KR100901064B1 - Method for manufacturing of nonpoisonous sulfur - Google Patents

Abstract

A method for producing non-toxic sulfur is provided to produce non-toxic sulfur at low cost by mixing radish juice, pine needle juice, Aralia elata juice, persimmon vinegar, calcium carbonate, acetic acid and sulfur water. A method for producing non-toxic sulfur comprises the following steps of: heating sulfur at 100°C~150°C for 30~50 minutes(S10); dissolving 100~200g of heated sulfur in 1 litter of water to obtain sulfur water(S20); mixing 41~60wt% of sulfur water, 15~25wt% of radish juice, 9~17wt% of pine needle juice, 8~12wt% of Aralia elata juice and 4~5wt% of persimmon vinegar to prepare a first mixed liquid(S30); aging 96~97wt% of the first mixed liquid and 3~4wt% of calcium carbonate at 120°C~180°C for 2~3 hours to prepare a second mixed liquid(S40); mixing 98~99wt% of the second mixed liquid and 1~2wt% of acetic acid to prepare a third mixed liquid(S50); heating the third mixed liquid at 60~80°C for 2~3 hours(S60); and standing the third mixed liquid at room temperature for 24 hours or more and cooling and precipitating the third mixed liquid(S70).

Description

Method for manufacturing of nonpoisonous sulfur

The present invention removes harmful components from the toxic mineral sulfur and mixes them with livestock feed to allow the livestock to ingest, thereby improving meat quality while increasing the growth rate and immunity of the livestock, and preventing and preventing various adult diseases in the human body ingesting the same. It relates to a method for producing non-toxic sulfur that can heal and improve health.

Modern people who have been exposed to many pollutions due to the development of science are absorbed into the human body in a polluted state by being exposed to a lot of toxic substances along with the polluted living environment. It is noted that it causes harm or causes various adult diseases.

In addition, in the livestock industry, a large amount of growth accelerators, antibiotics, hormones, and the like are used to promote the growth of livestock, and thus, livestock animals become weakly immune to diseases, and thus have a problem of being easily diseased.

Sulfur is known to be effective in relieving the toxicity of heavy metals, pesticides, and other chemicals that cause cancer and various incurable diseases. In the Dongbobogam, sulfur has a lot of heat and is toxic, but it drives cold air in the body. It is known to help the bodhisattva, to control the capture and fraud of the heart, to release the solitary, and to evaluate the weakness of sulfur in the classical Chinese literature. Therefore, the human body ingested the detoxified sulfur can see the effect, a safer way to provide a sulfur-ingested edible livestock. Therefore, there is a need to artificially supply an appropriate amount of sulfur to livestock with high deficiency of methyl sulfonyl methane.

Specifically, the components of natural sulfur strengthen the bones and joints of livestock and have a bactericidal action, and also minimize the smell of animal waste by reducing the components that cause odors such as ammonia and hydrogen sulfide, which are discharged from animal waste such as pig meal and milk powder. By decomposing nitrogen and phosphorus in livestock, it promotes rapid fermentation of livestock and smoothly supplies oxygen to the intestinal microorganisms, preventing invasion from various diseases, reducing mortality, and improving meat quality. Known. However, mineral sulfur is highly thermally toxic and has the effect of accumulating sulfur in the body when used as feed due to its strong toxicity and smell. There are many problems for livestock farmers.

However, mineral sulfur is very thermally toxic and cannot be surrendered without prior legal process, and life cannot be sustained by feeding unregulated sulfur to livestock or poultry.

For this reason, the conventional mineral sulfur supplied to livestock is applied only to ducks with good sulfur adaptation, and it is difficult to feed such mineral sulfur to pigs or cows with relatively low resistance to ducks.

Traditionally, sulfur has been heated and powdered for a certain time to remove harmful components of sulfur. However, the harmful components remain unneutralized, and when livestock or poultry are bred, more than 50% of them are killed. Due to the large amount of usage, care must be taken to ensure that the usage is limited.

In order to use sulfur more safely, various methods have been tried to effectively remove sulfur toxicity. For example, Korean Patent Publication No. 10-2002-74431 "Sulphur free from harmful components and its manufacturing method", Patent Registration 10-795663 "Sulfur free from toxicity and its manufacturing method and health food using the same", Patent Registration 10-655504 " Sulfur detoxification method, patent registration 10-843625, "Sulfur-free antibiotic free meat production method", patent registration 10-793815, "Method for removing sulfur toxicity." However, these techniques require significant time to neutralize a significant amount of harmful components by entering the manufacturing process in the absence of sulfur heating, and in addition to the vegetable mixtures for lower legislation, neutralizes toxic or acidity (pH) directly. There was no way to control the problem, so there was a problem with the full legal efficiency.

The present invention is to solve the problems associated with edible sulfur as described above, by first heating the sulfur used in the formulation to reduce harmful components primarily, calcium carbonate (CaCO in addition to the vegetable mixture mixed for the formulation) ₃ ) and neutralization and pH can be controlled by using acetic acid (CH ₃ COOH), even if feed to livestock, poultry, and farmed fish without any harm to the animals that consume it, growth rate and immunity It is to provide a method of producing non-toxic sulfur that can be increased, as well as beneficial to the human body ingesting it.

Yet another object of the present invention is to provide a method for producing non-toxic sulfur at a low cost due to the simple manufacturing method.

Technical features of non-toxic sulfur to achieve the intended purpose of the present invention is to heat the dissolution tank to a temperature of 100 ℃ ~ 150 ℃ for 30 to 50 minutes, and then the cooled gray-white sulfur is dissolved in 100 ~ 200g per liter of water 41-60% by weight of sulfurized water; 15-25 wt% juice; Pine needle juice 9-17 wt%; 8-12% by weight of mandarin juice; 4-5 wt% persimmon vinegar; Calcium carbonate (CaCO ₃ ) 3-4% by weight; Acetic acid (CH ₃ COOH) 1 to 2% by weight is mixed in stages.

The method for producing the non-toxic sulfur may include a first step (S10) of heating sulfur at a temperature of 100 ° C. to 150 ° C. for 30 to 50 minutes; A second step (S20) of dissolving sulfur obtained in the first step (S10) per 100 liters of water per liter of water to obtain sulfur water; 41 to 60% by weight of sulfur water obtained in the second step (S20), 15-25% by weight of radish juice, 9-17% by weight of pine needles juice, 8-12% by weight of mandarin juice, 4-5% by weight of persimmon vinegar A third step (S30) of forming a primary mixed solution by mixing; After adding 3-4 weight% of basic calcium carbonate (CaCO ₃ ) to 96-97 weight% of the primary mixed solution obtained in the third step (S30), and heated to a temperature of 120 ℃ ~ 180 ℃ for 2 to 3 hours A fourth step (S40) of stirring and aging to obtain a secondary mixed solution; A fifth step (S50) of obtaining a neutralized tertiary mixed solution by adding 1 to 2 wt% of acetic acid (CH ₃ COOH) to 98 to 99 wt% of the secondary mixed solution obtained in the fourth step (S40); A sixth step (S60) of heating and terminating the third mixed solution obtained in the fifth step (S50) at a temperature of 60 to 80 ° C for 2-3 hours; And the third mixture solution aged in the sixth step (S60) is left to stand at room temperature for more than 24 hours to cool and settle, and by the seventh step (S70) to take the mixed solution of the precipitate is removed.

The mixing ratio of radish juice, pine needle juice, ulmul juice, persimmon vinegar, calcium carbonate, and acetic acid is limited to a quantity set to remove satisfactory poison from sulfur through several repeated experiments. When the primary mixed solution is formed in excess or less than the limited amount, the detoxification time takes a long time and satisfactory state is not removed.

In the case of sulfur, in particular, sulfur is added in an amount of 41% by weight or more in consideration of the economic and efficient aspects of sulfur poisoning. However, when 60% by weight or more of sulfur is added, the finished sulfur is severely disgusting and harmful substances are not removed to the satisfaction of the use, which is impossible. Therefore, sulfur is most preferably added 41 to 60% by weight based on the total weight of the mixed solution.

In addition, in the step of aging the mixture, if the temperature is set to 60 ℃ or less, the aging is not properly made, and if it is set at a temperature of 80 ℃ or more, the components such as excessively evaporated persimmon vinegar and acetic acid components change, such as 60 ~ 80 ℃ temperature It is desirable to maintain.

In addition, when the aging time is 2 hours or less, the poison of sulfur is not removed as long as a predetermined effect can be obtained, and the toxic effect is not significantly different from 3 hours or more. Therefore, the aging time is most preferably 2-3 hours. At this time, it is preferable to ripen while stirring so that rapid and uniform aging.

The aged solution is cooled slowly, preferably left for at least 1 hour to settle down at the bottom, and then remove the precipitate to spray on livestock feed.

The non-toxic sulfur of the present invention prepared by the above method can be administered to feed for poultry and farmed fish as well as conventional livestock feed.

According to the present invention, by supplying non-toxic sulfur having a high production rate and low production cost, it is possible to supply general-purpose sulfur which can be used as an additive for pest control agents used for controlling pests of crops, horticulture and fruit trees. Feeding sulfur in feed for livestock and fish farms such as pigs, cows, and chickens can increase the content of non-toxic sulfur accumulated in pork, beef, and poultry. It can prevent and improve livestock growth and productivity. In addition, by reducing the odor generating components such as ammonia, hydrogen sulfide, etc. discharged from livestock, the odor of the livestock can be minimized, by promoting the rapid fermentation of livestock by decomposing nitrogen and phosphorus in the feces, and smooth oxygen to the intestinal microorganisms Feeding promotes digestion and absorption of feed, and ultimately, the sulfur content, which is a beneficial nutrient for the human body, can be easily consumed through edible livestock.

According to the present invention, by supplying non-toxic sulfur having high yield and low production cost, it is possible to supply general-purpose non-toxic sulfur which can be used as an additive of pest control agent used for controlling pests of crops, horticulture and fruit trees. In addition, by feeding non-toxic sulfur in the feed of livestock such as pigs, cows, chickens, etc., the non-toxic sulfur content that is beneficial to the human body can be easily ingested by increasing the content of non-toxic sulfur accumulated in pork, beef, and poultry. There is. In addition, by feeding non-toxic sulfur to livestock such as pigs, cows and chickens can improve the growth and productivity of livestock to contribute to the producers' profits.

Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.

Step 1 ( S10 )

While the burner is equipped, mineral sulfur is put into the dissolution tank with brown salt on the bottom surface, and the temperature in the dissolution tank is heated at a temperature of 100 ° C. to 150 ° C. for 30 to 50 minutes while all outlets are closed. Cool. At this time, the thermally toxic toxic gas and sulfurous acid gas generated from the sulfur in the dissolution tank is introduced into the cooler through a separate discharge pipe and then condensed and recovered.

Second step ( S20 )

The grayish white sulfur obtained in the first step (S10) is present in the form of a small lump of chromium, pulverized into a powder state passing through the 300 mesh in the pulverizer, and then dissolved in 100 ~ 200g per liter of water to obtain sulfur water.

At this time, it is preferable to use distilled water as water, and more preferably, Jiji water is used.

Step 3 ( S30 )

41-60% by weight of sulfur water obtained in the second step (S20), 15-25% by weight of radish, 9-17% by weight of pine needles juice, 8-12% by weight of mandarin juice, 4-5% by weight of persimmon vinegar Mix the mixture for 10 to 20 minutes at 60 to 100 rpm in a stirrer at room temperature to form a primary mixed solution.

Here, radish juice, pine needle juice, and mandarin juice serve to reduce the toxicity of sulfur. The natural appearance is selected from those collected in good condition, which is ground in a grinder without mixing water, and then extracted in a compactor. Is used.

Step 4 ( S40 )

96 to 97% by weight of the first mixed solution prepared in the third step (S30) and 3 to 4% by weight of calcium carbonate (CaCO ₃ ) are mixed at 60 to 80 rpm in a stirrer at a temperature of 120 to 180 ° C. Heat aging for a time to form a secondary mixed solution. The basic calcium carbonate serves to reduce the toxicity of sulfur, and is preferably added separately from the above-mentioned radish juice, pine needle juice, arbor juice, and persimmon vinegar.

Step 5 ( S50 )

98-99% by weight of the secondary mixed solution prepared in the fourth step (S40) and 1-2% by weight of acetic acid (CH ₃ COOH) at 60-80 rpm in a stirrer at room temperature to neutralize the tertiary mixed solution To create.

Sixth Step (S60)

The tertiary mixed solution prepared in the fifth step (S50) is aged by stirring and heating at 60 to 80 ℃ for 2 to 3 hours at 60 to 80 rpm in a stirrer.

Seventh Step (S70)

The third mixture solution aged in the sixth step (S60) is left at room temperature for at least 24 hours to cool and precipitate to obtain non-toxic sulfur in a separated state of precipitate.

According to the heating temperature of sulfur, the yield of removing harmful components is shown in Table 1 below.

Heating temperature 80 ℃ 90 ℃ 100 ℃ Yield About 55% About 85% About 45%

The results of measuring the main mineral and specific gravity by x-ray imaging of non-toxic sulfur and general sulfur of the present application prepared by the above method are shown in Table 2 below.

sample The main mineral importance Sulfur α-S 2.179 Sulfur treatment α-S 2.115

As a result of the measurement, both the main sulfur of the treated sulfur and the general sulfur of the present invention were α-S, but there was no change in the composition. This means that noxious components have been removed from the sulfur treated by the methods herein.

As described above, the present invention may be used by spraying and mixing 0.3 to 0.5 liters of the mixed solution of the present invention per kilogram of feed in a final step in preparing a feed of livestock, poultry, fish, algae, etc. as a liquid state.

In order to confirm the legislation of the present invention, the composition obtained at each step of the treatment process is mixed with poultry feed, and the 100 chickens are divided into four groups, and the composition obtained at each manufacturing step is administered for 1 month, respectively, and the result is 3 months later. Is shown in Table 3 below.

Step by step status Number of surviving individuals Feeding sulfur water in the second stage 50 Mixed solution administration feed of the third stage 99 Feed neutralized mixed solution of the 4th step 100 Feed phase mixed fermented solution of the fifth stage 100

As a result of the administration experiment, about half survived in the sulfur water of the second stage, but 99 rats survived in the mixed solution of radish juice, pine needle juice, arbor juice, and persimmon vinegar in the third stage, and were neutralized by CaCo3 and CH3COOH. In the aged mixed solution, all 100 survived.

Although 99 lived in the feed administered with the mixed solution of the third stage, the mortality of the poultry was considerably lowered considering that the mortality in the general breeding process was 10-15%. You can see that it improves the chicken's immunity.

In addition, the chickens fed the feed fed the mixed solution showed a 1.5 times faster growth rate than the chickens fed the conventional feed, and the ammonia gas generation rate of the cages was also reduced by 70%.

In addition, it can be seen that the general fishy smell that appears in the poultry was eliminated and the elasticity and taste of meat were improved.

And the mixed solution of the present invention is supplied to the laying hens (産卵 鷄) to produce eggs and compare the results of the eggs produced from the laying hens are shown in Table 4 below.

Common Egg Egg which fed this invention Methionine (%) 0.373 0.425 Cystine (%) 0.303 0.334 Sulfur (ppm) 12.08 26.92 Heavy rain unit (HU) 44.12 78.64 Egg yolk coefficient 0.337 0.450 Eggshell thickness (mm) 0.380 0.366

As can be seen from the experimental results of Table 4, the eggs produced by feeding the sulfur feed of the present application compared to the normal eggs showed that the content of sulfur containing amino acid methionine (methionine) and cystine (cystine) and sulfur were much higher.

In the Haugh Unit, which measures the freshness of eggs, the average egg was measured as 44.12, but the sulfur feed-fed egg of the present application was 78.64, indicating that the freshness was much higher.

In egg yolk coefficient, the average egg was measured as 0.337, but the egg produced by feeding the sulfur feed of the present invention was measured to 0.450, the freshness of the egg produced by feeding the sulfur feed of the present application was found to be significantly higher.

In eggshell thickness, the average egg was measured as 0.380mm, but the egg produced by feeding the sulfur feed of the present application was 0.366mm, and the egg according to the present invention was found to be thin, but the breaking strength was rather high.

In addition, the sensory test of the egg produced by feeding the sulfur feed of the present application was not only egg yolk dark and good elasticity, there was no characteristic fishy smell and taste very good.

In addition, as a result of mixing non-toxic sulfur in fish feed and feeding it to loach farms, loach that is fed by feeding a general feed is often weakly infected with skin diseases or infectious diseases due to its weak immunity. Eel did not use growth accelerators or hormones, but the growth rate increased, and immunity increased despite the absence of antibiotics.

Therefore, non-toxic sulfur according to the present invention can be used as an additive to feeds of chickens, ducks, as well as cattle, pigs, fish can improve productivity and quality.

1 is a flow chart showing a manufacturing process of the present invention

Claims (2)

A first step (S10) of heating sulfur at a temperature of 100 ° C. to 150 ° C. for 30 to 50 minutes; A second step (S20) of dissolving sulfur obtained in the first step (S10) per 100 liters of water per liter of water to obtain sulfur water; 41 to 60% by weight of sulfur water obtained in the second step (S20) 15 to 25% by weight of radish juice, pine needles juice 9 to 17% by weight, 8 to 12% by weight, 4 ~ 5% by weight persimmon vinegar 1 A third step (S30) of forming a difference mixture solution; 96 to 97% by weight of the first mixed solution obtained in the third step (S30) and 3 to 4% by weight of calcium carbonate (CaCO ₃ ) were aged at a temperature of 120 ° C. to 180 ° C. for 2 to 3 hours to prepare a second mixed solution. Obtaining a fourth step (S40); A fifth step (S50) of obtaining a tertiary mixed solution in which 98 to 99% by weight of the secondary mixed solution obtained in the fourth step (S40) and 1-2% by weight of acetic acid (CH ₃ COOH) are mixed; A sixth step (S60) of aging the third mixed solution obtained in the fifth step (S50) by heating at a temperature of 60 to 80 ° C. for 2 to 3 hours; Method for producing a non-toxic sulfur, characterized in that it comprises a seventh step (S70) for taking the third mixture solution aged in the sixth step (S60) and cooled and precipitated by leaving at least 24 hours at room temperature. delete

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