KR20020060989A - 15족 화합물로부터 유도된 올레핀 중합 조촉매 및 상기조촉매를 이용하는 방법 - Google Patents

15족 화합물로부터 유도된 올레핀 중합 조촉매 및 상기조촉매를 이용하는 방법 Download PDF

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KR20020060989A
KR20020060989A KR1020027007308A KR20027007308A KR20020060989A KR 20020060989 A KR20020060989 A KR 20020060989A KR 1020027007308 A KR1020027007308 A KR 1020027007308A KR 20027007308 A KR20027007308 A KR 20027007308A KR 20020060989 A KR20020060989 A KR 20020060989A
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South Korea
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tetrakis
methyl
ammonium
propyl
perfluoroethyl
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Korean (ko)
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로드리구에즈조지
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엑손 케미칼 패턴츠 인코포레이티드
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Publication of KR20020060989A publication Critical patent/KR20020060989A/ko
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/32—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D207/325—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with substituted hydrocarbon radicals directly attached to the ring nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D205/00—Heterocyclic compounds containing four-membered rings with one nitrogen atom as the only ring hetero atom
    • C07D205/02—Heterocyclic compounds containing four-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D205/04—Heterocyclic compounds containing four-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/04—Indoles; Hydrogenated indoles
    • C07D209/08—Indoles; Hydrogenated indoles with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to carbon atoms of the hetero ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/06—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by halogen atoms or nitro radicals
    • C07D295/073—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by halogen atoms or nitro radicals with the ring nitrogen atoms and the substituents separated by carbocyclic rings or by carbon chains interrupted by carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/02—Boron compounds
    • C07F5/027—Organoboranes and organoborohydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/54—Quaternary phosphonium compounds
    • C07F9/5442—Aromatic phosphonium compounds (P-C aromatic linkage)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerization Catalysts (AREA)
KR1020027007308A 1999-12-09 2000-12-11 15족 화합물로부터 유도된 올레핀 중합 조촉매 및 상기조촉매를 이용하는 방법 Ceased KR20020060989A (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US16976899P 1999-12-09 1999-12-09
US16987699P 1999-12-09 1999-12-09
US60/169,876 1999-12-09
US60/169,768 1999-12-09
PCT/US2000/033590 WO2001042249A1 (en) 1999-12-09 2000-12-11 Olefin polymerization cocatalysts derived from group-15 compounds and processes using them

Publications (1)

Publication Number Publication Date
KR20020060989A true KR20020060989A (ko) 2002-07-19

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KR1020027007308A Ceased KR20020060989A (ko) 1999-12-09 2000-12-11 15족 화합물로부터 유도된 올레핀 중합 조촉매 및 상기조촉매를 이용하는 방법

Country Status (11)

Country Link
EP (2) EP1252166B1 (enExample)
JP (1) JP2004500359A (enExample)
KR (1) KR20020060989A (enExample)
CN (1) CN1413217A (enExample)
AT (1) ATE309252T1 (enExample)
BR (1) BR0016270A (enExample)
CA (1) CA2391855A1 (enExample)
DE (1) DE60023945T2 (enExample)
ES (1) ES2249320T3 (enExample)
MX (1) MXPA02005642A (enExample)
WO (1) WO2001042249A1 (enExample)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0021301D0 (en) * 2000-08-30 2000-10-18 Borealis Tech Oy Supported catalyst
WO2003000740A2 (en) 2001-06-20 2003-01-03 Exxonmobil Chemical Patents Inc. Polyolefins made by catalyst comprising a noncoordinating anion and articles comprising them
CN100516165C (zh) * 2003-05-12 2009-07-22 住友化学株式会社 发光聚合物组合物
US7872086B2 (en) 2008-01-17 2011-01-18 Tonen Chemical Corporation Polymeric material and its manufacture and use
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
US9234093B2 (en) 2008-03-31 2016-01-12 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizates
US7799879B2 (en) 2008-08-01 2010-09-21 Exxonmobil Chemical Patents Inc. Catalyst system and process for olefin polymerization
SG195587A1 (en) * 2008-08-01 2013-12-30 Exxonmobil Chem Patents Inc Catalyst system and process for olefin polymerization
US8580902B2 (en) * 2008-08-01 2013-11-12 Exxonmobil Chemical Patents Inc. Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom
US9234060B2 (en) 2011-11-08 2016-01-12 Univation Technologies, Llc Methods of preparing a catalyst system
EP3827033B1 (en) 2018-07-23 2025-01-01 ExxonMobil Chemical Patents Inc. Preparation of bimodal rubber, thermoplastic vulcanizates, and articles made therefrom
CN113164932B (zh) * 2019-05-17 2023-09-08 Lg化学株式会社 使用无水烃溶剂制备助催化剂化合物的方法
CN115916892A (zh) 2020-07-02 2023-04-04 国际人造丝公司 含有茂金属多峰共聚物橡胶的热塑性硫化橡胶组合物及其制造方法
WO2022045175A1 (ja) * 2020-08-28 2022-03-03 Ａｇｃ株式会社 含フッ素アルキルアンモニウムボレート化合物及びその製造方法
JP7713343B2 (ja) * 2020-10-23 2025-07-25 三井化学株式会社 第１３族元素含有化合物、オレフィン重合用触媒、およびオレフィン重合体の製造方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
JPH04366109A (ja) * 1991-06-12 1992-12-18 Idemitsu Kosan Co Ltd スチレン系重合体の製造方法及びその触媒
ES2167336T3 (es) * 1992-08-05 2002-05-16 Exxonmobil Chem Patents Inc Catalizadores ionicos soportados de metal de transicion para la polimerizacion de olefinas.
EP0591756B1 (en) * 1992-09-22 1998-11-25 Idemitsu Kosan Company Limited Polymerization catalysts and process for producing polymers
US5885924A (en) * 1995-06-07 1999-03-23 W. R. Grace & Co.-Conn. Halogenated supports and supported activators
RU2178422C2 (ru) * 1996-03-27 2002-01-20 Дзе Дау Кемикал Компани Активатор катализаторов полимеризации олефинов, каталитическая система и способ полимеризации
PL331324A1 (en) * 1996-07-23 1999-07-05 Dow Chemical Co Catalyst composition for polymerisation of olefins, containing a compound of a metal belonging to the group 13
JPH11316434A (ja) * 1998-05-01 1999-11-16 Konica Corp ハロゲン化銀カラー写真感光材料の画像形成方法及び画像情報記録方法

Also Published As

Publication number Publication date
MXPA02005642A (es) 2002-09-02
CA2391855A1 (en) 2001-06-14
EP1252166A1 (en) 2002-10-30
BR0016270A (pt) 2002-08-13
JP2004500359A (ja) 2004-01-08
ES2249320T3 (es) 2006-04-01
DE60023945D1 (de) 2005-12-15
EP1661900A1 (en) 2006-05-31
DE60023945T2 (de) 2006-07-27
EP1252166B1 (en) 2005-11-09
WO2001042249A1 (en) 2001-06-14
CN1413217A (zh) 2003-04-23
ATE309252T1 (de) 2005-11-15

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