CN1413217A - 由含第15族阳离子化合物衍生的烯烃聚合催化剂及其使用方法 - Google Patents
由含第15族阳离子化合物衍生的烯烃聚合催化剂及其使用方法 Download PDFInfo
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- CN1413217A CN1413217A CN00817575A CN00817575A CN1413217A CN 1413217 A CN1413217 A CN 1413217A CN 00817575 A CN00817575 A CN 00817575A CN 00817575 A CN00817575 A CN 00817575A CN 1413217 A CN1413217 A CN 1413217A
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- amine
- methyl
- perfluoro
- biphenyl
- phosphine
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- 150000001875 compounds Chemical class 0.000 title claims abstract description 64
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 44
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 20
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims abstract description 11
- 238000000034 method Methods 0.000 title claims description 25
- 230000008569 process Effects 0.000 title claims description 11
- -1 amine compounds Chemical class 0.000 claims abstract description 664
- 239000003054 catalyst Substances 0.000 claims abstract description 56
- 239000000178 monomer Substances 0.000 claims abstract description 27
- 150000001450 anions Chemical class 0.000 claims abstract description 25
- 125000002524 organometallic group Chemical group 0.000 claims abstract description 14
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 9
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims abstract description 8
- 150000001412 amines Chemical class 0.000 claims description 283
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims description 83
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 54
- 229910052731 fluorine Inorganic materials 0.000 claims description 43
- 239000011737 fluorine Substances 0.000 claims description 43
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims description 42
- 229910000073 phosphorus hydride Inorganic materials 0.000 claims description 42
- 239000000203 mixture Substances 0.000 claims description 40
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 30
- 150000002500 ions Chemical class 0.000 claims description 30
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 claims description 28
- 150000002475 indoles Chemical class 0.000 claims description 25
- 125000004407 fluoroaryl group Chemical group 0.000 claims description 21
- 229910052751 metal Inorganic materials 0.000 claims description 20
- 239000002184 metal Substances 0.000 claims description 18
- 239000003446 ligand Substances 0.000 claims description 14
- 150000003053 piperidines Chemical class 0.000 claims description 14
- 150000003233 pyrroles Chemical class 0.000 claims description 14
- 239000003863 metallic catalyst Substances 0.000 claims description 13
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 12
- 229910052726 zirconium Inorganic materials 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- 125000005103 alkyl silyl group Chemical group 0.000 claims description 10
- 125000003118 aryl group Chemical group 0.000 claims description 10
- 239000002243 precursor Substances 0.000 claims description 10
- 239000002002 slurry Substances 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 8
- 150000003335 secondary amines Chemical class 0.000 claims description 8
- 238000006555 catalytic reaction Methods 0.000 claims description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 6
- 229910052735 hafnium Chemical group 0.000 claims description 6
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 6
- 230000007935 neutral effect Effects 0.000 claims description 6
- 239000010936 titanium Substances 0.000 claims description 6
- 229910052719 titanium Inorganic materials 0.000 claims description 6
- 239000007848 Bronsted acid Substances 0.000 claims description 5
- 125000002091 cationic group Chemical group 0.000 claims description 5
- 125000004122 cyclic group Chemical group 0.000 claims description 5
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims description 5
- 125000001153 fluoro group Chemical group F* 0.000 claims description 5
- 229910052698 phosphorus Chemical group 0.000 claims description 5
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 claims description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 4
- 239000007795 chemical reaction product Substances 0.000 claims description 4
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims description 4
- 125000001188 haloalkyl group Chemical group 0.000 claims description 4
- 125000005842 heteroatom Chemical group 0.000 claims description 4
- 239000011574 phosphorus Chemical group 0.000 claims description 4
- 230000000379 polymerizing effect Effects 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 239000012808 vapor phase Substances 0.000 claims description 4
- 125000000129 anionic group Chemical group 0.000 claims description 3
- HONIICLYMWZJFZ-UHFFFAOYSA-N azetidine Chemical compound C1CNC1 HONIICLYMWZJFZ-UHFFFAOYSA-N 0.000 claims description 3
- 150000001539 azetidines Chemical class 0.000 claims description 3
- 125000003709 fluoroalkyl group Chemical group 0.000 claims description 3
- 238000003780 insertion Methods 0.000 claims description 3
- 230000037431 insertion Effects 0.000 claims description 3
- 229920002521 macromolecule Polymers 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 claims 8
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims 2
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 claims 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims 1
- 241000370738 Chlorion Species 0.000 claims 1
- 229910000042 hydrogen bromide Inorganic materials 0.000 claims 1
- 239000000758 substrate Substances 0.000 claims 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-M triflate Chemical compound [O-]S(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-M 0.000 claims 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 claims 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 abstract description 15
- 229920000642 polymer Polymers 0.000 abstract description 9
- 239000012018 catalyst precursor Substances 0.000 abstract description 5
- 125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 abstract description 5
- 239000002685 polymerization catalyst Substances 0.000 abstract description 5
- 125000001424 substituent group Chemical group 0.000 abstract description 2
- 125000006659 (C1-C20) hydrocarbyl group Chemical group 0.000 abstract 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical group [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 239000012968 metallocene catalyst Substances 0.000 abstract 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 abstract 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 167
- ONUFSRWQCKNVSL-UHFFFAOYSA-N 1,2,3,4,5-pentafluoro-6-(2,3,4,5,6-pentafluorophenyl)benzene Chemical group FC1=C(F)C(F)=C(F)C(F)=C1C1=C(F)C(F)=C(F)C(F)=C1F ONUFSRWQCKNVSL-UHFFFAOYSA-N 0.000 description 146
- 239000004305 biphenyl Substances 0.000 description 68
- 235000010290 biphenyl Nutrition 0.000 description 68
- 125000005004 perfluoroethyl group Chemical group FC(F)(F)C(F)(F)* 0.000 description 58
- 125000005003 perfluorobutyl group Chemical group FC(F)(F)C(F)(F)C(F)(F)C(F)(F)* 0.000 description 42
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 42
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 37
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 28
- 125000005062 perfluorophenyl group Chemical group FC1=C(C(=C(C(=C1F)F)F)F)* 0.000 description 26
- 125000004216 fluoromethyl group Chemical group [H]C([H])(F)* 0.000 description 24
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 24
- 150000004645 aluminates Chemical class 0.000 description 22
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 22
- 239000002585 base Substances 0.000 description 21
- 238000006243 chemical reaction Methods 0.000 description 21
- LVBKFSBSCJBXNE-UHFFFAOYSA-N (1-fluorocyclohexa-2,4-dien-1-yl)benzene Chemical group C=1C=CC=CC=1C1(F)CC=CC=C1 LVBKFSBSCJBXNE-UHFFFAOYSA-N 0.000 description 20
- 125000001207 fluorophenyl group Chemical group 0.000 description 20
- LERDAFCBKALCKT-UHFFFAOYSA-N 1,2,3,4,5-pentafluoro-6-(2,3,4-trifluorophenyl)benzene Chemical group FC1=C(F)C(F)=CC=C1C1=C(F)C(F)=C(F)C(F)=C1F LERDAFCBKALCKT-UHFFFAOYSA-N 0.000 description 18
- KLECYOQFQXJYBC-UHFFFAOYSA-N 1-fluoro-2-phenylbenzene Chemical group FC1=CC=CC=C1C1=CC=CC=C1 KLECYOQFQXJYBC-UHFFFAOYSA-N 0.000 description 18
- 125000000217 alkyl group Chemical group 0.000 description 18
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 18
- 125000005817 fluorobutyl group Chemical group [H]C([H])(F)C([H])([H])C([H])([H])C([H])([H])* 0.000 description 18
- 125000003784 fluoroethyl group Chemical group [H]C([H])(F)C([H])([H])* 0.000 description 16
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 16
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 14
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- 239000000243 solution Substances 0.000 description 11
- 125000005916 2-methylpentyl group Chemical group 0.000 description 10
- ZMXDDKWLCZADIW-UHFFFAOYSA-N Vilsmeier-Haack reagent Natural products CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 10
- 239000012190 activator Substances 0.000 description 10
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 239000002904 solvent Substances 0.000 description 9
- VPBBMLNMHNDQOZ-UHFFFAOYSA-N 1,2,3,4,5-pentafluoro-6-(2-fluorophenyl)benzene Chemical group FC1=CC=CC=C1C1=C(F)C(F)=C(F)C(F)=C1F VPBBMLNMHNDQOZ-UHFFFAOYSA-N 0.000 description 8
- 230000004913 activation Effects 0.000 description 8
- 125000001028 difluoromethyl group Chemical group [H]C(F)(F)* 0.000 description 8
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 229910052782 aluminium Inorganic materials 0.000 description 7
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 7
- 125000001624 naphthyl group Chemical group 0.000 description 7
- 125000004215 2,4-difluorophenyl group Chemical group [H]C1=C([H])C(*)=C(F)C([H])=C1F 0.000 description 6
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 6
- 239000004411 aluminium Substances 0.000 description 6
- WBJSPZAOBDQEHZ-UHFFFAOYSA-N butyl-(1,1,2,2,2-pentafluoroethyl)-(2,3,4,5,6-pentafluorophenyl)phosphane Chemical compound CCCCP(C(F)(F)C(F)(F)F)C1=C(F)C(F)=C(F)C(F)=C1F WBJSPZAOBDQEHZ-UHFFFAOYSA-N 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- MVBAWHBVJAQIGL-UHFFFAOYSA-N fluoromethyl(methyl)phosphane Chemical compound CPCF MVBAWHBVJAQIGL-UHFFFAOYSA-N 0.000 description 6
- GFINCEWMUJAOPQ-UHFFFAOYSA-N hexyl-(1,1,2,2,2-pentafluoroethyl)-(2,3,4,5,6-pentafluorophenyl)phosphane Chemical compound CCCCCCP(C(F)(F)C(F)(F)F)C1=C(F)C(F)=C(F)C(F)=C1F GFINCEWMUJAOPQ-UHFFFAOYSA-N 0.000 description 6
- 239000012535 impurity Substances 0.000 description 6
- LVVACMOOTCZPBO-UHFFFAOYSA-N methyl(propyl)phosphane Chemical compound CCCPC LVVACMOOTCZPBO-UHFFFAOYSA-N 0.000 description 6
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 5
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 230000003197 catalytic effect Effects 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 5
- CEVADJFNQNIQIG-UHFFFAOYSA-N 1,2,3,4,5-pentafluoro-6-(2,3,4,5,6-pentafluorophenyl)benzene propyl(trifluoromethyl)phosphane Chemical compound FC(F)(F)PCCC.FC1=C(C(=C(C(=C1F)F)F)F)C1=C(C(=C(C(=C1F)F)F)F)F CEVADJFNQNIQIG-UHFFFAOYSA-N 0.000 description 4
- YNDPUFVJDGVXCI-UHFFFAOYSA-N 3-ethylheptyl-(2,3,4,5,6-pentafluorophenyl)-propylphosphane Chemical compound CCCCC(CC)CCP(CCC)C1=C(F)C(F)=C(F)C(F)=C1F YNDPUFVJDGVXCI-UHFFFAOYSA-N 0.000 description 4
- DAIBGMLQQANKPL-UHFFFAOYSA-N C(CCC)PCC.FC1=C(C(=C(C(=C1F)F)F)F)C1=C(C(=C(C(=C1F)F)F)F)F Chemical compound C(CCC)PCC.FC1=C(C(=C(C(=C1F)F)F)F)C1=C(C(=C(C(=C1F)F)F)F)F DAIBGMLQQANKPL-UHFFFAOYSA-N 0.000 description 4
- 239000002879 Lewis base Substances 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- KBOZCEWQCLFRFG-UHFFFAOYSA-N butyl-(2,3,4,5,6-pentafluorophenyl)-propylphosphane Chemical compound CCCCP(CCC)C1=C(F)C(F)=C(F)C(F)=C1F KBOZCEWQCLFRFG-UHFFFAOYSA-N 0.000 description 4
- LEWHZFAXVYCKIJ-UHFFFAOYSA-N butyl-methyl-(2,3,4,5,6-pentafluorophenyl)phosphane Chemical compound CCCCP(C)C1=C(F)C(F)=C(F)C(F)=C1F LEWHZFAXVYCKIJ-UHFFFAOYSA-N 0.000 description 4
- DLIJPAHLBJIQHE-UHFFFAOYSA-N butylphosphane Chemical compound CCCCP DLIJPAHLBJIQHE-UHFFFAOYSA-N 0.000 description 4
- LGNFBYWKAZMBHU-UHFFFAOYSA-N ethyl(nonyl)phosphane 1,2,3,4,5-pentafluoro-6-(2,3,4,5,6-pentafluorophenyl)benzene Chemical compound C(C)PCCCCCCCCC.FC1=C(C(=C(C(=C1F)F)F)F)C1=C(C(=C(C(=C1F)F)F)F)F LGNFBYWKAZMBHU-UHFFFAOYSA-N 0.000 description 4
- VWBULAPFYXUNCI-UHFFFAOYSA-N ethyl-(1,1,2,2,3,3,4,4,4-nonafluorobutyl)-(2,3,4,5,6-pentafluorophenyl)phosphane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)P(CC)C1=C(F)C(F)=C(F)C(F)=C1F VWBULAPFYXUNCI-UHFFFAOYSA-N 0.000 description 4
- FQUOUBNPKCOZGM-UHFFFAOYSA-N ethyl-(fluoromethyl)-(2,3,4,5,6-pentafluorophenyl)phosphane Chemical compound CCP(CF)C1=C(F)C(F)=C(F)C(F)=C1F FQUOUBNPKCOZGM-UHFFFAOYSA-N 0.000 description 4
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 4
- 239000007791 liquid phase Substances 0.000 description 4
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 4
- 229910044991 metal oxide Inorganic materials 0.000 description 4
- 150000002902 organometallic compounds Chemical class 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 229910052723 transition metal Inorganic materials 0.000 description 4
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 4
- 239000004711 α-olefin Substances 0.000 description 4
- CWLKTJOTWITYSI-UHFFFAOYSA-N 1-fluoronaphthalene Chemical compound C1=CC=C2C(F)=CC=CC2=C1 CWLKTJOTWITYSI-UHFFFAOYSA-N 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 3
- 239000004327 boric acid Substances 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 150000001925 cycloalkenes Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 150000002736 metal compounds Chemical class 0.000 description 3
- 229910052752 metalloid Inorganic materials 0.000 description 3
- 150000002738 metalloids Chemical group 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 230000037048 polymerization activity Effects 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- UKUCJNZPEMNYCX-UHFFFAOYSA-N (1-fluorocyclohexa-2,4-dien-1-yl)-(1,1,2,2,2-pentafluoroethyl)-propylphosphane Chemical compound CCCP(C(F)(F)C(F)(F)F)C1(F)CC=CC=C1 UKUCJNZPEMNYCX-UHFFFAOYSA-N 0.000 description 2
- OKJBBHLRKRUMFI-UHFFFAOYSA-N (1-fluorocyclohexa-2,4-dien-1-yl)-methyl-(1,1,2,2,2-pentafluoroethyl)phosphane Chemical compound FC(F)(F)C(F)(F)P(C)C1(F)CC=CC=C1 OKJBBHLRKRUMFI-UHFFFAOYSA-N 0.000 description 2
- OSCFAYXEEJWNJP-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenyl)-propyl-(trifluoromethyl)phosphane Chemical compound CCCP(C(F)(F)F)C1=C(F)C(F)=C(F)C(F)=C1F OSCFAYXEEJWNJP-UHFFFAOYSA-N 0.000 description 2
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- 239000011324 bead Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 125000002619 bicyclic group Chemical group 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000010538 cationic polymerization reaction Methods 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
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- 150000001941 cyclopentenes Chemical class 0.000 description 1
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- 238000006297 dehydration reaction Methods 0.000 description 1
- XOBNKAOAIBDHEQ-UHFFFAOYSA-L dichloroniobium Chemical compound Cl[Nb]Cl XOBNKAOAIBDHEQ-UHFFFAOYSA-L 0.000 description 1
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- XGCILSHUAUFSLI-UHFFFAOYSA-N dodecalithium;tetraborate Chemical class [Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] XGCILSHUAUFSLI-UHFFFAOYSA-N 0.000 description 1
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- FUWYMLYVUVBWSU-UHFFFAOYSA-N heptoxyboronic acid Chemical class CCCCCCCOB(O)O FUWYMLYVUVBWSU-UHFFFAOYSA-N 0.000 description 1
- 125000001072 heteroaryl group Chemical group 0.000 description 1
- PLAHQMWSZPRDKI-UHFFFAOYSA-N hexoxyboronic acid Chemical class CCCCCCOB(O)O PLAHQMWSZPRDKI-UHFFFAOYSA-N 0.000 description 1
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- 230000003993 interaction Effects 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
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- 238000004811 liquid chromatography Methods 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012685 metal catalyst precursor Substances 0.000 description 1
- QSLMQGXOMLSFAW-UHFFFAOYSA-N methanidylbenzene;zirconium(4+) Chemical compound [Zr+4].[CH2-]C1=CC=CC=C1.[CH2-]C1=CC=CC=C1.[CH2-]C1=CC=CC=C1.[CH2-]C1=CC=CC=C1 QSLMQGXOMLSFAW-UHFFFAOYSA-N 0.000 description 1
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 1
- JUHDUIDUEUEQND-UHFFFAOYSA-N methylium Chemical compound [CH3+] JUHDUIDUEUEQND-UHFFFAOYSA-N 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- YHPLDIMIJCPNBP-UHFFFAOYSA-N n-methyldocosan-1-amine Chemical class CCCCCCCCCCCCCCCCCCCCCCNC YHPLDIMIJCPNBP-UHFFFAOYSA-N 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- BRCSSEXPXACJJV-UHFFFAOYSA-N nonoxyboronic acid Chemical class CCCCCCCCCOB(O)O BRCSSEXPXACJJV-UHFFFAOYSA-N 0.000 description 1
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000010502 orange oil Substances 0.000 description 1
- 239000012044 organic layer Substances 0.000 description 1
- 150000002899 organoaluminium compounds Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-O oxonium Chemical group [OH3+] XLYOFNOQVPJJNP-UHFFFAOYSA-O 0.000 description 1
- 125000002097 pentamethylcyclopentadienyl group Chemical group 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- QKENRHXGDUPTEM-UHFFFAOYSA-N perfluorophenanthrene Chemical compound FC1(F)C(F)(F)C(F)(F)C(F)(F)C2(F)C3(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C3(F)C(F)(F)C(F)(F)C21F QKENRHXGDUPTEM-UHFFFAOYSA-N 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000005588 protonation Effects 0.000 description 1
- 125000001725 pyrenyl group Chemical group 0.000 description 1
- WYROLENTHWJFLR-ACLDMZEESA-N queuine Chemical compound C1=2C(=O)NC(N)=NC=2NC=C1CN[C@H]1C=C[C@H](O)[C@@H]1O WYROLENTHWJFLR-ACLDMZEESA-N 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000001374 small-angle light scattering Methods 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 230000003335 steric effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- LALRXNPLTWZJIJ-UHFFFAOYSA-N triethylborane Chemical group CCB(CC)CC LALRXNPLTWZJIJ-UHFFFAOYSA-N 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- JLPJTCGUKOBWRJ-UHFFFAOYSA-N tripentyl borate Chemical compound CCCCCOB(OCCCCC)OCCCCC JLPJTCGUKOBWRJ-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 238000012725 vapour phase polymerization Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
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- C07D207/32—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
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Abstract
公开了氟化胺化合物：R’iArF－ER2，其中ArF为氟芳基取代基，E为氮或磷，每个R独立地为C1－C20烃基取代基，或者两个R可连成未取代或取代的C2－C20脂环取代基，R’为C1－C20烃基或卤代烃基，i为0、1或2。这些化合物可被质子化并与适合的基本上非配位的阴离子配位制备聚合催化剂组分。这些催化剂组分与有机金属催化剂前体化合时，所述催化剂前体被活化成催化剂。使此催化剂在烯烃聚合条件下与单体混合制备聚合物。用[四(五氟苯基)硼酸][N－五氟苯基吡咯烷鎓]活化的金属茂催化剂观察到以高产率获得高数均分子量的聚合物。
Description
技术领域
本发明涉及离子催化剂体系，特别是使用离子催化剂体系的聚合方法；包括含第15族元素的阳离子和非配位阴离子的离子催化剂体系的前体；和含第15族元素的阳离子的使用方法。
背景技术
术语“非配位阴离子”(NCA)是目前通过配位或插入聚合和碳阳离子聚合的烯烃和乙烯基单体聚合领域认可的术语。参见例如EP 0 277004、US 5 198 401、Baird，Michael C.，et al.，J.Am.Chem.Soc.1994，116，6435-6436、US 5 312 881、US 5 668 234、和WO 98/03558。所述非配位阴离子被说成是作为聚合活性的金属茂阳离子配合物的稳定电子的抗衡离子。本文所用术语非配位阴离子适用于真正的非配位阴离子和至多弱配位使之不稳定足以允许烯属或炔属单体插入的阴离子。这些非配位阴离子可以含平衡电荷的抗衡阳离子的布朗斯台德酸盐的形式有效地加入聚合介质中、与有机金属催化剂化合物分离或在加入聚合介质之前与所述催化剂预混。
US 5 198 401和WO 97/35893涉及含氮的布朗斯台德酸阳离子，这些阳离子能通过给适合的不稳定基团提供质子夺取中性有机金属过渡金属催化剂前体化合物上的离去(不稳定)基团，从而使所述催化剂前体化合物变成阳离子，并提供相容的非配位抗衡阴离子。US 5 198 401描述了下式所示催化剂活化剂化合物：[(L’-H)+]d[(M’)m+Q1Q2…Qn]d-，其中L’为中性碱，H为氢原子，[(M’)m+Q1Q2…Qn]为与多个配体相连的金属或准金属原子，优选M为硼，两或多个Qn为芳族基团如苯基、萘基和蒽基，均优选是氟化的。L’的例子是各种三烷基取代的铵配合物和N，N-二烷基苯铵配合物。WO 97/35893描述了下式所示助催化剂活化剂化合物：[L*-H]+[BO’4]-，其中L*包括含氮的中性路易斯碱，B为+3价硼，Q’为氟化的C1-20烃基，优选氟化芳基。据说这些助催化剂化合物通过在所述布朗斯台德酸[L*-H]+中引入脂族基团如长链烷基或取代的烷基使之可溶于脂族溶剂。列举了二(氢化牛脂烷基)甲基铵和二(二十二烷基)甲基铵盐。
鉴于以上情况，仍需要能改善工业经济性的助催化剂活化化合物并提供这些助催化剂化合物的合成和制备方法。特别地，上述含氮助催化剂化合物的催化剂活化反应可通过在所述活化质子化反应中失去水合氢原子H+产生中性胺化合物。这些L化合物是路易斯碱，它们可与所述强路易斯酸-有机金属催化剂阳离子相互作用，某些情况下可能不利地影响总的聚合动力学。特别参见EP0 426 637，其中教导用碳鎓、氧鎓和硫鎓阳离子代替路易斯碱胺，从而可避免催化剂毒物和不想要的剩余胺。
发明内容
本发明实施方案涉及由一或多种烯属单体制备聚烯烃的方法，其中使所述烯烃与i)有机金属催化剂化合物和ii)包含氟芳基配体取代的仲胺或膦和基于第13族元素的非配位或弱配位阴离子的助催化剂配合物的反应产物混合。本发明助催化剂为表现出异常高聚合活性的有机金属催化剂配合物提供比现有技术碱度降低的剩余胺或膦化合物以及非配位或弱配位阴离子。
本文所用术语非配位阴离子适用于真正的非配位阴离子和配位作用低于烯属或炔属单体的配位阴离子。这些非配位阴离子可有效地以含本发明平衡电荷的抗衡阳离子的布朗斯台德酸盐的形式加入聚合介质中或在加入聚合介质中之前与有机金属催化剂化合物预混。
具体实施方式
本发明提供一种烯烃聚合方法，其中第13族助催化剂配合物和过渡金属有机金属催化剂前体化合物可结合形成活性的烯烃聚合催化剂。活化后或基本上与活化同时地，使所述催化剂暴露于有可接近的烯属、乙烯属或炔属不饱和的适合单体中。
使用通式[L-H]+[A]-(其中[A]-是适用于烯烃聚合的任何阴离子)，本发明路易斯碱化合物L典型地基于满足以下通式的氟化胺化合物：R’iArF-ER2，其中ArF为氟芳基配体，E为氮或磷，每个R独立地为C1-C20线型或支化烃基或烃基甲硅烷基取代基。此外，两个R’可连成取代或未取代的、卤化或未卤化的C2-C20脂环族、C2-C10烃基或C2-C10烃基甲硅烷基。R’为C1-C20烃基或卤代烃基。所述氮原子上的适合的氟芳基取代基可以是取代或未取代的苯基或联苯基。所述取代基可位于环碳原子上，或者所述环碳原子本身被取代产生杂芳环。一些实施方案使用全氟芳环。所述R’取代基可以是线型或支化的、氟化或未氟化的烷基或链烯基取代基。一些实施方案基于以下氟芳基配体取代的胺：ArF-NR2，其中所述氟芳基配体ArF可以是氟代或全氟代芳基。R代表如上所述取代或未取代的烷基或环烷基，可独立地选择。一些实施方案使用以下环状仲胺：N-五氟苯基吡咯烷、N-对九氟联苯基吡咯烷、N-十三氟三联苯基吡咯烷、N-五氟苯基吡咯、N-对九氟联苯基吡咯、N-十三氟三联苯基吡咯、N-五氟苯基哌啶、、N-对九氟联苯基哌啶、N-十三氟三联苯基哌啶、N-五氟苯基二氢吲哚、、N-对九氟联苯基二氢吲哚、N-十三氟三联苯基二氢吲哚、N-五氟苯基吲哚、、N-对九氟联苯基吲哚、N-十三氟三联苯基吲哚、N-五氟苯基氮杂环丁烷、N-对九氟联苯基氮杂环丁烷、N-十三氟三联苯基氮杂环丁烷、N-五氟苯基氮丙啶、N-对九氟联苯基氮丙啶、和N-十三氟三联苯基氮丙啶。
一些实施方案中，有效的本发明第13族助催化剂配合物由含4配位第13族阴离子配合物的离子盐衍生，表示为：
[L-H]+[(M’)Q1Q2…Qn]-，
其中[L-H]+如前面所定义，M为一或多种第13族金属或准金属，包括硼或铝。每个Q为能提供电子或位阻效应使[(M’)Q1Q2…Qn]-适合作非配位或弱配位阴离子(如本领域所理解的)的配体。如果阴离子是非配位或弱配位阴离子，则本文中称之为基本上非配位，意指如此弱地配位以致不稳定足以在聚合反应过程中允许烯属或炔属单体插入。也可选择足够数量的Q以致[(M’)Q1Q2…Qn]-总体上是有效的NCA。列举的Q取代基在其稠合或非稠合的环系中有4至20个碳原子，特别是6至20个碳原子。Q可以是取代的。这些取代尤其包括氟代芳基、全氟代芳基，也可包括除氟取代基之外的取代基如氟代烃基。优选的氟代芳基包括C6-C18芳基或烷芳基如苯基、联苯基、萘基及其烷基化衍生物。US 5 198401、5 296 433、5 278 119、5 447 895、5 688 634、5 895 771、WO93/02099、WO97/29845、WO99/43717、WO99/42467和共同待审的USSN 09/261 627(1999年3月3日申请)及其同族WO99/45052特别提及适用的Q取代基，引入本文供参考。
包含氟芳基配体取代的仲胺或膦和基于第13族元素的非配位或弱配位阴离子的助催化剂配合物一般可如下制备：使前面所定义的氟芳基配体取代的胺化合物与强布朗斯台德酸反应生成与所述酸的阴离子共轭碱抗衡的质子化的氟芳基配体取代的铵阳离子。然后使所得盐[R’iArF-ER2-H]+[X]-与包含如上所述适合NCA的第1或2族金属盐反应，除去包含所述布朗斯台德酸的共轭碱和所述第1或2族金属的盐。例如，可使四(五氟苯基)硼酸锂与质子化的氯化芳基铵化合产生四(五氟苯基)硼酸质子化芳基铵化合物和副产物LiCl。
一个Q基或配体还可与含官能团的金属氧化物、准金属氧化物或聚合载体相连。参见例如US 5 427 991和5 939 347，引入本文供参考。适用的金属或准金属载体包括所有金属或准金属氧化物。一些实施方案使用pKa等于或小于非晶形氧化硅的即pKa小于或等于约11的有表面羟基的载体。因此，脱水后保留有羟基的任何传统已知的氧化硅载体均适用于本发明。一些实施方案使用诸如金属氧化物、氧化硅、氧化硅-氧化铝、氧化铝、粘土等载体。最典型的是氧化硅颗粒、凝胶和玻璃珠。
聚合载体典型地含有羟基官能团。此外，可使用其它官能团包括任何伯烷基胺和仲烷基胺等，这些基团掺入聚合链结构中，能使所述第13族阴离子的配体之一质子化或代替之。参见例如US 5 288 677的含官能团的聚合物、US 5 427 991的官能化聚合物和USSN 09/277 339(1999年3月26日申请)及其同族WO99/50311中所述。也参见WO98/55518，其中质子化铵盐散布在用于制备负载型烯烃聚合催化剂的聚合物粒中。均引入本文供参考。
有NCA助催化剂的催化剂体系的其它已知负载方法也适用于负载本发明催化剂配合物。因此，本发明催化剂配合物也可物理地沉积或固定在适合的载体材料上。参见例如WO91/09882、WO93/11172、WO96/35726、US 4 463 135和US5 610 115中的教导。
本发明活化剂可活化所述催化剂前体时，适用于本发明的过渡金属烯烃聚合催化剂包括适用于传统齐格勒-纳塔型聚合的那些化合物和已知适用于聚合的金属茂化合物。这些典型地包括其中至少一个金属配体可被所述活化剂质子化的第3-11族过渡金属化合物。典型地，那些配体包括氢负离子、烷基和甲硅烷基、及其低级烷基取代的(C1-C10)衍生物。能被夺取的配体和包括这些配体的过渡金属化合物包括背景技术中所述的那些，参见例如US5 198 401和WO92/00333。从所述公开文献中公知这些化合物的合成。此外，所述金属配体包括不能用本发明助催化剂夺取的卤离子、氨基或烷氧基部分(例如二氯·二环戊二烯基合锆)时，可用诸如氢化或烷基锂或铝、烷基铝氧烷、或格利雅试剂等通过已知的烷基化反应使这些配体转化成可夺取的配体。也参见EP-A1-0 570 982在加入活化阴离子之前使有机铝化合物与二卤基取代的金属茂化合物反应。所有文献均引入本文供参考。
专利文献包含对包括或可使之烷基化以包括至少一个能被夺取形成催化活性阳离子的配体的金属茂化合物的其它描述，例如EP-A-0 129368、US 4 871 705、4 937 299、5 324 800、EP-A-0 418 044、EP-A-0591 756、WO-A-92/00333、WO-A-94/01471和WO97/22635。本发明将这种金属茂化合物描述成单-或双-环戊二烯基取代的第3、4、4或6族化合物，其中所述配体本身可被一或多个基团取代，可彼此桥连，也可通过杂原子与所述过渡金属桥连。所述配体和桥连元素的大小和组成对制备本发明催化剂体系无关紧要，但应以文献所述方式选择以提高聚合活性和产生要求的聚合物特性。彼此桥连时，所述环戊二烯基环(包括取代的环戊二烯基稠环体系如茚基、芴基、甘菊环基、及其取代的类似物)优选在2-位被低级烷基(C1-C6)取代(所述稠环体系中有或没有类似的4-位取代基)，可还包括烷基、环烷基、芳基、烷芳基、或芳烷基取代基，后者为线型、支化、或环状结构包括多环结构，例如US5 278264和5 304 614的那些。那些取代基应有烃基特征，典型地含有最多30个碳原子，但可以是含杂原子的，有1-5个非氢非碳原子，如N、S、O、P、Ge、B和Si。所有文献均引入本文供参考。
适用于制备线型聚乙烯或含乙烯共聚物(这里共聚物意指由至少两种不同单体形成的)的金属茂化合物基本上是本领域已知的任何金属茂化合物，参见WO-A-92/00333和US5 001 205、5 198 401、5 324 800、5 304 614和5 308 816具体列举的。用于制备全同立构或间同立构聚丙烯的金属茂催化剂的选择及相应催化剂的合成为本领域公知(专利文献和学术文献)，参见例如Journal of Organometallic Chemistry 369，359-370(1989)。典型地，那些催化剂是立体刚性、不对称、手性或桥连手性金属茂。参见例如US4 892 851、US5 017 714、US5 296 434、US5 278 264、WO-A-(PCT/US92/10066)、WO-A-93/19103、EP-A2-0 577581、EP-Al-0 578 838、和学术文献“The Influence of AromaticSubstituents on the Polymerization Behavior of BridgedZirconocene Catalysts”，Spaleck，W.，et al.，Organometallics1994，13，954-963、和“ansa-Zirconocene Polymerization Catalystswith Annelated Ring Ligands-Effects on Catalytic Activity andPolymer Chain Lengths”，Brinzinger，H.，et al.，Organometallics1994，13，964-970及其中的参考文献。虽然上面列举的许多参考文献涉及有铝烷氧活化剂的催化剂体系，但本发明活化剂可使类似的金属茂活化，条件是所述含卤离子、氨、或烷氧基的金属配体(存在时)被可夺取的配体置换，例如通过上述烷基化反应，而且另一配体是所述乙烯基-C＝C-可插入其中的基团，例如氢负离子、烷基或甲硅烷基。所有文献均引入本文供参考。
一些实施方案中，典型的金属茂化合物有下式：
LALBLC iMDE
其中LA为与M相连的取代的环戊二烯基或杂环戊二烯基配体；LB为针对LA定义的此类配体或为与M相连的杂原子配体；LA和LB可通过第14族连接基桥连在一起；LC i为可选的与M相连的中性不氧化配体(i等于0至3)；M为第4或5族金属；D和E独立地为不稳定的单阴离子配体，均与M相连，可选地彼此桥连、与LA或LB桥连。可通过夺取使D-M或E-M断裂。同样，单体或可聚合大分子单体可插入D-M或E-M中。可存在数量减少的不稳定配体，甚至不存在。相信所述还原价态的化合物将反应形成催化活性阳离子，事实上其功能与由饱和结构的化合物制备的基本相同。
非限制性的代表性的金属茂化合物包括单环戊二烯基化合物如异丙氧基·五甲基环戊二烯基合钛、三苄基·五甲基环戊二烯基合钛、二氯·二甲基甲硅烷基-四甲基环戊二烯基-叔丁氨基合钛、三甲基·五甲基环戊二烯基合钛、二甲基·二甲基甲硅烷基-四甲基环戊二烯基-叔丁氨基合锆、二氢·二甲基甲硅烷基-四甲基环戊二烯基-十二烷氨基合铪、二甲基·二甲基甲硅烷基-四甲基环戊二烯基-十二烷氨基合铪；未桥连的双环戊二烯基化合物如二甲基·双(1，3-丁基，甲基-环戊二烯基)合锆、二甲基·(四甲基环戊二烯基)·(正丙基环戊二烯基)合锆；桥连的双环戊二烯基化合物如二氯·二甲基甲硅烷基-双(四氢茚基)合锆和二甲基·硅杂环丁基-(四甲基环戊二烯基)(正丙基环戊二烯基)合锆；桥连的双茚基化合物如二氯·二甲基甲硅烷基-双茚基合锆、二甲基·二甲基甲硅烷基-双茚基合铪、二氯·二甲基甲硅烷基-双(2-甲基苯并茚基)合锆、二甲基·二甲基甲硅烷基-双(2-甲基苯并茚基)合锆；和含芴基配体的化合物例如二甲基·二苯基甲基-(芴基)(环戊二烯基)合锆；和其它单-和双-环戊二烯基化合物如US5 017 714、5 324800和EP-A-0 591 756中所列举的那些。所有文献均引入本文供参考。
代表性的传统齐格勒-纳塔型过渡金属化合物包括四苄基锆、四(二(三甲基甲硅烷基)甲基)锆、氧代三(三甲基甲硅烷基甲基)钒、三苄基铪、四苄基钛、二(六甲基-二硅叠氮基)二甲基钛、三(三甲基甲硅烷基甲基)二氯化铌、三(三甲基甲硅烷基甲基)二氯化钽。这些组合物的重要聚合特征是所述可夺取配体和所述乙烯(烯属)基可插入其中的配体。这些特征能从所述金属化合物中夺取配体，形成伴生的发明催化剂。
适合用作本发明烯烃聚合催化剂的其它有机金属化合物是可通过配体夺取转化成催化活性阳离子并由可被烯属不饱和单体如乙烯置换的非配位或弱配位阴离子稳定在活性电子状态的任何第3-11族有机金属化合物。
典型的化合物包括所述专利文献中所述的那些。WO96/23010、WO97/48735和Gibson，et al.，Chem.Comm.，pp.849-850(1998)公开了适用于活化和烯烃聚合的第8-10族化合物的二亚胺基配体。也参见WO97/48735。US5 502 124及其分案US5 504 049中描述了来自第5-10族金属的聚合催化剂体系，其中所述活性金属中心被高度氧化，由低配位数的多阴离子配体体系稳定。也参见US5 851 945的第5族有机金属催化剂和共同待审的USSN 09/302243(1999年4月29日申请)及其同族PCT/US99/09306的含三齿配体的第4-9族有机金属催化剂。WO99/30822及其优先权文件(包括1997年12月16日申请的USSN08/991 160)中描述并列举了用离子化助催化剂活化的适用于烯烃和含乙烯基的极性单体聚合的第11族催化剂前体化合物。这些文献均引入本文供参考。
US5 318 935描述了能使α-烯烃聚合的第4族金属的桥连和未桥连的双氨基催化剂化合物。D.H.McConville等在Organometallics 1995，14，5478-5480中描述了用于烯烃聚合的桥连双(芳氨基)第4族化合物。给出了合成方法和化合物表征。进一步描述了是活性1-己烯催化剂的桥连双(芳氨基)第4族化合物。参见D.H.McConville，et al.，Macromolecules 1996，29，5241-5243；也参见WO98/37109。适用于本发明的其它化合物包括WO96/40805中所述的那些。共同待审的USSN09/408050(1999年9月29日申请)及其同族PCT/US99/22690中公开了用于烯烃聚合的第3族或镧系金属阳离子配合物。所述前体金属化合物由一个单阴离子双齿配体和两个单阴离子配体稳定，可用本发明助催化剂活化。这些文献均引入本文供参考。
适用的有机金属催化剂前体化合物的其它描述可在文献中找到，包括或能烷基化以包括可从有机金属化合物中夺取的配体的任何有机金属催化剂前体化合物均适用。参见例如V.C.Gibson，et al.，“TheSearch for New-Generation Olefin Polymerization Catalysts：LifeBeyond Metallocenes”，Angew.Chem.Int.Ed.，38，428-447(1999)，引入本文供参考。
使用本发明催化剂时，特别是固定在载体上时，所述总催化剂体系可还包含一或多种清除化合物。本文所用术语“清除化合物”包括能有效地从反应中除去极性杂质的那些化合物。所有聚合反应物都可能向所述反应中带入杂质，特别是溶剂、单体和催化剂进料。这些杂质降低催化剂的活性和稳定性。它们的存在可能降低或消除催化活性，特别是在离子化阴离子前体活化的催化剂体系的情况下。这些杂质或毒物包括水、氧、金属杂质等。典型地在反应物加入反应容器之前从反应物中除去杂质，但在聚合过程中通常使用一些清除化合物。
所述清除化合物是已知的有机金属化合物如US5 153 157、5 241 025、5 767 587和WO-A-91/09882、WO-A-94/03506、WO-A-93/14132和WO95/07941的第13族化合物。典型的化合物包括三乙基铝、三乙基硼烷、三异丁基铝、甲基铝氧烷、异丁基铝氧烷和三正辛基铝。有与金属或准金属中心相连的庞大的或C6-C20线型烃基取代基的那些清除化合物与所述活性催化剂的相互作用最小。例子包括三乙基铝和庞大的化合物如三异丁基铝、三异戊烯基铝、和长链线型烷基取代的铝化合物如三正己基铝、三正辛基铝或三正十二烷基铝。与本发明催化剂一起使用的清除剂减少至提高活性的量，如果进料和聚合介质足够纯，则可完全避免。
本发明催化剂配合物适用于聚合已知可用金属茂配位聚合的单体。此条件是公知的，包括溶液、淤浆、气相、和高压聚合。如果本发明催化剂是负载型的，它们将特别适用于在单一反应器、串联或并联反应器中进行的采用固定床、移动床、流化床、淤浆或溶液法的已知操作方式。此外，负载型本发明催化剂的预聚可控制通常的淤浆或气相反应中聚合物粒子的形态。
液相(溶液、淤浆、悬浮液、本体相或组合)、高压液相、超临界流体相、或气相法中采用不同的本发明催化剂体系实施方案。这些过程都可在单一反应器、并联或串联反应器中进行。所述液相法包括使所述催化剂体系与烯烃单体在适合的稀释剂或溶剂中接触足够长时间以产生本发明聚合物。本发明方法中可使用脂族和芳族烃溶剂。特别适用的是己烷、环戊烷、环己烷及其烷基化衍生物。其它典型溶剂包括有4至20个碳原子、优选5至10个碳原子的线型或环状脂族烃。典型的溶剂还包括6-12个碳原子的芳烃。在本体和淤浆法中，所述催化剂典型地与液态单体浆液接触。在此情况下所述催化剂体系通常是负载型的。气相法典型地使用负载型催化剂，以适用于乙烯聚合的任何已知方式进行。说明性实例可见US4 543 399、4 588 790、5 028 670、5 382 638、5 352 749、5 408 017、5 436 304、5 453 471、5 463 999、5 767 208和WO95/07942。均引入本文供参考。
一些实施方案中，与本文所述催化剂组合物一起使用的单体包括2-20个碳原子的烯烃。其它实施方案中，用本发明催化剂制备的烯烃聚合物包含至少50％(摩尔)的乙烯或丙烯。因此，可制备各种乙烯或丙烯聚合物。
用于不同实施方案的代表性反应温度和压力示于表1中。
表1：反应温度和反应压力
| 实施方案 | 反应温度(℃) |
| ABCD | ≤220≥40≤250≥60 |
| 实施方案 | 反应压力(bar) |
| EFGHIJ | ≤2500≥0.1≤500≤1600≥1.0≥0.001 |
通过在低压(典型地＜50bar)下在40-250℃的典型温度下向装有悬浮于溶剂如己烷或甲苯中的本发明催化剂的反应容器中加入乙烯和可选的一或多种其它单体生产线型聚乙烯，包括高和超高分子量聚乙烯，包括均聚物和与其它α-烯烃单体或α-烯属或非共轭二烯烃的共聚物。本发明一些实施方案中用其它α-烯烃如C3-C20烯烃、二烯烃、乙烯基芳烃(如苯乙烯)或环烯烃作为单体。典型地通过冷却除去聚合热。例如，气相聚合可在2000-3000kPa和60-160℃下操作的连续流化床气相反应器中用作为反应改性剂的氢气(100-200ppm)、C4-C8共聚单体原料流(0.5-1.2mol％)和C2原料流(25-35mol％)进行。参见US 4 543 399、4 588 790、5 028 670、5 405 922和5 462 999，均引入本文供参考。
用本发明催化剂在传统的溶液聚合法中或用α-烯烃或环烯烃或其与其它化合物或单体的混合物作为悬浮本发明催化剂的稀释剂通过将乙烯气体引入浆液中可制备高分子量、低结晶度的乙烯-α-烯烃弹性体(包括乙烯-环烯烃和乙烯-α-烯烃-二烯烃)。典型的乙烯压力在10和1000psig(69-6895kPa)之间，稀释剂温度典型地在40和160℃之间。所述过程可在搅拌釜式反应器或多于一个串联或并联操作的反应器中进行。参见US5 001 205中公开的一般工艺条件。也参见WO96/33227和WO97/22639。所有文献关于聚合方法、金属茂的选择和适合的清除化合物的描述均引入本文供参考。
除上面具体描述的那些之外，其它烯烃不饱和单体也可用本发明催化剂聚合。例如，苯乙烯、烷基取代的苯乙烯、异丁烯和其它偕二取代的烯烃、亚乙基降冰片烯、降冰片二烯、二环戊二烯、和其它烯属不饱和单体包括其它环烯烃如环戊烯、降冰片烯和烷基取代的降冰片烯都可用本发明催化剂聚合。参见例如US 5 635 573和5 763 556。此外，也可使高达多于1000基体单元的α-烯属大分子单体(marchers)聚合产生含支链的烯烃聚合物。
本发明催化剂组合物可如前面所述单独地用于聚合，也可与其它烯烃聚合催化剂混合制备聚合物共混物。选择催化剂共混物和单体可在与使用单个催化剂类似的条件下制备共混物。从而可获得MWD增加从而加工性改善的聚合物和来自用混合催化剂体系制备的聚合物的其它传统益处。
聚乙烯均聚物或共聚物可有利地有0.87至0.95的密度。可使用至少0.88、优选至少0.90、特别是至少0.915的密度。所述密度可低于0.94，优选低于0.925。MI可在0.1至10、特别是0.5至8的范围内改变以在流延和吹塑薄膜过程中形成薄膜。所述丙烯均聚物和共聚物可用能形成全同立构、间同立构或无规立构序列的金属茂制备，MFR可为0.1至800，共聚单体含量为0至15％(摩尔)，熔点为170至90℃，所述聚丙烯的共聚单体可选自乙烯、C4-C12 α-烯烃、和C5-C12非共轭二烯烃之一或多种。
可在场外通过机械共混或现场用混合催化剂体系形成共混聚合物。一般相信现场共混提供更均匀的产品，可一步生产所述共混物。在现场共混中，使多于一种催化剂在同一反应器中混合同时产生不同的聚合物产品。此方法需要附加的催化剂合成。还需要各催化剂组分的活性、在特定条件下产生的聚合物产品、及其对聚合条件变化的响应匹配。
适用于实施本发明的化合物
典型的氟芳基配体取代的胺和膦
(1-氟联苯基)(3-乙基庚基)(乙基)胺；(1-氟联苯基)(丁基)(氟甲基)胺；(1-氟联苯基)(二氟甲基)胺；(1-氟联苯基)(甲基)(全氟乙基)胺；(1-氟联苯基)(丙基)(己基)胺；(1-氟联苯基)(甲基)(六氟壬基)胺；(1-氟苯基)(2-甲基苯基)(全氟乙基)胺；(1-氟苯基)(己基)(全氟甲基)胺；(1-氟苯基)(壬基)(全氟乙基)胺；(1-氟苯基)(甲基)(氟甲基)胺；(1-氟苯基)(氟甲基)(丁基)胺；(1-氟苯基)(全氟乙基)(甲基)胺；(1-氟苯基)(甲基)(全氟丁基)胺；(1-氟苯基)(己基)(全氟丁基)胺；(1-氟苯基)(甲基)(丙基)胺；(2，3-二氟苯基)(乙基)(氟甲基)胺；(2，3-二氟苯基)(全氟丁基)(氟甲基)胺；(2，3-二氟苯基)(全氟甲基)(甲基)胺；(2，3-二氟苯基)(壬基)(全氟乙基)胺；(2，3-二氟苯基)(壬基)(丙基)胺；(2，3-二氟苯基)(乙基)(全氟丁基)胺；(2，3-二氟苯基)(壬基)(丙基)胺；(2，3-二氟苯基)(全氟乙基)(2-甲基-5-丙基-己基)胺；(2，3-二氟苯基)(2-甲基苯基)(全氟乙基)胺；(2，3-二氟苯基)(甲基)(2-甲基戊基)胺；(2，3-二氟苯基)(丙基)(己基)胺；(2，4-二氟苯基)(全氟甲基)(2-甲基-5-丙基-己基)胺；(2，4-二氟苯基)(3-乙基庚基)(全氟乙基)胺；(2，4-二氟苯基)(全氟乙基)(氟甲基)胺；(2，4-二氟苯基)(壬基)(全氟丁基)胺；(2，4-二氟苯基)(己基)(氟甲基)胺；(2，4-二氟苯基)(乙基)(丁基)胺；(2，4-二氟苯基)(全氟乙基)(丁基)胺；(2，4-二氟苯基)(二甲基)胺；(2，4-二氟苯基)(乙基)(丙基)胺；(2，4-二氟苯基)(2-甲基-5-丙基-庚基)(乙基)胺；(2，4-二氟苯基)(甲基)(乙基)胺；(2，4-二氟苯基)(3-乙基庚基)(己基)胺；(2，4-二氟苯基)(己基)(全氟乙基)胺；(2，5-二氟苯基(二氟甲基)胺；(2，5-二氟苯基)(全氟乙基)(氟丁基)胺；(2，5-二氟苯基)(丙基)(壬基)胺；(2，5-二氟苯基)(2-甲基苯基)(乙基)胺；(2，5-二氟苯基)二(2，2，2-三氟乙基)胺；(2，5-二氟苯基)(丙基)(2-甲基-5-丙基-庚基)胺；(2，5-二氟苯基)(丁基)(2-甲基-5-丙基-庚基)胺；(2，5-二氟苯基)(丙基)(氟甲基)胺；(2，5-二氟苯基)(全氟乙基)(乙基)胺；(2-甲基-6-全氟甲基-全氟联苯基)(氟甲基)(氟丁基)胺；(2-甲基-6-全氟甲基-全氟联苯基)(氟甲基)(甲基)胺；(2-甲基-6-全氟甲基-全氟联苯基)(己基)(甲基)胺；(2-甲基-6-全氟甲基-全氟联苯基)(甲基)(全氟乙基)胺；(2-甲基-6-全氟甲基-全氟联苯基)(全氟乙基)(丁基)胺；(2-甲基-6-全氟甲基-全氟联苯基)(丁基)(全氟乙基)胺；(2-甲基-6-全氟甲基-全氟联苯基)(3-乙基庚基)(全氟乙基)胺；(2-甲基-6-全氟甲基-全氟联苯基)(全氟甲基)(己基)胺；(2-甲基-6-全氟甲基-全氟联苯基)(氟甲基)(壬基)胺；(2-甲基-6-全氟甲基-全氟联苯基)(甲基)(己基)胺；(2-甲基-6-全氟甲基-全氟联苯基)(己基)(丁基)胺；(2-甲基-6-全氟甲基-全氟联苯基)(二氟丁基)胺；(2-甲基-6-全氟甲基-全氟联苯基)(丁基)(全氟丁基)胺；(2-甲基-6-全氟甲基-全氟联苯基)(二己基)胺；(2-甲基-6-全氟甲基-全氟联苯基)(丁基)(丙基)胺；(2-甲基-6-全氟甲基-全氟联苯基)(氟甲基)(乙基)胺；(2-全氟甲基-6-全氟乙基-全氟联苯基)(六氟壬基)(氟甲基)胺；(2-全氟甲基-6-全氟乙基-全氟联苯基)(二氟丁基)胺；(2-全氟甲基-6-全氟乙基-全氟联苯基)(甲基)(乙基)胺；(2-全氟甲基-6-全氟乙基-全氟联苯基)(3-乙基庚基)(甲基)胺；(2-全氟甲基-6-全氟乙基-全氟联苯基)(全氟乙基)(全氟甲基)胺；(2-全氟甲基-6-全氟乙基-全氟联苯基)(二己基)胺；(2-全氟甲基-6-全氟乙基-全氟联苯基)(全氟丁基)(丁基)胺；(2-全氟甲基-6-全氟乙基-全氟联苯基)(全氟丁基)(丁基)胺；(2-全氟甲基-6-全氟乙基-全氟联苯基)(全氟丁基)(乙基)胺；(2-全氟甲基-6-全氟乙基-全氟联苯基)(丁基)(甲基)胺；(2-全氟甲基-6-全氟乙基-全氟联苯基)(二丙基)胺；(3-甲基-全氟苯基)(己基)(全氟乙基)胺；(3-甲基-全氟苯基)(六氟壬基)(氟甲基)胺；(3-甲基-全氟苯基)(乙基)(2-甲基戊基)胺；(3-甲基-全氟苯基)(乙基)(丙基)胺；(3-甲基-全氟苯基)(氟甲基)(氟乙基)胺；(3-甲基-全氟苯基)(丙基)(氟甲基)胺；(3-甲基-全氟苯基)(己基)(全氟乙基)胺；(3-甲基-全氟苯基)(丁基)(乙基)胺；(3-甲基-全氟苯基)(丙基)(氟甲基)胺；(3-甲基-全氟苯基)(己基)(丙基)胺；(3-全氟乙基-三氟苯基)(丙基)(氟甲基)胺；(3-全氟乙基-三氟苯基)(己基)(全氟乙基)胺；(3-全氟乙基-三氟苯基)(全氟乙基)(全氟甲基)胺；(3-全氟乙基-三氟苯基)(全氟丁基)(己基)胺；(3-全氟乙基-三氟苯基)(乙基)(全氟丁基)胺；(3-全氟乙基-三氟苯基)(二丙基)胺；(3-全氟乙基-三氟苯基)(甲基)(六氟壬基)胺；(3-全氟乙基-三氟苯基)(全氟乙基)(丙基)胺；(3-全氟乙基-三氟苯基)(氟甲基)(丁基)胺；(3-全氟乙基-三氟苯基)(全氟丁基)(2-甲基戊基)胺；(3-全氟乙基-三氟苯基)(全氟甲基)(乙基)胺；(3-全氟乙基-三氟苯基)(全氟丁基)(丙基)胺；(3-全氟乙基-三氟苯基)(丙基)(丁基)胺；(3-全氟乙基-三氟苯基)(六氟壬基)(己基)胺；(3-全氟甲基-三氟苯基)(六氟壬基)(丁基)胺；(3-全氟甲基-三氟苯基)(氟甲基)(丙基)胺；(3-全氟甲基-三氟苯基)(乙基)(2-甲基戊基)胺；(3-全氟甲基-三氟苯基)(全氟丁基)(丙基)胺；(3-全氟甲基-三氟苯基)(乙基)(氟甲基)胺；(3-全氟甲基-三氟苯基)(氟甲基)(甲基)胺；(3-全氟甲基-三氟苯基)(丙基)(乙基)胺；(3-全氟甲基-三氟苯基)(丁基)(全氟乙基)胺；(3-全氟甲基-三氟苯基)(己基)(氟甲基)胺；(联苯基)(壬基)(全氟乙基)胺；(联苯基)(2-甲基-5-丙基-庚基)(全氟乙基)胺；(联苯基)(丙基)(乙基)胺；(联苯基)(乙基)(丙基)胺；(联苯基)(乙基)(氟甲基)胺；(联苯基)(丁基)(乙基)胺；(联苯基)(乙基)(丁基)胺；(联苯基)(氟甲基)(甲基)胺；(联苯基)(全氟乙基)(己基)胺；(联苯基)(丁基)(乙基)胺；(联苯基)(甲基)(壬基)胺；(联苯基)(2-甲基戊基)(全氟丁基)胺；(联苯基)(丙基)(氟甲基)胺；(联苯基)(全氟乙基)(丙基)胺；(联苯基)(全氟甲基)(乙基)胺；(联苯基)(全氟甲基)(丙基)胺；(联苯基)(二甲基)胺；(联苯基)(甲基)(全氟丁基)胺；(联苯基)(氟甲基)(3-乙基庚基)胺；(联苯基)(甲基)(乙基)胺；(联苯基)(2-甲基戊基)(全氟丁基)胺；(联苯基)(丙基)(甲基)胺；(联苯基)(乙基)(全氟乙基)胺；(联苯基)(2-甲基-5-丙基-庚基)(全氟丁基)胺；(联苯基)(氟甲基)(2-甲基-5-丙基-庚基)胺；(联苯基)(二甲基)胺；(联苯基)(全氟乙基)(2-甲基-5-丙基-庚基)胺；(联苯基)(丙基)(全氟乙基)胺；(联苯基)(全氟丁基)(3-乙基庚基)胺；(联苯基)(丁基)(3-乙基庚基)胺；(联苯基)(二氟甲基)胺；(联苯基)(丙基)(甲基)胺；(联苯基)(全氟乙基)(己基)胺；(联苯基)(丙基)(3-乙基庚基)胺；(六氟联苯基)(丁基)(氟甲基)胺；(六氟联苯基)(全氟乙基)(壬基)胺；(六氟联苯基)(乙基)(己基)胺；(六氟联苯基)(己基)(2-甲基-5-丙基-庚基)胺；(八氟联苯基)(乙基)(全氟丁基)胺；(八氟联苯基)(殊途同归基)(全氟甲基)胺；(八氟联苯基)(2-甲基戊基)(全氟甲基)胺；(八氟联苯基)(丁基)(全氟乙基)胺；(八氟联苯基)(二丙基)胺；(八氟联苯基)(2-甲基-5-丙基-庚基)(乙基)胺；(八氟联苯基)(乙基)(丙基)胺；(八氟联苯基)(六氟壬基)(2-甲基-5-丙基-庚基)胺；(八氟联苯基)(全氟甲基)(氟丁基)胺；(全氟联苯基)(全氟甲基)(丁基)胺；(全氟联苯基)(丁基)(六氟壬基)胺；(全氟联苯基)(乙基)(2-甲基戊基)胺；(全氟联苯基)(乙基)(己基)胺；(全氟联苯基)(乙基)(全氟甲基)胺；(全氟联苯基)(丙基)(全氟乙基)胺；(全氟联苯基)(己基)(甲基)胺；(全氟联苯基)(2-甲基戊基)(全氟甲基)胺；(全氟联苯基)(甲基)(氟甲基)胺；(全氟联苯基)(二甲基)胺；(全氟联苯基)(氟甲基)胺；(全氟联苯基)(壬基)(乙基)胺；(全氟联苯基)(壬基)(氟甲基)胺；(全氟联苯基)(全氟丁基)(氟乙基)胺；(全氟联苯基)(二丁基)胺；(全氟联苯基)(全氟乙基)(丙基)胺；(全氟联苯基)(乙基)(丁基)胺；(全氟联苯基)(氟甲基)(丙基)胺；(全氟联苯基)(二乙基)胺；(全氟联苯基)(全氟乙基)(己基)胺；(全氟联苯基)(壬基)(全氟甲基)胺；(全氟联苯基)(己基)(丁基)胺；(全氟联苯基)(壬基)(氟甲基)胺；(全氟联苯基)(全氟丁基)(甲基)胺；(全氟联苯基)(3-乙基己基)(甲基)胺；(全氟联苯基)(壬基)(丙基)胺；(全氟联苯基)(己基)(丙基)胺；(全氟联苯基)(全氟丁基)(氟甲基)胺；(全氟联苯基)(丙基)(全氟乙基)胺；(全氟联苯基)(丁基)(全氟甲基)胺；(全氟联苯基)(二丁基)胺；(全氟联苯基)(乙基)(丙基)胺；(全氟联苯基)(丁基)(甲基)胺；(全氟联苯基)(丙基)(己基)胺；(全氟联苯基)(氟甲基)(氟甲基)胺；(全氟联苯基)(壬基)(丙基)胺；(全氟联苯基)(氟甲基)(甲基)胺；(全氟联苯基)(氟甲基)(2-甲基戊基)胺；(全氟联苯基)(丁基)(氟甲基)胺；(全氟联苯基)(全氟甲基)(丙基)胺；(全氟联苯基)(3-乙基庚基)(全氟丁基)胺；(全氟联苯基)(全氟甲基)(氟乙基)胺；(全氟联苯基)(己基)(丙基)胺；(全氟联苯基)(丙基)(丁基)胺；(全氟联苯基)(丁基)(全氟甲基)胺；(全氟联苯基)(全氟乙基)(氟甲基)胺；(全氟联苯基)(六氟壬基)(甲基)胺；(全氟联苯基)(氟甲基)(乙基)胺；(全氟联苯基)(全氟乙基)(2-甲基-5-丙基-庚基)胺；(全氟联苯基)(全氟丁基)(氟甲基)胺；(全氟联苯基)(全氟丁基)(氟甲基)胺；(全氟联苯基)(全氟丁基)(氟甲基)胺；(全氟联苯基)(己基)(丁基)胺；(全氟联苯基)(丙基)(丁基)胺；(全氟联苯基)(六氟壬基)(丙基)胺；(全氟联苯基)(全氟乙基)(甲基)胺；(全氟联苯基)(己基)(全氟甲基)胺；(全氟联苯基)(乙基)(全氟丁基)胺；(全氟联苯基)(甲基)(3-乙基庚基)胺；(全氟联苯基)(丙基)(乙基)胺；(全氟联苯基)(壬基)(甲基)胺；(全氟联苯基)(全氟乙基)(氟丁基)胺；(全氟联苯基)(全氟乙基)(甲基)胺；(全氟联苯基)(二氟甲基)胺；(全氟联苯基)(氟甲基)(氟甲基)胺；(全氟联苯基)(全氟甲基)(己基)胺；(全氟联苯基)(丙基)(全氟甲基)胺；(全氟联苯基)(氟甲基)胺；(全氟联苯基)(二丁基)胺；(全氟联苯基)(六氟壬基)(氟丁基)胺；(全氟联苯基)(全氟丁基)(己基)胺；(全氟苯基)(氟甲基)(己基)胺；(全氟苯基)(乙基)(己基)胺；(全氟苯基)(乙基)(己基)胺；(全氟苯基)(氟甲基)(甲基)胺；(全氟苯基)(丁基)(全氟乙基)胺；(全氟苯基)(乙基)(全氟丁基)胺；(全氟苯基)(二丙基)胺；(全氟苯基)(丙基)(乙基)胺；(全氟苯基)(二甲基)胺；(全氟苯基)(全氟甲基)(甲基)胺；(全氟苯基)(丁基)(六氟壬基)胺；(全氟苯基)(2-甲基-5-丙基-庚基)(己基)胺；(全氟苯基)(丁基)(甲基)胺；(全氟苯基)(丁基)(氟甲基)胺；(全氟苯基)(己基)(壬基)胺；(全氟苯基)(全氟丁基)(丙基)胺；(全氟苯基)(己基)(全氟甲基)胺；(全氟苯基)(氟甲基)(甲基)胺；(全氟苯基)(2-甲基戊基)(乙基)胺；(全氟苯基)(丙基)(甲基)胺；(全氟苯基)(丙基)(2-甲基戊基)胺；(全氟苯基)(全氟乙基)(乙基)胺；(全氟苯基)(全氟丁基)(丙基)胺；(全氟苯基)(甲基)(全氟乙基)胺；(全氟苯基)(甲基)(乙基)胺；(全氟苯基)(甲基)(乙基)胺；(全氟苯基)(全氟乙基)(氟丁基)胺；(全氟苯基)(3-乙基庚基)(丁基)胺；(全氟苯基)(全氟丁基)(氟乙基)胺；(全氟苯基)(丙基)(3-乙基庚基)胺；(全氟苯基)(全氟甲基)(3-乙基庚基)胺；(全氟苯基)(3-乙基庚基)(己基)胺；(全氟苯基)(甲基)(2-甲基-5-丙基-庚基)胺；(全氟苯基)(全氟乙基)(壬基)胺；(全氟苯基)(丙基)(甲基)胺；(全氟苯基)(全氟乙基)(己基)胺；(全氟苯基)(全氟丁基)(氟甲基)胺；(全氟苯基)(全氟丁基)(氟甲基)胺；(全氟苯基)(丙基)(壬基)胺；(全氟苯基)(全氟甲基)(氟甲基)胺；(全氟苯基)(己基)(全氟乙基)胺；(全氟苯基)(全氟甲基)(甲基)胺；(全氟苯基)(氟甲基)(氟乙基)胺；(全氟苯基)(甲基)(全氟甲基)胺；(全氟苯基)(丙基)(己基)胺；(全氟苯基)(甲基)(丁基)胺；(全氟苯基)(丁基)(甲基)胺；(全氟苯基)(全氟甲基)(己基)胺；(全氟苯基)(丁基)(甲基)胺；(全氟苯基)(2-甲基-5-丙基-庚基)(全氟甲基)胺；(全氟苯基)(2-甲基-5-丙基-庚基)(甲基)胺；(全氟苯基)(氟甲基)(氟丁基)胺；(全氟苯基)(丁基)(3-乙基庚基)胺；(全氟苯基)(壬基)(全氟甲基)胺；(全氟苯基)(全氟丁基)(己基)胺；(全氟苯基)(二甲基)胺；(全氟苯基)(氟甲基)(氟乙基)胺；(全氟苯基)(甲基)(全氟甲基)胺；(全氟苯基)(全氟甲基)(己基)胺；(全氟苯基)(乙基)(氟甲基)胺；(全氟苯基)(丙基)(3-乙基庚基)胺；(全氟苯基)(乙基)(氟甲基)胺；(全氟苯基)(二氟甲基)胺；(全氟苯基)(全氟丁基)(己基)胺；(全氟苯基)(氟甲基)(氟甲基)胺；(全氟苯基)(全氟甲基)(氟丁基)胺；(全氟苯基)(氟甲基)(甲基)胺；(全氟苯基)(己基)(全氟乙基)胺；(全氟苯基)(丙基)(全氟丁基)胺；(全氟苯基)(氟甲基)(氟乙基)胺；(全氟苯基)(甲基)(丁基)胺；(全氟苯基)(己基)(全氟丁基)胺；(全氟苯基)(己基)(氟甲基)胺；(全氟苯基)(甲基)(己基)胺；(全氟苯基)(二氟甲基)胺；(苯基)(氟甲基)(全氟丁基)胺；(苯基)(3-己基庚基)(壬基)胺；(苯基)(全氟丁基)(甲基)胺；(苯基)(二丙基)胺；(苯基)(丙基)(己基)胺；(苯基)(全氟甲基)(壬基)胺；(苯基)(乙基)(2-甲基戊基)胺；(苯基)(氟甲基)(己基)胺；(苯基)(丁基)(全氟丁基)胺；(苯基)(二丙基)胺；(苯基)(氟甲基)(甲基)胺；(苯基)(氟甲基)(甲基)胺；(苯基)(全氟丁基)(丙基)胺；(苯基)(甲基)(2-甲基戊基)胺；(苯基)(丁基)(己基)胺；(苯基)(己基)(氟甲基)胺；(苯基)(全氟丁基)(乙基)胺；(苯基)(全氟甲基)(丙基)胺；(苯基)(氟甲基)(氟乙基)胺；(苯基)(乙基)(丁基)胺；(苯基)(全氟乙基)(己基)胺；(苯基)(2-甲基戊基)(甲基)胺；(苯基)(丙基)(全氟丁基)胺；(苯基)(乙基)(甲基)胺；(苯基)(全氟丁基)(甲基)胺；(苯基)(全氟甲基)(2-甲基-5-丙基-庚基)胺；(苯基)(丁基)(全氟乙基)胺；(苯基)(全氟乙基)(己基)胺；(苯基)(氟甲基)(全氟丁基)胺；(苯基)(氟甲基)(2-甲基-5-丙基-庚基)胺；(苯基)(全氟丁基)(乙基)胺；(苯基)(乙基)(全氟乙基)胺；(苯基)(乙基)(甲基)胺；(四氟苯基)(二丙基)胺；(四氟苯基)(丁基)(甲基)胺；(四氟苯基)(丙基)(氟甲基)胺；(四氟苯基)(氟甲基)(乙基)胺；(四氟苯基)(丁基)(全氟乙基)胺；(四氟苯基)(乙基)(丙基)胺；(四氟苯基)(乙基)(氟甲基)胺；(1-氟联苯基)(乙基)(全氟丁基)膦；(1-氟联苯基)(二-3-乙基庚基)膦；(1-氟联苯基)(全氟乙基)(丙基)膦；(1-氟联苯基)(二丁基)膦；(1-氟联苯基)(乙基)(己基)膦；(1-氟联苯基)(甲基)(全氟甲基)膦；(1-氟联苯基)(3-乙基庚基)(己基)膦；(1-氟联苯基)(氟甲基)(丁基)膦；(1-氟联苯基)(3-乙基庚基)(丁基)膦；(1-氟苯基)(丙基)(全氟乙基)膦；(1-氟苯基)(丙基)(丁基)膦；(1-氟苯基)(全氟乙基)(甲基)膦；(1-氟苯基)(己基)(2-甲基-5-丙基-庚基)膦；(2，3-二氟苯基)(丙基)(乙基)膦；(2，3-二氟苯基)(甲基)(全氟乙基)膦；(2，3-二氟苯基)(丁基)(丙基)膦；(2，3-二氟苯基)(二氟甲基)膦；(2，3-二氟苯基)(全氟丁基)(乙基)膦；(2，4-二氟苯基)(丁基)(己基)膦；(2，4-二氟苯基)(己基)(全氟甲基)膦；(2，4-二氟苯基)(丙基)(丁基)膦；(2，4-二氟苯基)(己基)(丙基)膦；(2，4-二氟苯基)(2-甲基-5-丙基-庚基)(乙基)膦；(2，4-二氟苯基)(二甲基)膦；(2，5-二氟苯基)(2-甲基戊基)(乙基)膦；(2，5-二氟苯基)(丁基)(氟甲基)膦；(2-甲基-6-全氟甲基-全氟联苯基)(丙基)(甲基)膦；(2-甲基-6-全氟甲基-全氟联苯基)(2-甲基-5-丙基-庚基)(己基)膦；(2-甲基-6-全氟甲基-全氟联苯基)(2-甲基戊基)(甲基)膦；(2-全氟甲基-6-全氟乙基-全氟联苯基)(丙基)(氟甲基)膦；(2-全氟甲基-6-全氟乙基-全氟联苯基)(丁基)(乙基)膦；(2-全氟甲基-6-全氟乙基-全氟联苯基)(全氟乙基)(氟甲基)膦；(2-全氟甲基-6-全氟乙基-全氟联苯基)(丙基)(甲基)膦；(2-全氟甲基-6-全氟乙基-全氟联苯基)(己基)(2-甲基戊基)膦；(3-甲基-全氟苯基)(2-甲基-5-丙基-庚基)(氟甲基)膦；(3-甲基-全氟苯基)(甲基)(丙基)膦；(3-甲基-全氟苯基)(甲基)(氟甲基)膦；(3-甲基-全氟苯基)(氟甲基)(丁基)膦；(3-甲基-全氟苯基)(3-乙基庚基)(六氟壬基)膦；(3-甲基-全氟苯基)(全氟乙基)(氟甲基)膦；(3-全氟乙基-三氟苯基)(己基)(乙基)膦；(3-全氟乙基-三氟苯基)(全氟乙基)(丙基)膦；(3-全氟乙基-三氟苯基)二(2，2，2-三氟乙基)膦；(3-全氟乙基-三氟苯基)(甲基)(己基)膦；(3-全氟乙基-三氟苯基)(二乙基)膦；(3-全氟乙基-三氟苯基)(六氟壬基)(氟乙基)膦；(3-全氟乙基-三氟苯基)(六氟壬基)(丁基)膦；(3-全氟甲基-三氟苯基)(乙基)(氟甲基)膦；(3-全氟甲基-三氟苯基)(全氟乙基)(六氟壬基)膦；(3-全氟甲基-三氟苯基)(己基)(乙基)膦；(3-全氟甲基-三氟苯基)(己基)(六氟壬基)膦；(3-全氟甲基-三氟苯基)(全氟乙基)(丁基)膦；(3-全氟甲基-三氟苯基)(全氟丁基)(氟甲基)膦；(3-全氟甲基-三氟苯基)(氟甲基)(丁基)膦；(联苯基)(全氟丁基)(氟乙基)膦；(联苯基)(六氟壬基)(丁基)膦；(联苯基)(甲基)(氟甲基)膦；(联苯基)(全氟乙基)(全氟甲基)膦；(联苯基)(丁基)(氟甲基)膦；(联苯基)(六氟壬基)(己基)膦；(联苯基)(甲基)(六氟壬基)膦；(联苯基)(全氟丁基)(氟甲基)膦；(六氟联苯基)(丙基)(乙基)膦；(六氟联苯基)(甲基)(丙基)膦；(六氟联苯基)(氟甲基)(氟乙基)膦；(全氟联苯基)(丁基)(丙基)膦；(全氟联苯基)(二氟丁基)膦；(全氟联苯基)(乙基)(壬基)膦；(全氟联苯基)(氟甲基)(丁基)膦；(全氟联苯基)(丁基)(全氟甲基)膦；(全氟联苯基)(氟甲基)(氟甲基)膦；(全氟联苯基)(丙基)(全氟甲基)膦；(全氟联苯基)(甲基)(氟甲基)膦；(全氟联苯基)(丙基)(全氟乙基)膦；(全氟联苯基)(丙基)(全氟丁基)膦；(全氟联苯基)(全氟丁基)(氟甲基)膦；(全氟联苯基)(甲基)(氟甲基)膦；(全氟联苯基)(丁基)(全氟丁基)膦；(全氟联苯基)(二氟甲基)膦；(全氟联苯基)(乙基)(丁基)膦；(全氟联苯基)(己基)(全氟乙基)膦；(全氟联苯基)(全氟甲基)(丙基)膦；(全氟联苯基)(全氟甲基)(2-甲基戊基)膦；(全氟联苯基)(壬基)(乙基)膦；(全氟联苯基)二(2，2，2-三氟乙基)膦；(全氟联苯基)(甲基)(乙基)膦；(全氟联苯基)(丁基)(乙基)膦；(全氟联苯基)(2-甲基-5-丙基-庚基)(甲基)膦；(全氟联苯基)(氟甲基)(丙基)膦；(全氟联苯基)(2-甲基戊基)(甲基)膦；(全氟联苯基)(氟甲基)(己基)膦；(全氟联苯基)(乙基)(己基)膦；(全氟联苯基)(二甲基)膦；(全氟苯基)(丁基)(甲基)膦；(全氟苯基)(乙基)(全氟丁基)膦；(全氟苯基)(2-甲基-5-丙基-庚基)(乙基)膦；(全氟苯基)(全氟甲基)(己基)膦；(全氟苯基)(己基)(丙基)膦；(全氟苯基)(丙基)(氟甲基)膦；(全氟苯基)(乙基)(丁基)膦；(全氟苯基)(全氟乙基)(己基)膦；(全氟苯基)(己基)(六氟壬基)膦；(全氟苯基)(氟甲基)膦；(全氟苯基)(全氟丁基)(乙基)膦；(全氟苯基)(甲基)(丙基)膦；(全氟苯基)(全氟乙基)(丁基)膦；(全氟苯基)(氟甲基)(甲基)膦；(全氟苯基)(全氟甲基)(丙基)膦；(全氟苯基)(丁基)(六氟壬基)膦；(全氟苯基)(丁基)(2-甲基-5-丙基-庚基)膦；(全氟苯基)(丁基)(全氟乙基)膦；(全氟苯基)(丙基)(3-乙基庚基)膦；(全氟苯基)(二甲基)膦；(全氟苯基)(乙基)(全氟乙基)膦；(全氟苯基)(甲基)(丁基)膦；(全氟苯基)(丁基)(丙基)膦；(全氟苯基)(己基)(全氟乙基)膦；(全氟苯基)(氟甲基)(乙基)膦；(全氟苯基)(甲基)(3-乙基庚基)膦；(全氟苯基)(丙基)(乙基)膦；(全氟苯基)(丙基)(六氟壬基)膦；(全氟苯基)(3-乙基庚基)(丙基)膦；(全氟苯基)(己基)(甲基)膦；(全氟苯基)(丙基)(壬基)膦；(全氟苯基)(全氟丁基)(3-乙基庚基)膦；(全氟苯基)(丁基)(全氟乙基)膦；(全氟苯基)(全氟丁基)(氟甲基)膦；(全氟苯基)(氟甲基)(乙基)膦；(全氟苯基)(氟甲基)(甲基)膦；(全氟苯基)(二壬基)膦；(全氟苯基)(丁基)(丙基)膦；(全氟苯基)(全氟乙基)(氟甲基)膦；(全氟苯基)(全氟乙基)(己基)膦；(全氟苯基)(全氟丁基)(丙基)膦；(全氟苯基)(己基)(乙基)膦；(苯基)(全氟甲基)(全氟乙基)膦；(苯基)(丁基)(氟甲基)膦；(苯基)(丙基)(全氟乙基)膦；(苯基)(氟甲基)膦；(苯基)(氟甲基)(全氟丁基)膦；(苯基)(乙基)(全氟甲基)膦；(苯基)(丁基)(己基)膦；(苯基)(全氟甲基)(全氟乙基)膦；(苯基)(丙基)(2-甲基-5-丙基-庚基)膦；(苯基)(己基)(氟甲基)膦；(苯基)(乙基)(全氟丁基)膦；(苯基)(2-甲基-5-丙基-庚基)(己基)膦；(苯基)(全氟甲基)(氟甲基)膦；(苯基)(3-乙基庚基)(己基)膦；(苯基)(2-甲基-5-丙基-庚基)(氟甲基)膦；(苯基)(乙基)(全氟丁基)膦；(苯基)(丁基)(甲基)膦；(四氟苯基)(己基)(丙基)膦；(四氟苯基)(丁基)(全氟乙基)膦；(四氟苯基)(六氟壬基)(丙基)膦；(四氟苯基)(丁基)(己基)膦；(四氟苯基)(丁基)(甲基)膦；(四氟苯基)(己基)(甲基)膦；(四氟苯基)(己基)(氟甲基)膦。
典型的氟芳基配体取代的环状胺和膦
N-(1-氟联苯基)吲哚；N-(1-氟苯基)吲哚；N-(2，3-二氟苯基)吲哚；N-(2，4-二氟苯基)吲哚；N-(2，5-二氟苯基)吲哚；N-(2-甲基-6-全氟甲基-全氟联苯基)吲哚；N-(2-全氟甲基-6-全氟乙基-全氟联苯基)吲哚；N-(3-甲基-全氟苯基)吲哚；N-(3-全氟乙基-三氟苯基)吲哚；N-(3-全氟甲基-三氟苯基)吲哚；N-(联苯基)吲哚；N-(六氟联苯基)吲哚；N-(八氟联苯基)吲哚；N-(全氟联苯基)吲哚；N-(全氟苯基)吲哚；N-(苯基)吲哚；N-(四氟苯基)吲哚；N-(1-氟联苯基)二氢吲哚；N-(1-氟苯基)二氢吲哚；N-(2，3-二氟苯基)二氢吲哚；N-(2，4-二氟苯基)二氢吲哚；N-(2，5-二氟苯基)二氢吲哚；N-(2-甲基-6-全氟甲基-全氟联苯基)二氢吲哚；N-(2-全氟甲基-6-全氟乙基-全氟联苯基)二氢吲哚；N-(3-甲基-全氟苯基)二氢吲哚；N-(3-全氟乙基-三氟苯基)二氢吲哚；N-(3-全氟甲基-三氟苯基)二氢吲哚；N-(联苯基)二氢吲哚；N-(六氟联苯基)二氢吲哚；N-(八氟联苯基)二氢吲哚；N-(全氟联苯基)二氢吲哚；N-(全氟苯基)二氢吲哚；N-(苯基)二氢吲哚；N-(四氟苯基)二氢吲哚；N-(1-氟联苯基)二氢异吲哚；N-(1-氟苯基)二氢异吲哚；N-(2，3-二氟苯基)二氢异吲哚；N-(2，4-二氟苯基)二氢异吲哚；N-(2，5-二氟苯基)二氢异吲哚；N-(2-甲基-6-全氟甲基-全氟联苯基)二氢异吲哚；N-(2-全氟甲基-6-全氟乙基-全氟联苯基)二氢异吲哚；N-(3-甲基-全氟苯基)二氢异吲哚；N-(3-全氟乙基-三氟苯基)二氢异吲哚；N-(3-全氟甲基-三氟苯基)二氢异吲哚；N-(联苯基)二氢异吲哚；N-(六氟联苯基)二氢异吲哚；N-(八氟联苯基)二氢异吲哚；N-(全氟联苯基)二氢异吲哚；N-(全氟苯基)二氢异吲哚；N-(苯基)二氢异吲哚；N-(四氟苯基)二氢异吲哚；N-(1-氟联苯基)磷杂吡咯烷；N-(1-氟苯基)磷杂吡咯烷；N-(2，3-二氟苯基)磷杂吡咯烷；N-(2，4-二氟苯基)磷杂吡咯烷；N-(2，5-二氟苯基)磷杂吡咯烷；N-(2-甲基-6-全氟甲基-全氟联苯基)磷杂吡咯烷；N-(2-全氟甲基-6-全氟乙基-全氟联苯基)磷杂吡咯烷；N-(3-甲基-全氟苯基)磷杂吡咯烷；N-(3-全氟乙基-三氟苯基)磷杂吡咯烷；N-(3-全氟甲基-三氟苯基)磷杂吡咯烷；N-(联苯基)磷杂吡咯烷；N-(六氟联苯基)磷杂吡咯烷；N-(八氟联苯基)磷杂吡咯烷；N-(全氟联苯基)磷杂吡咯烷；N-(全氟苯基)磷杂吡咯烷；N-(苯基)磷杂吡咯烷；N-(四氟苯基)磷杂吡咯烷；N-(1-氟联苯基)磷杂吲哚；N-(1-氟苯基)磷杂吲哚；N-(2，3-二氟苯基)磷杂吲哚；N-(2，4-二氟苯基)磷杂吲哚；N-(2，5-二氟苯基)磷杂吲哚；N-(2-甲基-6-全氟甲基-全氟联苯基)磷杂吲哚；N-(2-全氟甲基-6-全氟乙基-全氟联苯基)磷杂吲哚；N-(3-甲基-全氟苯基)磷杂吲哚；N-(3-全氟乙基-三氟苯基)磷杂吲哚；N-(3-全氟甲基-三氟苯基)磷杂吲哚；N-(联苯基)磷杂吲哚；N-(六氟联苯基)磷杂吲哚；N-(八氟联苯基)磷杂吲哚；N-(全氟联苯基)磷杂吲哚；N-(全氟苯基)磷杂吲哚；N-(苯基)磷杂吲哚；N-(四氟苯基)磷杂吲哚；N-(1-氟联苯基)磷杂二氢吲哚；N-(1-氟苯基)磷杂二氢吲哚；N-(2，3-二氟苯基)磷杂二氢吲哚；N-(2，4-二氟苯基)磷杂二氢吲哚；N-(2，5-二氟苯基)磷杂二氢吲哚；N-(2-甲基-6-全氟甲基-全氟联苯基)磷杂二氢吲哚；N-(2-全氟甲基-6-全氟乙基-全氟联苯基)磷杂二氢吲哚；N-(3-甲基-全氟苯基)磷杂二氢吲哚；N-(3-全氟乙基-三氟苯基)磷杂二氢吲哚；N-(3-全氟甲基-三氟苯基)磷杂二氢吲哚；N-(联苯基)磷杂二氢吲哚；N-(六氟联苯基)磷杂二氢吲哚；N-(八氟联苯基)磷杂二氢吲哚；N-(全氟联苯基)磷杂二氢吲哚；N-(全氟苯基)磷杂二氢吲哚；N-(苯基)磷杂二氢吲哚；N-(四氟苯基)磷杂二氢吲哚；N-(1-氟联苯基)哌啶；N-(1-氟苯基)哌啶；N-(2，3-二氟苯基)哌啶；N-(2，4-二氟苯基)哌啶；N-(2，5-二氟苯基)哌啶；N-(2-甲基-6-全氟甲基-全氟联苯基)哌啶；N-(2-全氟甲基-6-全氟乙基-全氟联苯基)哌啶；N-(3-甲基-全氟苯基)哌啶；N-(3-全氟乙基-三氟苯基)哌啶；N-(3-全氟甲基-三氟苯基)哌啶；N-(联苯基)哌啶；N-(六氟联苯基)哌啶；N-(八氟联苯基)哌啶；N-(全氟联苯基)哌啶；N-(全氟苯基)哌啶；N-(苯基)哌啶；N-(四氟苯基)哌啶；N-(1-氟联苯基)吡咯；N-(1-氟苯基)吡咯；N-(2，3-二氟苯基)吡咯；N-(2，4-二氟苯基)吡咯；N-(2，5-二氟苯基)吡咯；N-(2-甲基-6-全氟甲基-全氟联苯基)吡咯；N-(2-全氟甲基-6-全氟乙基-全氟联苯基)吡咯；N-(3-甲基-全氟苯基)吡咯；N-(3-全氟乙基-三氟苯基)吡咯；N-(3-全氟甲基-三氟苯基)吡咯；N-(联苯基)吡咯；N-(六氟联苯基)吡咯；N-(八氟联苯基)吡咯；N-(全氟联苯基)吡咯；N-(全氟苯基)吡咯；N-(苯基)吡咯；N-(四氟苯基)吡咯；N-(1-氟联苯基)吡咯烷；N-(1-氟苯基)吡咯烷；N-(2，3-二氟苯基)吡咯烷；N-(2，4-二氟苯基)吡咯烷；N-(2，5-二氟苯基)吡咯烷；N-(2-甲基-6-全氟甲基-全氟联苯基)吡咯烷；N-(2-全氟甲基-6-全氟乙基-全氟联苯基)吡咯烷；N-(3-甲基-全氟苯基)吡咯烷；N-(3-全氟乙基-三氟苯基)吡咯烷；N-(3-全氟甲基-三氟苯基)吡咯烷；N-(联苯基)吡咯烷；N-(六氟联苯基)吡咯烷；N-(八氟联苯基)吡咯烷；N-(全氟联苯基)吡咯烷；N-(全氟苯基)吡咯烷；N-(苯基)吡咯烷；N-(四氟苯基)吡咯烷；
适用于烯烃聚合的典型的非配位阴离子
四(五氟萘基)硼酸根；四(2-甲基-5-丙基-庚基)铝酸根；四(2-甲基-5-丙基-庚基)硼酸根；四(2-甲基戊基)铝酸根；四(2-甲基戊基)硼酸根；四(3-乙基庚基)铝酸根；四(3-乙基庚基)硼酸根；四丁基铝酸根；四丁基硼酸根；四(乙基六氟萘基)铝酸根；四(乙基六氟萘基)硼酸根；四(七氟芴基)铝酸根；四(七氟芴基)硼酸根；四庚基铝酸根；四庚基硼酸根；四(六氟茚基)铝酸根；四(六氟茚基)硼酸根；四(六氟萘基)铝酸根；四(六氟萘基)硼酸根；四(六氟壬基)铝酸根；四(六氟壬基)硼酸根；四己基铝酸根；四己基硼酸根；四(甲基八氟联苯基)铝酸根；四(甲基八氟联苯基)硼酸根；四(甲基全氟萘基)铝酸根；四(甲基全氟萘基)硼酸根；四壬基铝酸根；四壬基硼酸根；四(八氟联苯基)铝酸根；四(八氟联苯基)硼酸根；四辛基铝酸根；四辛基硼酸根；四(五氟茚基)铝酸根；四(五氟茚基)硼酸根；四(五氟萘基)铝酸根；四(五氟萘基)硼酸根；四戊基铝酸根；四戊基硼酸根；四全氟蒽基铝酸根；四全氟蒽基硼酸根；四(全氟联苯基)铝酸根；四(全氟联苯基)硼酸根；四(全氟乙基全氟联苯基)铝酸根；四(全氟乙基全氟联苯基)硼酸根；四全氟芴基铝酸根；四全氟芴基硼酸根；四(全氟己基全氟苯基)铝酸根；四(全氟己基全氟苯基)硼酸根；四(全氟茚基)铝酸根；四(全氟茚基)硼酸根；四(全氟甲基全氟萘基)铝酸根；四(全氟甲基全氟萘基)硼酸根；四(全氟萘基)铝酸根；四(全氟萘基)硼酸根；四(全氟戊基全氟联苯基)铝酸根；四(全氟戊基全氟联苯基)硼酸根；四全氟菲基铝酸根；四全氟菲基硼酸根；四全氟苯基铝酸根；四全氟苯基硼酸根；四(全氟芘基)铝酸根；四(全氟芘基)硼酸根。
典型的本发明第13族助催化剂配合物
[四庚基铝酸][(2，4-二氟苯基)(氟甲基)(乙基)铵]；[四(六氟壬基)硼酸][(3-全氟乙基-三氟苯基)(二己基)磷鎓]；[四(全氟己基全氟苯基)硼酸][(2，3-二氟苯基)(丙基)(甲基)铵]；[四全氟苯基铝酸][(联苯基)(甲基)(六氟壬基)铵]；[四(六氟茚基)铝酸][(3-甲基-全氟苯基)(壬基)(丙基)铵]；[四(六氟壬基)铝酸][(联苯基)(全氟乙基)(丙基)铵]；[四全氟芴基硼酸][(八氟联苯基)(二乙基)铵]；[四(全氟萘基)硼酸][(2，3-二氟苯基)(乙基)(六氟壬基)磷鎓]；[四(八氟联苯基)铝酸][(苯基)(己基)(全氟乙基)铵]；[四(六氟茚基)硼酸][(全氟苯基)(己基)(2-甲基戊基)铵]；[四庚基硼酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(乙基)(六氟壬基)磷鎓]；[四戊基硼酸][(2，5-二氟苯基)(3-乙基庚基)(丙基)磷鎓]；[四丁基铝酸][(2，5-二氟苯基)(丙基)(2-甲基-5-丙基-庚基)铵]；[四(甲基八氟联苯基)硼酸][N-(2，5-二氟苯基)吡咯鎓]；[四全氟菲基硼酸][(3-甲基-全氟苯基)(全氟乙基)(2-甲基-5-丙基-庚基)磷鎓]；[四(乙基六氟萘基)硼酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(丁基)(2-甲基戊基)铵]；[四(全氟甲基全氟萘基)硼酸][N-(3-全氟甲基-三氟苯基)二氢异吲哚鎓]；[四庚基硼酸][(1-氟联苯基)(丁基)(乙基)磷鎓]；[四辛基硼酸][N-(2，4-二氟苯基)磷杂吲哚鎓]；[四(六氟壬基)硼酸][(2，4-二氟苯基)(2-甲基戊基)(六氟壬基)铵]；[四全氟蒽基铝酸][(全氟苯基)(己基)(壬基)铵]；[四全氟茚基硼酸][(全氟联苯基)(壬基)(己基)铵]；[四全氟菲基硼酸][(联苯基)(丙基)(氟甲基)磷鎓]；[四全氟芴基铝酸][N-(2，3-二氟苯基)磷杂吲哚鎓]；[四壬基硼酸][(2-甲基-6-全氟甲基-全氟联苯基)(氟甲基)(乙基)磷鎓]；[四(六氟茚基)硼酸][(1-氟联苯基)(六氟壬基)(2-甲基-5-丙基-庚基)铵]；[四全氟菲基硼酸][(2，3-二氟苯基)(全氟乙基)(氟甲基)磷鎓]；[四(2-甲基-5-丙基-庚基)硼酸][(2，5-二氟苯基)(3-乙基庚基)(丙基)磷鎓]；[四(六氟壬基)铝酸][(1-氟联苯基)(己基)(2-甲基戊基)铵]；[四(全氟萘基)硼酸][(全氟联苯基)(2-甲基-5-丙基-庚基)(甲基)铵]；[四全氟菲基铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(丙基)(甲基)铵]；[四(乙基六氟萘基)硼酸][(2-甲基-6-全氟甲基-全氟联苯基)(己基)(3-乙基庚基)铵]；[四(七氟芴基)铝酸][(全氟苯基)(六氟壬基)(丁基)铵]；[四(七氟芴基)铝酸][(四氟苯基)(六氟壬基)(2-甲基戊基)磷鎓]；[四(全氟萘基)铝酸][(八氟联苯基)(二己基)铵]；[四(3-乙基庚基)铝酸][(2，4-二氟苯基)(乙基)(2-甲基-5-丙基-庚基)磷鎓]；[四全氟芴基硼酸][(3-全氟甲基-三氟苯基)(壬基)(乙基)铵]；[四全氟苯基硼酸][(3-全氟乙基-三氟苯基)(2-甲基-5-丙基-庚基)(全氟乙基)磷鎓]；[四(七氟芴基)铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(3-乙基庚基)(乙基)磷鎓]；[四(2-甲基-5-丙基-庚基)铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(丁基)(己基)磷鎓]；[四辛基铝酸][(全氟联苯基)(2-甲基-5-丙基-庚基)(3-乙基庚基)铵]；[四(六氟壬基)硼酸][(2，5-二氟苯基)(丙基)(全氟乙基)铵]；[四(甲基全氟萘基)铝酸][(2，4-二氟苯基)(氟甲基)(乙基)铵]；[四(2-甲基戊基)铝酸][(全氟苯基)(氟甲基)(壬基)铵]；[四(八氟联苯基)铝酸][(全氟苯基)(甲基)(丙基)磷鎓]；[四丁基硼酸][N-(联苯基)磷杂吲哚鎓]；[四(五氟萘基)硼酸][(八氟联苯基)(甲基)(乙基)铵]；[四庚基铝酸][(3-全氟乙基-三氟苯基)(3-乙基庚基)(全氟乙基)铵]；[四壬基硼酸][(2，5-二氟苯基)(甲基)(3-乙基庚基)磷鎓]；[四(全氟戊基全氟联苯基)硼酸][(2-甲基-6-全氟甲基-全氟联苯基)(丙基)(2-甲基-5-丙基-庚基)铵]；[四(全氟乙基全氟联苯基)硼酸][(1-氟联苯基)(乙基)(3-乙基庚基)铵]；[四丁基铝酸][(1-氟苯基)(二壬基)磷鎓]；[四(全氟己基全氟苯基)硼本][(3-甲基-全氟苯基)(2-甲基戊基)(甲基)铵]；[四(全氟萘基)铝酸][(全氟联苯基)(2-甲基戊基)(3-乙基庚基)铵]；[四(全氟联苯基)铝酸][(2，5-二氟苯基)(3-乙基庚基)(己基)铵]；[四(全氟乙基全氟联苯基)铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(乙基)(壬基)磷鎓]；[四(甲基八氟联苯基)硼酸][N-(1-氟苯基)吲哚鎓]；[四全氟茚基铝酸][(2，5-二氟苯基)(己基)(甲基)铵]；[四戊基硼酸][(1-氟联苯基)(2-甲基戊基)(壬基)磷鎓]；[四(六氟萘基)铝酸][(2，3-二氟苯基)(己基)(氟甲基)铵]；[四(2-甲基戊基)铝酸][(四氟苯基)(己基)(甲基)铵]；[(四全氟芴基硼酸][(3-全氟甲基-三氟苯基)(丁基)(己基)铵]；[四(六氟萘基)硼酸][(1-氟联苯基)(壬基)(丙基)铵]；[四(全氟乙基全氟联苯基)铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(2-甲基-5-丙基-庚基)(甲基)磷鎓]；[四全氟菲基铝酸][(六氟联苯基)(乙基)(己基)铵]；[四全氟苯基硼酸][(3-全氟乙基-三氟苯基)(乙基)(3-乙基庚基)铵]；[四(六氟萘基)硼酸][(3-全氟甲基-三氟苯基)(2-甲基戊基)(全氟乙基)铵]；[四(五氟茚基)硼酸][(1-氟联苯基)(乙基)(2-甲基戊基)铵]；[四庚基铝酸][(2，3-二氟苯基)(壬基)(丁基)铵]；[四庚基硼酸][(2，5-二氟苯基)(丁基)(己基)铵]；[四(六氟茚基)硼酸][(1-氟苯基)(甲基)(六氟壬基)磷鎓]；[四(全氟萘基)硼酸][(3-全氟甲基-三氟苯基)(六氟壬基)(壬基)铵]；[四(全氟甲基全氟萘基)铝酸][(六氟联苯基)(丙基)(壬基)磷鎓]；[四丁基硼酸][(2，3-二氟苯基)(丙基)(己基)磷鎓]；[四(2-甲基-5-丙基-庚基)铝酸][(2，4-二氟苯基)(3-乙基庚基)(壬基)铵]；[四(甲基八氟联苯基)硼酸][(2，4-二氟苯基)(氟甲基)(己基)铵]；[四(全氟联苯基)硼酸][(八氟联苯基)(乙基)(丙基)铵]；[四全氟苯基硼酸][(2，3-二氟苯基)(2-甲基-5-丙基-庚基)(丁基)铵]；[四全氟苯基硼酸][(六氟联苯基)(二丙基)磷鎓]；[四(甲基全氟萘基)铝酸][(2，4-二氟苯基)(壬基)(乙基)磷鎓]；[四壬基硼酸][(2，3-二氟苯基)(丙基)(全氟乙基)磷鎓]；[四(全氟己基全氟苯基)铝酸][(全氟联苯基)(2-甲基-5-丙基-庚基)(甲基)铵]；[四(五氟茚基)铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(壬基)(丙基)铵]；[四(甲基全氟萘基)硼酸][(四氟苯基)(3-乙基庚基)(2-甲基戊基)铵]；[四(五氟萘基)硼酸][(2-甲基-6-全氟甲基-全氟联苯基)(甲基)(3-乙基庚基)磷鎓]；[四(全氟乙基全氟联苯基)铝酸][(全氟苯基)(二丁基)铵]；[四(五氟萘基)铝酸][(1-氟苯基)(氟甲基)(己基)铵]；[四全氟苯基硼酸][(3-全氟乙基-三氟苯基)(2-甲基-5-丙基-庚基)(己基)磷鎓]；[四(3-乙基庚基)硼酸][(2，4-二氟苯基)(乙基)(甲基)铵]；[四庚基硼酸][(八氟联苯基)(六氟壬基)(2-甲基戊基)铵]；[四(2-甲基戊基)铝酸][(2，3-二氟苯基)(二己基)磷鎓]；[四(甲基全氟萘基铝酸][(联苯基)(3-乙基庚基)(2-甲基戊基)磷鎓]；[四辛基硼酸][(四氟苯基)(乙基)(2-甲基-5-丙基-庚基)铵]；[四(全氟己基全氟苯基)铝酸][(八氟联苯基)(2-甲基戊基)(壬基)铵]；[四氟芴基铝酸][(八氟联苯基)(六氟壬基)(甲基)铵]；[四丁基铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(壬基)(六氟壬基)铵]；[四(全氟萘基)硼酸][(2，4-二氟苯基)(丙基)(氟甲基)铵]；[四(六氟茚基)硼酸][N-(1-氟联苯基)磷杂二氢吲哚鎓]；[四(七氟芴基)硼酸][(2，3-二氟苯基)(壬基)(甲基)铵]；[四辛基硼酸][(2-甲基-6-全氟甲基-全氟联苯基)(六氟壬基)(乙基)铵]；[四(全氟芘基)硼酸][(3-全氟甲基-三氟苯基)(3-乙基庚基)(甲基)铵]；[四(乙基六氟萘基)硼酸][(全氟苯基)(3-乙基庚基)(丙基)磷鎓]；[四辛基硼酸][(六氟联苯基)(六氟壬基)(丁基)铵]；[四(五氟茚基)铝酸][(2，3-二氟苯基)(甲基)(壬基)磷鎓]；[四(全氟联苯基)铝酸][(3-全氟甲基-三氟苯基)(乙基)(壬基)磷鎓]；[四(乙基六氟萘基)铝酸][(1-氟苯基)(丁基)(己基)铵]；[四全氟菲基硼酸][(全氟苯基)(甲基)(3-乙基庚基)铵]；[四(八氟联苯基)硼酸][(3-全氟乙基-三氟苯基)(丁基)(2-甲基戊基)磷鎓]；[四(五氟萘基)硼酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(3-乙基庚基)(2-甲基戊基)磷鎓]；[四(全氟甲基全氟萘基)铝酸][(2，3-二氟苯基)(己基)(2-甲基-5-丙基-庚基)铵]；[四(五氟萘基)硼酸][(2，4-二氟苯基)(2-甲基戊基)(甲基)磷鎓]；[四(七氟芴基)硼酸][(2，4-二氟苯基)(甲基)(丙基)铵]；[四(3-乙基庚基)硼酸][(全氟苯基)(丙基)(甲基)铵]；[四己基硼酸][(六氟联苯基)(乙基)(壬基)铵]；[四己基硼酸][(3-全氟甲基-三氟苯基)(乙基)(2-甲基-5-丙基-庚基)铵]；[四(全氟芘基)铝酸][(全氟苯基)(乙基)(2-甲基戊基)铵]；[四壬基铝酸][N-(八氟联苯基)磷杂吡咯烷鎓]；[四丁基铝酸][(2，3-二氟苯基)(2-甲基-5-丙基-庚基)(乙基)磷鎓]；[四(甲基八氟联苯基)硼酸][N-(2，3-二氟苯基)吡咯烷鎓]；[四(乙基六氟萘基)铝酸][(3-全氟甲基-三氟苯基)(3-乙基庚基)(2-甲基戊基)磷鎓]；[四全氟苯基硼酸][N-(四氟苯基)吡咯鎓]；[四(3-乙基庚基)铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(甲基)(六氟壬基)铵]；[四全氟苯基硼酸][N-(3-全氟乙基-三氟苯基)吲哚鎓]；[四戊基硼酸][N-(2-全氟甲基-6-全氟乙基-全氟联苯基)磷杂吡咯烷鎓]；[四(全氟联苯基)铝酸][(1-氟苯基)(己基)(2-甲基戊基)磷鎓]；[四辛基硼酸][(3-甲基-全氟苯基)(乙基)(丙基)铵]；[四(全氟萘基)铝酸][(3-全氟乙基-三氟苯基)(己基)(3-乙基庚基)铵]；[四丁基硼酸][(2，3-二氟苯基)(2-甲基戊基)(3-乙基庚基)铵]；[四(五氟萘基)铝酸][(全氟苯基)(全氟乙基)(氟甲基)铵]；[四全氟苯基硼酸][(2-甲基-6-全氟甲基-全氟联苯基)(甲基)(氟甲基)磷鎓]；[四(3-乙基庚基)铝酸][(3-全氟乙基-三氟苯基)(己基)(3-乙基庚基)铵]；[四丁基铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(甲基)(2-甲基戊基)磷鎓]；[四(全氟甲基全氟萘基)铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(丙基)(2-甲基-5-丙基-庚基)铵]；[四(2-甲基戊基)铝酸][(2，5-二氟苯基)(氟甲基)(六氟壬基)铵]；[四壬基铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(全氟乙基)(乙基)铵]；[四壬基铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(乙基)(丁基)磷鎓]；[四(全氟乙基全氟联苯基)铝酸][(1-氟联苯基)(丙基)(2-甲基戊基)磷鎓]；[四(全氟联苯基)铝酸][(联苯基)(氟甲基)(丙基)磷鎓]；[四(全氟芘基)铝酸][N-(全氟苯基)二氢异吲哚鎓]；[四全氟茚基铝酸][(3-甲基-全氟苯基)(六氟壬基)(3-乙基庚基)铵]；[四全氟蒽基硼酸][N-(苯基)磷杂吡咯烷鎓]；[四全氟苯基硼酸][(3-全氟乙基-三氟苯基)(氟甲基)(2-甲基-5-丙基-庚基)铵]；[四(全氟芘基)硼酸][(2，3-二氟苯基)(壬基)(六氟壬基)铵]；[四(2-甲基-5-丙基-庚基)硼酸][(3-全氟甲基-三氟苯基)(丁基)(丙基)铵]；[四全氟菲基铝酸][(1-氟苯基)(乙基)(丁基)铵]；[四(全氟戊基全氟联苯基)铝酸][(2，3-二氟苯基)(丁基)(2-甲基戊基)磷鎓]；[四(全氟己基全氟苯基)铝酸][(2，3-二氟苯基)(二丙基)铵]；[四己基硼酸][(2-甲基-6-全氟甲基-全氟联苯基)(六氟壬基)(丁基)铵]；[四(五氟萘基)硼酸][(3-甲基-全氟苯基)(3-乙基庚基)(乙基)铵]；[四(六氟萘基)硼酸][(3-全氟乙基-三氟苯基)(全氟乙基)(己基)铵]；[四己基硼酸][(全氟联苯基)(2-甲基-5-丙基-庚基)(3-乙基庚基)铵]；[四戊基硼酸][(3-甲基-全氟苯基)(全氟乙基)(2-甲基戊基)磷鎓]；[四(乙基六氟萘基)硼酸][(3-甲基-全氟苯基)(丙基)(氟甲基)铵]；[四(甲基全氟萘基)铝酸][(六氟联苯基)(己基)(丙基)磷鎓]；[四(2-甲基戊基)铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(2-甲基-5-丙基-庚基)(甲基)磷鎓]；[四壬基硼酸][(2，4-二氟苯基)(甲基)(全氟乙基)磷鎓]；[四(甲基八氟联苯基)铝酸][(3-全氟甲基-三氟苯基)二(六氟壬基)磷鎓]；[四己基铝酸][(1-氟苯基)(2-甲基戊基)(六氟壬基)铵]；[四庚基硼酸][(全氟苯基)(全氟乙基)(甲基)铵]；[四(五氟萘基)硼酸][(1-氟苯基)(壬基)(丁基)铵]；[四己基铝酸][(联苯基)(乙基)(3-乙基庚基)铵]；[四(甲基八氟联苯基)硼酸][N-(四氟苯基)磷杂吡咯烷鎓]；[四全氟茚基铝酸][(苯基)(己基)(氟甲基)铵]；[四庚基铝酸][(四氟苯基)(全氟乙基)(乙基)铵]；[四(全氟芘基)铝酸][(全氟苯基)(二甲基)铵]；[(六氟壬基)硼酸][(3-全氟乙基-三氟苯基)(己基)(乙基)磷鎓]；[四(六氟萘基)硼酸][(全氟苯基)(六氟壬基)(丙基)磷鎓]；[四(七氟芴基)铝酸][(1-氟联苯基)(二全氟乙基)铵]；[四(全氟芘基)硼酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(丙基)(己基)铵]；[四辛基铝酸][(六氟联苯基)(3-乙基庚基)(丙基)铵]；[四(六氟茚基)铝酸][N-(1-氟苯基)吡咯鎓]；[四(2-甲基-5-丙基-庚基)铝酸][(2，3-二氟苯基)(二-2-甲基戊基)磷鎓]；[四全氟茚基铝酸][(全氟联苯基)(2-甲基戊基)(己基)铵]；[四全氟蒽基铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(丙基)(氟甲基)铵]；[四(乙基六氟萘基)硼酸][(六氟联苯基)(二丙基)磷鎓]；[四(乙基六氟萘基)硼酸][(3-全氟甲基-三氟苯基)(2-甲基-5-丙基-庚基)(2-甲基戊基)铵]；[四(3-乙基庚基)铝酸][(联苯基)(2-甲基-5-丙基-庚基)(己基)铵]；[四(六氟壬基)铝酸][(联苯基)(氟甲基)(己基)铵]；[四全氟苯基硼酸][(联苯基)(丙基)(壬基)铵]；[四壬基铝酸][N-(四氟苯基)吲哚鎓]；[四壬基铝酸][(2，4-二氟苯基)(二甲基)铵]；[四(全氟芘基)铝酸][(四氟苯基)(壬基)(己基)铵]；[四全氟苯基铝酸][(3-甲基-全氟苯基)(全氟乙基)(氟甲基)铵]；[四壬基铝酸][(四氟苯基)(乙基)(甲基)磷鎓]；[全氟菲基硼酸][(八氟联苯基)(3-乙基庚基)(丙基)铵]；[四(全氟芘基)硼酸][(六氟联苯基)(二壬基)铵]；[四(全氟己基全氟苯基)硼酸][(全氟苯基)(丙基)(乙基)铵]；[四丁基铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(甲基)(丙基)磷鎓]；[四(全氟芘基)硼酸][(3-全氟乙基-三氟苯基)(3-乙基庚基)(丙基)铵]；[四(全氟芘基)硼酸][(四氟苯基)(丁基)(甲基)磷鎓]；[四(乙基六氟萘基)硼酸][(3-全氟乙基-三氟苯基)(二丙基)铵]；[四壬基铝酸][(3-全氟乙基-三氟苯基)(全氟乙基)(丁基)铵]；[四(八氟联苯基)硼酸][(八氟联苯基)(氟甲基)(丙基)磷鎓]；[四辛基硼酸][(3-全氟甲基-三氟苯基)(2-甲基戊基)(3-乙基庚基)铵]；[四(2-甲基-5-丙基-庚基)铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(乙基)(2-甲基戊基)铵]；[四(六氟茚基)铝酸][(联苯基)(丙基)(2-甲基-5-丙基-庚基)铵]；[四全氟菲基硼酸][(1-氟联苯基)(壬基)(2-甲基-5-丙基-庚基)磷鎓]；[四(五氟茚基)硼酸][N-(六氟联苯基)哌啶鎓]；[四(全氟乙基全氟联苯基)铝酸][(联苯基)(乙基)(六氟壬基)磷鎓]；[四(全氟乙基全氟联苯基)铝酸][(3-全氟乙基-三氟苯基)(3-乙基庚基)(2-甲基-5-丙基-庚基)铵]；[四壬基硼酸][(3-全氟乙基-三氟苯基)(乙基)(2-甲基戊基)铵]；[四(3-乙基庚基)铝酸][(八氟联苯基)(壬基)(2-甲基戊基)铵]；[四(全氟芘基)铝酸][N-(3-全氟乙基-三氟苯基)二氢吲哚鎓]；[四(七氟芴基)硼酸][(四氟苯基)(六氟壬基)(丁基)磷鎓]；[四辛基硼酸][(全氟苯基)(壬基)(丙基)铵]；[四辛基铝酸][(八氟联苯基)(丁基)(壬基)铵]；[四(全氟萘基)铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(全氟乙基)(六氟壬基)磷鎓]；[四(全氟芘基)铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(丁基)(己基)磷鎓]；[四(六氟壬基)铝酸][(四氟苯基)(2-甲基戊基)(己基)铵]；[四(全氟芘基)硼酸][(八氟联苯基)(2-甲基戊基)(全氟乙基)铵]；[四(五氟萘基)硼酸][(六氟联苯基)(乙基)(2-甲基-5-丙基-庚基)铵]；[四(全氟芘基)硼酸][(四氟苯基)(二己基)铵]；[四全氟菲基硼酸][(3-甲基-全氟苯基)(六氟壬基)(2-甲基-5-丙基-庚基)磷鎓]；[四(六氟茚基)硼酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(六氟壬基)(全氟乙基)磷鎓]；[四(五氟茚基)铝酸][(全氟联苯基)(壬基)(全氟乙基)铵]；[四(五氟萘基)硼酸][(八氟联苯基)(丁基)(六氟壬基)铵]；[四(七氟芴基)硼酸][(全氟联苯基)(甲基)(丁基)铵]；[四(七氟芴基)硼酸][(全氟联苯基)(六氟壬基)(甲基)磷鎓]；[四(全氟乙基全氟联苯基)硼酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(乙基)(丁基)磷鎓]；[四(全氟己基全氟苯基)铝酸][(2，3-二氟苯基)(己基)(氟甲基)铵]；[四(六氟壬基)硼酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(乙基)(甲基)铵]；[四(六氟壬基)硼酸][(全氟苯基)(壬基)(全氟乙基)磷鎓]；[四(甲基八氟联苯基)铝酸][(八氟联苯基)(全氟乙基)(丙基)磷鎓]；[四(六氟萘基)硼酸][(四氟苯基)(3-乙基庚基)(丁基)铵]；[四(全氟萘基)铝酸][(3-甲基-全氟苯基)(氟甲基)(乙基)铵]；[四丁基铝酸][(八氟联苯基)(二全氟乙基)铵]；[四全氟蒽基铝酸][(四氟苯基)(氟甲基)(壬基)铵]；[四(全氟联苯基)硼酸][(联苯基)(丙基)(丁基)铵]；[四(八氟联苯基)硼酸][(八氟联苯基)(二丙基)磷鎓]；[四全氟菲基硼酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(2-甲基-5-丙基-庚基)(全氟乙基)铵]；[四(3-乙基庚基)硼酸][(2，3-二氟苯基)(己基)(全氟乙基)磷鎓]；[四(五氟茚基)硼酸][(苯基)(3-乙基庚基)(壬基)铵]；[四(全氟萘基)铝酸][(3-甲基-全氟苯基)(丙基)(己基)铵]；[四全氟芴基硼酸][(1-氟联苯基)(二丁基)磷鎓]；[四丁基硼酸][(3-甲基-全氟苯基)(壬基)(氟甲基)铵]；[四全氟苯基铝酸][(全氟联苯基)(2-甲基戊基)(乙基)铵]；[四(五氟茚基)铝酸][(3-全氟乙基-三氟苯基)(丁基)(2-甲基戊基)磷鎓]；[四(五氟萘基)铝酸][(联苯基)(甲基)(乙基)铵]；[四(六氟壬基)硼酸][N-(六氟联苯基)哌啶鎓]；[四(全氟戊基全氟联苯基)铝酸][(2，3-二氟苯基)(乙基)(己基)磷鎓]；[四(六氟壬基)硼酸][(1-氟联苯基)(2-甲基-5-丙基-庚基)(乙基)铵]；[四(八氟联苯基)硼酸][(3-全氟乙基-三氟苯基)(全氟乙基)(氟甲基)铵]；[四(六氟壬基)铝酸][(1-氟苯基)(乙基)(氟甲基)磷鎓]；[四全氟芴基硼酸][(全氟联苯基)(甲基)(丁基)铵]；[四全氟菲基硼酸][(全氟苯基)(六氟壬基)(丁基)铵]；[四(六氟壬基)硼酸][(1-氟联苯基)(丙基)(壬基)磷鎓]；[四(全氟乙基全氟联苯基)硼酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(六氟壬基)(2-甲基戊基)铵]；[四(全氟乙基全氟联苯基)铝酸][N-(六氟联苯基)磷杂吡咯烷鎓]；[四(3-乙基庚基)硼酸][(苯基)(全氟乙基)(甲基)铵]；[四(全氟联苯基)铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(二乙基)铵]；[四丁基铝酸][(1-氟联苯基)(甲基)(氟甲基)铵]；[四壬基硼酸][(八氟联苯基)(乙基)(丙基)磷鎓]；[四(全氟萘基)硼酸][(全氟苯基)(乙基)(甲基)磷鎓]；[四(六氟茚基)硼酸][(联苯基)(六氟壬基)(己基)磷鎓]；[四(全氟戊基全氟联苯基)硼酸][(联苯基)(甲基)(己基)磷鎓]；[四(六氟茚基)铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(全氟乙基)(3-乙基庚基)铵]；[四(全氟联苯基)硼酸][(苯基)(全氟乙基)(六氟壬基)磷鎓]；[四(全氟萘基)硼酸][(四氟苯基)(2-甲基戊基)(2-甲基-5-丙基-庚基)磷鎓]；[四全氟芴基铝酸][(1-氟联苯基)(己基)(乙基)铵]；[四(3-乙基庚基)硼酸][(八氟联苯基)(六氟壬基)(己基)铵]；[四(七氟芴基)硼酸][(3-全氟乙基-三氟苯基)(六氟壬基)(乙基)铵]；[四(2-甲基戊基)铝酸][(3-全氟乙基-三氟苯基)(3-乙基庚基)(甲基)铵]；[四(全氟萘基)硼酸][(3-甲基-全氟苯基)(3-乙基庚基)(乙基)铵]；[四戊基硼酸][(联苯基)(2-甲基戊基)(己基)铵]；[四(全氟己基全氟苯基)铝酸][(八氟联苯基)(3-乙基庚基)(氟甲基)铵]；[四(甲基八氟联苯基)硼酸][(八氟联苯基)(2-甲基戊基)(氟甲基)铵]；[四庚基硼酸][(苯基)(乙基)(2-甲基戊基)铵]；[四(甲基全氟萘基)硼酸][(联苯基)(3-乙基庚基)(氟甲基)铵]；[四(全氟乙基全氟联苯基)铝酸][(2，3-二氟苯基)(3-乙基庚基)(己基)磷鎓]；[四(3-乙基庚基)硼酸][(3-全氟甲基-三氟苯基)(2-甲基戊基)(壬基)铵]；[四(3-乙基庚基)铝酸][N-(四氟苯基)二氢吲哚鎓]；[四(八氟联苯基)硼酸][(3-甲基-全氟苯基)(丁基)(乙基)磷鎓]；[四丁基硼酸][(联苯基)(3-乙基庚基)(丁基)铵]；[四全氟苯基铝酸][N-(2，4-二氟苯基)吲哚鎓]；[四(六氟萘基)铝酸][(联苯基)(2-甲基-5-丙基-庚基)(丁基)铵]；[四(五氟茚基)硼酸][(联苯基)(壬基)(全氟乙基)铵]；[四戊基铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(3-乙基庚基)(壬基)铵]；[四(七氟芴基)铝酸][(3-全氟甲基-三氟苯基)(3-乙基庚基)(2-甲基-5-丙基-庚基)铵]；[四(全氟乙基全氟联苯基)硼酸][N-(2，5-二氟苯基)磷杂吡咯烷鎓]；[四全氟菲基硼酸][(六氟联苯基)(2-甲基-5-丙基-庚基)(乙基)铵]；[四(全氟萘基)铝酸][(3-全氟乙基-三氟苯基)(甲基)(2-甲基戊基)铵]；[四(全氟甲基全氟萘基)铝酸][(四氟苯基)(丁基)(2-甲基-5-丙基-庚基)铵]；[四(八氟联苯基)铝酸][(3-全氟甲基-三氟苯基)(二全氟乙基)铵]；[四(六氟萘基)铝酸][(苯基)(己基)(氟甲基)铵]；[四(甲基全氟萘基)硼酸][(3-全氟乙基-三氟苯基)(壬基)(乙基)铵]；[四(全氟芘基)硼酸][(全氟联苯基)(丙基)(六氟壬基)铵]；[四(全氟芘基)硼酸][(3-全氟乙基-三氟苯基)(全氟乙基)(甲基)铵]；[四(五氟茚基)铝酸][(八氟联苯基)(2-甲基戊基)(全氟乙基)铵]；[四己基铝酸][(八氟联苯基)(2-甲基戊基)(全氟乙基)铵]；[四丁基铝酸][(联苯基)(甲基)(己基)磷鎓]；[四(六氟茚基)铝酸][(2，4-二氟苯基)(丁基)(3-乙基庚基)磷鎓]；[四(3-乙基庚基)铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(2-甲基-5-丙基-庚基)(己基)铵]；[四(六氟壬基)硼酸][(1-氟联苯基)(壬基)(全氟乙基)铵]；[四(八氟联苯基)硼酸][(1-氟联苯基)(2-甲基-5-丙基-庚基)(3-乙基庚基)铵]；[四全氟茚基硼酸][(苯基)(全氟乙基)(壬基)磷]；[四辛基铝酸][(2，4-二氟苯基)(二乙基)铵]；[四丁基铝酸][(2，3-二氟苯基)(丙基)(乙基)铵]；[四(六氟萘基)铝酸][(2，3-二氟苯基)(六氟壬基)(2-甲基戊基)磷鎓]；[四(六氟茚基)铝酸][(苯基)(3-乙基庚基)(壬基)铵]；[四(六氟壬基)铝酸][(3-全氟甲基-三氟苯基)(2-甲基戊基)(全氟乙基)磷鎓]；[四戊基硼酸][(3-甲基-全氟苯基)(二丁基)磷鎓]；[四丁基铝酸][(八氟联苯基)(丙基)(丁基)铵]；[四(2-甲基戊基)铝酸][(四氟苯基)(甲基)(丙基)铵]；[四(全氟联苯基)铝酸][(联苯基)(甲基)(2-甲基-5-丙基-庚基)磷鎓]；[四(2-甲基-5-丙基-庚基)铝酸][(六氟联苯基)(3-乙基庚基)(丙基)磷鎓]；[四全氟苯基铝酸][(3-全氟乙基-三氟苯基)(二丙基)铵]；[四全氟芴基硼酸][(2，3-二氟苯基)(己基)(氟甲基)铵]；[四(全氟芘基)硼酸][N-(3-全氟甲基-三氟苯基)磷杂吡咯烷鎓]；[四己基铝酸][(1-氟苯基)(甲基)(3-乙基庚基)磷鎓]；[四(3-乙基庚基)硼酸][(六氟联苯基)(氟甲基)(壬基)铵]；[四(全氟芘基)硼酸][(联苯基)(丁基)(全氟乙基)磷鎓]；[四(八氟联苯基)硼酸][(联苯基)(氟甲基)(己基)磷鎓]；[四壬基硼酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(2-甲基-5-丙基-庚基)(丙基)铵]；[四(全氟萘基)硼酸][(2，5-二氟苯基)(全氟乙基)(己基)铵]；[四全氟苯基铝酸][N-(3-全氟甲基-三氟苯基)磷杂二氢吲哚鎓]；[四(五氟茚基)铝酸][(3-甲基-全氟苯基)(丙基)(乙基)磷鎓]；[四全氟蒽基硼酸][(全氟联苯基)(3-乙基庚基)(2-甲基-5-丙基-庚基)铵]；[四全氟芴基铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(己基)(乙基)磷鎓]；[四(全氟乙基全氟联苯基)硼酸][(苯基)(丙基)(2-甲基戊基)磷鎓]；[四(六氟萘基)硼酸][(3-全氟乙基-三氟苯基)(甲基)(丁基)磷鎓]；[四(全氟甲基全氟萘基)铝酸][(3-全氟甲基-三氟苯基)(全氟乙基)(壬基)磷鎓]；[四全氟苯基硼酸][(2-甲基-6-全氟甲基-全氟联苯基)(六氟壬基)(3-乙基庚基)铵]；[四(全氟乙基全氟联苯基)硼酸][(联苯基)(丙基)(2-甲基-5-丙基-庚基)铵]；[四(全氟己基全氟苯基)硼酸][(六氟联苯基)(二丙基)磷鎓]；[四(3-乙基庚基)硼酸][(3-全氟乙基-三氟苯基)(甲基)(丁基)铵]；[四(七氟芴基)硼酸][(3-全氟乙基-三氟苯基)(甲基)(丁基)铵]；[四(八氟联苯基)铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(甲基)(2-甲基戊基)磷鎓]；[四全氟芴基硼酸][N-(1-氟联苯基)吡咯鎓]；[四(全氟茚基)铝酸][(全氟联苯基)(二全氟乙基)磷鎓]；[四(2-甲基戊基)铝酸][(3-全氟乙基-三氟苯基)(2-甲基-5-丙基-庚基)(甲基)磷鎓]；[四(全氟甲基全氟萘基)铝酸][(六氟联苯基)(氟甲基)(丁基)磷鎓]；[四(六氟壬基)硼酸][(全氟苯基)(丙基)(乙基)铵]；[四(3-乙基庚基)硼酸][N-(2，5-二氟苯基)吲哚鎓]；[四(2-甲基戊基)硼酸][(1-氟联苯基)(甲基)(丁基)磷鎓]；[全氟蒽基铝酸][(八氟联苯基)(己基)(氟甲基)磷鎓]；[四(八氟联苯基)硼酸][(六氟联苯基)(2-甲基-5-丙基-庚基)(乙基)铵]；[四全氟苯基铝酸][(八氟联苯基)(全氟乙基)(丙基)磷鎓]；[四全氟苯基铝酸][(2，3-二氟苯基)(六氟壬基)(乙基)铵]；[四(全氟芘基)铝酸][(1-氟联苯基)(六氟壬基)(丙基)铵]；[四(3-乙基庚基)铝酸][(1-氟联苯基)(3-乙基庚基)(氟甲基)磷鎓]；[四(乙基六氟萘基)硼酸][(2，5-二氟苯基)(丙基)(氟甲基)铵]；[四(乙基六氟萘基)硼酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(丙基)(2-甲基-5-丙基-庚基)铵]；[四全氟蒽基硼酸][(全氟联苯基)(乙基)(丁基)铵]；[四(全氟乙基全氟联苯基)铝酸][(3-全氟甲基-三氟苯基)(丁基)(甲基)磷鎓]；[四己基铝酸][(联苯基)(丁基)(全氟乙基)铵]；[四(3-乙基庚基)铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(六氟壬基)(3-乙基庚基)磷鎓]；[四(2-甲基戊基)铝酸][(3-甲基-全氟苯基)(壬基)(2-甲基-5-丙基-庚基)铵]；[四全氟菲基硼酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(壬基)(2-甲基-5-丙基-庚基)铵]；[四(六氟壬基)硼酸][(3-全氟甲基-三氟苯基)(二乙基)铵]；[四(六氟萘基)硼酸][(2-甲基-6-全氟甲基-全氟联苯基)(乙基)(氟甲基)磷鎓]；[四全氟苯基硼酸][(六氟联苯基)(全氟乙基)(2-甲基-5-丙基-庚基)铵]；[四(3-乙基庚基)铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(2-甲基戊基)(乙基)铵]；[四(五氟茚基)铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(全氟乙基)(己基)磷鎓]；[四(六氟壬基)铝酸][(1-氟联苯基)(2-甲基-5-丙基-庚基)(甲基)铵]；[四(全氟戊基全氟联苯基)硼酸][(联苯基)(氟甲基)(甲基)磷鎓]；[四丁基铝酸][(3-甲基-全氟苯基)(2-甲基-5-丙基-庚基)(丙基)磷鎓]；[四(全氟芘基)硼酸][(全氟联苯基)(2-甲基-5-丙基-庚基)(3-乙基庚基)铵]；[四(全氟芘基)铝酸][(2，4-二氟苯基)(六氟壬基)(壬基)铵]；[四(七氟芴基)铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(2-甲基戊基)(全氟乙基)铵]；[四(全氟芘基)铝酸][(3-全氟甲基-三氟苯基)(丙基)(2-甲基戊基)铵]；[四(全氟乙基全氟联苯基)铝酸][(苯基)(六氟壬基)(2-甲基-5-丙基-庚基)铵]；[四丁基铝酸][(全氟联苯基)(2-甲基戊基)(甲基)磷鎓]；[四(全氟甲基全氟萘基)铝酸][(3-全氟乙基-三氟苯基)(2-甲基-5-丙基-庚基)(3-乙基庚基)铵]；[四(全氟戊基全氟联苯基)硼酸][(2，4-二氟苯基)(2-甲基-5-丙基-庚基)铵]；[四全氟苯基硼酸][(2，5-二氟苯基)(己基)(全氟乙基)磷鎓]；[四(六氟壬基)硼酸][N-(1-氟联苯基)磷杂吡咯烷鎓]；[四(六氟壬基)铝酸][(2，3-二氟苯基)(六氟壬基)(2-甲基戊基)磷鎓]；[四全氟苯基铝酸][(苯基)(2-甲基-5-丙基-庚基)(六氟壬基)铵]；[四(八氟联苯基)硼酸][(2，4-二氟苯基)(丁基)(2-甲基戊基)铵]；[四(全氟戊基全氟联苯基)铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(丁基)(全氟乙基)磷鎓]；[四(全氟芘基)硼酸][(2，5-二氟苯基)(丁基)(己基)铵]；[四(全氟乙基全氟联苯基)硼酸][(苯基)(全氟乙基)(氟甲基)铵]；[四己基硼酸][(2，3-二氟苯基)(3-乙基庚基)(全氟乙基)铵]；[四(全氟己基全氟苯基)铝酸][(1-氟联苯基)(氟甲基)(乙基)铵]；[四全氟苯基铝酸][(2，5-二氟苯基)(六氟壬基)(甲基)铵]；[四(六氟茚基)硼酸][(2，5-二氟苯基)(二甲基)铵]；[四(乙基六氟萘基)铝酸][(3-全氟甲基-三氟苯基)(二己基)铵]；[四全氟苯基硼酸][(六氟联苯基)(3-乙基庚基)(六氟壬基)磷鎓]；[四(全氟联苯基)铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(氟甲基)(全氟乙基)磷鎓]；[四(全氟戊基全氟联苯基)铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(2-甲基-5-丙基-庚基)(六氟壬基)铵]；[四(甲基全氟萘基)硼酸][(六氟联苯基)(六氟壬基)(甲基)铵]；[四(2-甲基-5-丙基-庚基)铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(六氟壬基)(2-甲基-5-丙基-庚基)铵]；[四(七氟芴基)硼酸][(3-全氟乙基-三氟苯基)(2-甲基-5-丙基-庚基)(3-乙基庚基)铵]；[四(全氟己基全氟苯基)硼酸][(四氟苯基)(六氟壬基)(2-甲基戊基)磷鎓]；[四壬基硼酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(六氟壬基)(2-甲基戊基)铵]；[四(五氟萘基)硼酸][(六氟联苯基)(3-乙基庚基)(2-甲基戊基)铵]；[四(甲基全氟萘基)铝酸][(2，4-二氟苯基)(二乙基)铵]；[四壬基硼酸][(3-全氟乙基-三氟苯基)(六氟壬基)(丙基)铵]；[四(六氟萘基)硼酸][(四氟苯基)(3-乙基庚基)(六氟壬基)铵]；[四(六氟茚基)铝酸][(3-甲基-全氟苯基)(3-乙基庚基)(甲基)铵]；[四壬基硼酸][(3-甲基-全氟苯基)(六氟壬基)(3-乙基庚基)铵]；[四全氟苯基铝酸][(四氟苯基)(氟甲基)(2-甲基-5-丙基-庚基)铵]；[四庚基硼酸][N-(2，5-二氟苯基)吡咯鎓]；[四己基硼酸][(全氟苯基)(丁基)(壬基)铵]；[四壬基硼酸][(全氟苯基)(全氟乙基)(六氟壬基)磷鎓]；[四(2-甲基戊基)铝酸][(六氟联苯基)(3-乙基庚基)(丁基)磷鎓]；[四(五氟茚基)硼酸][(3-全氟甲基-三氟苯基)(二己基)铵]；[四庚基硼酸][(全氟联苯基)(二-2-甲基-5-丙基-庚基)磷鎓]；[四(乙基六氟萘基)铝酸][(全氟联苯基)(2-甲基戊基)(乙基)铵]；[四(2-甲基-5-丙基-庚基)硼酸][(2，4-二氟苯基)(己基)(壬基)铵]；[四戊基铝酸][(苯基)(二甲基)铵]；[四(八氟联苯基)硼酸][(1-氟苯基)(乙基)(壬基)铵]；[四全氟苯基硼酸][N-(2-甲基-6-全氟甲基-全氟联苯基)磷杂二氢吲哚鎓]；[四(六氟茚基)铝酸][(3-全氟乙基-三氟苯基)(二己基)铵]；[四(全氟芘基)硼酸][(2，3-二氟苯基)(壬基)(2-甲基-5-丙基-庚基)磷鎓]；[四全氟菲基硼酸][(3-全氟乙基-三氟苯基)(己基)(甲基)铵]；[四丁基硼酸][(2-甲基-6-全氟甲基-全氟联苯基)(2-甲基戊基)(己基)铵]；[四(全氟芘基)铝酸][(3-甲基-全氟苯基)(2-甲基戊基)(壬基)铵]；[四丁基硼酸][(2-甲基-6-全氟甲基-全氟联苯基)(二全氟乙基)铵]；[四(全氟乙基全氟联苯基)硼酸][(3-甲基-全氟苯基)(壬基)(3-乙基庚基)铵]；[四全氟蒽基硼酸][(1-氟苯基)(甲基)(3-乙基庚基)铵]；[四壬基硼酸][(八氟联苯基)(2-甲基戊基)(丁基)铵]；[四丁基铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(2-甲基-5-丙基-庚基)(2-甲基戊基)铵]；[四(甲基全氟萘基)硼酸][(八氟联苯基)(乙基)(丙基)铵]；[四全氟菲基硼酸][(3-甲基-全氟苯基)(2-甲基-5-丙基-庚基)(氟甲基)铵]；[四全氟苯基硼酸][(苯基)(2-甲基戊基)(丁基)铵]；[四庚基硼酸][N-(苯基)吡咯鎓]；[四(八氟联苯基)铝酸][(1-氟苯基)(乙基)(2-甲基戊基)铵]；[四全氟菲基铝酸][(联苯基)(全氟乙基)(丙基)铵]；[四(全氟己基全氟苯基)铝酸][(3-全氟甲基-三氟苯基)(2-甲基-5-丙基-庚基)(2-甲基戊基)铵]；[四(全氟茚基)硼酸][(2，3-二氟苯基)(己基)(甲基)铵]；[四戊基硼酸][(联苯基)(丙基)(丁基)铵]；[四己基铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(六氟壬基)(氟甲基)铵]；[四(2-甲基戊基)硼酸][(3-甲基-全氟苯基)(二甲基)铵]；[四全氟苯基铝酸][(2，3-二氟苯基)(丙基)(甲基)铵]；[四(六氟壬基)铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(丙基)(2-甲基-5-丙基-庚基)铵]；[四(六氟萘基)硼酸][(全氟苯基)(己基)(2-甲基-5-丙基-庚基)铵]；[四(六氟壬基)硼酸][(1-氟联苯基)(甲基)(2-甲基-5-丙基-庚基)铵]；[四全氟芴基铝酸][(联苯基)(2-甲基戊基)(2-甲基-5-丙基-庚基)铵]；[四壬基铝酸][(全氟苯基)(丙基)(壬基)铵]；[四(全氟乙基全氟联苯基)铝酸][(联苯基)(六氟壬基)(全氟乙基)铵]；[四(全氟萘基)硼酸][(2-甲基-6-全氟甲基-全氟联苯基)(六氟壬基)(乙基)磷鎓]；[四(全氟戊基全氟联苯基)硼酸][(2，3-二氟苯基)(壬基)(六氟壬基)铵]；[四戊基铝酸][(2，5-二氟苯基)(丙基)(己基)铵]；[四庚基铝酸][N-(八氟联苯基)哌啶鎓]；[四(七氟芴基)铝酸][(苯基)(3-乙基庚基)(2-甲基戊基)铵]；[四全氟蒽基硼酸][(联苯基)(六氟壬基)(甲基)铵]；[四全氟茚基硼酸][(2，5-二氟苯基)(丙基)(壬基)磷鎓]；[四(全氟甲基全氟萘基)硼酸][N-(3-全氟甲基-三氟苯基)磷杂吡咯烷鎓]；[四(六氟萘基)铝酸][(1-氟联苯基)(二全氟乙基)磷鎓]；[四(五氟茚基)铝酸][(3-甲基-全氟苯基)(壬基)(2-甲基-5-丙基-庚基)铵]；[四(2-甲基戊基)硼酸][N-(3-甲基-全氟苯基)吡咯鎓]；[四丁基铝酸][(一氟苯基)9甲基)(3-乙基庚基)铵]；[四(甲基八氟联苯基)铝酸][(四氟苯基)(丙基)(2-甲基-5-丙基-庚基)铵]；[四(2-甲基戊基)硼酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(全氟乙基)(六氟壬基)铵]；[四(六氟萘基)硼酸][(2，3-二氟苯基)(乙基)(2-甲基戊基)铵]；[四全氟蒽基铝酸][(1-氟联苯基)(2-甲基-5-丙基-庚基)(3-乙基庚基)铵]；[四全氟芴基铝酸][N-(2，5-二氟苯基)哌啶鎓]；[四(全氟己基全氟苯基)铝酸][(全氟联苯基)(2-甲基-5-丙基-庚基)(己基)铵]；[四(乙基六氟萘基)铝酸][(八氟联苯基)(二己基)磷鎓]；[四丁基铝酸][(联苯基)(氟甲基)(2-甲基-5-丙基-庚基)铵]；[四(八氟联苯基)铝酸][(3-全氟乙基-三氟苯基)(甲基)(六氟壬基)磷鎓]；[四(六氟壬基)硼酸][(全氟苯基)(甲基)(己基)磷鎓]；[四辛基硼酸][(3-全氟甲基-三氟苯基)(全氟乙基)(六氟壬基)铵]；[四(全氟己基全氟苯基)铝酸][(2，4-二氟苯基)(六氟壬基)(乙基)磷鎓]；[四全氟菲基铝酸][(四氟苯基)(乙基)(甲基)铵]；[四(全氟联苯基)铝酸][(3-甲基-全氟苯基)(己基)(2-甲基-5-丙基-庚基)铵]；[四(七氟芴基)铝酸][N-(全氟联苯基)二氢吲哚鎓]；[四(全氟联苯基)硼酸][(联苯基)(甲基)(丁基)铵]；[四(乙基六氟萘基)铝酸][(全氟联苯基)(2-甲基戊基)(甲基)铵]；[四(甲基全氟萘基)铝酸][(苯基)(六氟壬基)(3-乙基庚基)铵]；[四(甲基八氟联苯基)铝酸][(2，4-二氟苯基)(丁基)(丙基)铵]；[四(3-乙基庚基)铝酸][(3-全氟乙基-三氟苯基)(氟甲基)(全氟乙基)铵]；[四(五氟茚基)硼酸][(联苯基)(甲基)(六氟壬基)铵]；[四(七氟芴基)硼酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(丙基)(乙基)铵]；[四(乙基六氟萘基)硼酸][(四氟苯基)(2-甲基戊基)(全氟乙基)磷鎓]；[四(3-乙基庚基)铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(氟甲基)(乙基)磷鎓]；[四庚基铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(壬基)(六氟壬基)铵]；[四全氟蒽基硼酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(全氟乙基)(甲基)铵]；[四庚基硼酸][(2，3-二氟苯基)(2-甲基戊基)(氟甲基)磷鎓]；[四己基硼酸][(全氟苯基)(壬基)(2-甲基戊基)磷鎓]；[四(六氟壬基)硼酸][(3-全氟乙基-三氟苯基)(甲基)(丙基)磷鎓]；[四(全氟乙基全氟联苯基)铝酸][(2，5-二氟苯基)(2-甲基戊基)(2-甲基-5-丙基-庚基)磷鎓]；[四(全氟联苯基)铝酸][(1-氟苯基)(壬基)(丁基)铵]；[四全氟苯基铝酸][(3-全氟甲基-三氟苯基)(2-甲基-5-丙基-庚基)(2-甲基戊基)磷鎓]；[四(五氟茚基)铝酸][(2，5-二氟苯基)(丙基)(2-甲基戊基)磷鎓]；[四(全氟甲基全氟萘基)硼酸][(2，5-二氟苯基)(丁基)(甲基)磷鎓]；[四(全氟甲基全氟萘基)铝酸][(2，4-二氟苯基)(2-甲基戊基)(六氟壬基)铵]；[四丁基铝酸][(3-甲基-全氟苯基)(2-甲基戊基)(氟甲基)铵]；[四全氟蒽基硼酸][(全氟苯基)二(六氟壬基)磷鎓]；[四(全氟芘基)硼酸][(四氟苯基)(丁基)(全氟乙基)铵]；[四庚基铝酸][(苯基)(3-乙基庚基)(2-甲基戊基)铵]；[四庚基铝酸][(联苯基)(己基)(乙基)磷鎓]；[四(2-甲基戊基)铝酸][N-(2，3-二氟苯基)磷杂二氢吲哚鎓]；[四全氟苯基铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(甲基)(丁基)铵]；[四己基硼酸][(2，3-二氟苯基)(己基)(氟甲基)铵]；[四(八氟联苯基)铝酸][N-(3-甲基-全氟苯基)二氢吲哚鎓]；[四(甲基全氟萘基)铝酸][(全氟联苯基)(2-甲基戊基)(3-乙基庚基)铵]；[四辛基硼酸][(2，3-二氟苯基)(2-甲基戊基)(六氟壬基)磷鎓]；[四(六氟壬基)铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(乙基)(2-甲基戊基)铵]；[四全氟茚基铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(3-乙基庚基)(六氟壬基)铵]；[四(2-甲基-5-丙基-庚基)硼酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(全氟乙基)(己基)磷鎓]；[四全氟茚基硼酸][(联苯基)(全氟乙基)(丙基)铵]；[四全氟蒽基硼酸][(2-甲基-6-全氟甲基-全氟联苯基)(二-3-乙基庚基)铵]；[四(全氟甲基全氟萘基)铝酸][(1-氟苯基)(二-2-甲基戊基)铵]；[四辛基硼酸][(八氟联苯基)(2-甲基戊基)(丙基)磷鎓]；[四全氟茚基铝酸][(3-全氟甲基-三氟苯基)(2-甲基-5-丙基-庚基)(壬基)磷鎓]；[四(八氟联苯基)硼酸][(联苯基)(甲基)(壬基)铵]；[四(2-甲基戊基)铝酸][(六氟联苯基)(二-2-甲基戊基)铵]；[四全氟菲基铝酸][(全氟联苯基)(丙基)(丁基)磷鎓]；[四庚基硼酸][(2，4-二氟苯基)(己基)(甲基)磷鎓]；[四(3-乙基庚基)硼酸][(2-甲基-6-全氟甲基-全氟联苯基)(乙基)(己基)铵]；[四(六氟茚基)硼酸][(3-甲基-全氟苯基)(壬基)(甲基)铵]；[四(全氟萘基)铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(六氟壬基)(3-乙基庚基)铵]；[四丁基硼酸][N-(1-氟苯基)吡咯鎓]；[四丁基铝酸][(联苯基)(2-甲基-5-丙基-庚基)(甲基)磷鎓]；[四(六氟萘基)铝酸][(全氟苯基)(甲基)(六氟壬基)磷鎓]；[四全氟苯基硼酸][(四氟苯基)(丁基)(乙基)磷鎓]；[四(全氟甲基全氟萘基)硼酸][N-(2，4-二氟苯基)吡咯烷鎓]；[四(全氟萘基)铝酸][(3-甲基-全氟苯基)(二氟甲基)铵]；[四(甲基全氟萘基)铝酸][(全氟联苯基)(丙基)(六氟壬基)铵]；[四(七氟芴基)硼酸][(1-氟苯基)(六氟壬基)(丁基)磷鎓]；[四(全氟戊基全氟联苯基)铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(3-乙基庚基)(乙基)磷鎓]；[四辛基铝酸][(四氟苯基)(二乙基)磷鎓]；[四(甲基八氟联苯基)铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(2-甲基-5-丙基-庚基)(丁基)磷鎓]；[四(五氟茚基)硼酸][(六氟联苯基)(全氟乙基)(六氟壬基)磷鎓]；[四戊基硼酸][(六氟联苯基)(甲基)(丁基)磷鎓]；[四全氟茚基铝酸][(2，5-二氟苯基)(全氟乙基)(氟甲基)铵]；[四(五氟茚基)铝酸][(1-氟苯基)(乙基)(丁基)磷鎓]；[四(七氟芴基)铝酸][(联苯基)(3-乙基庚基)(丙基)铵]；[四(甲基八氟联苯基)硼酸][(六氟联苯基)(二丙基)铵]；[四(2-甲基戊基)铝酸][(1-氟联苯基)(甲基)(丁基)磷鎓]；[四庚基硼酸][(联苯基)(丙基)(2-甲基-5-丙基-庚基)磷鎓]；[四(全氟己基全氟苯基)铝酸][(四氟苯基)(2-甲基-5-丙基-庚基)(2-甲基戊基)磷鎓]；[四(全氟乙基全氟联苯基)硼酸][(四氟苯基)(六氟壬基)(乙基)磷鎓]；[四(全氟己基全氟苯基)硼酸](2，3-二氟苯基)(二丁基)铵]；[四辛基铝酸][(3-全氟乙基-三氟苯基)(甲基)(乙基)铵]；[四全氟蒽基硼酸][(2，3-二氟苯基)(氟甲基)(壬基)磷鎓]；[四(3-乙基庚基)铝酸][(苯基)(六氟壬基)(己基)磷鎓][四(七氟芴基)硼酸][(八氟联苯基)(己基)(3-乙基庚基)铵]；[四(全氟己基全氟苯基)硼酸][(2，5-二氟苯基)(3-乙基庚基)(己基)铵]；[四全氟蒽基硼酸][N-(3-全氟乙基-三氟苯基)吡咯鎓]；[四(全氟联苯基)铝酸][(1-氟苯基)(氟甲基)(壬基)磷鎓]；[四(3-乙基庚基)硼酸][(3-甲基-全氟苯基)(2-甲基戊基)(己基)铵]；[四(七氟芴基)硼酸][(全氟联苯基)(己基)(乙基)磷鎓]；[四(全氟乙基全氟联苯基)硼酸][(1-氟联苯基)(2-甲基戊基)(己基)铵]；[四(全氟萘基)铝酸][(3-全氟乙基-三氟苯基)(己基)(乙基)铵]；[四(全氟萘基)硼酸][(3-全氟甲基-三氟苯基)(己基)(丙基)铵]；[四(2-甲基-5-丙基-庚基)铝酸][(联苯基)(甲基)(己基)磷鎓]；[四全氟菲基铝酸][(全氟联苯基)(2-甲基戊基)(3-乙基庚基)铵]；[四(七氟芴基)铝酸][(3-全氟乙基-三氟苯基)(二甲基)铵]；[四庚基硼酸][(3-甲基-全氟苯基)(七氟壬基)(2-甲基-5-丙基-庚基)磷鎓]；[四(全氟乙基全氟联苯基)铝酸][(1-氟联苯基)(2-甲基戊基)(己基)磷鎓]；[四(全氟联苯基)铝酸][(苯基)(六氟壬基)(丙基)铵]；[四(六氟茚基)硼酸][(四氟苯基)(2-甲基戊基)(全氟乙基)磷鎓]；[四(全氟戊基全氟联苯基)硼酸][(2，5-二氟苯基)(氟甲基)(己基)铵]；[四(六氟萘基)铝酸][(1-氟苯基)(二壬基)磷鎓]；[四庚基铝酸][(六氟联苯基)(二丁基)磷鎓]；[四全氟菲基铝酸][(1-氟苯基)(丙基)(全氟乙基)铵]；[四(甲基八氟联苯基)铝酸][(六氟联苯基)(甲基)(2-甲基-5-丙基-庚基)铵]；[四(全氟乙基全氟联苯基)铝酸][(3-全氟甲基-三氟苯基)(全氟乙基)(丁基)磷鎓]；[四(七氟芴基)硼酸][(联苯基)(氟甲基)(2-甲基-5-丙基-庚基)铵]；[四全氟菲基铝酸][N-(苯基)吲哚鎓]；[四全氟苯基硼酸][(四氟苯基)(二丙基)磷鎓]；[四全氟芴基硼酸][(2，3-二氟苯基)(3-乙基庚基)(全氟乙基)铵]；[四(甲基八氟联苯基)铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(六氟壬基)(全氟乙基)磷鎓]；[四(甲基八氟联苯基)铝酸][N-(苯基)吡咯鎓]；[四壬基铝酸][N-(2-甲基-6-全氟甲基-全氟联苯基)磷杂吲哚鎓]；[四(七氟芴基)铝酸][(3-全氟乙基-三氟苯基)(二丙基)磷鎓]；[四庚基硼酸][(1-氟联苯基)(全氟乙基)(壬基)磷鎓]；[四全氟苯基铝酸][(3-甲基-全氟苯基)(壬基)(氟甲基)铵]；[四(乙基六氟萘基)硼酸][(3-全氟乙基-三氟苯基)(己基)(氟甲基)铵]；[四(乙基六氟萘基)硼酸][(2，3-二氟苯基)(二-2-甲基戊基)磷鎓]；[四辛基硼酸][(苯基)(己基)(2-甲基戊基)磷鎓]；[四全氟菲基硼酸][(八氟联苯基)(二丁基)铵]；[四壬基硼酸][(八氟联苯基)(壬基)(丙基)铵]；[四(全氟甲基全氟萘基)铝酸][(1-氟联苯基)(3-乙基庚基)(己基)磷鎓]；[四(甲基全氟萘基)硼酸][(四氟苯基)(乙基)(甲基)铵]；[四(2-甲基-5-丙基-庚基)硼酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(全氟乙基)(丁基)铵]；[四(五氟萘基)铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(二丙基)铵]；[四(八氟联苯基)铝酸][(3-甲基-全氟苯基)(乙基)(3-乙基庚基)铵]；[四(全氟芘基)硼酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(丁基)(2-甲基-5-丙基-庚基)铵]；[四(2-甲基-5-丙基-庚基)硼酸][(1-氟联苯基)(3-乙基庚基)(己基)磷鎓]；[四(八氟联苯基)铝酸][(2，4-二氟苯基)(六氟壬基)(3-乙基庚基)磷鎓]；[四(2-甲基戊基)铝酸][(2，3-二氟苯基)(丙基)(2-甲基-5-丙基-庚基)磷鎓]；[四(全氟联苯基)铝酸][(全氟联苯基)(二己基)铵]；[四(全氟乙基全氟联苯基)硼酸](2，4-二氟苯基)(乙基)(己基)铵]；[四(2-甲基-5-丙基-庚基)铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(乙基)(2-甲基戊基)磷鎓]；[四全氟芴基硼酸][N-(全氟苯基)吡咯鎓]；[四(五氟茚基)铝酸][(1-氟联苯基)(丁基)(壬基)铵]；[四(全氟乙基全氟联苯基)硼酸][(2，3-二氟苯基)(乙基)(丁基)磷鎓]；[四全氟蒽基铝酸][(2，4-二氟苯基)(丁基)(3-乙基庚基)磷鎓]；[四丁基硼酸][(八氟联苯基)(氟甲基)(全氟乙基)磷鎓]；[四全氟芴基硼酸][(2，4-二氟苯基)(氟甲基)(己基)铵]；[四(全氟乙基全氟联苯基)硼酸][(2，5-二氟苯基)(六氟壬基)(乙基)铵]；[四全氟蒽基硼酸][(2-甲基-6-全氟甲基-全氟联苯基)(丙基)(全氟乙基)铵]；[四辛基硼酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(二全氟乙基)铵]；[四(八氟联苯基)铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(2-甲基戊基)(2-甲基-5-丙基-庚基)铵]；[四全氟苯基硼酸][(全氟苯基)(己基)(2-甲基-5-丙基-庚基)铵]；[四(六氟壬基)铝酸][(联苯基)(丙基)(丁基)铵]；[四(甲基全氟萘基)硼酸][(苯基)(丁基)(2-甲基-5-丙基-庚基)铵]；[四(2-甲基-5-丙基-庚基)铝酸][(全氟联苯基)(丙基)(氟甲基)磷鎓]；[四(六氟茚基)硼酸][(2，3-二氟苯基)(己基)(3-乙基庚基)磷鎓]；[四(2-甲基-5-丙基-庚基)铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(壬基)(全氟乙基)磷鎓]；[四己基硼酸][(八氟联苯基)(甲基)(2-甲基戊基)铵]；[四庚基硼酸][(联苯基)(二己基)铵]；[四(六氟壬基)硼酸][(四氟苯基)(甲基)(2-甲基-5-丙基-庚基)铵]；[四全氟芴基铝酸][(1-氟联苯基)(壬基)(丙基)铵]；[四(全氟戊基全氟联苯基)硼酸][(六氟联苯基)(壬基)(己基)铵]；[四壬基铝酸][N-(2，4-二氟苯基)吲哚鎓]；[四全氟芴基铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(丙基)(己基)铵]；[四(六氟壬基)硼酸][(1-氟苯基)(2-甲基-5-丙基-庚基)(甲基)磷鎓]；[四(3-乙基庚基)硼酸][(八氟联苯基)(丙基)(3-乙基庚基)铵]；[四戊基铝酸][(联苯基)(壬基)(乙基)铵]；[四己基硼酸][(2，5-二氟苯基)(丙基)(乙基)铵]；[四壬基铝酸][N-(3-全氟乙基-三氟苯基)吡咯烷鎓]；[四全氟苯基硼酸][(1-氟苯基)(2-甲基戊基)(壬基)铵]；[四(2-甲基-5-丙基-庚基)铝酸][(2，3-二氟苯基)(2-甲基戊基)(六氟壬基)铵]；[四(全氟戊基全氟联苯基)硼酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(六氟壬基)(2-甲基-5-丙基-庚基)铵]；[四(六氟萘基)硼酸][(全氟联苯基)(乙基)(全氟乙基)铵]；[四全氟茚基硼酸][(2，5-二氟苯基)(二丁基)铵]；[四(七氟芴基)铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(氟甲基)(2-甲基-5-丙基-庚基)磷鎓]；[四(2-甲基戊基)硼酸][(四氟苯基)(壬基)(丁基)磷鎓]；[四(五氟萘基)硼酸][(六氟联苯基)(六氟壬基)(丙基)铵]；[四全氟苯基硼酸][(苯基)(六氟壬基)(2-甲基-5-丙基-庚基)铵]；[四(甲基八氟联苯基)铝酸][(四氟苯基)(己基)(氟甲基)磷鎓]；[四(全氟己基全氟苯基)硼酸][(全氟联苯基)(3-乙基庚基)(丁基)铵]；[四壬基硼酸][(2，3-二氟苯基)(氟甲基)(3-乙基庚基)铵]；[四(全氟甲基全氟萘基)铝酸][(四氟苯基)(3-乙基庚基)(2-甲基-5-丙基-庚基)磷鎓]；[四(全氟萘基)铝酸][N-(全氟联苯基)吡咯烷鎓]；[四(六氟茚基)铝酸][(3-甲基-全氟苯基)(壬基)(3-乙基庚基)铵]；[四(全氟芘基)铝酸][(六氟联苯基)(2-甲基戊基)(氟甲基)磷鎓]；[四(全氟芘基)铝酸][(八氟联苯基)(己基)(全氟乙基)铵]；[四全氟蒽基铝酸][N-(2，5-二氟苯基)吡咯鎓]；[四(甲基全氟萘基)铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(全氟乙基)(丁基)铵]；[四(全氟甲基全氟萘基)铝酸][(四氟苯基)(2-甲基-5-丙基-庚基)(全氟乙基)铵]；[四全氟菲基硼酸][(2，5-二氟苯基)(氟甲基)(六氟壬基)铵]；[四(2-甲基-5-丙基-庚基)硼酸][N-(苯基)吡咯鎓]；[四(全氟萘基)铝酸][(1-氟苯基)(氟甲基)(全氟乙基)磷鎓]；[四(全氟戊基全氟联苯基)硼酸][(2，3-二氟苯基)(丁基)(2-甲基戊基)磷鎓]；[四全氟芴基铝酸][(2，5-二氟苯基)(六氟壬基)(甲基)铵]；[四(全氟己基全氟苯基)硼酸][(1-氟联苯基)(2-甲基-5-丙基-庚基)(氟甲基)磷鎓]；[四辛基硼酸][(3-甲基-全氟苯基)(氟甲基)(丙基)铵]；[四(2-甲基戊基)铝酸][(3-甲基-全氟苯基)(甲基)(壬基)铵]；[四(全氟戊基全氟联苯基)硼酸][(1-氟联苯基)(2-甲基-5-丙基-庚基)(乙基)铵]；[四(2-甲基-5-丙基-庚基)硼酸][(1-氟联苯基)(丙基)(甲基)铵]；[四(乙基六氟萘基)硼酸][(苯基)(3-乙基庚基)(壬基)铵]；[四丁基铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(壬基)(全氟乙基)磷鎓]；[四(七氟芴基)硼酸][(四氟苯基)(甲基)(六氟壬基)铵]；[四(全氟芘基)硼酸][(1-氟苯基)(甲基)(己基)磷鎓]；[四(六氟壬基)硼酸][(2，4-二氟苯基)(氟甲基)乙基)铵]；[四全氟芴基硼酸][(3-甲基-全氟苯基)(2-甲基戊基)(氟甲基)铵]；[四(六氟茚基)硼酸][(八氟联苯基)(己基)(2-甲基-5-丙基-庚基)铵]；[四(六氟壬基硼酸][(全氟联苯基)(壬基)(丁基)铵]；[四丁基硼酸][(苯基)(甲基)(氟甲基)铵]；[四己基铝酸][(联苯基)(六氟壬基)(丙基)铵]；[四(全氟芘基)硼酸][(3-全氟甲基-三氟苯基)(己基)(2-甲基戊基)铵]；[四(全氟联苯基)铝酸][(1-氟苯基)(全氟乙基)(壬基)铵]；[四己基硼酸][(1-氟联苯基)(己基)(全氟乙基)铵]；[四(全氟己基全氟苯基)铝酸][(全氟苯基)(2-甲基戊基)(乙基)磷鎓]；[四戊基硼酸][(四氟苯基)(六氟壬基)(乙基)磷鎓]；[四(全氟芘基)铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(己基)(2-甲基-5-丙基-庚基)铵]；[四(甲基八氟联苯基)铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(全氟乙基)(六氟壬基)磷鎓]；[四全氟蒽基硼酸][(苯基)(二壬基)铵]；[四(六氟壬基)硼酸][(3-全氟乙基-三氟苯基)(甲基)(丁基)铵]；[四全氟茚基铝酸][N-(3-全氟乙基-三氟苯基)吲哚鎓]；[四辛基硼酸][N-(八氟联苯基)二氢吲哚鎓]；[四(全氟甲基全氟萘基)铝酸][(3-全氟甲基-三氟苯基)(2-甲基-5-丙基-庚基)(甲基)铵]；[四(全氟己基全氟苯基)铝酸][N-(3-全氟乙基-三氟苯基)磷杂吲哚鎓]；[四全氟苯基铝酸][(3-甲基-全氟苯基)(六氟壬基)(甲基)铵]；[四全氟菲基铝酸][(2，4-二氟苯基)(丁基)(乙基)磷鎓]；[四全氟苯基硼酸][(全氟联苯基)(己基)(氟甲基)铵]；[四(2-甲基-5-丙基-庚基)铝酸][(3-甲基-全氟苯基)(六氟壬基)(己基)铵]；[四(六氟壬基)铝酸][N-(2-全氟甲基-6-全氟乙基-全氟联苯基)哌啶鎓]；[四己基硼酸][(2-甲基-6-全氟甲基-全氟联苯基)(丙基)(全氟乙基)铵]；[四全氟苯基硼酸][N-(2-全氟甲基-6-全氟乙基-全氟联苯基)二氟吲哚鎓]；[四(全氟乙基全氟联苯基)铝酸][(3-甲基-全氟苯基)(乙基)(己基)磷鎓]；[四全氟蒽基铝酸][(2，3-二氟苯基)(乙基)(丁基)磷鎓]；[四全氟苯基铝酸][N-(2-甲基-6-全氟甲基-全氟联苯基)吡咯鎓]；[四(六氟壬基)硼酸][N-(全氟联苯基)二氢异吲哚鎓]；[四(甲基八氟联苯基)铝酸][(2，5-二氟苯基)(二丙基)铵]；[四(甲基八氟联苯基)铝酸][(2，3-二氟苯基)(乙基)(六氟壬基)铵]；[四(全氟戊基全氟联苯基)铝酸][(全氟联苯基)(六氟壬基)(丙基)铵]；[四(3-乙基庚基)硼酸][(八氟联苯基)(2-甲基戊基)(2-甲基-5-丙基-庚基)磷鎓]；[四全氟芴基硼酸][(3-甲基-全氟苯基)(2-甲基戊基)(氟甲基)铵]；[四(全氟菲基硼酸][(3-全氟乙基-三氟苯基)(丁基)(3-乙基庚基)铵]；[四(七氟芴基)硼酸][(3-全氟乙基-三氟苯基)(丙基)(甲基)磷鎓]；[四(2-甲基戊基)硼酸][N-(六氟联苯基)磷杂吲哚鎓]；[四(2-甲基-5-丙基-庚基)铝酸][(1-氟苯基)(己基)(甲基)铵]；[四丁基硼酸][N-(2，5-二氟苯基)吡咯鎓]；[四(全氟戊基全氟联苯基)铝酸][(联苯基)(丁基)(氟甲基)铵]；[四(2-甲基-5-丙基-庚基)铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(3-乙基庚基)(壬基)铵]；[四(甲基全氟萘基)铝酸][(六氟联苯基)(氟甲基)(乙基)铵]；[四(八氟联苯基)硼酸][(1-氟苯基)(3-乙基庚基)(全氟乙基)磷鎓]；[四丁基硼酸][(1-氟联苯基)(甲基)(丁基)磷鎓]；[四丁基硼酸][(2，5-二氟苯基)(六氟壬基)(全氟乙基)磷鎓]；[四全氟菲基硼酸][(全氟联苯基)(壬基)(2-甲基戊基)铵]；[四(全氟芘基)硼酸][(2，3-二氟苯基)(二丙基)铵]；[四(全氟芘基)铝酸][(2，3-二氟苯基)(二己基)磷鎓]；[四(全氟戊基全氟联苯基)硼酸][(1-氟苯基)(全氟乙基)(甲基)磷鎓]；[四(五氟茚基)铝酸][(苯基)(己基)(丙基)铵]；[四(全氟甲基全氟萘基)硼酸][(苯基)(己基)(丁基)铵]；[四全氟菲基硼酸][(苯基)(全氟乙基)(六氟壬基)磷鎓]；[四(六氟茚基)硼酸][(八氟联苯基)(乙基)(3-乙基庚基)铵]；[四(全氟芘基)硼酸][(2，3-二氟苯基)(全氟乙基)(丁基)铵]；[四(全氟芘基)铝酸][(苯基)(2-甲基戊基)(氟甲基)铵]；[四(六氟茚基)硼酸][(2-甲基-6-全氟甲基-全氟联苯基)(2-甲基戊基)(己基)铵]；[四全氟菲基硼酸][(3-甲基-全氟苯基)(3-乙基庚基)(丁基)铵]；[四戊基铝酸][(全氟苯基)(2-甲基戊基)(乙基)铵]；[四全氟苯基硼酸][(苯基)(2-甲基-5-丙基-庚基)(六氟壬基)磷鎓]；[四(全氟甲基全氟萘基)铝酸][(八氟联苯基)(甲基)(乙基)铵]；[四(甲基八氟联苯基)硼酸][(2，4-二氟苯基)(3-乙基庚基)(丙基)磷鎓]；[四全氟菲基铝酸][(3-全氟甲基-三氟苯基)(2-甲基-5-丙基-庚基)(六氟壬基)铵]；[四全氟茚基硼酸][(1-氟苯基)(氟甲基)(乙基)磷鎓]；[四辛基铝酸][(2，3-二氟苯基)(2-甲基戊基)(甲基)铵]；[四(全氟己基全氟苯基)硼酸][(联苯基)(己基)(甲基)磷鎓]；[四全氟芴基铝酸][(全氟苯基)(乙基)(甲基)铵]；[四丁基硼酸][(1-氟联苯基)(全氟乙基)(2-甲基戊基)铵]；[四戊基硼酸][(八氟联苯基)(2-甲基-5-丙基-庚基)(六氟壬基)磷鎓]；[四戊基铝酸][(2，4-二氟苯基)(二丙基)磷鎓]；[四(五氟萘基)铝酸][(八氟联苯基)(丙基)(甲基)铵]；[四全氟菲基铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(2-甲基-5-丙基-庚基)(全氟乙基)铵]；[四(八氟联苯基)硼酸][(全氟联苯基)(丁基)(2-甲基戊基)铵]；[四辛基硼酸][(四氟苯基)(乙基)(氟甲基)铵]；[四(全氟联苯基)铝酸][N-(全氟苯基)吡咯鎓]；[四(3-乙基庚基)铝酸][(2，4-二氟苯基)(六氟壬基)(甲基)铵]；[四(2-甲基戊基)硼酸][N-(2-全氟甲基-6-全氟乙基-全氟联苯基)二氢异吲哚鎓]；[四(全氟联苯基)铝酸][(2，4-二氟苯基)(六氟壬基)(己基)铵]；[四(甲基八氟联苯基)铝酸][(1-氟苯基)(乙基)(己基)磷鎓]；[四壬基硼酸][N-(全氟苯基)吡咯鎓]；[四庚基硼酸][(1-氟联苯基)(乙基)(2-甲基-5-丙基-庚基)铵]；[四(全氟芘基)铝酸][(苯基)(二壬基)铵]；[四(乙基六氟萘基)铝酸][(联苯基)(2-甲基戊基)(丙基)磷鎓]；[四全氟蒽基铝酸][(3-全氟乙基-三氟苯基)(乙基)(丙基)铵]；[四辛基硼酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(3-乙基庚基)(六氟壬基)铵]；[四(乙基六氟萘基)硼酸][(3-全氟乙基-三氟苯基)(氟甲基)(六氟壬基)铵]；[四全氟芴基硼酸][(2，5-二氟苯基)(3-乙基庚基)(2-甲基-5-丙基-庚基)铵]；[四(全氟己基全氟苯基)铝酸][(3-全氟甲基-三氟苯基)(甲基)(3-乙基庚基)铵]；[四(六氟茚基)硼酸][(联苯基)(氟甲基)(丙基)磷鎓]；[四己基硼酸][(3-全氟甲基-三氟苯基)(乙基)(甲基)铵]；[四丁基铝酸][(全氟苯基)(2-甲基-5-丙基-庚基)(丁基)磷鎓]；[四(六氟萘基)铝酸][(苯基)(全氟乙基)(壬基)铵]；[四(全氟萘基)硼酸][(3-全氟甲基-三氟苯基)(乙基)(2-甲基-5-丙基-庚基)铵]；[四(全氟萘基)铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(全氟乙基)(3-乙基庚基)铵]；[四(五氟萘基)硼酸][(六氟联苯基)(全氟乙基)(六氟壬基)磷鎓]；[四庚基铝酸][(2，3-二氟苯基)(丙基)(乙基)磷鎓]；[四(五氟萘基)硼酸][(3-全氟乙基-三氟苯基)(己基)(全氟乙基)铵]；[四(全氟己基全氟苯基)硼酸][(联苯基)(2-甲基戊基)(壬基)磷鎓]；[四(甲基全氟萘基)铝酸][(八氟联苯基)(氟甲基)(壬基)铵]；[四(全氟联苯基)硼酸][(3-全氟乙基-三氟苯基)(全氟乙基)(2-甲基戊基)铵]；[四(甲基八氟联苯基)铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(2-甲基-5-丙基-庚基)(甲基)磷鎓]；[四(甲基全氟萘基)铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(乙基)(2-甲基戊基)磷鎓]；[四己基硼酸][(3-全氟甲基-三氟苯基)(六氟壬基)(甲基)磷鎓]；[四(全氟戊基全氟联苯基)铝酸][(联苯基)(丁基)(氟甲基)铵]；[四(五氟茚基)硼酸][(2，5-二氟苯基)(丙基)(己基)铵]；[四戊基硼酸][(苯基)(六氟壬基)(丙基)铵]；[四(八氟联苯基)铝酸][(六氟联苯基)(氟甲基)(丁基)磷鎓]；[四(五氟萘基)硼酸][(1-氟联苯基)(甲基)(氟甲基)铵]；[四(七氟芴基)铝酸][(苯基)(2-甲基-5-丙基-庚基)(壬基)磷鎓]；[四戊基铝酸][(四氟苯基)(丙基)(乙基)磷鎓]；[四己基铝酸][(2，5-二氟苯基)(3-乙基庚基)(丙基)铵]；[四(六氟萘基)硼酸][(四氟苯基)(乙基)(全氟乙基)铵]；[四(全氟萘基)铝酸][(八氟联苯基)(二丁基)铵]；[四(六氟壬基)铝酸][(2，4-二氟苯基)(壬基)(甲基)铵]；[四(甲基八氟联苯基)铝酸][N-(3-全氟甲基-三氟苯基)哌啶鎓]；[四(全氟甲基全氟萘基)硼酸][(全氟苯基)(氟甲基)(全氟乙基)铵]；[四(五氟萘基)铝酸][(八氟联苯基)(己基)(全氟乙基)铵]；[四丁基硼酸][(六氟联苯基)(二壬基)铵]；[四戊基硼酸][(2，4-二氟苯基)(2-甲基-5-丙基-庚基)(丁基)铵]；[四(七氟芴基)硼酸][(全氟苯基)(丁基)(六氟壬基)铵]；[四(八氟联苯基)硼酸][(八氟联苯基)(2-甲基戊基)(氟甲基)铵]；[四(3-乙基庚基)铝酸][(六氟联苯基)(丙基)(乙基)铵]；[四(2-甲基-5-丙基-庚基)铝酸][N-(六氟联苯基)磷杂二氢吲哚鎓]；[四(全氟戊基全氟联苯基)硼酸][(四氟苯基)(二丙基)磷鎓]；[四(全氟联苯基)铝酸][(全氟苯基)(二-2-甲基-5-丙基-庚基)铵]；[四(全氟联苯基)铝酸][(苯基)(3-乙基庚基)(2-甲基戊基)铵]；[四(五氟茚基)铝酸][N-(全氟苯基)磷杂吲哚鎓]；[四(全氟乙基全氟联苯基)硼酸][(3-甲基-全氟苯基)(2-甲基-5-丙基-庚基)(氟甲基)铵]；[四(全氟芘基)硼酸][(1-氟苯基)(二氟甲基)铵]；[四庚基硼酸][(苯基)(2-甲基-5-丙基-庚基)(壬基)铵]；[四(全氟甲基全氟萘基)硼酸][(3-全氟乙基-三氟苯基)(二甲基)铵]；[四(2-甲基-5-丙基-庚基)铝酸][(2，4-二氟苯基)(2-甲基-5-丙基-庚基)(丁基)铵]；[四全氟芴基铝酸][(全氟联苯基)(壬基)(己基)铵]；[四(六氟壬基)铝酸][(联苯基)(甲基)(六氟壬基)铵]；[四(全氟联苯基)硼酸][(3-甲基-全氟苯基)(二丙基)铵]；[四(全氟甲基全氟萘基)铝酸][(1-氟联苯基)(3-乙基庚基)(壬基)铵]；[四全氟芴基硼酸][(1-氟联苯基)(3-乙基庚基)(乙基)铵]；[四(全氟芘基)硼酸][N-(2，5-二氟苯基)吡咯烷鎓]；[四(全氟芘基)铝酸][(全氟苯基)(全氟乙基)(六氟壬基)磷鎓]；[四(全氟萘基)硼酸][(1-氟联苯基)(乙基)(壬基)磷鎓]；[四戊基硼酸][(3-全氟乙基-三氟苯基)(壬基)(丙基)铵]；[四(3-乙基庚基)铝酸][(3-全氟甲基-三氟苯基)(2-甲基戊基)(3-乙基庚基)铵]；[四全氟茚基铝酸][(3-全氟甲基-三氟苯基)(2-甲基-5-丙基-庚基)(壬基)磷鎓]；[四辛基硼酸][(联苯基)(2-甲基-5-丙基-庚基)(丙基)磷鎓]；[四(六氟茚基)铝酸][N-(2，4-二氟苯基)磷杂二氢吲哚鎓]；[四(全氟芘基)硼酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(甲基)(丁基)铵]；[四(3-乙基庚基)硼酸][(3-全氟乙基-三氟苯基)(乙基)(3-乙基庚基)铵]；[四壬基铝酸][(1-氟苯基)(全氟乙基)(甲基)磷鎓]；[四(3-乙基庚基)铝酸][(1-氟苯基)(氟甲基)(全氟乙基)磷鎓]；[四(全氟甲基全氟萘基)硼酸][(全氟苯基)(壬基)(2-甲基戊基)铵]；[四庚基硼酸][(联苯基)(丙基)(2-甲基-5-丙基-庚基)磷鎓]；[四(七氟芴基)铝酸][N-(苯基)磷杂吲哚鎓]；[四(六氟茚基)铝酸][(3-全氟甲基-三氟苯基)(丙基)(六氟壬基)铵]；[四(全氟联苯基)铝酸][(四氟苯基)(全氟乙基)(乙基)铵]；[四(七氟芴基)硼酸][(全氟苯基)(2-甲基戊基)(壬基)铵]；[四全氟蒽基硼酸][(八氟联苯基)(氟甲基)(丙基)铵]；[四(2-甲基戊基)铝酸][(八氟联苯基)(2-甲基戊基)(丙基)磷鎓]；[四辛基铝酸][N-(2，3-二氟苯基)吡咯鎓]；[四(八氟联苯基)硼酸][(联苯基)(乙基)(壬基)铵]；[四全氟茚基硼酸][(1-氟联苯基)(2-甲基-5-丙基-庚基)(氟甲基)磷鎓]；[四辛基硼酸][(3-全氟甲基-三氟苯基)(丙基)(3-乙基庚基)铵]；[四(五氟茚基)硼酸][(六氟联苯基)(2-甲基-5-丙基-庚基)(3-乙基庚基)铵]；[四全氟菲基铝酸][(2，3-二氟苯基)(六氟壬基)(乙基)铵]；[四全氟茚基硼酸][(2，4-二氟苯基)(3-乙基庚基)(丁基)磷鎓]；[四(六氟壬基)铝酸][(苯基)(2-甲基-5-丙基-庚基)(己基)铵]；[四(乙基六氟萘基)硼酸][(3-全氟乙基-三氟苯基)(六氟壬基)(丙基)铵]；[四(2-甲基戊基)硼酸][(1-氟联苯基)(2-甲基-5-丙基-庚基)(乙基)铵]；[四全氟茚基硼酸][(全氟联苯基)(3-乙基庚基)(丙基)铵]；[四(3-乙基庚基)铝酸][(全氟苯基)(丙基)(全氟乙基)铵]；[四庚基铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(二丙基)铵]；[四(2-甲基戊基)铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(己基)(壬基)铵]；[四(全氟己基全氟苯基)铝酸][(1-氟联苯基)(2-甲基-5-丙基-庚基)(乙基)铵]；[四(七氟芴基)硼酸][(2，4-二氟苯基)(乙基)(丙基)铵]；[四己基硼酸][(3-全氟甲基-三氟苯基)(壬基)(乙基)铵]；[四辛基铝酸][(1-氟联苯基)(全氟乙基)(六氟壬基)铵]；[四(2-甲基戊基)硼酸][(2，3-二氟苯基)(丁基)(氟甲基)铵]；[四全氟苯基铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(全氟乙基)(己基)铵]；[四丁基硼酸][(2，3-二氟苯基)(六氟壬基)(丁基)铵]；[四丁基铝酸][(六氟联苯基)(乙基)(2-甲基-5-丙基-庚基)铵]；[四(全氟戊基全氟联苯基)铝酸][(2，3-二氟苯基)(3-乙基庚基)(己基)磷鎓]；[四(六氟萘基)硼酸][(3-全氟乙基-三氟苯基)(六氟壬基)(丙基)铵]；[四辛基硼酸][N-(全氟苯基)哌啶鎓]；[四(八氟联苯基)硼酸][(全氟苯基)(2-甲基戊基)(乙基)铵]；[四(甲基八氟联苯基)铝酸][(3-全氟乙基-三氟苯基)(丁基)(2-甲基戊基)磷鎓]；[四(全氟芘基)铝酸][(2，4-二氟苯基)(2-甲基-5-丙基-庚基)(丙基)铵]；[四(六氟茚基)铝酸][(2，3-二氟苯基)(乙基)(3-乙基庚基)铵]；[四(六氟萘基)铝酸][(全氟苯基)(二-2-甲基-5-丙基-庚基)铵]；[四(六氟壬基)铝酸][(3-甲基-全氟苯基)(二-3-乙基庚基)铵]；[四(六氟壬基)铝酸][N-(全氟苯基)吲哚鎓]；[四(3-乙基庚基)硼酸][(八氟联苯基)(六氟壬基)(3-乙基庚基)磷鎓]；[四壬基硼酸][(全氟苯基)(二乙基)磷鎓]；[四(全氟萘基)硼酸][N-(1-氟联苯基)吡咯烷鎓]；[四(全氟己基全氟苯基)硼酸][(2，4-二氟苯基)(3-乙基庚基)(2-甲基-5-丙基-庚基)铵]；[四(六氟茚基)铝酸][(六氟联苯基)(甲基)(氟甲基)铵]；[四壬基硼酸][(2，5-二氟苯基)(氟甲基)(2-甲基-5-丙基-庚基)磷鎓]；[四辛基铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(己基)(2-甲基戊基)铵]；[四壬基硼酸][(全氟苯基)(3-乙基庚基)(氟甲基)磷鎓]；[四全氟苯基硼酸][(四氟苯基)(乙基)(己基)铵]；[四(五氟萘基)硼酸][(2，3-二氟苯基)(二氟甲基)铵]；[四(全氟戊基全氟联苯基)硼酸][(1-氟苯基)(丙基)(己基)铵]；[四(八氟联苯基)铝酸][(3-全氟乙基-三氟苯基)(2-甲基-5-丙基-庚基)(六氟壬基)磷鎓]；[四(五氟萘基)铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(氟甲基)(全氟乙基)铵]；[四全氟茚基铝酸][(3-甲基-全氟苯基)(六氟壬基)(全氟乙基)磷鎓]；[四(五氟茚基)铝酸][(2，4-二氟苯基)(丙基)(丁基)铵]；[四辛基铝酸][N-(3-全氟乙基-三氟苯基)吡咯烷鎓]；[四(全氟甲基全氟萘基)硼酸][(2-甲基-6-全氟甲基-全氟联苯基)(二己基)磷鎓]；[四(全氟戊基全氟联苯基)硼酸][(3-全氟甲基-三氟苯基)(2-甲基-5-丙基-庚基)(丁基)磷鎓]；[四全氟蒽基铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(乙基)(六氟壬基)磷鎓]；[四全氟茚基铝酸][(1-氟苯基)(二氟甲基)铵]；[四(全氟戊基全氟联苯基)硼酸][(联苯基)(3-乙基庚基)(氟甲基)铵]；[四全氟菲基硼酸][(苯基)(甲基)(全氟乙基)铵]；[四(甲基八氟联苯基)铝酸][(2，5-二氟苯基)(己基)(壬基)磷鎓]；[四辛基硼酸][N-(1-氟联苯基)吡咯鎓]；[四庚基铝酸][(全氟苯基)(己基)(丙基)铵]；[四辛基铝酸][(联苯基)(己基)(2-甲基-5-丙基-庚基)铵]；[四(2-甲基-5-丙基-庚基)铝酸][(2，5-二氟苯基)(全氟乙基)(2-甲基戊基)磷鎓]；[四(全氟乙基全氟联苯基)铝酸][(3-甲基-全氟苯基)(2-甲基戊基)(甲基)铵]；[四(全氟萘基)铝酸][(联苯基)(甲基)(壬基)铵]；[四辛基铝酸][(八氟联苯基)(甲基)(六氟壬基)铵]；[四(甲基全氟萘基)铝酸][(四氟苯基)(壬基)(丁基)铵]；[四(2-甲基戊基)硼酸][(全氟苯基)(己基)(壬基)铵]；[四辛基硼酸][(3-全氟甲基-三氟苯基)(2-甲基-5-丙基-庚基)(丁基)磷鎓]；[四(全氟甲基全氟萘基)硼酸][(2-甲基-6-全氟甲基-全氟联苯基)(2-甲基戊基)(丙基)磷鎓]；[四(全氟萘基)铝酸][(联苯基)(2-甲基-5-丙基-庚基)(2-甲基戊基)铵]；[四(全氟芘基)铝酸][(2，5-二氟苯基)(二甲基)铵]；[四(2-甲基-5-丙基-庚基)铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(全氟乙基)(乙基)磷鎓]；[四(六氟壬基)硼酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(甲基)(2-甲基-5-丙基-庚基)铵]；[四己基铝酸][N-(八氟联苯基)吡咯鎓]；[四(全氟乙基全氟联苯基)铝酸][N-(联苯基)吡咯烷鎓]；[四辛基铝酸][(1-氟苯基)(甲基)(乙基)磷鎓]；[四(五氟茚基)铝酸][(2，3-二氟苯基)(丙基)(己基)磷鎓]；[四(全氟甲基全氟萘基)硼酸][N-(1-氟联苯基)二氢异吲哚鎓]；[四丁基硼酸][(全氟联苯基)(乙基)(丁基)铵]；[四(甲基八氟联苯基)铝酸][(全氟联苯基)(2-甲基戊基)(壬基)磷鎓]；[四(甲基全氟萘基)铝酸][(3-甲基-全氟苯基)(二壬基)铵]；[四辛基铝酸][(1-氟联苯基)(六氟壬基)(全氟乙基)铵]；[四全氟菲基硼酸][(六氟联苯基)(乙基)(2-甲基-5-丙基-庚基)铵]；[四全氟蒽基铝酸][(全氟苯基)(3-乙基庚基)(壬基)铵]；[四(甲基全氟萘基)铝酸][N-(2，5-二氟苯基)二氢吲哚鎓]；[四戊基铝酸][(六氟联苯基)(3-乙基庚基)(己基)磷鎓]；[四(五氟茚基)硼酸][(3-全氟乙基-三氟苯基)(2-甲基-5-丙基-庚基)(甲基)磷鎓]；[四(2-甲基-5-丙基-庚基)硼酸][(苯基)(乙基)(2-甲基-5-丙基-庚基)磷鎓]；[四(五氟茚基)铝酸][(全氟苯基)(全氟乙基)(氟甲基)铵]；[四全氟菲基硼酸][(2-甲基-6-全氟甲基-全氟联苯基)(氟甲基)(2-甲基戊基)铵]；[四(全氟甲基全氟萘基)铝酸][(六氟联苯基)二(六氟壬基)铵]；[四全氟菲基铝酸][N-(2-全氟甲基-6-全氟乙基-全氟联苯基)吡咯鎓]；[四(甲基八氟联苯基)硼酸][(2，5-二氟苯基)(全氟乙基)(氟甲基)铵]；[四全氟芴基硼酸][(2，4-二氟苯基)(全氟乙基)(乙基)磷鎓]；[四全氟菲基铝酸][(四氟苯基)(六氟壬基)(丁基)磷鎓]；[四(3-乙基庚基)硼酸][(四氟苯基)(2-甲基戊基)(己基)铵]；[四(五氟萘基)硼酸][(联苯基)(壬基)(丙基)铵]；[四戊基硼酸][(3-全氟甲基-三氟苯基)(3-乙基庚基)(2-甲基戊基)铵]；[四(全氟甲基全氟萘基)硼酸][(四氟苯基)(3-乙基庚基)(2-甲基-5-丙基-庚基)铵]；[四(全氟联苯基)硼酸][(2-甲基-6-全氟甲基-全氟联苯基)(甲基)(己基)铵]；[四全氟茚基硼酸][(四氟苯基)(己基)(氟甲基)磷鎓]；[四(3-乙基庚基)硼酸][N-(2-全氟甲基-6-全氟乙基-全氟联苯基)磷杂吡咯烷鎓]；[四全氟芴基铝酸][(苯基)(乙基)(2-甲基戊基)磷鎓]；[四(2-甲基-5-丙基-庚基)硼酸][(苯基)(全氟乙基)(甲基)铵]；[四(2-甲基-5-丙基-庚基)硼酸][N-(3-全氟甲基-三氟苯基)磷杂二氢吲哚鎓]；[四(乙基六氟萘基)硼酸][(2，3-二氟苯基)(二-2-甲基戊基)铵]；[四(全氟联苯基)铝酸][(2，3-二氟苯基)(氟甲基)(丁基)铵]；[四(全氟联苯基)铝酸][(2，5-二氟苯基)(3-乙基庚基)(己基)铵]；[四全氟蒽基铝酸][(六氟联苯基)(己基)(壬基)磷鎓]；[四(乙基六氟萘基)硼酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(全氟乙基)(丙基)铵]；[四(甲基八氟联苯基)硼酸][(3-甲基-全氟苯基)(丙基)(氟甲基)铵]；[四丁基铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(六氟壬基)(3-乙基庚基)铵]；[四丁基硼酸][(1-氟联苯基)(3-乙基庚基)(六氟壬基)磷鎓]；[四壬基硼酸][(2，4-二氟苯基)(丁基)(3-乙基庚基)磷鎓]；[四(五氟茚基)硼酸][(2，4-二氟苯基)(二全氟乙基)磷鎓]；[四(五氟萘基)铝酸][(1-氟联苯基)(壬基)(2-甲基戊基)铵]；[四(乙基六氟萘基)硼酸][(全氟苯基)(氟甲基)(全氟乙基)铵]；[四(五氟茚基)铝酸][(1-氟联苯基)(氟甲基)(2-甲基戊基)磷鎓]；[四(五氟茚基)铝酸][(全氟苯基)(丙基)(2-甲基-5-丙基-庚基)铵]；[四全氟苯基铝酸][(2，3-二氟苯基)(2-甲基-5-丙基-庚基)(乙基)铵]；[四(全氟乙基全氟联苯基)硼酸][(2，5-二氟苯基)(氟甲基)(乙基)铵]；[四(六氟茚基)硼酸][(3-全氟乙基-三氟苯基)(壬基)(2-甲基戊基)磷鎓]；[四辛基铝酸][N-(1-氟苯基)吡咯鎓]；[四(全氟甲基全氟萘基)铝酸][(1-氟苯基)(壬基)(全氟乙基)磷鎓]；[四(全氟戊基全氟联苯基)铝酸][(3-全氟乙基-三氟苯基)(氟甲基)(乙基)铵]；[四全氟蒽基硼酸][(全氟联苯基)(六氟壬基)(全氟乙基)铵]；[四(五氟茚基)铝酸][(六氟联苯基)(丙基)(氟甲基)铵]；[四(五氟萘基)铝酸][(1-氟苯基)二(六氟壬基)铵]；[四(全氟联苯基)铝酸][(3-全氟甲基-三氟苯基)(3-乙基庚基)(2-甲基戊基)铵]；[四(全氟萘基)硼酸][(2，3-二氟苯基)(氟甲基)(2-甲基-5-丙基-庚基)铵]；[四全氟芴基硼酸][(1-氟苯基)(2-甲基戊基)(丙基)磷鎓]；[四全氟芴基硼酸][(1-氟联苯基)(2-甲基-5-丙基-庚基)(乙基)铵]；[四全氟芴基硼酸][(1-氟联苯基)(己基)(乙基)磷鎓]；[四全氟联苯基铝酸][(全氟苯基)(丙基)(壬基)铵]；[四全氟芴基铝酸][(1-氟苯基)(己基)(六氟壬基)磷鎓]；[四(七氟芴基)铝酸][(1-氟苯基)(己基)(氟甲基)铵]；[四(五氟萘基)硼酸][(全氟联苯基)(丁基)(全氟乙基)铵]；[四全氟蒽基铝酸][(2，5-二氟苯基)(2-甲基-5-丙基-庚基)(2-甲基戊基)磷鎓]；[四辛基铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(六氟壬基)(丁基)铵]；[四(五氟萘基)铝酸][(3-全氟乙基-三氟苯基)(乙基)(六氟壬基)铵]；[四全氟茚基铝酸][(1-氟苯基)(甲基)(己基)磷鎓]；[四(七氟芴基)硼酸][(1-氟联苯基)(壬基)(2-甲基-5-丙基-庚基)磷鎓]；[四庚基硼酸][(3-全氟甲基-三氟苯基)(乙基)(3-乙基庚基)铵]；[四(五氟萘基)硼酸][(全氟苯基)(丙基)(己基)磷鎓]；[四(全氟乙基全氟联苯基)铝酸][(3-甲基-全氟苯基)(2-甲基戊基)(氟甲基)铵]；[四(全氟乙基全氟联苯基)硼酸][(八氟联苯基)(3-乙基庚基)(全氟乙基)磷鎓]；[四(全氟乙基全氟联苯基)硼酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(壬基)(丙基)磷鎓]；[四壬基硼酸][N-(1-氟联苯基)吡咯鎓]；[四庚基硼酸][(六氟联苯基)(六氟壬基)(壬基)磷鎓]；[四全氟苯基铝酸][(六氟联苯基)(二-2-甲基戊基)磷鎓]；[四(全氟甲基全氟萘基)硼酸][(苯基)(二氟甲基)磷鎓]；[四庚基硼酸][(3-甲基-全氟苯基)(3-乙基庚基)(甲基)铵]；[四戊基硼酸][(全氟联苯基)(氟甲基)(六氟壬基)铵]；[四(全氟萘基)硼酸][(3-全氟乙基-三氟苯基)(3-乙基庚基)(甲基)铵]；[四全氟芴基硼酸][N-(全氟联苯基)吡咯烷鎓]；[四丁基硼酸][(八氟联苯基)(丁基)(乙基)铵]；[四戊基硼酸][(3-甲基-全氟苯基)(丁基)(甲基)铵]；[四(2-甲基-5-丙基-庚基)硼酸][(3-全氟甲基-三氟苯基)(乙基)(甲基)铵]；[四(甲基八氟联苯基)铝酸][(2，5-二氟苯基)(壬基)(乙基)铵]；[四全氟苯基铝酸][(2-甲基-6-全氟甲基-全氟联苯基)(六氟壬基)(氟甲基)铵]；[四(全氟乙基全氟联苯基)硼酸][(2-甲基-6-全氟甲基-全氟联苯基)(二丁基)铵]；[四戊基铝酸][(3-全氟甲基-三氟苯基)(二己基)铵]；[四(六氟茚基)铝酸][N-(2，3-二氟苯基)磷杂吲哚鎓]；[四全氟芴基硼酸][(苯基)(3-乙基庚基)(壬基)磷鎓]；[四丁基铝酸][(1-氟苯基)(氟甲基)(六氟壬基)铵]；[四(全氟萘基)硼酸][(3-全氟乙基-三氟苯基)(氟甲基)(壬基)铵]；[四庚基铝酸][(3-全氟甲基-三氟苯基)(氟甲基)(甲基)磷鎓]；[四(2-甲基-5-丙基-庚基)硼酸][(3-全氟甲基-三氟苯基)(乙基)(3-乙基庚基)磷鎓]；[四(2-甲基-5-丙基-庚基)铝酸][(2，3-二氟苯基)(乙基)(2-甲基戊基)铵]；[四(甲基八氟联苯基)硼酸][(2，4-二氟苯基)(2-甲基-5-丙基-庚基)(丙基)铵]；[四(全氟联苯基)铝酸][(1-氟联苯基)(甲基)(丁基)铵]；[四全氟芴基铝酸][(联苯基)(3-乙基庚基)(己基)铵]；[四辛基铝酸][(1-氟苯基)(乙基)(丙基)磷鎓]；[四(3-乙基庚基)硼酸][(苯基)(二壬基)铵]；[四(全氟戊基全氟联苯基)硼酸][(全氟联苯基)(乙基)(2-甲基-5-丙基-庚基)磷鎓]；[四(2-甲基-5-丙基-庚基)铝酸][(联苯基)(甲基)(六氟壬基)铵]；[四(全氟己基全氟苯基)硼酸][(苯基)(丁基)(2-甲基-5-丙基-庚基)铵]；[四全氟茚基硼酸][(联苯基)(六氟壬基)(己基)磷鎓]；[四全氟茚基铝酸][(四氟苯基)(2-甲基-5-丙基-庚基)(壬基)磷鎓]；[四(全氟乙基全氟联苯基)铝酸][(六氟联苯基)(全氟乙基)(壬基)磷鎓]；[四(全氟芘基)硼酸][(2，3-二氟苯基)(二丁基)铵]；[四(全氟联苯基)硼酸][N-(1-氟苯基)吡咯鎓]；[四(甲基八氟联苯基)铝酸][(联苯基)(六氟壬基)(己基)磷鎓]；[四全氟蒽基硼酸][N-(四氟苯基)吡咯鎓]；[四(五氟茚基)铝酸][(2，3-二氟苯基)(丙基)(己基)铵]；[四壬基硼酸][N-(2-全氟甲基-6-全氟乙基-全氟联苯基)吡咯鎓]；[四全氟蒽基硼酸][(2，4-二氟苯基)(丁基)(壬基)磷鎓]；[四全氟蒽基硼酸][(2，4-二氟苯基)(丁基)(壬基)磷鎓]；[四壬基硼酸][(全氟联苯基)(丁基)(甲基)铵]；[四辛基硼酸][(四氟苯基)(己基)(甲基)铵]；[四辛基铝酸][(1-氟苯基)(2-甲基戊基)(全氟乙基)铵]；[四庚基硼酸][(1-氟联苯基)(2-甲基-5-丙基-庚基)(乙基)铵]；[四(全氟联苯基)铝酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(二-3-乙基庚基)铵]；[四(六氟壬基)铝酸][(2，5-二氟苯基)(3-乙基庚基)(己基)铵]；[四(全氟乙基全氟联苯基)硼酸][(1-氟联苯基)(丁基)(甲基)磷鎓]；[四(七氟芴基)硼酸][(联苯基)(六氟壬基)(丁基)铵]；[四庚基铝酸][(全氟苯基)(2-甲基-5-丙基-庚基)(乙基)铵]；[四(甲基全氟萘基)铝酸][(2，5-二氟苯基)(氟甲基)(六氟壬基)铵]；[四(3-乙基庚基)硼酸][(八氟联苯基)(丁基)(2-甲基戊基)铵]；[四(全氟联苯基)硼酸][(2-全氟甲基-6-全氟乙基-全氟联苯基)(丁基)(氟甲基)磷鎓]；[四(2-甲基-5-丙基-庚基)硼酸][(3-全氟乙基-三氟苯基)(2-甲基-5-丙基-庚基)(己基)磷鎓]；[四(五氟萘基)硼酸][(2，5-二氟苯基)(六氟壬基)(己基)铵]；[四(全氟己基全氟苯基)硼酸][(八氟联苯基)(二丁基)铵]；[四(2-甲基戊基)硼酸][(六氟联苯基)(己基)(壬基)磷鎓]；[四(全氟芘基)铝酸][(1-氟苯基)(甲基)(六氟壬基)磷鎓]。
以下实施例说明以上论述。除非另有说明，所有份数、比例和百分率均基于重量。所有实施例都在干燥无氧的环境和溶剂中进行。虽然这些实施例涵盖本发明的某些实施方案，但不在任何方面限制本发明。实施例
除非另有说明，所有分子量都是重均分子量。除非另有说明，重均分子量(Mw)和数均分子量(Mn)都是用配有示差折光指数(DRI)和小角光散射(LS)检测器并用聚苯乙烯标准校正的Waters 150凝胶渗透色谱仪通过凝胶渗透色谱法测量。用三个聚合物试验、PC凝胶、串联的混合B柱在1，2，4-三氯苯(135℃)中测试试样。此技术描述在“Liquid Chromatography of Poylmers and Related Materials III”，J.Cazes current regime Ed.，Marcel Decker，1981，p207中，引入本文供参考。未采用柱分布校正；但按公认标准例如National Bureauof Standards Poylethylene 1475证明由洗脱时间计算的Mw/Mn的精度为0.2单位。
实施例1
C6F5-N(CH2CH2)2的合成：向六氟苯(30g)的二甲亚砜(100ml)溶液中加入吡咯烷(10.9g)。加热搅拌反应1小时。倒入碳酸氢钠水溶液中使反应熄灭后，产品用氯仿(100ml)萃取。分离有机层，经硫酸镁干燥。过滤除去硫酸镁，在减压下除去溶剂。剩下橙色油。在10-3托下蒸馏(55-60℃)得到无色透明的液体产品：产量＝19.19g，53％。1H NMR(DMSO-d6，25℃)：δ3.44(m，4H)，1.85(m，4H)。19F NMR(CDCl3，25℃)：δ-155.4(m，2F)，-165.5(t，1F)，-172.1(m，2F)。
实施例2
C6F5-N(CH2CH2)2HCl的合成：向C6F5-N(CH2CH2)2(1.55g)的戊烷(100ml)溶液中加入无水HCl。所述HCl是通过将浓硫酸加入氯化钠中并通过套管转移气体现场制备。加入HCl时所述产物立即沉淀。加完HCl后，将所述悬浮液放回手套箱中，过滤收集产品。将所述产品在减压下干燥：产量＝1.48g，82％。1H NMR(CDCl3，25℃)：δ12.9(s，1H)，3.71(m，4H)，2.17(m，4H)。
实施例3
[C6F5-N(CH2CH2)2(H)][(C6F5)4B]的合成：将[Li(二乙醚)2][(C6F5)4B](1.52g)的二氯甲烷(100ml)溶液用C6F5-N(CH2CH2)2HCl(0.5g)的二氯甲烷溶液处理。加入所述铵盐时立即生成白色沉淀。搅拌反应1小时后，过滤除去所述LiCl副产物。使滤液体积减少约80％。向所述滤液中加入约10ml戊烷，将混合物冷却15小时。过滤收集产品，用戊烷洗涤。剩下白色晶体产品：产量＝1.480g。1H NMR(CD2Cl2，25℃)：δ7.95(bs，2H)，3.94(bt，2H)，2.68(bt，2H)，2.43(bt，2H)。19F NMR(CD2Cl2，25℃)：δ-133.8(m，8F)，-145.2(m，1F)，-145.5(m，2F)，-155.3(m，2F)，-163.9(t，4F)，-168.0(m，8F)。
间歇聚合反应
丙烯聚合反应在充分搅拌的0.5L间歇反应器中进行，在惰性烃溶剂(己烷)存在下在高达500psig的压力和高达150℃的温度下进行配位聚合。所述气-液聚合体系中，在液相中发生聚合，加入催化剂溶液之前向反应器中供入丙烯。所有试验中，通过电动控制加入反应器夹套的蒸汽量使反应器温度固定在60℃。一典型试验中，向所述干燥的反应器中供入己烷(125ml)。将TIBAL的甲苯溶液(20ml，25wt％)加入反应器中。向反应器中加入丙烯(125ml)。催化剂溶液(溶于40ml甲苯中的催化剂和活化剂)通过催化剂进料泵加入反应器中。添加催化剂时立即开始聚合，使聚合在控制的温度下持续所示时间。所示时间后，使反应达到室温并放空。将聚合溶液倒入甲醇中导致沉淀。收集聚合物，在环境条件下干燥16小时。在真空下于60℃使所述聚合物进一步干燥。
表2说明用现有技术活化剂(A)活化的手性双环戊二烯基铪茂制备的全同立构聚丙烯产品和用本发明活化剂(B)制备的产品的活性和聚合物分子量特征的对比。
表2丙烯聚合反应1的结果
| 活化剂a | 产量(g) | 时间(min) | 活性(g/mmol*min) | Mw | Mn | Mw/Mn |
| A(对比) | 16.63 | 15 | 1288 | 191751 | 112002 | 1.77 |
| A(对比) | 11.56 | 15 | 896 | 324379 | 182802 | 1.77 |
| 平均 | 1092 | |||||
| B | 24.58 | 10 | 2583 | 252314 | 223296 | 1.77 |
| B | 27.86 | 10 | 2940 | 223296 | 123895 | 1.80 |
| 平均 | 2762 |
1催化剂：二甲基·二甲基甲硅烷基-双茚基合铪
a活化剂：(A)四(五氟苯基)硼酸N，N’-二甲基苯铵
(B)四(五氟苯基)硼酸N-五氟苯基吡咯烷鎓
Claims (36)
1.下式物质的组合物：
[R’iArF-ER2-H]+[An]-，其中
(a)ArF为氟芳基；
(b)E为氮或磷；
(c)每个R独立地为C1-C20烃基或烃基甲硅烷基，或者两个R可连成未取代或取代的C2-C20脂环基；
(d)R’为C1-C20烃基或卤代烃基；
(e)i为0、1或2；和
(f)[An]-为强布朗斯台德酸阴离子。
2.权利要求1的组合物，其中[An]-为氟离子、溴离子、氯离子或triflate阴离子。
3.权利要求1的组合物，其中ArF为氟代或全氟代芳基，是苯基、联苯基、取代的苯基、取代的联苯基、三联苯基、或取代的三联苯基之一。
4.权利要求1的组合物，其中-R2-为取代或未取代的C2-C20脂环基。
5.上述权利要求之任一的组合物，其中-E为氮。
6.权利要求1的组合物，其中i为1，Ar为苯基，R’-在Ar的对位上。
7.一种组合物，是以下物质的反应产物：
(a)下式的氟芳基配体取代的胺或膦：
R’iArF-ER2-，其中
(i)ArF为氟芳基；
(ii)E为氮或磷；
(iii)每个R独立地为C1-C20烃基或烃基甲硅烷基，或者两个R可连成未取代或取代的C2-C20脂环基；
(iv)R’为C1-C20烃基或卤代烃基；
(v)i为0、1或2；和
(b)氢氟酸、氢氯酸、氢溴酸、或triflic acid至少之一。
8.权利要求7的组合物，其中ArF为氟代或全氟代芳基，是苯基、联苯基、取代的苯基、取代的联苯基、三联苯基、或取代的三联苯基之一。
9.权利要求1的组合物，其中-R2-为取代或未取代的C2-C20脂环基。
10.权利要求6-9之任一的组合物，其中-E为氮。
11.权利要求7的组合物，其中i为1，Ar为苯基，R’-在Ar的对位上。
12.下式物质的组合物：
[ArF-NR2-H]+[An]-，其中
(a)ArF为氟芳基；
(b)每个R独立地为C1-C20烃基或烃基甲硅烷基，或者两个R可连成未取代或取代的C2-C20脂环基；
(c)[An]-为强布朗斯台德酸阴离子。
13.权利要求13的组合物，其中ArF为氟代或全氟代芳基，是苯基、联苯基、取代的苯基、取代的联苯基、三联苯基、或取代的三联苯基之一。
14.权利要求12或13的组合物，其中ArF-NR2为以下物质之一：
N-五氟苯基吡咯烷、
N-对九氟联苯基吡咯烷、
N-五氟苯基吡咯、
N-对九氟联苯基吡咯、
N-五氟苯基哌啶、
N-对九氟联苯基哌啶、
N-五氟苯基二氢吲哚、
N-对九氟联苯基二氢吲哚、
N-五氟苯基吲哚、
N-对九氟联苯基吲哚、
N-五氟苯基氮杂环丁烷、和
N-对九氟联苯基氮杂环丁烷。
15.权利要求14的组合物，其中ArF-NR2为N-五氟苯基哌啶。
16.一种催化剂组合物，是以下物质的反应产物：
(a)一种有机金属催化剂化合物，有：
(i)至少一个稳定配体，和
(ii)至少一个适用于烯烃插入且能被夺取形成活性金属中性的不稳定配体；和
(b)一种助催化剂化合物，包含：
(i)包含氟芳基配体取代的仲胺或膦的阳离子，其中所述芳基部分是苯基、取代的苯基、联苯基、取代的联苯基、三联苯基和取代的三联苯基之一；和
(ii)包含第13族元素的阴离子，其中所述阴离子是基本上非配位的。
17.权利要求16的催化剂组合物，其中所述助催化剂化合物由下式表示：
[R’iArF-ER2-H]+[(M’)Q1Q2…Qn]-，其中
(a)ArF为氟芳基；
(b)E为氮或磷；
(c)每个R独立地为C1-C20烃基或烃基甲硅烷基，或者两个R可连成未取代或取代的C2-C20脂环基；
(d)R’为C1-C20烃基或卤代烃基；
(e)i为0、1或2；
(f)M’为至少一种第13族元素；
(g)n为至少1；和
(h)Q与M相连，使[(M’)Q1Q2…Qn]-是基本上非配位的。
18.权利要求17的组合物，其中每个Q配体包含至少一个氟代芳基或至少一个取代的芳基，其中所述取代基包括氟代烃基。
19.权利要求18的催化剂组合物，其中每个Q配体在稠环或侧环体系中包含5至20个碳原子。
20.权利要求18的催化剂组合物，其中每个Q配体都是全氟代的。
21.权利要求17或18的催化剂组合物，其中R’iArF-ER2为选自N-五氟苯基吡咯烷、N-对九氟联苯基吡咯烷、N-十三氟三联苯基吡咯烷、N-五氟苯基吡咯、N-对九氟联苯基吡咯、N-十三氟三联苯基吡咯、N-五氟苯基哌啶、N-对九氟联苯基哌啶、N-十三氟三联苯基哌啶、N-五氟苯基二氢吲哚、N-对九氟联苯基二氢吲哚、N-十三氟三联苯基二氢吲哚、N-五氟苯基吲哚、N-对九氟联苯基吲哚、N-十三氟三联苯基吲哚、N-五氟苯基氮杂环丁烷、N-对九氟联苯基氮杂环丁烷、N-十三氟三联苯基氮杂环丁烷、N-五氟苯基氮丙啶、N-对九氟联苯基氮丙啶、和N-十三氟三联苯基氮丙啶。
22.权利要求16-20之任一的催化剂组合物，其中所述催化剂化合物是能活化成阳离子用于烯烃聚合的第3-11族化合物。
23.权利要求21的催化剂组合物，其中所述催化剂化合物是能活化成阳离子用于烯烃聚合的第3-11族化合物。
24.权利要求22的催化剂组合物，其中所述催化剂化合物是下式的第3-6族金属茂：
LALBLC iMDE，其中
(a)LA与M相连，为取代或未取代的环戊二烯基或杂环戊二烯基配体；
(b)LB与M相连，为取代或未取代的环戊二烯基或杂环戊二烯基或为杂原子配体；
其中LA和LB任选地通过含第14族元素的连接基连在一起；
(c)LC i为可选的与M相连的中性不氧化配体(i等于0至3)；
(d)M为第3-6族金属；
(e)D和E为与M相连的不稳定配体，可选地彼此相连、与LA或LB相连，
其中D或E可被所述助催化剂配合物从M中以单阴离子形式夺取，单体或可聚合大分子单体可插入M-D或M-E中用于聚合。
25.权利要求24的催化剂组合物，其中M为钛，LB为与M相连的杂原子。
26.权利要求24的催化剂组合物，其中M为锆或铪，LB为与M相连的取代或未取代的环戊二烯基或杂环戊二烯基配体。
27.一种用于烯烃聚合的催化剂体系，包括：
(a)有至少一个稳定配体和一个适用于烯烃插入的不稳定配体的有机金属催化剂阳离子，其中所述催化剂阳离子对于烯烃聚合是活性的；
(b)中性的氟芳基配体取代的仲胺或膦；和
(c)基本上非配位的第13族阴离子。
28.权利要求27的催化剂，有权利要求16-20之任一所述特征。
29.由一或多种单体制备聚烯烃的方法，包括使所述单体在聚合条件下与烯烃聚合催化剂混合，所述烯烃聚合催化剂是以下物质的反应产物：
(a)有至少一个稳定配体和至少一个适用于烯烃插入且可被夺取留下阳离子金属中心的不稳定配体的有机金属催化剂化合物；和
(b)基于第13族元素的助催化剂配合物，包含
(i)有质子化的氟芳基配体取代的仲胺或膦的阳离子和
(ii)基本上非配位的阴离子。
30.权利要求29的方法，其中Q包括氟代芳基或有氟代烃基取代基的芳基。
31.权利要求29或30的方法，其中所述催化剂化合物是能活化成阳离子用于烯烃聚合的第3-11族化合物。
32.权利要求29或30的方法，其中所述烯烃聚合条件包括在大于或等于30℃至小于或等于300℃的温度和大于或等于0至小于或等于2000巴的压力下进行的溶液、超临界压力、本体、淤浆或气相法。
33.权利要求32的方法，其中所述方法是本体、淤浆或气相法，所述活化的催化剂化合物负载或固定在粒状载体之上。
34.有氟芳基配体取代的仲胺或膦用于制备包含基本上非配位的阴离子的基于第13族元素的助催化剂配合物的用途。
35.一种前体用于制备聚烯烃的用途，其中所述前体包括基于第13族元素的助催化剂配合物，包含有氟芳基配体取代的仲胺或膦的阳离子和基本上非配位的阴离子。
36.一种前体用于制备烯烃聚合催化剂的用途，其中所述前体包括基于第13族元素的助催化剂配合物，包含有氟芳基配体取代的仲胺或膦的阳离子和基本上非配位的阴离子。
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| US60/169,876 | 1999-12-09 | ||
| US60/169,768 | 1999-12-09 |
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| BR (1) | BR0016270A (zh) |
| CA (1) | CA2391855A1 (zh) |
| DE (1) | DE60023945T2 (zh) |
| ES (1) | ES2249320T3 (zh) |
| MX (1) | MXPA02005642A (zh) |
| WO (1) | WO2001042249A1 (zh) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0021301D0 (en) | 2000-08-30 | 2000-10-18 | Borealis Tech Oy | Supported catalyst |
| WO2003000740A2 (en) * | 2001-06-20 | 2003-01-03 | Exxonmobil Chemical Patents Inc. | Polyolefins made by catalyst comprising a noncoordinating anion and articles comprising them |
| US7872086B2 (en) | 2008-01-17 | 2011-01-18 | Tonen Chemical Corporation | Polymeric material and its manufacture and use |
| TW200936619A (en) | 2007-11-15 | 2009-09-01 | Univation Tech Llc | Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom |
| US9234093B2 (en) | 2008-03-31 | 2016-01-12 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates |
| CN103951769A (zh) | 2008-08-01 | 2014-07-30 | 埃克森美孚化学专利公司 | 催化剂体系和用于烯烃聚合的方法 |
| US8580902B2 (en) * | 2008-08-01 | 2013-11-12 | Exxonmobil Chemical Patents Inc. | Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom |
| US7799879B2 (en) | 2008-08-01 | 2010-09-21 | Exxonmobil Chemical Patents Inc. | Catalyst system and process for olefin polymerization |
| WO2013070601A2 (en) | 2011-11-08 | 2013-05-16 | Univation Technologies, Llc | Methods of preparing a catalyst system |
| CN112703210B (zh) | 2018-07-23 | 2022-10-28 | 埃克森美孚化学专利公司 | 制备双峰橡胶、热塑性硫化橡胶和由其制成的制品 |
| WO2020235868A1 (ko) * | 2019-05-17 | 2020-11-26 | 주식회사 엘지화학 | 무수 탄화수소 용매를 이용한 조촉매 화합물의 제조방법 |
| CN115916892A (zh) | 2020-07-02 | 2023-04-04 | 国际人造丝公司 | 含有茂金属多峰共聚物橡胶的热塑性硫化橡胶组合物及其制造方法 |
| KR20230057430A (ko) | 2020-08-28 | 2023-04-28 | 에이지씨 가부시키가이샤 | 함불소 알킬 암모늄 보레이트 화합물 및 그 제조 방법 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5198401A (en) * | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
| JPH04366109A (ja) * | 1991-06-12 | 1992-12-18 | Idemitsu Kosan Co Ltd | スチレン系重合体の製造方法及びその触媒 |
| JPH07509752A (ja) * | 1992-08-05 | 1995-10-26 | エクソン・ケミカル・パテンツ・インク | オレフィン重合用の担持されたイオン遷移金属触媒 |
| DE69322225T2 (de) * | 1992-09-22 | 1999-05-12 | Idemitsu Kosan Co | Polymerisationskatalysatore und Verfahren zur Herstellung von Polymeren |
| US5885924A (en) * | 1995-06-07 | 1999-03-23 | W. R. Grace & Co.-Conn. | Halogenated supports and supported activators |
| RU2178422C2 (ru) * | 1996-03-27 | 2002-01-20 | Дзе Дау Кемикал Компани | Активатор катализаторов полимеризации олефинов, каталитическая система и способ полимеризации |
| EP0914353B1 (en) * | 1996-07-23 | 2002-09-04 | The Dow Chemical Company | Olefin polymerization catalyst composition comprising group 13 compound |
| JPH11316434A (ja) * | 1998-05-01 | 1999-11-16 | Konica Corp | ハロゲン化銀カラー写真感光材料の画像形成方法及び画像情報記録方法 |
-
2000
- 2000-12-11 BR BR0016270-1A patent/BR0016270A/pt not_active IP Right Cessation
- 2000-12-11 CN CN00817575A patent/CN1413217A/zh active Pending
- 2000-12-11 AT AT00986321T patent/ATE309252T1/de not_active IP Right Cessation
- 2000-12-11 WO PCT/US2000/033590 patent/WO2001042249A1/en active IP Right Grant
- 2000-12-11 EP EP05020099A patent/EP1661900A1/en not_active Withdrawn
- 2000-12-11 EP EP00986321A patent/EP1252166B1/en not_active Expired - Lifetime
- 2000-12-11 CA CA002391855A patent/CA2391855A1/en not_active Abandoned
- 2000-12-11 DE DE60023945T patent/DE60023945T2/de not_active Expired - Lifetime
- 2000-12-11 MX MXPA02005642A patent/MXPA02005642A/es not_active Application Discontinuation
- 2000-12-11 JP JP2001543547A patent/JP2004500359A/ja not_active Withdrawn
- 2000-12-11 KR KR1020027007308A patent/KR20020060989A/ko not_active Application Discontinuation
- 2000-12-11 ES ES00986321T patent/ES2249320T3/es not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE60023945D1 (de) | 2005-12-15 |
| ES2249320T3 (es) | 2006-04-01 |
| KR20020060989A (ko) | 2002-07-19 |
| MXPA02005642A (es) | 2002-09-02 |
| EP1661900A1 (en) | 2006-05-31 |
| DE60023945T2 (de) | 2006-07-27 |
| EP1252166A1 (en) | 2002-10-30 |
| ATE309252T1 (de) | 2005-11-15 |
| EP1252166B1 (en) | 2005-11-09 |
| JP2004500359A (ja) | 2004-01-08 |
| CA2391855A1 (en) | 2001-06-14 |
| WO2001042249A1 (en) | 2001-06-14 |
| BR0016270A (pt) | 2002-08-13 |
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