to 8 (preferably 3: 7) and finished with an inner wall 1 to 15 cm thick, and infrared rays generating heat above 35 ^o C (preferably 40 ° C). A halogen lamp is installed on the ceiling of the drying chamber, and the first detoxified sulfur powder is put into the drying chamber, and the heat is irradiated for more than 1 hour, and the far-infrared energy is emitted from the mica and ocher, and the first detoxified sulfur powder is heated. Detoxify sulfur powder by removing residual toxicity contained in fine water grains inside (4 steps)

10Å ~ 5000Å of radiation of far infrared energy emissivity of 0.88 or more at 5 ~ 20㎛ and W / m ² * ㎛, more than 3.42 × 10 ² of far infrared energy at 40 ^o C When far-infrared energy having a wavelength is charged in general water for about 2 hours, it is converted into far-infrared energy water (hereinafter referred to as 'far-infrared energy water').

The ratio of the far-infrared energy water (water), kaolin, waste cooking oil and caustic soda is added to a heater at 8,000: 200: 1: 1, respectively, heated to a temperature of 100 ° C. to 300 ° C. and simultaneously operated by mixing with a stirrer. A liquid phase sulfur compound (1) is prepared by removing the impurities by melt mixing for continuous dilution for 3 hours.

Meanwhile, the liquid phase sulfur compound (1) is moved to a stainless steel container, and 15% by weight of far infrared energy water is added to the liquid phase sulfur compound, while 0.02% by weight of propolis and 0.05% by weight of dry ash (borrow). , 0.1% by weight of dried ash bark, 0.1% by weight of dried poplar roots, 0.02% by weight of neem oil, 0.1% by weight of organic calcium, 0.2% by weight of lacquer essence, boil for another 30 minutes, then overflow When spraying 0.1% by weight of far-infrared energy water to maintain foam for 15 minutes, lowering the temperature by 50 ℃ at 30 minutes intervals, further heating for 2 hours to melt and remove impurities (step 6) Is made of.

After the molten contents were transferred to the liquid phase process sulfur and the compound (1) and (2) to the liquid phase process sulfur and the compound filling device to drop the temperature and precipitate for 24 hours, the residue is removed and the impurities are removed. Extracting the red wine-colored high concentration liquid formulation sulfur compound and filling into a PET bottle (step 7).

For mass production of admiral (legal) sulfur of the present invention In the second step of legalizing (detoxifying) the first sulfur, the 12 hours of impregnating and aging mineral powder toxic sulfur in the 'oak charcoal component cold water' described above can be drastically reduced by using the far-infrared energy charging device of the drying room. The far-infrared energy amplifying radiator is manufactured by using water, paper, printing ink, paint, and cotton cloth as the material for the far-infrared energy amplifying radiator, and the far-infrared energy is charged by charging the far-infrared energy in general water. It replaces 'cold water of oak charcoal' with 'far-infrared energy water' by converting it into purified water and drastically shorten the ripening time of toxic sulfur to 2 hours, and it is applied to agricultural and livestock products to produce agricultural and livestock products. Filling far-infrared energy with general water, characterized by improving the product quality of agricultural and livestock products, such as purifying and removing toxic substances. How to process the particles are converted to fine far-infrared energy water (水) and can be produced by applying them to nongsuchuksan water.

When applying and producing the powdered process sulfur and the highly concentrated liquid process sulfur and the compound (1) (2) according to the present invention to agricultural and livestock products, it is more effective to apply and produce according to the exact application technology method for each type of agricultural and livestock products.

Powder method sulfur and highly concentrated liquid sulfur solution of the present invention and a method of applying the compound to the agricultural and livestock products

(1) For agricultural products, dilute grains, root vegetables, and leafy vegetables with 6 Kg of powdered powdered sulfur per 100 m ² of soil or fertilizer application with far-infrared energy water. Far-infrared energy 0.1% by weight of liquid-phase sulfur and its compounds relative to water, and 300 g of powdered-sulfur sulfur per fruit per fruit or an appropriate amount of pesticide application for fruit trees. When diluted with far-infrared energy water, 0.1% by weight of highly concentrated liquid process sulfur and its compounds, and 200 g of powdered process sulfur per seedling, or an appropriate amount of pesticide application are used for fruit. When diluted with far-infrared energy water, 0.1% by weight of highly concentrated liquid process sulfur and its compound compared to far-infrared energy water, and 20 g of powdered sugar process sugar per flower seed Or fertilizer application amount by far infrared energy water When interpret, it is possible to achieve a method of fertilizing a far infrared energy water (水) compared to highly concentrated liquid legal sulfur and 0.01% by weight of the compound.

Fertilized application of crops of legal sulfur [Regulated sulfur content per ² m of soil 100] Crop Divisions
Fertilization method Cereals
(穀類) Root vegetables
Leafy vegetables Fruit tree Fruits Flowers
Mixed fertilization Sulfur Powder or
Sulfur money 12Kg 12 kg 800 g 400 g - Legal sulfur 3 kg 3 kg 200 g 100 g 20g When only fertilizing sulfur 6 kg 6 kg 300 g 200 g 20g Application of Liquid Sulfur Compounds
Of water in case of dilution 0.1
weight% 0.1
weight% 0.1
weight% 0.1
weight% 0.01 wt%

곡 Grains, such as rice and barley, or root vegetables such as potatoes, carrots, sweet potatoes, and radish, and leafy vegetables such as cabbage and lettuce, so that they can be easily fixed to soil before planting or seeding. In addition, it can also be fertilized by mixing with money, but at this time, poultry, or money, is used for poultry farms and pigs that feed legally mixed sulfur with feed. (Iii) Because farmers can receive free or very low prices, they naturally recycle sulfur powder or sulfur money. In addition, unlike the conventional powder and the powdered powder, such sulfur pig powder and egg powder have a significantly reduced odor, so there is almost no inconvenience when fertilizing.

Thus, if the fertilizer by mixing sulfur manure or money minute when suitable when fertilizer mixed with soil 100m ² per sulfur manure or sulfur money-minute 12kg of powder Legislation sulfur 3Kg and fertilizing only powder Legislation sulfur, the Land 100m ² It is appropriate to fertilize 6 kg per sugar evenly. However, in order to mix the soil with powdered sulfur, agricultural soils can be ground or cultivated, and the depth of soil overturning should be at least 50 cm so that the powdered sulfur can be easily fixed in the soil.

Next, apply far infrared energy water to the soil containing legal sulfur, and evenly spray 30 liters of far infrared energy water per ² m of soil to facilitate fermentation of powder legal sulfur in the soil. Powdered sulfur will purify or detoxify toxic substances such as residual pesticides in the soil or various heavy metals, and neutralize PH 6-7 to acidified soil of pH 4.5-5.5. Thereafter, after planting or seeding, the grain roots absorb sulfur components matured in the soil, so that the grains contain more than twice the sulfur components of the grains of general grains, and the residual pesticides are irradiated by the far-infrared rays emitted from the legal sulfur of the present invention. It will grow into an eco-friendly functional sulfur grain that will be removed.

In the case of spraying liquid-phase sulfur and its compounds, it is effective to dilute using far-infrared energy water according to the present invention when spraying pesticides. At this time, the liquid-phase sulfur and its compounds are 0.1% by weight relative to far-infrared energy water. Mix and dilute with pesticide and spray. In this case, the residual pesticides are significantly reduced, the fineness and fruiting are improved, and the insects are resistant to pests, and the yield is increased, as well as the production of environmentally functional sulfur grains.

과 For fruit trees such as citrus fruits, Halla bong, apples, pears, persimmons, and grapes, when the fruit is in bloom, fertilize the sulfur evenly around the root of the fruit tree. At this time, the sulfur-based powder or sulfur pig powder (豚 糞) may be fertilized by mixing with the legal sulfur, in this case, fertilized by mixing 800 g of sulfur-based powder or sulfur pig powder and 200 g of legal sulfur per fertilized fruit. Then, 4 L of far-infrared energy water is sprayed evenly around the root of the fruit tree to facilitate the fixation of the legal sulfur. At this time, the legal sulfur component is aged in the fruit tree root soil to purify or detoxify toxic substances such as residual pesticides or substances of various harmful components such as heavy metals.

Seedling roots absorb sulfur components in the soil, and after fruiting and fruiting, they absorb sulfur components, and the far-infrared energy radiated from legal sulfur grows into an eco-friendly functional sulfur orchard that purifies and removes residual pesticides from the fruit surface. It is characterized by.

In the case of spraying liquid-phase sulfur and its compounds, the diluted far-infrared energy water according to the present invention and liquid-phase sulfur and its compounds are mixed with 0.1% by weight of the far-infrared energy water with pesticides. After that, it is sprayed. In this case, the residual pesticides are significantly reduced, the sugar content is increased, the fruiting rate is improved, the fruiting rate is not only reduced, but also become stronger to pests, characterized by the production of environmentally friendly functional sulfur orchards.

과 In the case of fruits such as cucumbers, tomatoes, melons, and watermelons, spray the legal sulfur before fruiting (着 果). At this time, you can fertilize the sulfur-based powder or sulfur pig powder with the legal sulfur.For each seedling, you can fertilize the sulfur-based powder or sulfur pig powder 400g and the legal sulfur 100g. 200g of fertilized sulfur is applied around the roots of the seedlings.

Then, evenly spray 2 liters of far-infrared energy water per seedling to ensure that the sulfur is easily fixed to the seedling root. At this time, the legal sulfur component is aged in the seedling soil to contain sulfur components while purifying or detoxifying toxic substances such as residual pesticides, various harmful substances such as heavy metals, and the like.

Seedling roots absorb sulfur components in the soil, and after fruiting, they contain sulfur components, and the far-infrared energy radiated from legal sulfur is used to grow and remove pesticides remaining on the fruit surface, thereby growing as an eco-friendly functional sulfur fruit. It is characterized by.

In addition, when spraying the liquid legal process sulfur and its compounds, the diluted far infrared energy water (water) and the liquid sulfur compound according to the present invention are diluted 0.1 wt% with far-infrared energy water (water) and then diluted with pesticides when spraying pesticides. Spray it. In this case, the residual pesticides are significantly reduced and the sugar content goes up, the fruiting rate improves and the fruiting rate decreases.

화 In the case of flowers such as chrysanthemums, lilies and eggs, 20 g of legal sulfur per seedling plate is mixed with soil and manure. At this time, the sulfur component is evenly sprayed with 0.3 L of far-infrared energy water (water) per seedling plate so that the seedling plate can be easily fixed and solidified. Thereafter, the seed sown on the seedling plate contains a sulfur component, after the growth and flowering, it is possible to obtain the effect of lasting more than 1.5 times the duration of flowering than general flowers.

In the case of spraying liquid-phase sulfur and its compounds, it may be diluted with far-infrared energy water and its liquid by diluting 0.01% by weight of far-infrared energy water. In this case, the germination rate is improved, and after flowering and growing, it is possible to obtain the effect of lasting more than 1.5 times longer than the general flowers.

② In case of livestock and aquatic products, when the legal sulfur is fed at the livestock farms, 0.2% by weight of legal sulfur is added to the existing feed. At this time, the statutory sulfur salary should be adjusted according to pigs, broilers and eggs.

 Livestock products salary method of legal sulfur (mixing 1,000% 2% by weight of feed) division Pig Broiler Egg Sow General money Legal Sulfur Blend
Feeding Method 6-12 weeks of pregnancy
salary Salary 40 days before shipment Salary from 10-day-old chick Continuously salary

㉠ In the case of pigs, the mother pigs are paid only during the sixth to twelve weeks of gestation, and are suspended until childbirth, and then again from the last week of maternity to the idle period. This is because it is advisable to stop the legal sulfur supplement during the mammalian period because it can reduce the milk content of the mother pig during the mammalian period. When a mother pig ingests sulfur, the mortality rate of the piglet is reduced and a healthy piglet can be given to pathogens and infectious diseases.

In the case of general pigs, when fed with legal sulfur from 40 days before shipment, the meat quality improves, and the functional non-antibiotic sulfur that contains 60% or more of unsaturated fatty acids and no antibiotic is detected. You can ship pigs.

㉡ In the case of broiler (肉鷄), when the legal sulfur of the present invention is fed to the existing feed from the 10-day-old chicks, the mortality is reduced and the weight is more than 10% more than the general broiler in the same breeding period, the meat quality is gained It can be shipped as a functional non-antibiotic sulfur chicken with no antibiotics detected.

In the case of eggs, if the diet is continuously fed with 0.2% by weight of legal sulfur in the feed, the blue rate decreases, the egg production rate increases, and the egg is produced more than 85% even when the egg is over 40 weeks old. Esau has a savory taste without the unique fishy smell, and can be shipped as a functional non-antibiotic sulfur egg that is not detected as antibiotics because sulfur is detected more than four times compared to ordinary eggs.

③ In the case of aquatic products, by adding 0.2% by weight of the legal sulfur of the present invention to the existing feed fed by the fish farmers, and feeding 60 days before shipment, by growing far-infrared energy water (water), the antibacterial and immunity of the aquatic products is increased. As the mortality rate is lowered, the yield is increased, and the residual antibiotics contained in the aquatic products are removed, so it is superior in all fields to general aquatic products such as chewability, cohesiveness and elasticity during sensory evaluation, and is recognized for its excellent quality. More than twice as much detection can be shipped antibiotic-free sulfur products.

The present invention is a mineral sulfur preparation method that can be produced in a small amount while using a conventional, complex and much time and cost by using a toxic deodorizing (powder) sulfur powder and a liquid process sulfur and a compound manufacturing method thereof that can be produced in large quantities as described above. It is more convenient and quicker, and it can detoxify (mineral) the toxicity of mineral sulfur at low cost in a short time, and can also manufacture highly concentrated liquid sulfur and its compounds, which are convenient for application to agricultural and livestock products. Characterized as being done.

Powdered sulfur, liquid sulfur, and the compound and far-infrared energy water according to the present invention are applied to agricultural and livestock products together in agricultural and livestock farms to prevent pests, increase production, increase sugar content, and improve pesticides. It has the effect of substance detoxification, and in livestock products, it is possible to produce eco-friendly agricultural products such as non-agricultural non-antibiotics and non-toxic products that are not detected by increasing immunity (antibacterial), decreasing mortality (improving productivity), residual antibiotics, heavy metals, etc. It works.

By applying powdered sulfur or liquid sulfur and its compounds to agricultural and livestock products, farmers can reduce the use of pesticides, antibiotics, and toxic substances, and reduce production costs. Increasing yields and lower mortality can lead to higher incomes for farming and fishing villages.

On the other hand, consumers can enjoy eco-friendly and safe foods without worrying about residual pesticides, antibiotics, and toxic substances, as well as functional sulfur agricultural and livestock products that help health promotion. Can be.

In addition, rural areas can neutralize soil acidified with pesticides or toxic substances at low cost, resulting in increased harvests. Livestock farmers and fishing villages can replace the abuse of antibiotics used for livestock products with legal sulfur to make the most of domestic agricultural and livestock products. By completely breaking down the export barriers such as residual pesticides and antibiotics, which have become obstacles, the free trade era (FTA) can be faced to enhance the international competitiveness of the agricultural and livestock industry.

In addition, people use eco-friendly functional sulfur agricultural and livestock products to prevent the onset of diabetes, kidney disease, etc. due to skin protection, hair loss prevention, strong skeletal maintenance and kidney function deterioration by utilizing the unique sulfur function. Functional sulfur application products can be produced.

1 is a block diagram of a mineral sulfur powder detoxification apparatus

The technical configuration of the present invention will be described in detail with reference to the accompanying drawings.

Filling the nonwoven fabric with a certain amount of 5Kg, 10Kg, 20Kg or more through the packing machine filling device after injecting mineral powder sulfur with 99% purity into the silo bin.

The ratio of oak charcoal to cold water is 1 ~ 5: 20 ~ 30 (preferably 1: 20) and impregnated oak charcoal in cold water after 3 to 15 hours (preferably 12 hours). Containing cold water or Far-infrared energy filling In the drying chamber, a centrifugal dehydrator containing water containing far-infrared energy, prepared by first charging general water with far-infrared energy, impregnated the packaged sulfur whole with a nonwoven fabric bag, and then 50-60 rpm by an inverter device. Rotation of left and right alternately for 1 to 3 hours (preferably 2 hours) at low speed, followed by primary sulfur process for aging and complete dehydration at high speed (step 2)

At least 35 ^o C (preferably 40 ° C) in a drying room with 1 to 15 cm thick (preferably 10 cm) thick, mixed with the mica and ocher at a ratio of 2 to 4: 6 to 8 (preferably 3 to 7). ) Heat the infrared halogen lamp capable of generating heat in the drying chamber, add the first detoxified sulfur to the inside of the drying chamber, and extract the heat for 1 hour to contain the fine water particles in the first detoxified sulfur. Residual toxicity is eliminated. In particular, the drying chamber has a far infrared emission rate of 0.88 or more at 520 μm emitted from villus and ocher, and far infrared rays of 3.42X10 ² or more at W / m ² * μm, 40 ^o C and a wavelength of 10Å ~ 5000Å Powdered process sulfur is manufactured by the far-infrared energy which has (3 steps).

Example  One : Sulfur powder decontamination method

In this example, the mechanism for decontamination of sulfur and the amount of one-time operation of sulfur were manufactured according to the 500kg standard.

First step; Packing mineral sulfur powder in nonwoven

500kg of mineral powder sulfur is put into silo bin (Fig. 1.A-1) using electric hoist, and then 5kg, 10kg, 20kg, etc. through sulfur packing charger (Fig. 1, A-2) by operating timer device. A certain amount of furnace can be put in a nonwoven fabric and packed. In this embodiment, a total of 25 bags were packed in units of 20 kg.

Second stage; 1st sulfur decontamination stage

Fill the centrifugal dehydrator (Fig. 1, B-1) with 200 liters of cold water, pack 10 kg of oak charcoal in a net cloth, impregnate it in cold water, and then ripen for 12 hours. In the centrifugal dehydrator, which filled and contained far-infrared energy in water and turned it into far-infrared ray energy water, impregnated 25 bags of sulfur and left and right alternately for 2 hours at a low speed of 50-60 rpm by an inverter device. After undergoing the first sulfur sulphur process to mature by rotating, it was completely dehydrated at high speed. The longer the dehydration time was, the lower the water content in the sulfur content was, and the powder sulfur content was also reduced. In the embodiment, the sulfur content of the legal sulfur was 5%, and the analysis thereof is as shown in Table 3 below.

Comparison of Water Content and Legal Sulfur Contents by Minutes of Dehydration Time division Moisture content Legal sulfur content Remarks Initial impregnation stage 30% 500 kg Before dehydration After 2 minutes dehydration 7% 496 kg After 3 minutes dehydration 5% 495 kg Set as standard After 4 minutes dehydration 2% 494 kg

3rd step: Powder Sulfur Process

Drying room 25 bags of decontaminated sulfur were put inside and the drying chamber (Fig. 1, C-3) was sealed, and then the infrared halogen lamp (C-1) was adjusted to 35 ^° C or more (preferably 40 ° C). At the same time as the sulfur process drying process, at 5 ~ 20㎛ of the villus and ocher irradiated by radiant heat of more than 35 ℃ (preferably ^40o C) of the drying chamber, far infrared emission rate of 0.88 or higher at W / m ² * ㎛, 40 ^o C Far-infrared energy is charged by drying the far-infrared energy having a wavelength of 10 Å to 5000 방사 for 2 hours and simultaneously charging the far-infrared energy for 2 hours while operating the far-infrared charging device equipped with 3.42X10 ² or more far-infrared radiation energy. Powder-producing sulfur containing was obtained.

Meanwhile above Second time far infrared rays to the general water (水) prior to the production phase entry to determine the radiation amount of the far infrared energy water (水) contained in the containing cold water and the far infrared energy charging Oak Charcoal component of my centrifugal dehydrator of stage 2 Energy Cold water containing oak charcoal was used as a result of filling the water turned into water containing far-infrared energy and using it. As a result, far-infrared energy water has more effect of emitting far infrared energy than cold water containing oak charcoal. there was. The far-infrared energy emissivity of the biotite and loess at that time is shown in <Table 4>.

Far Infrared Test Results of Cicada in Korea Building Materials Testing Institute Test Items Test result Test Methods Far infrared ray emission amount
(40 ^o C) Emissivity (5-20㎛) 0.927 KICM-FIR-1005 Radiant energy (W / m ² ) 3.74 x 10 ²

X-ray imaging, specific gravity measurement and far-infrared emission (40 ^o C) of toxic sulfur and mineral sulfur before detoxification were analyzed as shown in Table 5 below. .

Results of Cicada Far-Infrared Testing by Korea Institute of Construction Materials Test classification and
Sample Name X-ray Far infrared ray energy emission amount (40 ^o C) State minerals importance Emissivity (5-20㎛) Radiation energy (W / m ² ) Mineral sulfur α-S 2.18 0.850 - Legal sulfur α-S 2.14 0.907 - Test Methods XRD test KICM-FIR-1005

X-ray measurement showed that both the detoxified sulfur and general sulfur main minerals of the present invention were α-S, and there was no change in composition, but the specific sulfur of the mineral sulfur was 2.18, whereas the detoxified sulfur according to the present invention was 2.14. The specific gravity was reduced to 0.04. The detoxified sulfur according to the present invention is determined that the toxin component has been removed, and the far-infrared emission measurement result shows that the emissivity of mineral sulfur is 0.850, while the emissivity of detoxified sulfur according to the present invention exhibits a numerical value of 0.907. It has been found that toxic sulfur emits and contains far more infrared energy than mineral sulfur.

Example  2: liquid method sulfur manufacturing method

In this example, a stainless steel heating vessel for preparing liquid-phase sulfur and its compound was manufactured to 200 L standard of liquid-phase sulfur and its compound. The stirrer used 0.4 kW power and was heated by pine wood fire.

The powder is processed in the fine powder sulfur of 30 to 70 nanometers (nm) unit decontamination (treatment) in the third step.

4th step: Liquid-phase sulfur production

In a 200 liter stainless steel heating vessel equipped with a stirrer, 100 l of far-infrared energy water prepared by the present invention and 30 kg of powder process sulfur of 30 to 70 nanometers (nm) are mixed and heated and melted at 100 to 300 ° C. Liquid phase sulfur is produced.

Step 5: Manufacture Liquid Sulfur Compound (1)

In addition, in order to prepare a liquid-phase sulfur compound (1) that can maximize the fertilization effect when applied to agricultural and livestock products, put the liquid-phase sulfur solution already prepared in a container, and then add 2.5 kg of kaolin, 12.5 ml of waste cooking oil, 12.5 of caustic soda. g was added, mixed using a stirrer, and melted over 3 hours while heating to 100 ° C. to 300 ° C. to prepare an additive liquid phase sulfur compound.

Step 6: Preparation of Liquid Phase Sulfur Compound (2)

40 g of propolis, 100 g of dried ash vinegar, 200 g of dried ash scallop, 200 g of dried popcorn root, Nim oil in the molten liquid in the heating vessel, that is, the first additive melting step, that is, liquid phase sulfur compound (1) 40 ml, 200 g of organic calcium, 400 ml of lacquer essence are mixed and mixed, and when boiled for another 30 minutes, when the bubble overflows, 400 ml of far-infrared energy water is added little by little, and the foam is maintained for 15 minutes. In addition, the temperature was lowered by about 50 ° C. every 30 minutes, and further heated for 2 hours to prepare a liquid phase sulfur compound (2) through a mixed melting step of the liquid phase sulfur and secondary additives.

Step 7: Extraction of Liquid Process Sulfur and Its Compounds

200 l of nano (nm) powdered sulfur and a mixture of primary and secondary additives, that is, liquid sulfur and its compounds (1) and (2), were melted in a stainless steel heating vessel (represented in Figure 2.E-1). After slowly cooling, the mixture is aged for 24 hours, and then the precipitate is removed and only the liquid part is filtered out. PET) Extract and store in a bottle.

After diluting the liquid process sulfur and the compound 500ml prepared by the present invention as described above in 500 l of far-infrared energy water in a control unit (SS group), and then sprayed in cucumber house 1,000m ² of cucumber farms, harvesting The functional sulfur cucumber in the experimental zone has a yield of about 30% more than the cucumber in the control zone, and since its structure is dense and the production of cucumbers grown straight without bending, more than 80% of them are judged as first class in the auction market. In addition, residual pesticides were not detected, which had the expected effect of increasing farm household income.Residual pesticides were not detected as a result of inspecting residual pesticides from cucumbers fertilized with liquid sulfur compounds of the present invention by requesting Kangwon-do Institute of Health and Environment. .

The emulsified sulfur powder according to the present invention was applied to rice farms, poultry farms , and eel farms, respectively.

Case 1: functional eco-friendly sulfur rice

One hundred milliliters of the legal sulfur powder of the present invention was evenly fertilized on a 1,000 m ² paddy field of rice cultivators, followed by rotary grinding, which was planted a month later. After fertilizing sulfur, the sensory test on harvested rice revealed that the rice was denser and more fragrant, and more calcium was detected than normal rice, which was expected to be good for preventing various adult diseases. .

The effect was able to be recognized as excellent functional rice, commissioned by the Rural Development Administration Livestock Science Institute, the results of the component analysis of the legal sulfur rice of the present invention was analyzed as shown in Table 7 below.

Analysis of Sulfur Components in Legislative Sulfur Rice from Rural Development Administration Ingredient Name and Sample Name Component analysis result (%) S Sulfur rice 0.150

Case 2: functional eco-friendly sulfur egg

Two chicken breeding dongs are selected from a poultry farm that produces 35,000 eggs per chicken breeding hen and produces eggs. The chickens of B-dong were fed by mixing 0.2% by weight of the legal sulfur of the present invention in general feed, and analyzed eggs three times at an interval of one month from one month. As described above, the chicken egg fed the legal sulfur of the present invention contains glutathione and cysteine in a large amount compared to the egg of general chicken, which is effective in preventing adult diseases, and has a lot of DHA, lecithin, and essential amino acids, which are used for brain development of adolescents. As a result, it was found that Salmonella and non-antibiotic eggs without antibiotics contained twice as much sulfur as those of normal eggs. Table <8> is a result of comparing and analyzing the productivity of the chicken produced by mixing the legal sulfur of the present invention in the feed (test) and chicken (control) mixed with omega-3.

Comparative results of egg productivity between experimental and control groups (%) division 1 month 2 months 3 months Spawn rate Mortality Spawn rate Mortality Spawn rate Mortality A building [control] 88.74 4.650 90.20 5.231 90.35 6.521 B building [experiment ward] 91.94 3.365 93.25 3.610 91.03 4.070

The results of the above table are the results of analysis in the laboratory of the applied poultry farmer, the sulfur of the present invention, which is lower than the omega-3 compared to the chicken of the control group which is fed the high-priced omega-3 in the conventional feed. Chickens in the experimental diets fed the same diet were found to have improved egg-drift productivity with higher egg production and lower poultry mortality.

Therefore, I asked the Incheon Institute of Health and Environment to test whether or not sulfur eggs containing the legal sulfur according to the present invention in the existing feed were contained in antibiotics. The results are shown in Table 9 below.

Investigation result of sulfur egg test by Incheon Institute of Health and Environment Test Item Inspection standard result Judgment Salmonella Not detected Not detected Fit Flubendazole (mg / kg) 0.4 or less Not detected Fit Oxytetracycline (mg / kg) 0.2 or less Not detected Fit Judgment Verified test

As described above, the eggs produced by chickens fed the legal sulfur according to the present invention were found to have no pathogens or antibiotics detected at all. <Table 10> below shows the sulfur content analysis results of sulfur eggs requested by the Rural Development Institute.

Analysis of Sulfur Contents of Sulfur Eggs at the National Academy of Animal Science, Rural Development Administration Ingredient Name
Test Sample Name Component Analysis Result (Unit%) S Sulfur Egg 0.225

As a result of component analysis of sulfur eggs, the sulfur content of the sulfur eggs produced by the chickens fed the legal sulfur according to the present invention was found to contain more sulfur components than those of chickens not fed legal sulfur.

Case Study 3: Functional Sulfur Eel

0.2% by weight of the legal sulfur of the present invention was added to the eel feed and fed to the eel from 20 days before shipment.

The eel produced by feeding as above was darker in color, bigger in flesh weight, and higher in weight yield than normal eel, and increased in minerals such as magnesium, calcium, titanium, cobalt, zinc and copper. As a result, the taste, succulentity, texture of meat, and the general symbol showed a much better response than general eel. Especially, unlike sulfur eel, sulfur eel had no feeling of fat (oil). On the other hand, it was evaluated that it was very good to have diarrhea after eating.

As a result of sulfur component analysis, 0.2% by weight of the legal sulfur of the present invention was added to the eel feed, and the sulfur content of the eel fed from 20 days before shipment was found to contain more sulfur content than the general eel not fed the sulfur feed.

By applying powdered sulfur or high concentrated liquid sulfur and its compounds and far-infrared energy water according to the present invention to agricultural and livestock products, soil, feed, etc. As a result, the company has been able to develop, produce, and supply agricultural and livestock products containing eco-functional sulfur, which purifies and removes toxic substances contained in the human body, as well as pursuing a healthier life.

Claims (10)

Packing mineral sulfur powder in a predetermined amount (step 1);
Impregnating the charcoal in water for a predetermined time, and then impregnating the packaged sulfur powder by putting the charcoal-derived water or far-infrared energy water into a centrifugal dehydrator;
Dehydrating the water using a centrifugal dehydrator to detoxify the mineral sulfur powder (primary detoxification) (step 3);
Injecting the first detoxified sulfur powder into a drying chamber in which far-infrared energy is emitted, and then heating the drying chamber to at least 35 ° C. to remove secondary residual toxicity by radiating far infrared rays and heat drying (step 4); Sulfur powder decontamination method, characterized in that consisting of.
The powder sulfur decontamination method according to claim 1, wherein water is impregnated with charcoal for 10 to 15 hours.
The method of claim 1, wherein the drying chamber is a sulfur powder detoxification method, characterized in that the inner wall with a thickness of 1 ~ 10cm by mixing the mica and the ocher from which far-infrared energy is emitted in a ratio of 2 to 4: 6 to 8.
The sulfur powder of claim 1, wherein the drying chamber emits more than 0.88 far-infrared emissivity at 5-20 μm and w / m ² * μm, and more than 3.42 × 10 ² far-infrared rays at 40 ^° C. Decontamination method.
The method of claim 1, wherein the far-infrared energy water is used by replacing paper, plastics, printing ink, paint, and cloth of a large-area material with raw materials of the far-infrared energy radiating medium. .
Far-infrared energy water is added to a heating vessel, and the first detoxified sulfur powder is processed into 30 to 100 nanometer (nm) -sized micro-process sulfur and put into the heating vessel, and then the far-infrared energy water is used by using a stirrer. Method for producing a liquid legal sulfur by mixing and heating the sulfur powder.
The method of claim 6, wherein 70-90 wt% of far-infrared energy water is mixed with 10-30 wt% of the fine process sulfur.
According to claim 6, Far-infrared energy water (water), kaolin, waste cooking oil, caustic soda (sodium hydroxide) are each added at a ratio of 8,000: 200: 1: 1 and heated to a temperature of 100 ~ 300 ℃ and using a stirrer Liquid process sulfur production method characterized in that the mixing.
The method of claim 6, 15% by weight of far-infrared energy water, 0.02% by weight of propolis, 005% by weight of dried ash, 0.01% by weight of dried ash bark, 0.1% by weight of dried poplar root, 0.02% by weight of neem oil , 0.1% by weight of organic calcium, 0.2% by weight of lacquer essence, and after 30 minutes, the bubble is sprayed with 0.1% by weight of far-infrared energy water to maintain the foam for 15 minutes, and then lowered by 50 ℃ every 30 minutes. Method for producing a liquid phase sulfur process, characterized in that for further heating for 2 hours to melt.
The method for producing a liquid phase sulfur process according to claim 6, further comprising an impurity removal device for removing impurities.

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