KR20080049067A

KR20080049067A - 중합체 용융물의 유동성을 개선하는 방법

중합체 용융물의 유동성을 개선하는 방법 Download PDF

Info

Publication number: KR20080049067A
Authority: KR; South Korea
Prior art keywords: alkyl; substituted; unsubstituted; acid; amino
Prior art date: 2005-09-28
Legal status : Ceased

Application number

KR1020087007235A

Other languages

English (en)

Korean (ko)

Inventor

클라우스 스톨

쿠르트 호프만

브루노 로칭게르

한스-베르너 쉬미드트

Original Assignee

시바 홀딩 인코포레이티드

Priority date

2005-09-28

Filing date

2006-09-21

Publication date

2008-06-03

2006-09-21 Application filed by 시바 홀딩 인코포레이티드 filed Critical 시바 홀딩 인코포레이티드

2008-06-03 Publication of KR20080049067A publication Critical patent/KR20080049067A/ko

Status Ceased legal-status Critical Current

Links

239000000155 melt Substances 0.000 title claims abstract description 19
229920000642 polymer Polymers 0.000 title description 70
239000000654 additive Substances 0.000 claims abstract description 92
230000000996 additive effect Effects 0.000 claims abstract description 63
238000000034 method Methods 0.000 claims abstract description 47
229920001169 thermoplastic Polymers 0.000 claims abstract description 31
150000002894 organic compounds Chemical class 0.000 claims abstract description 11
239000007787 solid Substances 0.000 claims abstract description 10
229910010272 inorganic material Inorganic materials 0.000 claims abstract description 4
150000002484 inorganic compounds Chemical class 0.000 claims abstract description 3
238000010309 melting process Methods 0.000 claims abstract description 3
-1 hydroxy, amino Chemical group 0.000 claims description 222
125000000217 alkyl group Chemical group 0.000 claims description 112
239000000203 mixture Substances 0.000 claims description 42
239000002253 acid Substances 0.000 claims description 32
125000004432 carbon atom Chemical group C* 0.000 claims description 32
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 24
150000001875 compounds Chemical class 0.000 claims description 23
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 21
229920006395 saturated elastomer Polymers 0.000 claims description 21
125000003277 amino group Chemical group 0.000 claims description 18
125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 17
125000005842 heteroatom Chemical group 0.000 claims description 16
125000001181 organosilyl group Chemical group [SiH3]* 0.000 claims description 14
125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 claims description 13
125000003118 aryl group Chemical group 0.000 claims description 13
239000000126 substance Substances 0.000 claims description 13
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 12
125000000753 cycloalkyl group Chemical group 0.000 claims description 12
239000000600 sorbitol Substances 0.000 claims description 12
239000004743 Polypropylene Substances 0.000 claims description 11
229920000768 polyamine Polymers 0.000 claims description 11
238000012545 processing Methods 0.000 claims description 11
239000004698 Polyethylene Substances 0.000 claims description 10
229910052736 halogen Inorganic materials 0.000 claims description 10
229920000573 polyethylene Polymers 0.000 claims description 10
KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 9
150000007513 acids Chemical class 0.000 claims description 9
125000001931 aliphatic group Chemical group 0.000 claims description 9
150000002367 halogens Chemical class 0.000 claims description 9
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 9
238000002425 crystallisation Methods 0.000 claims description 8
230000008025 crystallization Effects 0.000 claims description 8
125000004493 2-methylbut-1-yl group Chemical group CC(C*)CC 0.000 claims description 7
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 7
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 7
125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 claims description 7
238000002844 melting Methods 0.000 claims description 7
230000008018 melting Effects 0.000 claims description 7
125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 7
239000001301 oxygen Substances 0.000 claims description 7
229910052760 oxygen Inorganic materials 0.000 claims description 7
125000003538 pentan-3-yl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])[H] 0.000 claims description 7
229920001155 polypropylene Polymers 0.000 claims description 7
125000002577 pseudohalo group Chemical group 0.000 claims description 7
125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 7
125000003548 sec-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 7
125000001973 tert-pentyl group Chemical group [H]C([H])([H])C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 7
125000003542 3-methylbutan-2-yl group Chemical group [H]C([H])([H])C([H])(*)C([H])(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 6
125000003860 C1-C20 alkoxy group Chemical group 0.000 claims description 6
239000004215 Carbon black (E152) Substances 0.000 claims description 6
239000006057 Non-nutritive feed additive Substances 0.000 claims description 6
125000002723 alicyclic group Chemical group 0.000 claims description 6
238000001125 extrusion Methods 0.000 claims description 6
238000013467 fragmentation Methods 0.000 claims description 6
238000006062 fragmentation reaction Methods 0.000 claims description 6
229930195733 hydrocarbon Natural products 0.000 claims description 6
238000004519 manufacturing process Methods 0.000 claims description 6
125000003358 C2-C20 alkenyl group Chemical group 0.000 claims description 5
125000005428 anthryl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C3C(*)=C([H])C([H])=C([H])C3=C([H])C2=C1[H] 0.000 claims description 5
125000002529 biphenylenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3C12)* 0.000 claims description 5
125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 claims description 5
125000001624 naphthyl group Chemical group 0.000 claims description 5
125000000649 benzylidene group Chemical group [H]C(=[*])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 4
125000002941 2-furyl group Chemical group O1C([*])=C([H])C([H])=C1[H] 0.000 claims description 3
125000004189 3,4-dichlorophenyl group Chemical group [H]C1=C([H])C(Cl)=C(Cl)C([H])=C1* 0.000 claims description 3
125000003682 3-furyl group Chemical group O1C([H])=C([*])C([H])=C1[H] 0.000 claims description 3
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
WLYPBMBWKYALCG-UHFFFAOYSA-N [2,4-bis(trifluoromethyl)phenyl]boronic acid Chemical group OB(O)C1=CC=C(C(F)(F)F)C=C1C(F)(F)F WLYPBMBWKYALCG-UHFFFAOYSA-N 0.000 claims description 3
KPCZJLGGXRGYIE-UHFFFAOYSA-N [C]1=CC=CN=C1 Chemical group [C]1=CC=CN=C1 KPCZJLGGXRGYIE-UHFFFAOYSA-N 0.000 claims description 3
SZPWXAOBLNYOHY-UHFFFAOYSA-N [C]1=CC=NC2=CC=CC=C12 Chemical group [C]1=CC=NC2=CC=CC=C12 SZPWXAOBLNYOHY-UHFFFAOYSA-N 0.000 claims description 3
125000003545 alkoxy group Chemical group 0.000 claims description 3
125000003282 alkyl amino group Chemical group 0.000 claims description 3
125000005332 alkyl sulfoxy group Chemical group 0.000 claims description 3
125000004414 alkyl thio group Chemical group 0.000 claims description 3
125000002619 bicyclic group Chemical group 0.000 claims description 3
125000004772 dichloromethyl group Chemical group [H]C(Cl)(Cl)* 0.000 claims description 3
125000000623 heterocyclic group Chemical group 0.000 claims description 3
125000001165 hydrophobic group Chemical group 0.000 claims description 3
230000003993 interaction Effects 0.000 claims description 3
125000006340 pentafluoro ethyl group Chemical group FC(F)(F)C(F)(F)* 0.000 claims description 3
229910052717 sulfur Inorganic materials 0.000 claims description 3
239000011593 sulfur Substances 0.000 claims description 3
230000000903 blocking effect Effects 0.000 claims description 2
230000001747 exhibiting effect Effects 0.000 claims description 2
239000001257 hydrogen Substances 0.000 claims description 2
229910052739 hydrogen Inorganic materials 0.000 claims description 2
125000006501 nitrophenyl group Chemical group 0.000 claims description 2
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125000005843 halogen group Chemical group 0.000 claims 1
125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical class C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 49
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229910052757 nitrogen Inorganic materials 0.000 description 32
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 20
150000003254 radicals Chemical class 0.000 description 17
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LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
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150000001412 amines Chemical class 0.000 description 11
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239000002184 metal Substances 0.000 description 9
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QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 5
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