KR20000068055A - 올레핀 중합용 성분 및 촉매 - Google Patents
올레핀 중합용 성분 및 촉매 Download PDFInfo
- Publication number
- KR20000068055A KR20000068055A KR1019997000951A KR19997000951A KR20000068055A KR 20000068055 A KR20000068055 A KR 20000068055A KR 1019997000951 A KR1019997000951 A KR 1019997000951A KR 19997000951 A KR19997000951 A KR 19997000951A KR 20000068055 A KR20000068055 A KR 20000068055A
- Authority
- KR
- South Korea
- Prior art keywords
- catalyst component
- solid catalyst
- group
- cycloalkyl
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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- 239000003054 catalyst Substances 0.000 title claims abstract description 41
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 33
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 21
- 239000011949 solid catalyst Substances 0.000 claims abstract description 43
- 150000001875 compounds Chemical class 0.000 claims abstract description 40
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 34
- 125000000753 cycloalkyl group Chemical group 0.000 claims abstract description 28
- 125000003710 aryl alkyl group Chemical group 0.000 claims abstract description 25
- 125000002877 alkyl aryl group Chemical group 0.000 claims abstract description 16
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 16
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 16
- 239000001257 hydrogen Substances 0.000 claims abstract description 15
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 13
- 125000003118 aryl group Chemical group 0.000 claims abstract description 12
- 150000003609 titanium compounds Chemical class 0.000 claims abstract description 12
- 150000002148 esters Chemical class 0.000 claims abstract description 11
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 10
- 150000004820 halides Chemical class 0.000 claims abstract description 8
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 8
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 6
- 125000005119 alkyl cycloalkyl group Chemical group 0.000 claims abstract description 5
- -1 hydrocarbyl radical Chemical group 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 23
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 20
- 239000011777 magnesium Substances 0.000 claims description 12
- UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 claims description 8
- 229910052749 magnesium Inorganic materials 0.000 claims description 7
- 150000003377 silicon compounds Chemical class 0.000 claims description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 5
- 238000004438 BET method Methods 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 125000005234 alkyl aluminium group Chemical group 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 claims description 3
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims description 2
- 150000005840 aryl radicals Chemical class 0.000 claims description 2
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 claims description 2
- AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 claims description 2
- NETBVGNWMHLXRP-UHFFFAOYSA-N tert-butyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C(C)(C)C NETBVGNWMHLXRP-UHFFFAOYSA-N 0.000 claims description 2
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 claims description 2
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 claims description 2
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 claims description 2
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 claims description 2
- JAYPHJBLPAEMEX-UHFFFAOYSA-N trimethoxy(2-methylpentan-2-yl)silane Chemical compound CCCC(C)(C)[Si](OC)(OC)OC JAYPHJBLPAEMEX-UHFFFAOYSA-N 0.000 claims description 2
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims 1
- UABFFWVEXACZGD-UHFFFAOYSA-N trimethyl(pentoxy)silane Chemical compound CCCCCO[Si](C)(C)C UABFFWVEXACZGD-UHFFFAOYSA-N 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract description 16
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract description 16
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract description 14
- 229920000642 polymer Polymers 0.000 abstract description 10
- 239000008096 xylene Substances 0.000 abstract description 6
- 239000010936 titanium Substances 0.000 description 16
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 13
- 238000011282 treatment Methods 0.000 description 13
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 11
- OFOBLEOULBTSOW-UHFFFAOYSA-L Malonate Chemical compound [O-]C(=O)CC([O-])=O OFOBLEOULBTSOW-UHFFFAOYSA-L 0.000 description 10
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- BYQFBFWERHXONI-UHFFFAOYSA-N diethyl 2-propan-2-ylpropanedioate Chemical compound CCOC(=O)C(C(C)C)C(=O)OCC BYQFBFWERHXONI-UHFFFAOYSA-N 0.000 description 8
- 238000003756 stirring Methods 0.000 description 7
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 6
- 150000002690 malonic acid derivatives Chemical class 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 235000011147 magnesium chloride Nutrition 0.000 description 5
- DQEUFPARIOFOAI-UHFFFAOYSA-N 2-propan-2-ylpropanedioic acid Chemical compound CC(C)C(C(O)=O)C(O)=O DQEUFPARIOFOAI-UHFFFAOYSA-N 0.000 description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 229940078552 o-xylene Drugs 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000006228 supernatant Substances 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZGQKHXRAUPQSFM-UHFFFAOYSA-N bis(2-methylpropyl) 2-propan-2-ylpropanedioate Chemical compound CC(C)COC(=O)C(C(C)C)C(=O)OCC(C)C ZGQKHXRAUPQSFM-UHFFFAOYSA-N 0.000 description 3
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 3
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 2
- LTMRRSWNXVJMBA-UHFFFAOYSA-L 2,2-diethylpropanedioate Chemical compound CCC(CC)(C([O-])=O)C([O-])=O LTMRRSWNXVJMBA-UHFFFAOYSA-L 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 238000012662 bulk polymerization Methods 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- NFKGQHYUYGYHIS-UHFFFAOYSA-N dibutyl propanedioate Chemical compound CCCCOC(=O)CC(=O)OCCCC NFKGQHYUYGYHIS-UHFFFAOYSA-N 0.000 description 2
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 2
- RPNFNBGRHCUORR-UHFFFAOYSA-N diethyl 2-butylpropanedioate Chemical compound CCCCC(C(=O)OCC)C(=O)OCC RPNFNBGRHCUORR-UHFFFAOYSA-N 0.000 description 2
- FGYDHYCFHBSNPE-UHFFFAOYSA-N diethyl phenylmalonate Chemical compound CCOC(=O)C(C(=O)OCC)C1=CC=CC=C1 FGYDHYCFHBSNPE-UHFFFAOYSA-N 0.000 description 2
- 150000008282 halocarbons Chemical class 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 150000002391 heterocyclic compounds Chemical class 0.000 description 2
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 2
- 229920001580 isotactic polymer Polymers 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 239000012265 solid product Substances 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 238000005809 transesterification reaction Methods 0.000 description 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- LXZMZHYNXRYMSW-UHFFFAOYSA-N 2-(2,2-dimethylpentan-3-yloxycarbonyl)-3-methylbutanoic acid Chemical compound CCC(C(C)(C)C)OC(=O)C(C(C)C)C(O)=O LXZMZHYNXRYMSW-UHFFFAOYSA-N 0.000 description 1
- FXAAWWANRRQCIG-UHFFFAOYSA-N 3-methyl-2-(2-methylpentan-3-yloxycarbonyl)butanoic acid Chemical compound CCC(C(C)C)OC(=O)C(C(C)C)C(O)=O FXAAWWANRRQCIG-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- IYXGSMUGOJNHAZ-UHFFFAOYSA-N Ethyl malonate Chemical class CCOC(=O)CC(=O)OCC IYXGSMUGOJNHAZ-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 238000002083 X-ray spectrum Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- MEWFSXFFGFDHGV-UHFFFAOYSA-N cyclohexyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C1CCCCC1 MEWFSXFFGFDHGV-UHFFFAOYSA-N 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- FEMLCMXTVPLEDA-UHFFFAOYSA-N dibutyl 2-propan-2-ylpropanedioate Chemical compound CCCCOC(=O)C(C(C)C)C(=O)OCCCC FEMLCMXTVPLEDA-UHFFFAOYSA-N 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- NIXFNZVGGMZGPZ-UHFFFAOYSA-N diethyl 2,2-bis(2-methylpropyl)propanedioate Chemical compound CCOC(=O)C(CC(C)C)(CC(C)C)C(=O)OCC NIXFNZVGGMZGPZ-UHFFFAOYSA-N 0.000 description 1
- WHKKUUPZLWUOIW-UHFFFAOYSA-N diethyl 2,2-dibutylpropanedioate Chemical compound CCCCC(CCCC)(C(=O)OCC)C(=O)OCC WHKKUUPZLWUOIW-UHFFFAOYSA-N 0.000 description 1
- ZKBBUZRGPULIRN-UHFFFAOYSA-N diethyl 2,2-diethylpropanedioate Chemical compound CCOC(=O)C(CC)(CC)C(=O)OCC ZKBBUZRGPULIRN-UHFFFAOYSA-N 0.000 description 1
- UPQZOUHVTJNGFK-UHFFFAOYSA-N diethyl 2-methylpropanedioate Chemical compound CCOC(=O)C(C)C(=O)OCC UPQZOUHVTJNGFK-UHFFFAOYSA-N 0.000 description 1
- GDWAYKGILJJNBB-UHFFFAOYSA-N diethyl 2-prop-2-enylpropanedioate Chemical compound CCOC(=O)C(CC=C)C(=O)OCC GDWAYKGILJJNBB-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 230000002140 halogenating effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- YTAURYICCYOTOZ-UHFFFAOYSA-L magnesium;3-methoxyphenolate Chemical compound [Mg+2].COC1=CC=CC([O-])=C1.COC1=CC=CC([O-])=C1 YTAURYICCYOTOZ-UHFFFAOYSA-L 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 150000003961 organosilicon compounds Chemical class 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 238000012721 stereospecific polymerization Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- HXLWJGIPGJFBEZ-UHFFFAOYSA-N tert-butyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C(C)(C)C HXLWJGIPGJFBEZ-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI97A001350 | 1997-06-09 | ||
| IT97MI001350A IT1292109B1 (it) | 1997-06-09 | 1997-06-09 | Componenti e catalizzatori per la polimerizzazione di olefine |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20000068055A true KR20000068055A (ko) | 2000-11-25 |
Family
ID=11377321
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019997000951A Withdrawn KR20000068055A (ko) | 1997-06-09 | 1998-06-02 | 올레핀 중합용 성분 및 촉매 |
Country Status (15)
Families Citing this family (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1160625A (ja) | 1997-08-22 | 1999-03-02 | Idemitsu Petrochem Co Ltd | オレフィン重合用固体触媒成分、オレフィン重合用触 媒及びオレフィン重合体の製造方法 |
| EP1396503A4 (en) * | 2001-04-23 | 2007-03-14 | Idemitsu Kosan Co | SOLID CATALYST COMPONENT FOR POLYMERIZATION OF OLEFIN |
| US20050187359A1 (en) * | 2002-05-10 | 2005-08-25 | Idemitsu Kosan Co., Ltd | Solid catalyst component for olefin polymerization, catalyst for olefin polymerization and method for producing olefin polymer |
| US6790804B2 (en) * | 2002-06-27 | 2004-09-14 | Fina Technology, Inc. | Magnesium-diketonate complex derived polyolefin catalysts, method of making same, method of polymerizing with same |
| EP1586589A4 (en) * | 2003-01-22 | 2008-02-06 | Idemitsu Kosan Co | OLEFIN POLYMERIZATION CATALYSTS AND METHODS FOR PRODUCING OLEFIN POLYMER |
| CN100338018C (zh) | 2004-10-29 | 2007-09-19 | 中国石油化工股份有限公司 | 一种环戊酯类化合物及其合成方法和应用 |
| JP5340916B2 (ja) * | 2007-03-30 | 2013-11-13 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分、重合用触媒およびこれを用いたオレフィン類重合体の製造方法 |
| CN101735346B (zh) * | 2008-11-07 | 2012-05-30 | 中国石油天然气股份有限公司 | 一种丙烯均聚和共聚的催化剂及其制备方法和应用 |
| EP2730590B1 (en) | 2011-07-06 | 2018-04-04 | Toho Titanium CO., LTD. | Solid catalyst component for olefin polymerization, catalyst for olefin polymerization, and method for producing olefin polymer |
| EP2679609A1 (en) | 2012-06-28 | 2014-01-01 | Lummus Novolen Technology Gmbh | Sterically demanding dialkoxydialkylsilanes as external donors for ziegler catalysts for the polymerization of propylene |
| TWI639626B (zh) * | 2013-09-30 | 2018-11-01 | 中國石油化工科技開發有限公司 | Catalyst composition for olefin polymerization and application thereof |
| US9593184B2 (en) | 2014-10-28 | 2017-03-14 | Formosa Plastics Corporation, Usa | Oxalic acid diamides as modifiers for polyolefin catalysts |
| CN104402776B (zh) * | 2014-12-05 | 2017-06-13 | 中国石油天然气股份有限公司 | 一种二元醇磺酸酯化合物及其制备方法与应用 |
| CN106608940B (zh) * | 2015-10-27 | 2019-06-28 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分的制备方法 |
| CN106608939B (zh) * | 2015-10-27 | 2019-08-20 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分的制备方法 |
| US9777084B2 (en) | 2016-02-19 | 2017-10-03 | Formosa Plastics Corporation, Usa | Catalyst system for olefin polymerization and method for producing olefin polymer |
| FI3517555T3 (fi) | 2016-09-23 | 2024-12-30 | China Petroleum & Chem Corp | Katalyyttikomponentti käytettäväksi olefiinipolymeroinnissa, katalyytti ja niiden käyttöjä |
| FI3517553T3 (fi) | 2016-09-23 | 2024-02-02 | China Petroleum & Chem Corp | Katalyyttikomponentti käytettäväksi olefiinin polymeroinnissa, katalyytti, ja niiden käyttö |
| US9815920B1 (en) | 2016-10-14 | 2017-11-14 | Formosa Plastics Corporation, Usa | Olefin polymerization catalyst components and process for the production of olefin polymers therewith |
| US10822438B2 (en) | 2017-05-09 | 2020-11-03 | Formosa Plastics Corporation | Catalyst system for enhanced stereo-specificity of olefin polymerization and method for producing olefin polymer |
| US10124324B1 (en) | 2017-05-09 | 2018-11-13 | Formosa Plastics Corporation, Usa | Olefin polymerization catalyst components and process for the production of olefin polymers therewith |
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| PL4297972T3 (pl) | 2021-02-26 | 2025-04-07 | Basell Polyolefine Gmbh | Platforma drukarska do wytwarzania przyrostowego metodą wytłaczania |
| KR20240017933A (ko) | 2021-06-10 | 2024-02-08 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 폴리프로필렌 조성물 및 이로부터 제조되는 광원 피복재 |
| CN117460777B (zh) | 2021-06-16 | 2024-08-16 | 巴塞尔聚烯烃意大利有限公司 | 填充聚烯烃组合物 |
| US20240309189A1 (en) | 2021-07-12 | 2024-09-19 | Basell Poliolefine Italia S.R.L. | Filled polyolefin composition |
| EP4422867A1 (en) | 2021-10-28 | 2024-09-04 | Basell Polyolefine GmbH | Reinforced polypropylene composition |
| EP4453088A1 (en) | 2021-12-23 | 2024-10-30 | Basell Poliolefine Italia S.r.l. | Soft polyolefin composition |
| EP4519349A1 (en) | 2022-05-06 | 2025-03-12 | Basell Poliolefine Italia S.r.l. | Plastic material and shaped article obtained therefrom |
| KR20230160977A (ko) | 2022-05-17 | 2023-11-27 | 에이치앤오바이오시스(주) | 항암 치료에 사용되는 5종 이상의 생약 추출물 |
| WO2023247227A1 (en) | 2022-06-20 | 2023-12-28 | Basell Poliolefine Italia S.R.L. | Multilayer film |
| JP2025521958A (ja) | 2022-08-03 | 2025-07-10 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | ヒートシールフィルム用ポリプロピレン組成物 |
| KR20250129692A (ko) | 2022-12-19 | 2025-08-29 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 착색 열가소성 조성물 |
| US20250066513A1 (en) | 2023-08-23 | 2025-02-27 | Formosa Plastics Corporation, U.S.A. | Catalyst System For Enhanced Stereo-Specificity Of Olefin Polymerization |
| US20250066514A1 (en) | 2023-08-24 | 2025-02-27 | Formosa Plastics Corporation, U.S.A. | Catalysts component and process for the production of polypropylene having high melt flow rate with high isotacticity |
| US20250115686A1 (en) | 2023-10-09 | 2025-04-10 | Formosa Plastics Corporation, U.S.A. | Olefin polymerization catalyst components containing silane and process for the production of polypropylene having high isotacticity at high melt flow rate |
| WO2025168499A1 (en) | 2024-02-07 | 2025-08-14 | Basell Poliolefine Italia S.R.L. | Translucent polypropylene-based material for additive manufacturing |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL162661B (nl) | 1968-11-21 | 1980-01-15 | Montedison Spa | Werkwijze om een katalysator te bereiden voor de poly- merisatie van alkenen-1. |
| YU35844B (en) | 1968-11-25 | 1981-08-31 | Montedison Spa | Process for obtaining catalysts for the polymerization of olefines |
| GB1603724A (en) | 1977-05-25 | 1981-11-25 | Montedison Spa | Components and catalysts for the polymerisation of alpha-olefins |
| IT1098272B (it) | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
| IT1209255B (it) | 1980-08-13 | 1989-07-16 | Montedison Spa | Catalizzatori per la polimerizzazione di olefine. |
| JPS58138706A (ja) | 1982-02-12 | 1983-08-17 | Mitsui Petrochem Ind Ltd | オレフイン系重合体の製造方法 |
| IT1190683B (it) * | 1982-02-12 | 1988-02-24 | Montedison Spa | Componenti e catalizzatori per la polimerizzazione di olefine |
| JPS59207904A (ja) * | 1983-05-11 | 1984-11-26 | Mitsui Petrochem Ind Ltd | オレフイン重合体の製造方法 |
| JPS59215301A (ja) * | 1983-05-24 | 1984-12-05 | Mitsui Petrochem Ind Ltd | エチレンの重合もしくは共重合方法 |
| DD226876A1 (de) * | 1984-09-05 | 1985-09-04 | Dresden Arzneimittel | Verfahren zur herstellung von disubstituierten malonsaeureestern |
| JPH0717704B2 (ja) * | 1985-07-09 | 1995-03-01 | 三菱油化株式会社 | オレフイン重合体の製造法 |
| KR930001064B1 (ko) * | 1988-09-13 | 1993-02-15 | 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 | 올레핀중합용 촉매성분 및 그 제조방법, 올레핀중합용 촉매 및 올레핀의 중합방법 |
| IT1230134B (it) | 1989-04-28 | 1991-10-14 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine. |
| GB8925945D0 (en) | 1989-11-16 | 1990-01-04 | Shell Int Research | Olefin polymerization catalysts |
| IT1262934B (it) | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1262935B (it) | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| EP0598609B1 (en) * | 1992-11-18 | 1997-04-23 | Mitsui Petrochemical Industries, Ltd. | Catalyst for olefin polymerization and process for olefin polymerization using the same |
| CA2172635A1 (en) * | 1993-09-30 | 1995-04-06 | Noriyuki Tani | Transition metal compound, olefin polymerization catalyst, and process for producing olefin polymer by using said catalyst |
| JP3472935B2 (ja) * | 1994-02-18 | 2003-12-02 | 三井化学株式会社 | エチレン系重合体およびその製造方法、エチレン重合用固体状チタン触媒成分ならびにエチレン重合用触媒 |
| JP3489889B2 (ja) * | 1994-12-01 | 2004-01-26 | 昭和電工株式会社 | オレフィン重合用固体触媒成分の製造方法、オレフィン重合用触媒及びオレフィン重合体の製造方法 |
-
1997
- 1997-06-09 IT IT97MI001350A patent/IT1292109B1/it active IP Right Grant
-
1998
- 1998-06-02 EP EP98934907A patent/EP0918802B2/en not_active Expired - Lifetime
- 1998-06-02 DE DE69802491T patent/DE69802491T3/de not_active Expired - Lifetime
- 1998-06-02 JP JP50148799A patent/JP4306807B2/ja not_active Expired - Fee Related
- 1998-06-02 ES ES98934907T patent/ES2167091T5/es not_active Expired - Lifetime
- 1998-06-02 CN CN98801092A patent/CN1236372A/zh active Pending
- 1998-06-02 TR TR1999/00266T patent/TR199900266T1/xx unknown
- 1998-06-02 KR KR1019997000951A patent/KR20000068055A/ko not_active Withdrawn
- 1998-06-02 AU AU84354/98A patent/AU8435498A/en not_active Abandoned
- 1998-06-02 WO PCT/EP1998/003287 patent/WO1998056830A2/en not_active Application Discontinuation
- 1998-06-02 BR BR9804959A patent/BR9804959A/pt not_active Application Discontinuation
- 1998-06-02 CA CA002262605A patent/CA2262605A1/en not_active Abandoned
- 1998-06-08 MY MYPI98002545A patent/MY133464A/en unknown
- 1998-06-09 US US09/094,049 patent/US6294497B1/en not_active Expired - Lifetime
-
1999
- 1999-02-08 NO NO990573A patent/NO990573L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| CA2262605A1 (en) | 1998-12-17 |
| US6294497B1 (en) | 2001-09-25 |
| ITMI971350A0 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1997-06-09 |
| MY133464A (en) | 2007-11-30 |
| WO1998056830A2 (en) | 1998-12-17 |
| IT1292109B1 (it) | 1999-01-25 |
| DE69802491T3 (de) | 2005-04-14 |
| ES2167091T3 (es) | 2002-05-01 |
| EP0918802B1 (en) | 2001-11-14 |
| BR9804959A (pt) | 1999-08-24 |
| DE69802491D1 (de) | 2001-12-20 |
| EP0918802A2 (en) | 1999-06-02 |
| WO1998056830A3 (en) | 1999-03-11 |
| JP2000516987A (ja) | 2000-12-19 |
| EP0918802B2 (en) | 2004-10-06 |
| JP4306807B2 (ja) | 2009-08-05 |
| AU8435498A (en) | 1998-12-30 |
| CN1236372A (zh) | 1999-11-24 |
| ES2167091T5 (es) | 2005-04-16 |
| ITMI971350A1 (it) | 1998-12-09 |
| TR199900266T1 (xx) | 1999-09-21 |
| NO990573L (no) | 1999-03-16 |
| DE69802491T2 (de) | 2002-06-27 |
| NO990573D0 (no) | 1999-02-08 |
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