KR101346018B1 - Method for producing liquid type detoxicated sulfur - Google Patents

Abstract

The present invention relates to a method of preparing sulfur powder or liquid sulfur, which is prepared by using sucrose, green beans, oak extract, plum extract, motherwort extract, and sesame seed in sulfur dissolving solution. Addition of powdered or liquid sulfur to the feed for livestock or aquaculture products can increase the growth rate and immunity of livestock or aquatic products, and can also control plant diseases when sprayed during plant cultivation.

Description

Method for producing liquid sulfur and method for growing crops using liquid sulfur {Method for producing liquid type detoxicated sulfur}

The present invention relates to a sulfur legal method for producing toxic sulfur with sulfur harmless to the human body. More specifically, the sulfur dissolving solution prepared using radish juice, green bean, oak extract, plum extract, motherwort extract and sesame The present invention relates to a process for producing a process sulfur powder or liquid process sulfur, and a process sulfur powder or liquid process sulfur produced by the above method.

Sulfur is a kind of carloken element belonging to group 6B of the periodic table. It maintains a solid state of yellow at room temperature, but its reactivity is very high at high temperature to react with almost all metals except gold and platinum to form sulfides. In nature, mainly sulfides such as pyrite, gallium, splint and brass, combined with natural sulfur or heavy metals in the glass state, or sulfates such as barite, pumice, gypsum, volcanic gas, hydrogen sulfides such as hot springs and mineral springs, and sulfurous acid. It is in the form of gas, sulfuric acid.

Sulfur is the fourth most abundant mineral in the human body after calcium, phosphorus and potassium. It is found in all cells of the body and is a component of the important amino acids cystine, cysteine and methionine. Essential for life, it is also a constituent of the vitamins thiamin and biotin and is present in saliva, bile and hormone insulin. It also accounts for 0.15% of body weight and sulfur accounts for 10% of the body's mineral content. In this way, sulfur is one of the most important substances that should be indispensable for metabolic activities such as breathing and assimilation of living things.

However, mineral inorganic sulfur or synthetic organic sulfur is highly thermally toxic and thus strong enough to be harmful to human life if consumed directly.

On the other hand, legislation refers to the process of treating protozoa collected from nature as a non-toxic functional substance in oriental medicine. In oriental medicine, to use natural plants, animals, and minerals without harm to the human body. The process of processing. In other words, various methods such as dividing the bulky ones, softening the hard ones, and removing the toxic ones are used.They are also used to increase the therapeutic effect of new toxic raw materials or to produce new effects. it means.

Another traditional process of legislation was to feed sulfur-enriched feeds to certain animals, such as ducks, which are known for their special detoxification, and then consume the meat with humans. However, this method is limited to only certain animals such as ducks. Recently, humans consume meat from poultry or livestock, which is made by mixing sulfur with legally minimized toxicity through a certain sulfur legal process. The method is being tried.

However, as the most widely known sulfur legislation method, even after the sulfur is added and sealed in a fraudulent vessel, it is heated for about 48 hours, and even if powdered legislative sulfur is not accurately controlled, the poultry or livestock is killed. Although not killed, most of them are excreted as feces, indicating a weak absorption rate.

Increasing use of chemical fertilizers and pesticides used to grow agricultural products in farms and the emergence of microorganisms, such as pesticide residues and various viruses that are highly resistant to them, not only cause significant effects such as deterioration and poisoning of farms and agricultural products, but also acidification of soil. There is a serious problem in Edo, and there is a tendency for consumers to have access to healthy food in recent years. Therefore, considering the situation to find the solution to the development of natural fertilizer, etc. in order to solve the problems that occur during the cultivation of agricultural products, the technical problems and costs are realized to enhance the immunity of the agricultural products themselves, thereby preventing the damage caused by the abuse of chemical fertilizers and pesticides. Increasingly, a healthy national diet and an improved farming environment are inevitably raised due to economic growth.

Recently, a new sulfur fertilizer technology to be supplied to crops or land has been developed to recognize the above problems and to promote the eco-friendliness and growth of crops. To this end, sulfur poisoning must be sufficient, but the reality is not, and there is no satisfactory sulfur legislation that can replace the pests of pesticides.

Korean Patent Application Publication No. 10-2011-0109008 has a low possibility of killing even when used in feeds such as poultry, livestock, fish and shellfish, high absorption rate in meat, and at the same time, production costs are increased by using vegetable oils commonly found in the surrounding area. Inexpensive and mass-produced sulfur legislation method and the composition related to the liquid sulfur to remove the toxic components through the composition is disclosed. In addition, Korean Laid-Open Patent Publication No. 10-2006-62243 relates to a method for legally regulating sulphurous sulfur to be consumed by an animal, and a chicken feed containing the same, wherein the sulfur is melted in a container by heating and melting the sulfur. Cooling decontamination step of adding the molten sulfur to the mixture of cold water and wood clay (kaolin) or clay to cool the detoxification step, the sulfur drying step of separating and drying the cold detoxified sulfur from the mixed solution, the sulfur melting step, cooling detoxification step and sulfur The repeating step of repeating the drying step 9 or more times, the composition comprising a step of pulverizing the dried detoxified sulfur into a powder. Korean Patent No. 0874404 discloses a sulfur legal method using alkaline reduced water, and Korean Patent Publication No. 2009-0024534 discloses a method for preparing legal sulfur from which noxious components are removed. Separating the extract from the precipitated sulfur by heating and cooling a mixture of radish juice, green beans, oak extract, plum extract, motherwort extract, and goblin; Preparation of sulfur powder and liquid formulation sulfur comprising the step of separating the extract and precipitated sulfur by heating after adding radish, mung beans, oak extract, plum extract, motherwort extract, gooseweed and water to the separated sulfur and heating. It differs from the method.

In order to solve the above problems, the present invention can improve the growth of livestock and can be used as an antibiotic substitute, in order to prepare a legal sulfur that can improve the pest prevention effect of agricultural products, green beans in sulfur-free, sulfur solution, It is an object of the present invention to prepare a process sulfur powder or liquid process sulfur, characterized in that the extract is prepared after the addition of the extract of the oak, plum extract, motherwort extract and sesame.

In order to solve the above problems, the present invention is added by adding water to the sulfur and then heated to produce a sulfur solution and mixed with added sulfur juice, green bean, oak extract, plum extract, motherwort extract and sesame beetle to the prepared sulfur solution The mixture was heated and cooled to separate the upper layer extract and precipitated sulfur, and to the separated sulfur was added radish juice, green beans, oak extract, plum extract, motherwort extract, sesame, and water, followed by cooling. It provides a process for producing a process sulfur powder or a liquid process sulfur, characterized in that the extract is prepared by separating the extract and precipitated sulfur.

The preparation of the legal sulfur powder or liquid legal sulfur by the method of the present invention can effectively remove the toxicity of sulfur having a strong toxicity can be grafted to agricultural, water, livestock products. More specifically, in the case of feeding the cattle by adding the legal sulfur powder of the present invention to the feed for livestock such as pigs, cows, and chickens, the growth rate of the livestock is improved, so that it is possible to reduce the cost of breeding before shipping. In addition, it is possible not only to replace antibiotics by boosting immunity, but also to provide consumers with high quality meat due to good meat quality. In addition, when the formulation of the sulfur powder of the present invention in the aquatic product feed to provide aquatic products with fast shipment, the meat quality is improved, and the water purification is excellent, which can help other diseases caused by water during aquaculture. In addition, when the liquid legal process sulfur of the present invention is diluted in water and fertilized in a place where agricultural products are grown, there is an effect of controlling a disease caused by fungi.

1 shows a regulated sulfur powder.
Figure 2 is a schematic diagram showing a method for producing the legal sulfur of the present invention.

In order to achieve the object of the present invention,

(a) heating the sulfur to a predetermined time and temperature to cool and then adding water to prepare a sulfur solution;

(b) heating the mixture of radish juice, mung bean, oak extract, plum extract, motherwort extract and sesame to the sulfur solution prepared in step (a), and then cooled, to separate the extract from the upper layer and precipitated sulfur Making;

(c) to the separated sulfur of step (b) by adding radish juice, mung bean, oak extract, plum extract, motherwort extract, gooseweed and ocher jijangsu water, heating and cooling to separate the extract and precipitated sulfur of the upper layer Making; And

(d) it provides a method for producing a legal sulfur powder comprising the step of mixing each sulfur separated in step (c) and then drying.

The ocher Jijisu water used in the above is stirred in a large container or jar with the ocher powder 1: about 20 water, and stirred well, and after about 60 hours after the powder is diluted, the ocher is settled as clear water. Means.

The radish juice is made by grinding and pressing radish, green beans are prepared by grinding in a blender, and the extract of the oak means that it is produced by mixing the oak and water in a ratio of 10: 1 by weight. Plum extract is extracted in a fermented state by putting the plum into fermented jars, leaf herbaceous liquor and sesame extract is prepared by extrusion mixing the weight ratio of leaf herb liquor and water, sesame and sesame and water 10: 1.

Preferably, the method for producing the legal sulfur powder of the present invention

(a) mixing sulfur by heating sulfur at 80 to 160 ° C. for 50 to 70 minutes in a weight ratio of 1-1.5: 4-6 to prepare a sulfur solution;

(b) 20 ~ 30% by weight of juice, green bean 5 ~ 10% by weight, oak extract 3 ~ 5%, plum extract 1 ~ 2% by weight, motherwort extract 1 ~ 2% by weight, and the mixture of 1 ~ 2% by weight of the ghost grass was heated at 100-120 ℃ for 60-90 minutes and then cooled for 4-5 hours, the cooled mixture was again 100-150 Heating at 캜 and then cooling to separate the upper extract and precipitated sulfur;

(c) 10 ~ 20% by weight of radish, 1 ~ 2% by weight of green beans, 3 ~ 5% by weight of oak extract, 1 ~ 2% by weight of plum extract, motherwort extract 1 ~ 2 Add 100% by weight, 1 ~ 2% by weight, and 400-600% by weight of ocher liquor, and heat the mixture at 100 ~ 120 ℃ for 60 ~ 90 minutes, and then cool the mixture for 4 ~ 5 hours again. Heating at 150 ° C. and then cooling to separate the upper extract and precipitated sulfur; And

(d) may comprise the step of drying the sulfur separated in step (c),

More preferably,

(a) heating the sulfur at 80 to 160 ° C. for 60 minutes to cool, and then putting 500 L of water into 150 kg of sulfur to prepare a sulfur solution;

(b) 20 ~ 30% by weight of radish juice, 5 ~ 10% by weight of mung bean, 3 ~ 5% by weight of oak extract, 1 ~ 2 weight of plum extract, compared to 50% by weight (= 325 kg) of the sulfur solution prepared in step (a) %, Motherwort extract 1-2% by weight, 1 ~ 2% by weight of the ghost grass mixture was heated at 100-120 ℃ for 60-90 minutes, then cooled for 4-5 hours, the cooled mixture was again 150 Heating at 캜 and then cooling to separate the upper extract and precipitated sulfur;

(c) 15% by weight of radish in the separated sulfur of step (b), 1 to 2% by weight of green beans, 3 to 5% by weight of oak extract, 1 to 2% by weight of plum extract, 1-2% by weight of motherwort extract, goblin The mixture was heated at 100-120 ° C. for 60-90 minutes with the addition of 1-2% by weight of the paste and 200-250 L of Jijangsu, and then cooled again at 150 ° C. after cooling for 4-5 hours. Separating and precipitated sulfur; And

(d) is prepared by drying the sulfur separated in step (c), and again using the remaining 50% by weight (= 325kg) of the sulfur solution prepared in step (a) b), c) , and may be prepared through step d).

The present invention also relates to

(a) heating sulfur to add water and then preparing a sulfur solution;

(b) heating the mixture of radish juice, green beans, oak extract, plum extract, motherwort extract and sesame to the sulfur solution prepared in step (a), followed by cooling and separating the extract and precipitated sulfur; ;

(c) adding radish juice, mung bean, oak extract, plum extract, motherwort extract, gooseweed and water to the separated sulfur of step (b), followed by cooling to separate the extract from the precipitated sulfur; And

(d) it provides a method for producing a liquid sulfur formulation, characterized in that it comprises the step of mixing each extract separated in step (b) and (c).

Preferably, the method for preparing liquid sulfur of the present invention is

(a) mixing sulfur by heating sulfur at 80 to 160 ° C. for 50 to 70 minutes in a weight ratio of 1-1.5: 4-6 to prepare a sulfur solution;

(b) 20 ~ 30% by weight of juice, green bean 5 ~ 10% by weight, oak extract 3 ~ 5%, plum extract 1 ~ 2% by weight, motherwort extract 1 ~ 2% by weight, and the mixture of 1 ~ 2% by weight of the ghost grass was heated at 100-120 ℃ for 60-90 minutes and then cooled for 4-5 hours, the cooled mixture was again 100-150 Heating at 캜 and then cooling to separate the upper extract and precipitated sulfur;

(c) 10-20% by weight of sucrose in the separated sulfur of step (b), 1-2% by weight of mung beans, 3-5% by weight of oak extract, 1-2% by weight of plum extract, 1-2% by weight of motherwort extract , 1 ~ 2% by weight of bogeyweed and 400-600% by weight of Jijangsu were heated for 60 ~ 90 minutes at 100 ~ 120 ℃, and then heated again at 100 ~ 150 ℃ for 4 ~ 5 hours. Cooling to separate the upper extract and precipitated sulfur; And

(d) mixing the extracts separated in the steps (b) and (c), and

More preferably,

(a) heating the sulfur at 80 to 160 ° C. for 60 minutes to cool, and then putting 500 L of water into 150 kg of sulfur to prepare a sulfur solution;

(b) 20 ~ 30% by weight of radish juice, 5 ~ 10% by weight of mung bean, 3 ~ 5% by weight of oak extract, 1 ~ 2 weight of plum extract, compared to 50% by weight (= 325 kg) of the sulfur solution prepared in step (a) %, Motherwort extract 1-2% by weight, 1 ~ 2% by weight of the ghost grass mixture was heated at 100-120 ℃ for 60-90 minutes, then cooled for 4-5 hours, the cooled mixture was again 150 Heating at 캜 and then cooling to separate the upper extract and precipitated sulfur;

(c) 15% by weight of radish in the separated sulfur of step (b), 1 to 2% by weight of green beans, 3 to 5% by weight of oak extract, 1 to 2% by weight of plum extract, 1-2% by weight of motherwort extract, goblin The mixture was heated at 100-120 ° C. for 60-90 minutes with the addition of 1-2% by weight of the paste and 200-250 L of Jijangsu, and then cooled again at 150 ° C. after cooling for 4-5 hours. Separating and precipitated sulfur; And

(d) comprising the steps of mixing the respective extracts separated in step (b) and (c), and also using the remaining 50% by weight (= 325kg) of the sulfur solution prepared in step (a) It can be prepared again through steps b), c) and d).

In the manufacturing method of the process sulfur powder or liquid process sulfur of the present invention, the plum extract may be prepared by mixing the plum and sugar after ripening, the motherwort extract or extract of the mother tree can be prepared by hot water extraction of motherwort or oak tree However, the present invention is not limited thereto.

The present invention also provides a legal sulfur powder prepared by the above method.

The present invention also provides a liquid process sulfur produced by the above method.

The present invention also provides a method for producing livestock or aquatic product feed, which can enhance the growth rate and immunity, characterized in that by adding the legal sulfur powder to livestock or aquatic product feed.

In the method for preparing livestock or farmed aquatic feed of the present invention, the livestock may be pigs, cattle, ducks or chickens, the fish may be flatfish, salmon, sweetfish, mountain trout or trout, but is not limited thereto.

When the livestock is a pig, feeding sows with 0.08 to 0.12% of the legal sulfur powder in the feed from the initial feed after the feeding of the sows, the first 5 to 7 days smells a lot of money, but after that the smell of money Almost no growth as the epidermal color of the pig changes to pink, can be replaced by antibiotics resistant to various diseases, can be shipped earlier than the pigs not fed the sulfur of the present invention has a feed-saving effect.

In addition, if the livestock is poultry, such as ducks or chickens, immediately after hatching, the formulation of the legal sulfur powder in the feed to 0.8 ~ 0.1% of the feed weight has the advantage of less mortality and significantly reduce the smell of feces. It can replace antibiotics. In addition, the growth is fast and the meat quality is good and has a feed-saving effect.

In addition, when the livestock is a cow, the cow can be shipped for a long time, so the first three months from the beginning of the six months before the formulation of the legal sulfur powder to 0.1%, and the last three months to 0.15% of the feed weight When fed, grows well without the use of antibiotics and other medications, improves meat quality and improves feed rate, resulting in reduced feed.

In addition, if the formulation of the formulation sulfur powder 0.08 ~ 0.1% by weight of the aquatic product feed does not suffer from diseases without the use of antibiotics and other drugs, the meat quality is improved with rapid shipment, due to the water purification during the aquaculture It can help with other diseases.

The present invention also provides a method for cultivating crops having pest control, wherein the liquid sulfur is used at a place where crops are grown.

In the cultivation method of the crop of the present invention, the liquid phase sulfur may be diluted 200-300 times in water, preferably 250-fold diluted, but is not limited thereto.

In addition, in the cultivation method of the crop of the present invention, the crop may be strawberry, watermelon, melon, melon, tomato, cucumber or rice, but is not limited thereto.

In addition, in the cultivation method of the crop of the present invention, the disease may be gray mold, anthrax, brown rice, white leaf blight, powdery mildew, fungal nucleus or leaf fungal disease, but is not limited thereto.

Hereinafter, the present invention will be described in detail with reference to Production Examples and Examples. However, the following Preparation Examples and Examples are merely to illustrate the present invention, and the content of the present invention is not limited to the following Preparation Examples and Examples.

Manufacturing example  1: Process for preparing sulfur powder and liquid sulfur

(a) 500 L of water was put into 150 kg of sulfur heated at 80 to 160 ° C. for 1 hour to prepare a sulfur solution.

(b) 50 to 50% by weight of the sulfur solution prepared by 20% to 30% by weight of juice, green bean 5 to 10% by weight, oak extract 3 to 5% by weight, plum extract 1 to 2% by weight, motherwort extract 1 to 2% by weight , 1 to 2% by weight of the mixture was heated for 60 to 90 minutes at 100 ~ 120 ℃ and then cooled for 4 to 5 hours, the cooled mixture was heated again at 150 ℃ and cooled, the upper layer of The extract and precipitated sulfur were separated.

(c) 15% by weight of radish in the separated sulfur of step (b), 1 to 2% by weight of green beans, 3 to 5% by weight of oak extract, 1 to 2% by weight of plum extract, 1-2% by weight of motherwort extract, grass 1 to 2% by weight and 200-300L of ocher Jijisu water were added, and the mixture was heated at 100-120 ° C. for 60-90 minutes, and then cooled for 4-5 hours. And precipitated sulfur were separated.

(d) The sulfur separated in step (c) was dried to obtain a legal sulfur powder. Further, each of the separated extracts of steps (b) and (c) was mixed to obtain liquid legal sulfur.

Example  1: Frequency of Growth and Disease Occurrence of Pigs with Feeding Sulfur

In order to investigate the growth frequency and weaning frequency of weaned pigs according to the feed supplements with sulfur, 20 weeded piglets were disclosed. The treated group was treated with the processed sulfur powder by the method of the treated group (Preparation Example 1) and the manufacturing example 1 of the present invention, which was fed the feed containing 0.1% of the legal sulfur powder of the present invention to the weight of the feed from the initial feed after the breastfeeding was finished. Prepared, but without the juice, green beans, oak extract, plum extract, motherwort extract and sesame seedlings prepared by adding a dietary sulfur powder (control) added 0.1% of the feed fed control was repeated 10 times. The nutrient level of the experimental feed was in accordance with the recommended amount according to the NRC specification standard (1998), and the test period was performed for 6 weeks.

As a result, compared to the control, the treatment-treated sulfur powder prepared by the method of the present invention showed a higher weight gain per day than the control, and no disease occurred. Therefore, it could be confirmed that the preparation of the legal sulfur powder by the method of the present invention is economical because the food saving effect is increased due to the rapid shipment of pigs, and it can be used as an antibiotic replacement agent against various diseases.

Frequency of Growth and Disease Occurrence of Pigs with Feeding Sulfur Control Treatment tool (manufacturing example 1) Weight gain per day (g / day) 439 565 The number of diseases 2 0

Daily gain = (end weight-start weight) / 42

Example  2: plant pest control effect

Liquid formulation sulfur prepared by the method of Preparation Example 1 and the liquid formulation sulfur by the method of Preparation Example 1, but without the use of radish, green beans, oak extract, plum extract, motherwort extract and sesame beetle (Control) Each was mixed with PDA at a concentration of 5 mg / ml, autoclaved and dispensed into 9 cm Petri dishes to make a medium. Inoculate 5 mm each of the tip of Botrytis cinerea mycelium, which causes gray fungus disease of strawberry precultured on PDA in the prepared medium, and incubate for 4 days at 22 ° C incubator and compare the mycelial growth rate with the untreated. The antimicrobial activity was assayed and the results are shown in Table 2.

As a result, the treatment process (Manufacturing Example 1) treated with liquid phase sulfur produced by the method of the present invention compared to the treatment-free Botrytis cineraria ( Botrytis cinerea ) growth inhibition was 93%, which was higher than 76% of the control.

Botrytis Ceria cinerea ) growth inhibition effect (%) Production Example 1 Control Growth inhibition effect (%) 93% 76%

Claims (4)

(a) mixing sulfur by heating sulfur at 80 to 160 ° C. for 50 to 70 minutes in a weight ratio of 1-1.5: 4-6 to prepare a sulfur solution;
(b) 20 ~ 30% by weight of juice, green bean 5 ~ 10% by weight, oak extract 3 ~ 5%, plum extract 1 ~ 2% by weight, motherwort extract 1 ~ 2% by weight, and the mixture of 1 ~ 2% by weight of the ghost grass was heated at 100-120 ℃ for 60-90 minutes and then cooled for 4-5 hours, the cooled mixture was again 100-150 Heating at 캜 and then cooling to separate the upper extract and precipitated sulfur;
(c) 10 ~ 20% by weight of radish, 1 ~ 2% by weight of green beans, 3 ~ 5% by weight of oak extract, 1 ~ 2% by weight of plum extract, motherwort extract 1 ~ 2 100% by weight, 1 ~ 2% by weight, and 400-600% by weight of ocher liquor were additionally heated at 100-120 ° C. for 60-90 minutes, and then the mixture was cooled for 4-5 hours. Heating at ˜150 ° C. and then cooling to separate the upper extract and precipitated sulfur;
(d) a method for producing a liquid phase sulfur formulation, comprising the step of mixing the respective extracts separated in the step (b) and (c).
Liquid sulfur prepared by the method of claim 1. delete delete

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