KR20110058808A - 유기 태양 전지 제조를 위한 개선된 용매계 - Google Patents
유기 태양 전지 제조를 위한 개선된 용매계 Download PDFInfo
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- KR20110058808A KR20110058808A KR1020117005618A KR20117005618A KR20110058808A KR 20110058808 A KR20110058808 A KR 20110058808A KR 1020117005618 A KR1020117005618 A KR 1020117005618A KR 20117005618 A KR20117005618 A KR 20117005618A KR 20110058808 A KR20110058808 A KR 20110058808A
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- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/10—Deposition of organic active material
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F19/00—Integrated devices, or assemblies of multiple devices, comprising at least one photovoltaic cell covered by group H10F10/00, e.g. photovoltaic modules
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/30—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising bulk heterojunctions, e.g. interpenetrating networks of donor and acceptor material domains
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
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- H10K30/50—Photovoltaic [PV] devices
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/60—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation in which radiation controls flow of current through the devices, e.g. photoresistors
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- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
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- H10K85/113—Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
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- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
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| US9046408P | 2008-08-20 | 2008-08-20 | |
| US61/090,464 | 2008-08-20 |
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| EP (1) | EP2327116A1 (enExample) |
| JP (1) | JP2012500500A (enExample) |
| KR (1) | KR20110058808A (enExample) |
| WO (1) | WO2010021921A1 (enExample) |
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| KR20230116558A (ko) * | 2022-01-28 | 2023-08-04 | 한국과학기술연구원 | 수분차단막을 이용한 화합물의 형성방법, 및 이를 이용한 칼코파이라이트 화합물 박막과 태양전지의 제조방법 |
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Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4110263A1 (de) * | 1991-03-28 | 1992-10-01 | Hoechst Ag | Waessrige dispersion aus intrinsisch elektrisch leitfaehigen polyalkoxythiophenen, verfahren zu ihrer herstellung und ihre verwendung |
| US5331183A (en) * | 1992-08-17 | 1994-07-19 | The Regents Of The University Of California | Conjugated polymer - acceptor heterojunctions; diodes, photodiodes, and photovoltaic cells |
| US6166172A (en) * | 1999-02-10 | 2000-12-26 | Carnegie Mellon University | Method of forming poly-(3-substituted) thiophenes |
| US6454880B1 (en) * | 1999-09-29 | 2002-09-24 | Herbert (Lonny) A. Rickman, Jr. | Material for die casting tooling components, method for making same, and tooling components made from the material and process |
| KR20080110928A (ko) * | 2001-03-10 | 2008-12-19 | 메르크 파텐트 게엠베하 | 유기 반도체 용액 및 분산액 |
| US6602974B1 (en) * | 2001-12-04 | 2003-08-05 | Carnegie Mellon University | Polythiophenes, block copolymers made therefrom, and methods of forming the same |
| US7147936B2 (en) * | 2002-08-23 | 2006-12-12 | Agfa Gevaert | Layer configuration with improved stability to sunlight exposure |
| EP1566845A4 (en) * | 2002-11-28 | 2009-08-12 | Nippon Oil Corp | PHOTOELECTRIC CONVERSION ELEMENT |
| DE102004007777A1 (de) * | 2004-02-18 | 2005-09-08 | Covion Organic Semiconductors Gmbh | Lösungen organischer Halbleiter |
| DE102004023276A1 (de) * | 2004-05-11 | 2005-12-01 | Covion Organic Semiconductors Gmbh | Lösungen organischer Halbleiter |
| KR20070102661A (ko) * | 2004-09-24 | 2007-10-19 | 플렉스트로닉스, 인크 | 광기전 전지에서의 헤테로 원자를 갖는 위치 규칙적폴리(3-치환 티오펜) |
| WO2006086480A2 (en) * | 2005-02-10 | 2006-08-17 | Plextronics, Inc. | Hole injection/transport layer compositions and devices |
| WO2006101953A2 (en) * | 2005-03-16 | 2006-09-28 | Plextronics, Inc. | Copolymers of soluble poly (thiophenes) with improved electronic performance |
| JP5193851B2 (ja) * | 2005-04-01 | 2013-05-08 | カーネギー メロン ユニバーシティ | レジオレギュラーポリマー、ポリチオフェンおよびブロックコポリマーを含む導電性ポリマーのリビング合成法 |
| US9136489B2 (en) * | 2006-05-02 | 2015-09-15 | Mitsubishi Chemical Corporation | Method for producing organic photoelectric conversion device and organic photoelectric conversion device |
| WO2008066933A2 (en) * | 2006-12-01 | 2008-06-05 | The Regents Of The University Of California | Enhancing performance characteristics of organic semiconducting films by improved solution processing |
| US20080299293A1 (en) * | 2007-05-02 | 2008-12-04 | Plextronics, Inc. | Solvent system for conjugated polymers |
| US8227691B2 (en) * | 2007-10-31 | 2012-07-24 | The Regents Of The University Of California | Processing additives for fabricating organic photovoltaic cells |
| KR101683026B1 (ko) * | 2008-04-11 | 2016-12-07 | 닛산 가가쿠 고교 가부시키 가이샤 | 도핑된 공액 중합체, 소자, 및 소자의 제조 방법 |
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- 2009-08-14 KR KR1020117005618A patent/KR20110058808A/ko not_active Ceased
- 2009-08-14 JP JP2011523885A patent/JP2012500500A/ja not_active Withdrawn
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20200100875A (ko) * | 2012-06-19 | 2020-08-26 | 캠브리지 디스플레이 테크놀로지 리미티드 | 반도체 층을 제조하는 방법 |
| KR20230116558A (ko) * | 2022-01-28 | 2023-08-04 | 한국과학기술연구원 | 수분차단막을 이용한 화합물의 형성방법, 및 이를 이용한 칼코파이라이트 화합물 박막과 태양전지의 제조방법 |
Also Published As
| Publication number | Publication date |
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| EP2327116A1 (en) | 2011-06-01 |
| JP2012500500A (ja) | 2012-01-05 |
| WO2010021921A1 (en) | 2010-02-25 |
| US20100043876A1 (en) | 2010-02-25 |
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