KR20020060989A - 15족 화합물로부터 유도된 올레핀 중합 조촉매 및 상기조촉매를 이용하는 방법 - Google Patents

15족 화합물로부터 유도된 올레핀 중합 조촉매 및 상기조촉매를 이용하는 방법 Download PDF

Info

Publication number
KR20020060989A
KR20020060989A KR1020027007308A KR20027007308A KR20020060989A KR 20020060989 A KR20020060989 A KR 20020060989A KR 1020027007308 A KR1020027007308 A KR 1020027007308A KR 20027007308 A KR20027007308 A KR 20027007308A KR 20020060989 A KR20020060989 A KR 20020060989A
Authority
KR
South Korea
Prior art keywords
tetrakis
methyl
ammonium
propyl
perfluoroethyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
KR1020027007308A
Other languages
English (en)
Korean (ko)
Inventor
로드리구에즈조지
Original Assignee
엑손 케미칼 패턴츠 인코포레이티드
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 엑손 케미칼 패턴츠 인코포레이티드 filed Critical 엑손 케미칼 패턴츠 인코포레이티드
Publication of KR20020060989A publication Critical patent/KR20020060989A/ko
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/32—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D207/325—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with substituted hydrocarbon radicals directly attached to the ring nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D205/00—Heterocyclic compounds containing four-membered rings with one nitrogen atom as the only ring hetero atom
    • C07D205/02—Heterocyclic compounds containing four-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D205/04—Heterocyclic compounds containing four-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/04—Indoles; Hydrogenated indoles
    • C07D209/08—Indoles; Hydrogenated indoles with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to carbon atoms of the hetero ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/06—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by halogen atoms or nitro radicals
    • C07D295/073—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by halogen atoms or nitro radicals with the ring nitrogen atoms and the substituents separated by carbocyclic rings or by carbon chains interrupted by carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/02—Boron compounds
    • C07F5/027—Organoboranes and organoborohydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/54—Quaternary phosphonium compounds
    • C07F9/5442—Aromatic phosphonium compounds (P-C aromatic linkage)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
KR1020027007308A 1999-12-09 2000-12-11 15족 화합물로부터 유도된 올레핀 중합 조촉매 및 상기조촉매를 이용하는 방법 Ceased KR20020060989A (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US16987699P 1999-12-09 1999-12-09
US16976899P 1999-12-09 1999-12-09
US60/169,768 1999-12-09
US60/169,876 1999-12-09
PCT/US2000/033590 WO2001042249A1 (en) 1999-12-09 2000-12-11 Olefin polymerization cocatalysts derived from group-15 compounds and processes using them

Publications (1)

Publication Number Publication Date
KR20020060989A true KR20020060989A (ko) 2002-07-19

Family

ID=26865359

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020027007308A Ceased KR20020060989A (ko) 1999-12-09 2000-12-11 15족 화합물로부터 유도된 올레핀 중합 조촉매 및 상기조촉매를 이용하는 방법

Country Status (11)

Country Link
EP (2) EP1661900A1 (enExample)
JP (1) JP2004500359A (enExample)
KR (1) KR20020060989A (enExample)
CN (1) CN1413217A (enExample)
AT (1) ATE309252T1 (enExample)
BR (1) BR0016270A (enExample)
CA (1) CA2391855A1 (enExample)
DE (1) DE60023945T2 (enExample)
ES (1) ES2249320T3 (enExample)
MX (1) MXPA02005642A (enExample)
WO (1) WO2001042249A1 (enExample)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0021301D0 (en) 2000-08-30 2000-10-18 Borealis Tech Oy Supported catalyst
WO2003000740A2 (en) * 2001-06-20 2003-01-03 Exxonmobil Chemical Patents Inc. Polyolefins made by catalyst comprising a noncoordinating anion and articles comprising them
CN100516165C (zh) * 2003-05-12 2009-07-22 住友化学株式会社 发光聚合物组合物
US7872086B2 (en) 2008-01-17 2011-01-18 Tonen Chemical Corporation Polymeric material and its manufacture and use
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
US9234093B2 (en) 2008-03-31 2016-01-12 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizates
US8580902B2 (en) 2008-08-01 2013-11-12 Exxonmobil Chemical Patents Inc. Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom
US7799879B2 (en) 2008-08-01 2010-09-21 Exxonmobil Chemical Patents Inc. Catalyst system and process for olefin polymerization
CN103951769A (zh) 2008-08-01 2014-07-30 埃克森美孚化学专利公司 催化剂体系和用于烯烃聚合的方法
KR102022132B1 (ko) 2011-11-08 2019-09-17 유니베이션 테크놀로지즈, 엘엘씨 촉매 시스템의 제조 방법
EP3827033B1 (en) 2018-07-23 2025-01-01 ExxonMobil Chemical Patents Inc. Preparation of bimodal rubber, thermoplastic vulcanizates, and articles made therefrom
JP7205983B2 (ja) * 2019-05-17 2023-01-17 エルジー・ケム・リミテッド 無水炭化水素溶媒を用いた助触媒化合物の製造方法
KR102677352B1 (ko) 2019-10-28 2024-06-20 엑손모빌 케미칼 패턴츠 인코포레이티드 장쇄 알콕시 작용기를 갖는 양이온을 함유하는 비배위 음이온 활성화제
WO2022005634A1 (en) 2020-07-02 2022-01-06 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizate compositions containing metallocene multimodal copolymer rubber and processes for making same
WO2022045175A1 (ja) * 2020-08-28 2022-03-03 Ａｇｃ株式会社 含フッ素アルキルアンモニウムボレート化合物及びその製造方法
JP7713343B2 (ja) * 2020-10-23 2025-07-25 三井化学株式会社 第１３族元素含有化合物、オレフィン重合用触媒、およびオレフィン重合体の製造方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
JPH04366109A (ja) * 1991-06-12 1992-12-18 Idemitsu Kosan Co Ltd スチレン系重合体の製造方法及びその触媒
EP1110974B1 (en) * 1992-08-05 2007-11-28 ExxonMobil Chemical Patents Inc. Method for preparing a supported activator component
US5461127A (en) * 1992-09-22 1995-10-24 Idemitsu Kosan Co., Ltd. Polymerization catalysts and process for producing polymers
US5885924A (en) * 1995-06-07 1999-03-23 W. R. Grace & Co.-Conn. Halogenated supports and supported activators
EP0889912B1 (en) * 1996-03-27 2000-07-12 The Dow Chemical Company Highly soluble olefin polymerization catalyst activator
HU223376B1 (hu) * 1996-07-23 2004-06-28 Dow Global Technologies Inc. A 13. csoport vegyületét tartalmazó olefin polimerizációs katalizátor készítmények
JPH11316434A (ja) * 1998-05-01 1999-11-16 Konica Corp ハロゲン化銀カラー写真感光材料の画像形成方法及び画像情報記録方法

Also Published As

Publication number Publication date
MXPA02005642A (es) 2002-09-02
ES2249320T3 (es) 2006-04-01
WO2001042249A1 (en) 2001-06-14
JP2004500359A (ja) 2004-01-08
CA2391855A1 (en) 2001-06-14
EP1252166B1 (en) 2005-11-09
ATE309252T1 (de) 2005-11-15
DE60023945D1 (de) 2005-12-15
CN1413217A (zh) 2003-04-23
EP1661900A1 (en) 2006-05-31
BR0016270A (pt) 2002-08-13
DE60023945T2 (de) 2006-07-27
EP1252166A1 (en) 2002-10-30

Similar Documents

Publication Publication Date Title
US6147173A (en) Nitrogen-containing group 13 anionic complexes for olefin polymerization
CA2330529A1 (en) Olefin polymerization process using activated lewis acid-base complexes
EP1252166B1 (en) Olefin polymerization cocatalysts derived from group-15 cationic compounds and processes using them
US6489480B2 (en) Group-15 cationic compounds for olefin polymerization catalysts
JP2002544282A (ja) ジ−及びトリ−ヘテロ原子置換インデニル金属錯体
US6822057B2 (en) Olefin polymerization catalysts derived from Group-15 cationic compounds and processes using them
US6919291B2 (en) Fluorinated zwitterionic cocatalyst activators for olefin polymerization
EP1240170B1 (en) Carbenium cationic complexes suitable for polymerization catalysts
CA2412608A1 (en) Siloxy substituted cocatalyst activators for olefin polymerization
US6475946B1 (en) Olefin polymerization catalysis with aryl substituted carbenium cationic complexes
EP1268575B1 (en) Nitrogen-containing group-13 anionic compounds for olefin polymerization
US6909008B2 (en) Cocatalyst compositions
US6809209B2 (en) Nitrogen-containing group-13 anionic compounds for olefin polymerization
US6346636B1 (en) Siloxy substituted cocatalyst activators for olefin polymerization
US6476164B1 (en) Carbenium cationic complexes suitable for polymerization catalysts

Legal Events

Date Code Title Description
PA0105 International application

Patent event date: 20020607

Patent event code: PA01051R01D

Comment text: International Patent Application

PG1501 Laying open of application
A201 Request for examination
PA0201 Request for examination

Patent event code: PA02012R01D

Patent event date: 20051212

Comment text: Request for Examination of Application

E801 Decision on dismissal of amendment
PE0801 Dismissal of amendment

Patent event code: PE08012E01D

Comment text: Decision on Dismissal of Amendment

Patent event date: 20061110

Patent event code: PE08011R01I

Comment text: Amendment to Specification, etc.

Patent event date: 20051212

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

Comment text: Notification of reason for refusal

Patent event date: 20070223

Patent event code: PE09021S01D

E601 Decision to refuse application
PE0601 Decision on rejection of patent

Patent event date: 20070607

Comment text: Decision to Refuse Application

Patent event code: PE06012S01D

Patent event date: 20070223

Comment text: Notification of reason for refusal

Patent event code: PE06011S01I