JP2004500359A - １５族化合物から誘導されるオレフィン重合助触媒及びその使用法 - Google Patents

１５族化合物から誘導されるオレフィン重合助触媒及びその使用法 Download PDF

Info

Publication number
JP2004500359A
JP2004500359A JP2001543547A JP2001543547A JP2004500359A JP 2004500359 A JP2004500359 A JP 2004500359A JP 2001543547 A JP2001543547 A JP 2001543547A JP 2001543547 A JP2001543547 A JP 2001543547A JP 2004500359 A JP2004500359 A JP 2004500359A
Authority
JP
Japan
Prior art keywords
tetrakis
methyl
ammonium
borate
propyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP2001543547A
Other languages
English (en)
Japanese (ja)
Other versions
JP2004500359A5 (enExample
Inventor
ロドリゲス、ジョージ
Original Assignee
エクソンモービル・ケミカル・パテンツ・インク
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by エクソンモービル・ケミカル・パテンツ・インク filed Critical エクソンモービル・ケミカル・パテンツ・インク
Publication of JP2004500359A publication Critical patent/JP2004500359A/ja
Publication of JP2004500359A5 publication Critical patent/JP2004500359A5/ja
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/32—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D207/325—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with substituted hydrocarbon radicals directly attached to the ring nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D205/00—Heterocyclic compounds containing four-membered rings with one nitrogen atom as the only ring hetero atom
    • C07D205/02—Heterocyclic compounds containing four-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D205/04—Heterocyclic compounds containing four-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/04—Indoles; Hydrogenated indoles
    • C07D209/08—Indoles; Hydrogenated indoles with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to carbon atoms of the hetero ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/06—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by halogen atoms or nitro radicals
    • C07D295/073—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by halogen atoms or nitro radicals with the ring nitrogen atoms and the substituents separated by carbocyclic rings or by carbon chains interrupted by carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/02—Boron compounds
    • C07F5/027—Organoboranes and organoborohydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/54—Quaternary phosphonium compounds
    • C07F9/5442—Aromatic phosphonium compounds (P-C aromatic linkage)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerization Catalysts (AREA)
JP2001543547A 1999-12-09 2000-12-11 １５族化合物から誘導されるオレフィン重合助触媒及びその使用法 Withdrawn JP2004500359A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US16976899P 1999-12-09 1999-12-09
US16987699P 1999-12-09 1999-12-09
PCT/US2000/033590 WO2001042249A1 (en) 1999-12-09 2000-12-11 Olefin polymerization cocatalysts derived from group-15 compounds and processes using them

Publications (2)

Publication Number Publication Date
JP2004500359A true JP2004500359A (ja) 2004-01-08
JP2004500359A5 JP2004500359A5 (enExample) 2008-02-21

Family

ID=26865359

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2001543547A Withdrawn JP2004500359A (ja) 1999-12-09 2000-12-11 １５族化合物から誘導されるオレフィン重合助触媒及びその使用法

Country Status (11)

Country Link
EP (2) EP1252166B1 (enExample)
JP (1) JP2004500359A (enExample)
KR (1) KR20020060989A (enExample)
CN (1) CN1413217A (enExample)
AT (1) ATE309252T1 (enExample)
BR (1) BR0016270A (enExample)
CA (1) CA2391855A1 (enExample)
DE (1) DE60023945T2 (enExample)
ES (1) ES2249320T3 (enExample)
MX (1) MXPA02005642A (enExample)
WO (1) WO2001042249A1 (enExample)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013501843A (ja) * 2009-08-14 2013-01-17 エクソンモービル・ケミカル・パテンツ・インク 触媒系、オレフィン重合方法、及びそれから製造されたポリマー組成物
JP2022511901A (ja) * 2019-05-17 2022-02-01 エルジー・ケム・リミテッド 無水炭化水素溶媒を用いた助触媒化合物の製造方法
JPWO2022045175A1 (enExample) * 2020-08-28 2022-03-03
JP2022069397A (ja) * 2020-10-23 2022-05-11 三井化学株式会社 第１３族元素含有化合物、オレフィン重合用触媒、およびオレフィン重合体の製造方法

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0021301D0 (en) * 2000-08-30 2000-10-18 Borealis Tech Oy Supported catalyst
WO2003000740A2 (en) 2001-06-20 2003-01-03 Exxonmobil Chemical Patents Inc. Polyolefins made by catalyst comprising a noncoordinating anion and articles comprising them
CN100516165C (zh) * 2003-05-12 2009-07-22 住友化学株式会社 发光聚合物组合物
US7872086B2 (en) 2008-01-17 2011-01-18 Tonen Chemical Corporation Polymeric material and its manufacture and use
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
US9234093B2 (en) 2008-03-31 2016-01-12 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizates
US7799879B2 (en) 2008-08-01 2010-09-21 Exxonmobil Chemical Patents Inc. Catalyst system and process for olefin polymerization
SG195587A1 (en) * 2008-08-01 2013-12-30 Exxonmobil Chem Patents Inc Catalyst system and process for olefin polymerization
US9234060B2 (en) 2011-11-08 2016-01-12 Univation Technologies, Llc Methods of preparing a catalyst system
EP3827033B1 (en) 2018-07-23 2025-01-01 ExxonMobil Chemical Patents Inc. Preparation of bimodal rubber, thermoplastic vulcanizates, and articles made therefrom
CN115916892A (zh) 2020-07-02 2023-04-04 国际人造丝公司 含有茂金属多峰共聚物橡胶的热塑性硫化橡胶组合物及其制造方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
JPH04366109A (ja) * 1991-06-12 1992-12-18 Idemitsu Kosan Co Ltd スチレン系重合体の製造方法及びその触媒
ES2167336T3 (es) * 1992-08-05 2002-05-16 Exxonmobil Chem Patents Inc Catalizadores ionicos soportados de metal de transicion para la polimerizacion de olefinas.
EP0591756B1 (en) * 1992-09-22 1998-11-25 Idemitsu Kosan Company Limited Polymerization catalysts and process for producing polymers
US5885924A (en) * 1995-06-07 1999-03-23 W. R. Grace & Co.-Conn. Halogenated supports and supported activators
RU2178422C2 (ru) * 1996-03-27 2002-01-20 Дзе Дау Кемикал Компани Активатор катализаторов полимеризации олефинов, каталитическая система и способ полимеризации
PL331324A1 (en) * 1996-07-23 1999-07-05 Dow Chemical Co Catalyst composition for polymerisation of olefins, containing a compound of a metal belonging to the group 13
JPH11316434A (ja) * 1998-05-01 1999-11-16 Konica Corp ハロゲン化銀カラー写真感光材料の画像形成方法及び画像情報記録方法

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013501843A (ja) * 2009-08-14 2013-01-17 エクソンモービル・ケミカル・パテンツ・インク 触媒系、オレフィン重合方法、及びそれから製造されたポリマー組成物
JP2022511901A (ja) * 2019-05-17 2022-02-01 エルジー・ケム・リミテッド 無水炭化水素溶媒を用いた助触媒化合物の製造方法
JP7205983B2 (ja) 2019-05-17 2023-01-17 エルジー・ケム・リミテッド 無水炭化水素溶媒を用いた助触媒化合物の製造方法
US12318766B2 (en) 2019-05-17 2025-06-03 Lg Chem, Ltd. Method for preparing cocatalyst compound using anhydrous hydrocarbon solvent
TWI889682B (zh) * 2019-05-17 2025-07-11 南韓商Ｌｇ化學股份有限公司 使用無水烴溶劑製備輔觸媒化合物之方法
JPWO2022045175A1 (enExample) * 2020-08-28 2022-03-03
WO2022045175A1 (ja) * 2020-08-28 2022-03-03 Ａｇｃ株式会社 含フッ素アルキルアンモニウムボレート化合物及びその製造方法
JP7720505B2 (ja) 2020-08-28 2025-08-08 Ａｇｃ株式会社 含フッ素アルキルアンモニウムボレート化合物及びその製造方法
JP2022069397A (ja) * 2020-10-23 2022-05-11 三井化学株式会社 第１３族元素含有化合物、オレフィン重合用触媒、およびオレフィン重合体の製造方法
JP7713343B2 (ja) 2020-10-23 2025-07-25 三井化学株式会社 第１３族元素含有化合物、オレフィン重合用触媒、およびオレフィン重合体の製造方法

Also Published As

Publication number Publication date
MXPA02005642A (es) 2002-09-02
CA2391855A1 (en) 2001-06-14
EP1252166A1 (en) 2002-10-30
BR0016270A (pt) 2002-08-13
ES2249320T3 (es) 2006-04-01
DE60023945D1 (de) 2005-12-15
EP1661900A1 (en) 2006-05-31
KR20020060989A (ko) 2002-07-19
DE60023945T2 (de) 2006-07-27
EP1252166B1 (en) 2005-11-09
WO2001042249A1 (en) 2001-06-14
CN1413217A (zh) 2003-04-23
ATE309252T1 (de) 2005-11-15

Similar Documents

Publication Publication Date Title
US6147173A (en) Nitrogen-containing group 13 anionic complexes for olefin polymerization
JP5252714B2 (ja) プロピレンコポリマーを生産する方法
JP2003524013A (ja) オレフィン重合用助触媒として有用な有機金属化合物
JP2004500359A (ja) １５族化合物から誘導されるオレフィン重合助触媒及びその使用法
US6489480B2 (en) Group-15 cationic compounds for olefin polymerization catalysts
US6822057B2 (en) Olefin polymerization catalysts derived from Group-15 cationic compounds and processes using them
US6919291B2 (en) Fluorinated zwitterionic cocatalyst activators for olefin polymerization
EP1240170B1 (en) Carbenium cationic complexes suitable for polymerization catalysts
WO2002000738A1 (en) Siloxy substituted cocatalyst activators for olefin polymerization
US6541410B1 (en) Siloxy substituted cocatalyst activators for olefin polymerization
US6475946B1 (en) Olefin polymerization catalysis with aryl substituted carbenium cationic complexes
EP1268575B1 (en) Nitrogen-containing group-13 anionic compounds for olefin polymerization
US6809209B2 (en) Nitrogen-containing group-13 anionic compounds for olefin polymerization
US6909008B2 (en) Cocatalyst compositions
WO2003051892A1 (en) Partially fluorinated naphthyl-based borates
US6476164B1 (en) Carbenium cationic complexes suitable for polymerization catalysts
US6346636B1 (en) Siloxy substituted cocatalyst activators for olefin polymerization
JP3070257B2 (ja) オレフィン重合体の製造方法
JP3302415B2 (ja) 内部オレフィン重合用触媒及び内部オレフィン重合体の製造方法

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20071211

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20071217

A761 Written withdrawal of application

Free format text: JAPANESE INTERMEDIATE CODE: A761

Effective date: 20081125