KR20050094839A - 브롬- 및 요오드-함유 플루오로플라스틱 중합체를 특징으로하는 동시 경화성 블렌드 - Google Patents
브롬- 및 요오드-함유 플루오로플라스틱 중합체를 특징으로하는 동시 경화성 블렌드 Download PDFInfo
- Publication number
- KR20050094839A KR20050094839A KR1020057012888A KR20057012888A KR20050094839A KR 20050094839 A KR20050094839 A KR 20050094839A KR 1020057012888 A KR1020057012888 A KR 1020057012888A KR 20057012888 A KR20057012888 A KR 20057012888A KR 20050094839 A KR20050094839 A KR 20050094839A
- Authority
- KR
- South Korea
- Prior art keywords
- curable
- blend
- combinations
- iodine
- fluoroplastic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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- 229920002313 fluoropolymer Polymers 0.000 title claims abstract description 75
- 239000000203 mixture Substances 0.000 title claims abstract description 55
- 229920000642 polymer Polymers 0.000 title claims description 12
- KURZCZMGELAPSV-UHFFFAOYSA-N [Br].[I] Chemical compound [Br].[I] KURZCZMGELAPSV-UHFFFAOYSA-N 0.000 title 1
- 239000000178 monomer Substances 0.000 claims abstract description 32
- 229920001973 fluoroelastomer Polymers 0.000 claims abstract description 30
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims abstract description 29
- 229920001971 elastomer Polymers 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 21
- 239000005060 rubber Substances 0.000 claims abstract description 21
- 150000002978 peroxides Chemical class 0.000 claims abstract description 17
- 239000004811 fluoropolymer Substances 0.000 claims abstract description 13
- 239000002245 particle Substances 0.000 claims abstract description 12
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 125000001246 bromo group Chemical group Br* 0.000 claims abstract description 9
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 19
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 18
- 229910052740 iodine Inorganic materials 0.000 claims description 16
- 239000004816 latex Substances 0.000 claims description 14
- 229920000126 latex Polymers 0.000 claims description 14
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 13
- 229910052794 bromium Inorganic materials 0.000 claims description 13
- 239000011630 iodine Substances 0.000 claims description 10
- 239000000155 melt Substances 0.000 claims description 7
- 239000011258 core-shell material Substances 0.000 claims description 6
- RRZIJNVZMJUGTK-UHFFFAOYSA-N 1,1,2-trifluoro-2-(1,2,2-trifluoroethenoxy)ethene Chemical class FC(F)=C(F)OC(F)=C(F)F RRZIJNVZMJUGTK-UHFFFAOYSA-N 0.000 claims description 5
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 238000012546 transfer Methods 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 239000012986 chain transfer agent Substances 0.000 claims description 3
- 150000002170 ethers Chemical class 0.000 claims description 3
- RWWUGYJWSVESJC-UHFFFAOYSA-N 1,4-dibromo-1,1,2,2,3,3,4,4-octafluorobutane Chemical compound FC(F)(Br)C(F)(F)C(F)(F)C(F)(F)Br RWWUGYJWSVESJC-UHFFFAOYSA-N 0.000 claims description 2
- FJBFPHVGVWTDIP-UHFFFAOYSA-N dibromomethane Chemical compound BrCBr FJBFPHVGVWTDIP-UHFFFAOYSA-N 0.000 claims description 2
- NZZFYRREKKOMAT-UHFFFAOYSA-N diiodomethane Chemical compound ICI NZZFYRREKKOMAT-UHFFFAOYSA-N 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- JILAKKYYZPDQBE-UHFFFAOYSA-N 1,1,2,2,3,3,4,4-octafluoro-1,4-diiodobutane Chemical compound FC(F)(I)C(F)(F)C(F)(F)C(F)(F)I JILAKKYYZPDQBE-UHFFFAOYSA-N 0.000 claims 1
- -1 bromotrifluoroethylene, iodotrifluoroethylene Chemical group 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract description 6
- 239000007787 solid Substances 0.000 description 16
- AYCANDRGVPTASA-UHFFFAOYSA-N 1-bromo-1,2,2-trifluoroethene Chemical group FC(F)=C(F)Br AYCANDRGVPTASA-UHFFFAOYSA-N 0.000 description 13
- 238000007720 emulsion polymerization reaction Methods 0.000 description 9
- 238000006116 polymerization reaction Methods 0.000 description 7
- 238000012360 testing method Methods 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 5
- OMNCMLIVRODHHP-UHFFFAOYSA-N 1,2,3,3,4,4,5,5-octafluoro-1-[1,2,3,3,4,4,5,5-octafluoro-5-(trifluoromethoxy)pent-1-enoxy]-5-(trifluoromethoxy)pent-1-ene Chemical compound FC(OC(F)=C(F)C(F)(F)C(F)(F)C(F)(F)OC(F)(F)F)=C(F)C(F)(F)C(F)(F)C(F)(F)OC(F)(F)F OMNCMLIVRODHHP-UHFFFAOYSA-N 0.000 description 4
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- 238000004876 x-ray fluorescence Methods 0.000 description 3
- BZPCMSSQHRAJCC-UHFFFAOYSA-N 1,2,3,3,4,4,5,5,5-nonafluoro-1-(1,2,3,3,4,4,5,5,5-nonafluoropent-1-enoxy)pent-1-ene Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)=C(F)OC(F)=C(F)C(F)(F)C(F)(F)C(F)(F)F BZPCMSSQHRAJCC-UHFFFAOYSA-N 0.000 description 2
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 2
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- 239000012935 ammoniumperoxodisulfate Substances 0.000 description 2
- YOALFLHFSFEMLP-UHFFFAOYSA-N azane;2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctanoic acid Chemical compound [NH4+].[O-]C(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YOALFLHFSFEMLP-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 231100000481 chemical toxicant Toxicity 0.000 description 2
- 238000000748 compression moulding Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
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- 229920003023 plastic Polymers 0.000 description 2
- 239000003505 polymerization initiator Substances 0.000 description 2
- 238000000518 rheometry Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000003440 toxic substance Substances 0.000 description 2
- BLTXWCKMNMYXEA-UHFFFAOYSA-N 1,1,2-trifluoro-2-(trifluoromethoxy)ethene Chemical compound FC(F)=C(F)OC(F)(F)F BLTXWCKMNMYXEA-UHFFFAOYSA-N 0.000 description 1
- NOSXUFXBUISMPR-UHFFFAOYSA-N 1-tert-butylperoxyhexane Chemical compound CCCCCCOOC(C)(C)C NOSXUFXBUISMPR-UHFFFAOYSA-N 0.000 description 1
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
- ODBCKCWTWALFKM-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhex-3-yne Chemical compound CC(C)(C)OOC(C)(C)C#CC(C)(C)OOC(C)(C)C ODBCKCWTWALFKM-UHFFFAOYSA-N 0.000 description 1
- YKTNISGZEGZHIS-UHFFFAOYSA-N 2-$l^{1}-oxidanyloxy-2-methylpropane Chemical group CC(C)(C)O[O] YKTNISGZEGZHIS-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- DVRZVZRBRMFOEG-UHFFFAOYSA-N BrC(C(C(=C(C(=C(F)F)F)F)F)(F)F)(F)F Chemical compound BrC(C(C(=C(C(=C(F)F)F)F)F)(F)F)(F)F DVRZVZRBRMFOEG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 238000011088 calibration curve Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
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- 230000000052 comparative effect Effects 0.000 description 1
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- 239000002826 coolant Substances 0.000 description 1
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- 238000004132 cross linking Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- WRIRWRKPLXCTFD-UHFFFAOYSA-N malonamide Chemical compound NC(=O)CC(N)=O WRIRWRKPLXCTFD-UHFFFAOYSA-N 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 125000005394 methallyl group Chemical group 0.000 description 1
- JPQBRSQJGWOTGC-UHFFFAOYSA-N methyl(silyloxysilyloxy)silane Chemical compound C[SiH2]O[SiH2]O[SiH3] JPQBRSQJGWOTGC-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- BLYOHBPLFYXHQA-UHFFFAOYSA-N n,n-bis(prop-2-enyl)prop-2-enamide Chemical compound C=CCN(CC=C)C(=O)C=C BLYOHBPLFYXHQA-UHFFFAOYSA-N 0.000 description 1
- DYUWTXWIYMHBQS-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCNCC=C DYUWTXWIYMHBQS-UHFFFAOYSA-N 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 230000036316 preload Effects 0.000 description 1
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- 238000003825 pressing Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 238000010074 rubber mixing Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000011257 shell material Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical compound NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- KJWHEZXBZQXVSA-UHFFFAOYSA-N tris(prop-2-enyl) phosphite Chemical compound C=CCOP(OCC=C)OCC=C KJWHEZXBZQXVSA-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/16—Homopolymers or copolymers or vinylidene fluoride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/53—Core-shell polymer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/18—Homopolymers or copolymers or tetrafluoroethene
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/340,969 US6734254B1 (en) | 2003-01-13 | 2003-01-13 | Co-curable blends featuring bromine-and iodine-containing fluoroplastic polymers |
| US10/340,969 | 2003-01-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20050094839A true KR20050094839A (ko) | 2005-09-28 |
Family
ID=32230023
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020057012888A Ceased KR20050094839A (ko) | 2003-01-13 | 2003-12-01 | 브롬- 및 요오드-함유 플루오로플라스틱 중합체를 특징으로하는 동시 경화성 블렌드 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6734254B1 (https=) |
| EP (1) | EP1583797B1 (https=) |
| JP (2) | JP4648005B2 (https=) |
| KR (1) | KR20050094839A (https=) |
| CN (1) | CN100372888C (https=) |
| AT (1) | ATE551396T1 (https=) |
| AU (1) | AU2003293192A1 (https=) |
| WO (1) | WO2004065482A1 (https=) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7312289B2 (en) * | 2003-03-03 | 2007-12-25 | Unimatec Co., Ltd. | Fluorine-containing elastomer and its composition |
| ATE546471T1 (de) * | 2003-03-25 | 2012-03-15 | 3M Innovative Properties Co | In der schmelze verarbeitbare thermoplastische fluorpolymere mit verbesserter verarbeitbarkeit und verfahren zu ihrer herstellung |
| US7354974B2 (en) * | 2004-05-20 | 2008-04-08 | Dupont Performance Elastomers Llc | Blends of perfluoroelastomers and fluoroplastics |
| ITMI20041253A1 (it) | 2004-06-22 | 2004-09-22 | Solvay Solexis Spa | Gel di fluoroelastomeri |
| ITMI20041251A1 (it) * | 2004-06-22 | 2004-09-22 | Solvay Solexis Spa | Gel di perfluoroelastomeri |
| CN101111538B (zh) * | 2004-12-30 | 2011-03-30 | 3M创新有限公司 | 氟聚合物纳米颗粒涂料组合物 |
| KR100607352B1 (ko) * | 2004-12-30 | 2006-07-31 | 주식회사 하이닉스반도체 | 리프레쉬 오실레이터 제어 회로 |
| US20070100062A1 (en) * | 2005-10-28 | 2007-05-03 | Lyons Donald F | Process for the manufacture of fluoroelastomers having bromine or lodine atom cure sites |
| JP5162818B2 (ja) * | 2005-11-17 | 2013-03-13 | ユニマテック株式会社 | 含フッ素共重合体ブレンド物 |
| US20070141305A1 (en) * | 2005-12-21 | 2007-06-21 | Toshihiro Kasai | Superhydrophobic coating |
| US20070141306A1 (en) * | 2005-12-21 | 2007-06-21 | Toshihiro Kasai | Process for preparing a superhydrophobic coating |
| ES2623436T3 (es) * | 2008-03-27 | 2017-07-11 | Daikin Industries, Ltd. | Composición de elastómero que contiene flúor reticulable con peróxido |
| EP2194094A1 (en) * | 2008-12-08 | 2010-06-09 | Solvay Solexis S.p.A. | (Per)fluoroelastomer composition |
| CN102120857A (zh) * | 2011-04-19 | 2011-07-13 | 铁岭蓝天橡胶制品有限公司 | 耐乙醇甲醇汽车燃油胶管防渗透内层胶胶料配方 |
| CN102558719B (zh) * | 2011-12-29 | 2014-07-02 | 中昊晨光化工研究院 | 一种耐低温含氟弹性体及其制备方法 |
| JP2018522113A (ja) | 2015-07-13 | 2018-08-09 | スリーエム イノベイティブ プロパティズ カンパニー | ヨウ素末端基を有するフッ素化熱硬化性プラスチック |
| EP3365389A4 (en) | 2015-10-23 | 2019-05-29 | 3M Innovative Properties Company | COMPOSITION WITH AMORPHIC FLUOROPOLYMER AND FLUOROON PLASTIC PARTICLES AND METHOD FOR THE PRODUCTION THEREOF |
| CN113195629A (zh) | 2018-12-20 | 2021-07-30 | 3M创新有限公司 | 非晶态全氟化聚合物的胶乳共混物以及来源于其的制品 |
| CN116710513A (zh) * | 2021-01-07 | 2023-09-05 | Nok株式会社 | 氟橡胶组合物和密封材料 |
| WO2023285909A1 (en) | 2021-07-12 | 2023-01-19 | 3M Innovative Properties Company | Fluoroelastomers with perfluorinated thermoplastic fillers |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4000356A (en) | 1972-06-19 | 1976-12-28 | Dynamit Nobel Aktiengesellschaft | Process for the preparation of thermoplastically workable fluoro-olefin polymers |
| DE2229607A1 (de) | 1972-06-19 | 1974-01-17 | Dynamit Nobel Ag | Verfahren zur herstellung von thermoplastisch verarbeitbaren fluorolefin-polymerisaten |
| US4277586A (en) | 1974-11-20 | 1981-07-07 | Asahi Glass Company, Ltd. | Process for preparing a propylene-tetrafluoroethylene copolymer |
| US4035565A (en) | 1975-03-27 | 1977-07-12 | E. I. Du Pont De Nemours And Company | Fluoropolymer containing a small amount of bromine-containing olefin units |
| US3987126A (en) * | 1975-07-31 | 1976-10-19 | E. I. Du Pont De Nemours And Company | Fluoroelastomer blend composition |
| JPS539848A (en) | 1976-07-16 | 1978-01-28 | Asahi Glass Co Ltd | Heat treatment of fluorine-containing elastomers |
| JPS53125491A (en) | 1977-04-08 | 1978-11-01 | Daikin Ind Ltd | Fluorine-containing polymer easily curable and its curable composition |
| IT1187684B (it) | 1985-07-08 | 1987-12-23 | Montefluos Spa | Procedimento per la preparazione di fluoroelastomeri vulcanizzabili e prodotti cosi' ottenuti |
| IT1235545B (it) | 1989-07-10 | 1992-09-09 | Ausimont Srl | Fluoroelastomeri dotati di migliore processabilita' e procedimento di preparazione |
| US5037921A (en) | 1990-03-01 | 1991-08-06 | E. I. Du Pont De Nemours And Company | Base resistant fluoroelastomers with improved processibility and curability |
| IT1255633B (it) | 1992-05-22 | 1995-11-09 | Ausimont Spa | Copolimeri fluoroelastomerici e fluoroplastomerici dotati di elevata resistenza alle basi |
| US5285002A (en) | 1993-03-23 | 1994-02-08 | Minnesota Mining And Manufacturing Company | Fluorine-containing polymers and preparation and use thereof |
| IT1265461B1 (it) | 1993-12-29 | 1996-11-22 | Ausimont Spa | Fluoroelastomeri comprendenti unita' monomeriche derivanti da una bis-olefina |
| IT1276979B1 (it) | 1995-10-20 | 1997-11-03 | Ausimont Spa | Composizioni fluoroelastomeriche |
| JP3867428B2 (ja) * | 1998-03-06 | 2007-01-10 | ユニマテック株式会社 | 含フッ素共重合体組成物 |
| KR100612706B1 (ko) | 1998-03-23 | 2006-08-16 | 다이네온 엘엘씨 | 퍼플루오르 탄성중합체 조성물 |
| US6203873B1 (en) | 1998-05-22 | 2001-03-20 | Dayco Products, Inc. | Blends of fluoroelastomer interpolymers with thermo fluoroplastic interpolymers and the use of such blends in hoses |
| IT1308627B1 (it) | 1999-02-23 | 2002-01-09 | Ausimont Spa | Composizioni fluoroelastomeriche. |
| IT1308628B1 (it) * | 1999-02-23 | 2002-01-09 | Ausimont Spa | Composizioni fluoroelastomeriche. |
| JP2001011272A (ja) * | 1999-07-02 | 2001-01-16 | Nippon Mektron Ltd | 含フッ素重合体組成物 |
| US6593416B2 (en) * | 2000-02-01 | 2003-07-15 | 3M Innovative Properties Company | Fluoropolymers |
| US6720360B1 (en) * | 2000-02-01 | 2004-04-13 | 3M Innovative Properties Company | Ultra-clean fluoropolymers |
| US6310141B1 (en) | 2000-06-27 | 2001-10-30 | Dyneon Llc | Fluoropolymer-containing compositions |
| JP4345214B2 (ja) * | 2000-09-20 | 2009-10-14 | ユニマテック株式会社 | 含フッ素共重合体組成物 |
| ITMI20011059A1 (it) * | 2001-05-22 | 2002-11-22 | Ausimont Spa | Composizioni fluoroelastomeriche |
| ITMI20011060A1 (it) * | 2001-05-22 | 2002-11-22 | Ausimont Spa | Composizioni fluoroelastomeriche |
| ITMI20011061A1 (it) * | 2001-05-22 | 2002-11-22 | Ausimont Spa | Composizioni fluoroelastomeriche |
-
2003
- 2003-01-13 US US10/340,969 patent/US6734254B1/en not_active Expired - Lifetime
- 2003-12-01 AU AU2003293192A patent/AU2003293192A1/en not_active Abandoned
- 2003-12-01 WO PCT/US2003/038111 patent/WO2004065482A1/en not_active Ceased
- 2003-12-01 EP EP03790183A patent/EP1583797B1/en not_active Expired - Lifetime
- 2003-12-01 CN CNB2003801086048A patent/CN100372888C/zh not_active Expired - Fee Related
- 2003-12-01 JP JP2004566925A patent/JP4648005B2/ja not_active Expired - Fee Related
- 2003-12-01 KR KR1020057012888A patent/KR20050094839A/ko not_active Ceased
- 2003-12-01 AT AT03790183T patent/ATE551396T1/de active
-
2010
- 2010-08-06 JP JP2010177611A patent/JP2010242108A/ja not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| JP2010242108A (ja) | 2010-10-28 |
| US6734254B1 (en) | 2004-05-11 |
| CN1735658A (zh) | 2006-02-15 |
| EP1583797A1 (en) | 2005-10-12 |
| ATE551396T1 (de) | 2012-04-15 |
| JP2006513300A (ja) | 2006-04-20 |
| EP1583797B1 (en) | 2012-03-28 |
| AU2003293192A1 (en) | 2004-08-13 |
| CN100372888C (zh) | 2008-03-05 |
| WO2004065482A1 (en) | 2004-08-05 |
| JP4648005B2 (ja) | 2011-03-09 |
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